The invention discloses glass
powder and conductive
copper paste for an MLCC (multilayer
ceramic capacitor) and a preparation method of the glass
powder and the conductive
copper paste. The formula of the glass
powder comprises 18.0% to 28.0% of SiO2, 25.0% to 35.0% of B2O3, 30.0% to 45.0% of BaO, 0% to 10% of CaO, 0% to 5% of Na2O, 0% to 8.0% of TiO2, 0% to 6% of CuO, 0% to 5.0% of Sb2O3 and 0% to 5.0% of NaF. Basic components of the glass powder do not contain Bi and Zn, a
system is SiO2-B2O3-Na2O-BaO, TiO2, CuO, Sb2O3, NaF and the like are added into the basic glass components, Sb2O3 can reduce the
surface tension of the glass and improve the wettability between the glass and the
copper powder and
ceramic, and TiO2 and CuO enhance the
acid resistance of the glass and increase the compactness of an interface. NaF is used as a glass liquid
clarifying agent, so that the clarifying speed of the glass liquid can be increased, the high-temperature
viscosity of the glass powder can be reduced, the flowability of the glass powder is enhanced, and the interface densification speed is increased. The average particle size of the glass powder is 1.8-2.5 microns, and the
thermal expansion coefficient of the glass is 6.5-9.5 ppm / DEG C. The glass powder has an obvious
sintering assisting effect on the copper paste, after the copper paste is applied to an MLCC
ceramic substrate to be sintered, the copper paste and the
ceramic substrate have firm physical and chemical bonding, and the MLCC shows excellent electrical properties,
adhesive force and good
electroplating liquid resistance.