28861 results about "Ceramic materials" patented technology

The invention relates to a zirconia-based all-ceramic false tooth and a preparation method thereof. A core layer of the zirconia-based all-ceramic false tooth is prepared from the following components in parts by mass: 90 to 94 parts of ZrO2, 5 to 9 parts of Y2O3, 0.1 to 0.5 part of Al2O3, 0.01 to 0.5 part of Fe2O3, 0.01 to 0.5 part of Er2O3 and 0 to 0.2 part of MnO2, and a shell layer of the zirconia-based all-ceramic false tooth is prepared from the following components in parts by mass: 24.5 to 49.5 parts of CaCO3, 45 to 50 parts of SiO2, 0 to 25 parts of MgO, 0.01 to 0.5 part of Fe2O3, 0.01 to 0.5 part of Er2O3 and 0 to 0.2 part of MnO2. The preparation process comprises the following steps: performing dry pressing and isostatic pressing on raw materials of the core layer, presintering, and carving to obtain a zirconia-based false tooth biscuit; meanwhile, calcining raw materials of a shell layer, then adding deionized water, a dispersing agent and an adhesive, and carrying out ball milling and mixing to obtain calcium-magnesium-silicon-based ceramic slurry; and coating the calcium-magnesium-silicon-based ceramic slurry on the surface of the zirconium oxide-based false tooth biscuit, and sintering to obtain the zirconium oxide-based all-ceramic false tooth provided by the invention. The zirconia-based all-ceramic false tooth has good jade texture and is closer to the natural color of natural teeth.

The invention provides a pre-buried brazing flux aluminum alloy brazing filler metal plate blank and a preparation method thereof, a pre-buried brazing flux composite aluminum alloy brazing plate strip and a preparation process and application thereof. After the mixed powder of the aluminum-silicon alloy and the brazing flux is pressed into the cylinder, the cylinder is extruded into the aluminum alloy brazing filler metal plate blank with the pre-embedded brazing flux through the semi-continuous extruding machine, the production efficiency is high, the yield is high, and the prepared aluminum alloy brazing filler metal plate blank with the pre-embedded brazing flux is uniform in component and good in extensibility. The prepared pre-buried brazing flux aluminum alloy brazing filler metal plate blank and an aluminum alloy core material are easy to roll and compound, the obtained pre-buried brazing flux composite aluminum alloy brazing plate strip has a good compound interface, does not have obvious defects such as slag inclusion, bubbles, layering and peeling, has the mechanical property meeting the requirements, has excellent ductility and good brazing performance, and is suitable for large-scale production. And the brazing effect with other aluminum components is good, the surface of a workpiece is bright, and soldering flux traces are not left. The technology can greatly simplify the manufacturing process of the aluminum heat exchanger, and can be used for large-scale industrial production.

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The application provides a microcrystalline glass product, and components of the microcrystalline glass product are shown in percentage by weight, and the microcrystalline glass product contains SiO2: 40-55%; Al2O3: 15-30%; Li2O: 0.1-6%; ZnO: 9-20%; MgO: 0.1-6%; and TiO2: 0.5-7%. Through reasonable component design, the microcrystalline glass product obtained by the application has excellent mechanical properties and is suitable for display devices or electronic devices.

The invention discloses a high-strength and high-toughness aluminum nitride ceramic and a preparation method thereof, and relates to the technical field of ceramics, a sol-gel method is adopted to coat the surface of aluminum nitride with a stable shell layer to form a core-shell structure, meanwhile, the low lattice mismatch rate of a core-shell interface is utilized to reduce thermal resistance, and toughness and thermal conductivity are both considered; according to the external magnetic field tape casting method, the magnetic dipole moment orientation principle is utilized, an external magnetic field is applied in the tape casting stage, the in-plane mechanical property is improved, and the fracture toughness is improved through the magnetism of aluminum nitride whiskers; a reinforcement is introduced to improve the mechanical property and corrosion resistance of the aluminum nitride ceramic material, multi-granularity powder is compounded, large-particle aluminum nitride powder is used as a sintering and heat-conducting framework material, and high activity provided by submicron particles is utilized to promote sintering, so that the sintering temperature of aluminum nitride can be remarkably reduced, and the performance is greatly improved; and the aluminum nitride substrate expands more application fields on a future packaging circuit.

The application discloses a transparent strengthened glass ceramic with high stress depth, which contains spinel crystals and zirconia crystals in a crystal phase of the strengthened glass ceramic, and does not contain Li-containing crystals; the strengthened glass ceramic has a compressive stress region extending from a surface thereof to a compression depth, a compressive stress layer depth DOL_0 of the strengthened glass ceramic is greater than or equal to 14% of a thickness of the strengthened glass ceramic, and a tensile stress line density of the strengthened glass ceramic is greater than or equal to 25000 MPa / mm. By introducing more Li ions and Na ions into a spinel glass ceramic component, the prepared transparent spinel glass ceramic can be chemically strengthened, a transparent strengthened glass ceramic with high CS, DOL_0, CT_AV and CT_LD is obtained, and the strengthened glass ceramic exhibits excellent drop resistance.

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention relates to a high-strength stable solid waste-based composite cementing material and a preparation method and application thereof in the field of building materials. The high-strength stable solid waste-based composite cementing material is prepared from the following raw materials in parts by weight: 70-85 parts of composite solid waste micro powder; 10 to 20 parts of Portland cement clinker; 3-8 parts of a composite activator; 0.5 to 2 parts of a nano-scale function regulator; wherein the composite solid waste micro powder is prepared by mixing and grinding the following raw materials in parts by weight: 40-60 parts of blast furnace slag powder; 20 to 30 parts of fly ash; 10-20 parts of chemically modified electrolytic manganese residue powder; and 5-15 parts of steel slag powder. According to the preparation method, sodium metasilicate is adopted to assist medium-temperature calcination to chemically modify the electrolytic manganese residues, so that not only is the gelation activity of the electrolytic manganese residues effectively excited, but also free-state manganese, cadmium and other heavy metal ions in the electrolytic manganese residues are fixed in situ in newly formed zeolite-like silicate mineral lattices through thermochemical reconstruction; and a brand new technical path is opened up for safe and high-value utilization of the typical hazardous waste, namely the electrolytic manganese residues.

The invention relates to an additive manufacturing method and application of an aluminum-based silicon carbide composite material complex component, and the additive manufacturing method of the aluminum-based silicon carbide composite material complex component comprises the following steps: step 1, uniformly mixing silicon carbide powder and aluminum alloy powder, and drying; 2, establishing a structural model for the target part, and importing the structural model into selective laser melting forming equipment; thirdly, selective laser melting forming is conducted; fourthly, linear cutting and surface treatment are conducted; and fifthly, hot isostatic pressing treatment is conducted. The invention further provides application of the aluminum-based silicon carbide composite material complex component to precise structural components such as aviation structural components, guided missile and satellite components and optical instruments. According to the method, the problem of subsequent large-allowance removal of the aluminum-based silicon carbide composite material component is solved, the wettability between the aluminum alloy and the silicon carbide particles is improved, the mechanical property meets the application requirement, and the aluminum-based silicon carbide structural component with stable performance is obtained.

The invention relates to the technical field of composite material forming, and discloses a compression molding process optimization method of a carbon fiber reinforced composite material thin material. According to the method, multi-dimensional process parameters such as temperature gradient distribution data, pressure load change data and resin flow rate data in the compression molding process are collected in real time through a distributed sensing network; establishing a process state evaluation model to carry out initial defect feature recognition on the parameters, and generating an initial defect feature spectrum; performing defect mode matching on the initial defect characteristic spectrum based on the material characteristic database, and separating a main defect data stream from a secondary defect data stream; constructing a real-time compensation instruction set according to the main defect data flow, and synchronously driving a mold pressing equipment executing mechanism to carry out dynamic process parameter correction; the corrected secondary defect data flow is fed back to the material characteristic database to update the defect mode matching rule; and iteratively executing dynamic process parameter correction until a process convergence condition is met, and outputting a quality control report of the finally formed thin material.

The invention provides an early-strength rapid-repair grouting material and a preparation method thereof, and the early-strength rapid-repair grouting material is mainly prepared from the following raw materials: 50 to 150 parts of sulphoaluminate cement, 10 to 150 parts of aluminate cement, 200 to 350 parts of a regenerated gelling powder material, 1200 to 1400 parts of quartz sand, 50 to 100 parts of silica fume, 10 to 150 parts of mineral powder, 10 to 100 parts of fly ash, 15 to 50 parts of a composite retarder, 0.1 to 2 parts of a water reducing agent and 1 to 10 parts of an early strength agent. 0.01 to 1 part of a water-retaining agent and 200 to 300 parts of water. The early-strength quick-repair grouting material is characterized in that activated low-cementitious active mineral solid waste is adopted as a main cementitious material, and the product has excellent construction stability, low-carbon weather resistance, corrosion resistance, micro-expansion quick-hardening early strength and economical efficiency.

The invention discloses an integrated preparation method of a SiC-based composite material environment barrier coating in the technical field of aviation thermal structure materials, which comprises the following steps: cleaning a substrate, carrying out vacuum impregnation of phenolic resin and curing, coating Si slurry to form a bonding layer, coating rare earth silicate slurry to form a barrier layer, and drying to obtain the SiC-based composite material environment barrier coating. And finally carrying out high-temperature heat treatment in an inert atmosphere. According to the method, through an integrated slurry coating and gradient curing process, the performance of a base body is protected, and meanwhile efficient preparation of the coating is achieved; by adopting an integrated slurry coating and gradient curing technology and combining with an optimized medium-temperature sintering process, the matrix performance is effectively protected while the compactness of the coating is ensured, the bonding strength and interface stability of the coating are improved through the design of the phenolic resin transition layer and the silicon bonding layer in cooperation with the rare earth silicate barrier layer, and the bonding strength of the coating is improved. And the coating shows excellent protection performance in a high-temperature corrosion environment.

The invention discloses preheating-free welding maritime work steel with excellent low-temperature toughness and a preparation method of the preheating-free welding maritime work steel, and belongs to the field of steel and iron material preparation. The produced steel plate has good comprehensive mechanical properties through alloy component-secondary rolling-controlled cooling process coupling design, the problem that the strength, plasticity, low-temperature toughness and preheating-free post-welding performance of the steel plate are difficult to match and harmonize is solved, the steel plate has ultrahigh-strength plasticity, excellent low-temperature toughness and excellent Z-direction performance, and room-temperature preheating-free welding can be achieved.

The invention discloses a high-content steel slag-based functionalized nano-composite cementing material and a preparation method thereof, and belongs to the technical field of solid waste resource comprehensive utilization. The nano composite cementing material is prepared from the following raw materials in parts by mass: 50 to 65 parts of steel slag, 10 to 20 parts of fly ash, 10 to 25 parts of carbide slag, 8 to 15 parts of desulfurized gypsum, 0.3 to 1.0 part of nano silicon dioxide and 0.003 to 0.03 part of silane coupling agent. On the basis of a solid waste synergism theory and an internal alkali excitation effect, quaternary solid wastes such as steel slag and fly ash are optimized and compounded by adopting methods of mechanical-thermal activation, addition of modified nano silicon dioxide, synergistic gelling between solid wastes and the like; the paint is prepared through gradient grinding and a medium-temperature wet curing process. The preparation method is simple, high-temperature calcination is not needed, cement clinker and exogenous excitant do not need to be added, the obtained cementing material can replace part of cement to be applied to the fields of road bases, mine filling, low-carbon building material products and the like, resource utilization and high-value utilization of regional bulk industrial solid waste can be achieved, and carbon emission and production cost are effectively reduced.

The invention relates to the technical field of friction materials, and particularly discloses an electromagnetic brake friction material prepared from granules and a preparation process of the electromagnetic brake friction material in order to solve the problem that an existing electromagnetic brake friction plate is difficult to prepare or insufficient in performance. The reinforcing material comprises plasma modified aramid pulp, coupling modified composite mineral fibers, SiO2 coated tetrapod-like zinc oxide whiskers and carbon fiber-aluminum silicon whiskers; the filler comprises modified needle-like wollastonite and organic modified precipitated barium sulfate; the adhesive comprises boron-silicon synergistic modified phenolic resin and modified carboxy nitrile rubber. The raw materials are improved, and granules are prepared by adopting a mixing and crushing process, so that the content of an adhesive can be greatly reduced, meanwhile, the die filling efficiency can be improved, the die thickness and the high-temperature heat fading of the friction material can be reduced, a cold press molding process can be omitted, and the qualification rate of finished friction materials can be improved.

The invention discloses an anti-shrinkage light, soft and elastic sole foaming material and a preparation method thereof, and belongs to the technical field of footwear products. The light, soft and elastic sole foaming material is formed by chemically foaming an EVA (Ethylene Vinyl Acetate) composite raw material, the EVA composite raw material is prepared from 50 to 70 parts of EVA, 20 to 40 parts of olefin thermoplastic elastomer, 10 to 20 parts of styrene elastomer, 1.5 to 3 parts of maleic anhydride grafted ethylene-octylene copolymer compatilizer, 0.4 to 0.8 part of peroxide cross-linking agent, 3 to 4 parts of foaming agent, 1 to 1.5 parts of zinc oxide, 1 to 1.5 parts of polyethylene wax substance and 0.5 to 1.5 parts of poly (butylene succinate). 0.3 to 1 part of polyamide 12 microspheres and 2 to 3 parts of nano montmorillonite. The foaming material can resist shrinkage when being used as a shoe sole part, and has good rebound performance and the like, so that the high-quality requirement of sneakers, the mass production stability and the like are met.

The invention relates to the field of coatings, in particular to an industrial anticorrosive coating and a preparation method thereof. The coating comprises film-forming resin, a curing agent, a solvent and an anti-corrosion composite nanofiller. The anti-corrosion composite nanofiller has a three-layer structure, wherein an inner core is mesoporous silica loaded with an organic corrosion inhibitor; the middle shell layer is an amino-functionalized metal organic framework material grown in situ; and the outer layer is a low-surface-energy layer formed by modification of a hydrophobic modifier.

The invention discloses a light telegraph pole cement material and a preparation method thereof, and relates to the technical field of cement concrete. The method comprises the following steps: firstly, carrying out acid pickling, silane coupling agent grafting and nanoparticle vacuum impregnation treatment on shale ceramsite to obtain modified light ceramsite; the preparation method comprises the following steps: ultrasonically dispersing graphene oxide, compounding with Portland cement clinker and modified fly ash, and reacting with epoxy resin emulsion, a curing agent and a silane coupling agent to prepare organic-inorganic composite modified cement; the bamboo skeleton is subjected to silane coupling agent pretreatment to obtain a modified skeleton; then, mixing composite cement, an additive and water into slurry, adding the modified ceramsite and aggregate, and performing high-speed stirring and ultrasonic dispersion to form homogeneous concrete slurry; and finally, putting the modified bamboo skeleton into a mold, injecting the slurry, and performing centrifugal forming, steam curing and natural curing to obtain the cement material. The prepared lightweight telegraph pole cement material has excellent mechanical strength.

The invention provides a carbon ceramic resistor and a preparation method thereof, and relates to the technical field of special material production of power systems and electrical equipment. The preparation method comprises the steps that carbon-containing electric conductor raw materials are mixed to obtain a first mixed raw material, and the carbon-containing electric conductor raw materials comprise, by mass, 15 parts of gluconic acid, 10 parts of aluminum oxide and 55 parts of deionized water; performing hydrothermal reaction on the first mixed raw material to obtain a carbon-containing conductor precursor; the carbon-containing conductor precursor is carbonized in a protective atmosphere, a carbon-containing conductor of a core-shell structure is obtained, and the carbon-containing conductor takes aluminum oxide as an inner core and takes a conductive carbon material formed by gluconic acid as a conductive outer shell; mixing the carbon-containing electric conductor with the core-shell structure with a carbon ceramic matrix raw material to obtain a resistor blank; and sintering the resistor blank to obtain the carbon ceramic resistor. The uniformity, the stability and the reliability of the carbon ceramic resistor are improved, so that the carbon ceramic resistor can better meet the application requirements of ultrahigh-voltage and extra-high-voltage alternating-current power transmission systems.

The invention provides a low-carbon concrete coarse aggregate close packing combination grading formula and a determination method, and relates to the technical field of building materials, the formula comprises a coarse aggregate skeleton, a fine aggregate, a low-carbon cementing material, water and an admixture, the coarse aggregate skeleton is composed of four different size fractions, and the purpose is to achieve the closest packing to reduce the cement requirement and improve the cement quality. The low-carbon cementing material is composed of cement, a conventional low-carbon mineral admixture and a low-carbon composite mineral admixture, and the low-carbon composite mineral admixture comprises an active component A and a micro-filling component B. The determination method comprises the steps of system characterization and model establishment, slurry skeleton iterative collaborative optimization and formula determination. The porosity is reduced to the maximum extent by optimizing coarse aggregate grading, the cement consumption is greatly reduced, meanwhile, through the synergistic effect of the high-performance, high-proportion and low-carbon admixture, the working performance, physical and mechanical properties and durability of the concrete are ensured, carbon emission and material cost are remarkably reduced, industrial solid waste is effectively utilized, and the economic benefit is increased. And green low-carbon preparation of the concrete is realized.

The invention discloses an anti-aging flame-retardant polyvinyl chloride material and a preparation method thereof. The anti-aging flame-retardant polyvinyl chloride material comprises the following raw material components in parts by weight: 100 parts of PVC resin, 0.6-2.4 parts of a lubricant, 15-27 parts of a plasticizer and 14-25 parts of a composite flame-retardant anti-aging reinforcing filler, wherein the composite flame-retardant anti-aging reinforcing filler is obtained by sequentially carrying out antioxidant loading and polymer grafting modification on a compound of graphene oxide, basic magnesium sulfate whiskers and mesoporous alumina. The prepared polyvinyl chloride has excellent aging resistance, flame retardance and mechanical strength, is good in thermal stability and excellent in comprehensive performance, and has a wide market application prospect.

The invention provides a copper-steel composite heat pipe and a preparation method thereof, and relates to the technical field of heat pipes, the copper-steel composite heat pipe comprises a steel-copper composite pipe, and the steel-copper composite pipe is composed of a copper inner pipe and a steel outer pipe. An internal copper structure is arranged in the steel-copper composite pipe; the internal copper structure is copper powder or a copper wire mesh. The copper powder is unilateral copper powder or bilateral copper powder or ring copper powder; the copper wire mesh is a copper mesh, or a copper mesh and a copper wire capillary, or a copper wire capillary. The steel outer pipe is made of steel 316L, and the copper inner pipe is made of copper C1020. The copper-steel combined material is used, the cost is saved, and it is guaranteed that materials are saved in the whole heat dissipation field. The double-layer combination of the copper inner pipe (C1020, high heat conduction) and the steel outer pipe (316L, corrosion resistance and high strength) is adopted, the efficient heat conduction of copper is utilized, and the environment erosion resistance and mechanical impact resistance of steel are utilized, so that the heat pipe is adaptive to complex working conditions (such as industrial high-temperature, humid or corrosion risk scenes), and the service life of the heat pipe is prolonged.

The invention belongs to the technical field of radar stealth materials and high-temperature electromagnetic protection, and particularly relates to design and a preparation method of a high-temperature-resistant wave-absorbing material based on alumina fibers. According to the material, a high-temperature-resistant ceramic precursor serves as a base body, a reinforcing phase is formed by alternately stacking alumina fiber cloth and an alumina fiber web tire containing chopped silicon carbide fibers, and a three-dimensional reinforcing structure is formed through a needling technology; the chopped silicon carbide fibers are directionally distributed in the net tire in a non-uniform mode, an enhanced area array with the local geometric regular pattern is constructed, the size and the arrangement period change in a gradient mode in the thickness direction, a vertical dielectric gradient structure is formed in the material, and multi-path propagation, reflection and polarization loss of electromagnetic waves are improved; the surface of alumina fiber cloth is coated with a ceramic interface layer, so that the interface bonding strength and thermal stability are improved; the ceramic matrix is densified for multiple rounds, so that the structure is compact; the material has excellent electromagnetic absorption performance, heat resistance and mechanical strength, and is suitable for high-temperature electromagnetic environments such as aerospace, missile bay sections and the like.

The invention relates to the technical field of electric wires and cables, discloses a high-elasticity waterproof cable based on blending of water-blocking powder and an elastomer, and aims to solve the problems that in the prior art, during long-term dynamic service, interlayer separation is easily caused by interfacial stress superposition, so that elasticity attenuation and waterproof barrier damage are caused, and the service life is affected. According to the invention, the sodium polyacrylate water-blocking powder is subjected to composite modification and is blended with an elastomer matrix, modified nano silicon dioxide is matched for dispersion, an inner and outer layer gradient insulation structure is designed, and ultrasonic dispersion, nitrogen protection steam cross-linking and other processes are combined; the cable is sequentially provided with the conductor layer, the conductor shielding layer, the gradient insulation layer, the insulation shielding layer and the sheath layer from inside to outside, interface stress concentration is reduced, interlayer combination stability is enhanced, and the cable can still keep excellent elastic recovery capability and waterproof barrier integrity under high-frequency torsion and repeated dry-wet cycles.

The invention belongs to the field of materials, and particularly relates to a composite thermal interface material and a preparation method thereof. The preparation method comprises the following steps: plating non-reactive metal, non-reactive metal carbide or non-reactive ceramic on the surface of diamond micro powder, inducing lattice defects on the surface of a plating layer and alloying a local interface by combining a mechanical force field, and defoaming to obtain the composite thermal interface material. The composite thermal interface material has high thermal conductivity and long-term stability, and the contradiction between excessive alloying of a traditional reactive coating and high interface thermal resistance of a non-reactive coating is solved. The method is particularly suitable for the field of thermal management of high-end electronic devices such as 5G chips and power modules.

The invention provides a phenolic resin-based spherical silicon-carbon composite material as well as a preparation method and application thereof, and belongs to the technical field of lithium battery materials. The preparation method comprises the following steps: preparing spherical phenolic resin by adopting a suspension polymerization method, curing to obtain phenolic resin microspheres, preparing porous carbon spheres by taking the phenolic resin microspheres as a carbon precursor in a carbonization and alkali activation manner, carrying out CVD vapor deposition on nano silicon, and carrying out carbon coating to obtain the phenolic resin-based spherical silicon-carbon composite material. The phenolic resin is utilized to form a highly cross-linked network structure after curing, the carbon spheres obtained after carbonization have good mechanical strength and rigidity, the porous structure of the porous carbon spheres provides a volume change buffering structure for nano-silicon, the lithium ion path is shortened, the spherical structure is beneficial to uniform dispersion, nano-silicon particles are prevented from gathering, and the performance of the lithium ion battery is improved. And the porous carbon spheres with high specific surface area can also improve the interface reaction activity, so that the problems of high volume expansion, low conductivity and slow ion diffusivity of silicon are solved.

The invention relates to the technical field of conductive copper paste, in particular to conductive copper paste prepared by combining liquid nonferrous metal with graphene and a preparation method of the conductive copper paste. The preparation method comprises the following steps: weighing nano-copper coated graphene composite powder, a liquid nonferrous metal, a binder, trifluoropropyltrimethoxysilane, an auxiliary agent and copper powder, and then preparing trifluoropropyltrimethoxysilane into a dilute solution; copper powder and the nano-copper coated graphene composite powder are mixed to obtain composite powder; the liquid nonferrous metal and the composite powder are stirred to obtain metal paste; and adding a resin solution and an auxiliary agent into the metal paste to form printing paste, and then standing and curing. According to the conductive copper paste, the liquid nonferrous metal serves as a main binding phase, the defect that the welding thrust is low due to a traditional resin system is overcome, the problems of dispersion and interface compatibility are solved through cooperation of the nano-copper-coated graphene and the silane coupling agent, and finally the conductive copper paste with extremely low resistance, high stability and ultrahigh welding thrust is obtained.

The invention discloses a vacuum-assisted pultrusion preforming device for a composite material. The vacuum-assisted pultrusion preforming device comprises a yarn threading plate, a gum dipping tank, a gum extruding roller and a vacuum-assisted preforming mold which are sequentially arranged in the pultrusion direction, wherein fiber bundles penetrate through the yarn threading plate in a layered mode, the gum dipping tank is used for containing resin, and the gum extruding roller is used for extruding redundant resin. The vacuum auxiliary preforming mold is provided with a preforming mold cavity, a vacuum cavity is formed in one section of the preforming mold cavity of the vacuum auxiliary preforming mold, an air exhaust hole is formed in the upper portion of the vacuum cavity, and a semi-permeable membrane allowing gas to pass through but blocking resin to pass through is arranged at the air exhaust hole. And the air exhaust hole is externally connected with a vacuumizing device. The vacuum-assisted pultrusion preforming device can effectively discharge microbubbles in resin and fiber bundles, effectively control uniform distribution of the content of the resin and remarkably promote full infiltration of high-viscosity resin to fibers.

The invention relates to a bionic Al / SiC composite material with a three-dimensional network multilevel structure and a preparation method of the bionic Al / SiC composite material, and belongs to the technical field of new material preparation. According to the method, through the collaborative process of freeze casting and organic foam impregnation, the problem that in the prior art, the multilevel aperture and the complex network structure are difficult to cooperatively regulate and control is solved. The preparation method comprises the following specific steps: preparing tert-butyl alcohol-based ceramic slurry, impregnating the slurry with polyurethane foam, performing freeze casting molding, removing a solvent through freeze drying, performing high-temperature sintering to form SiC ceramic with a three-dimensional reticular hierarchical pore structure, and finally preparing the Al / SiC composite material through a vacuum pressure infiltration process. Wherein a sintering aid is added into the slurry, so that the sintering temperature is obviously reduced; the specification (40-60 ppi) of polyurethane foam, the solid phase content (20-30 vol.%) of slurry, the freezing speed (0-90 DEG C) and the content (5-20 wt.%) of a sintering aid are regulated and controlled. And the cross-scale collaborative design of micron-scale directional holes and millimeter-scale mesh holes is realized. The Al / SiC composite material prepared by the invention has the advantages that the compressive strength, fracture toughness and other properties are obviously higher than those of the traditional single-aperture porous ceramic, and the Al / SiC composite material is suitable for the fields of manufacturing and energy absorption of precise instruments, electronic packaging and optical devices.