691results about "Non-aqueous electrolyte accumulators" patented technology

The present invention relates to novel electroactive energy storing polyacetylene-co-polysulfur (PAS) materials of general formula (C2Sx)n wherein x is greater than 1 to about 100, and n is equal to or greater than 2. This invention also relates to novel rechargeable electrochemical cells containing positive electrode materials comprised of said polyacetylene-co-polysulfur materials with improved storage capacity and cycle life at ambient and sub-ambient temperatures.

The negative electrode for a non-aqueous electrolyte secondary battery of the present invention includes a conductive porous substrate, and a conductive material and an active material filled in pores of the porous substrate. The active material contains at least one of a metal element and a semi-metal element capable of reversibly absorbing and desorbing lithium.

A method of manufacturing a solid electrolyte battery includes a step of thermally pressing a composite layer including a positive electrode ink layer, an electrolyte ink layer and a negative electrode ink layer that are formed by coating a positive electrode ink, an electrolyte ink and a negative electrode ink. Further, the positive electrode ink, the electrolyte ink and the negative electrode ink contain a polymer electrolyte. By this method, it is possible to improve the flow of ions across respective interlayers of a positive electrode active material layer, a solid electrolyte layer and a negative electrode active material layer.

The present invention provides a separator for non-aqueous electrolyte batteries which neither breaks nor slips off at the time of fabrication of battery, gives excellent battery fabricability, causes no internal short-circuit caused by contact between electrodes even if the electrodes are externally short-circuited, can inhibit ignition of battery and produces high energy density and excellent cycle life, and further provides a non-aqueous electrolyte battery using the separator and a method for manufacturing the separator. That is, the present invention relates to a separator for non-aqueous electrolyte batteries which comprises a porous base containing at least one member selected from a porous film, a woven fabric or nonwoven fabric containing an organic fiber and a paper and an organometallic compound applied to the porous base; a method for the manufacture of the separator for non-aqueous electrolyte batteries which comprises allowing said porous base to contact with a solution of organometallic compound by impregnation, coating or spraying, followed by drying or curing with heating to apply the organometallic compound to the porous base; and a non-aqueous electrolyte battery using the separator.

A lithium battery comprises a pouch (4) and a lithium battery module (2) packaged in the pouch (4). The pouch (4) is formed from a battery packaging laminated structure (10). The laminated structure (10) has an outermost layer (11), a barrier layer (12) and an innermost layer (14), or an outermost layer (11), a barrier layer (12), an intermediate layer (13) and an innermost layer (14) superposed in that order. The outermost layer (11) is formed of a formable base material, the barrier layer (12) is formed of a impermeable base material having a barrier property, the intermediate layer (13) is formed of a formable base material and the innermost layer (14) is formed of a heat-adhesive base material.

A redox chemical shuttle comprising an aromatic compound substituted with at least one tertiary carbon organic group and at least one alkoxy group (for example, 2,5-di-tert-butyl-1,4-dimethoxybenzene) provides repeated overcharge protection in rechargeable lithium-ion cells.

To provide a lithium secondary cell, which is excellent in productivity since a cell structure is simple and easy for assembly. Provided is a lithium secondary cell having: an internal electrode body including a positive electrode plate, a negative electrode plate, the positive electrode plate and the negative electrode plate being wound and laminated around an external periphery wall of a hollow cylindrical winding core, and inside the internal electrode body a nonaqueous electrolyte solution being impregnated, a cylindrical cell case contained in this internal electrode body 1 with both ends being opened, and two electrode caps sealing the above described internal electrode body 1 at both the open ends of this cell case. The electrode cap has a plate member sealing the internal electrode body and disposed so as to seal both the open ends of the above described cell case, an external terminal member protruding onto the surface of the electrode caps to lead out currents to outside, and an internal terminal member brought into connection with the internal electrode body and taking out currents from the internal electrode body, and an elastic body and at least two of the above described plate member, the external terminal member and the internal terminal member are joined together for construction. Furthermore, there is also provided an assembly of lithium secondary cells.

A rechargeable lithium-ion cell contains a positive electrode, negative electrode, charge-carrying electrolyte containing charge carrying medium and lithium salt, and an N-substituted or C-substituted phenothiazine compound dissolved in or dissolvable in the electrolyte. The substituted phenothiazine compound has an oxidation potential above the positive electrode recharged potential and serves as a cyclable redox chemical shuttle providing cell overcharge protection.

A non-aqueous electrolyte battery that contains a molten salt electrolyte and has the enhanced output performances and cycle performances can be provided. The electrolyte has a molar ratio of lithium salt to molten salt of from 0.3 to 0.5, and the non-aqueous electrolyte battery has a positive electrode having a discharge capacity of 1.05 or more times that of a negative electrode thereof.

A cylindrical lithium-ion battery with excellent safety where abnormal heat generation and remarkable deformation of a battery container do not occur even at an abnormal time is provided. When an average diameter of a winding group 6 is A mm, an inner diameter of the battery container 5 is B mm, a longitudinal length of the winding group 6 except for lead pieces extending from the winding group 6 is H mm, and the number of windings where a layer of one unit comprising a negative electrode member/separator/negative electrode member/separator is wound around a shaft core 11 is W, a calculation value K obtained by a formula; K=(B-A)x(10000/(WxH) is set to 0.89 or more. When the calculation value K is 0.89 or more, a gap (B-A) between an outer periphery of the winding group 6 and an inner periphery of the battery container 5 that enables the winding group 6 to expand in its diameter direction at an abnormal time is properly secured.

Composite cathode active materials having a large diameter active material and a small diameter active material are provided. The ratio of the average particle diameter of the large diameter active material to the average particle diameter of the small diameter active material ranges from about 6:1 to about 100:1. Mixing the large and small diameter active materials in a proper weight ratio improves packing density Additionally, including highly stable materials and highly conductive materials in the composite cathode active materials improves volume density, discharge capacity and high rate discharge capacity.

Disclosed is a cathode electrode having a cathode active material layer stacked on a current collector. The cathode active material layer includes a porous conductive material having a surface coated with sulfur and/or a sulfur-containing organic compound and/or pores filled with sulfur and/or a sulfur-containing organic compound. A lithium secondary battery employing the cathode electrode also is disclosed. The cathode electrode is structurally stable during charging and discharging since the structure of the cathode active material layer can be maintained even at the phase transition of sulfur during charging and discharging.

Anode active materials, methods of producing the same and lithium batteries using the same are provided. More particularly, an anode active material having high capacity and excellent capacity retention, a method of producing the same and a lithium battery having a long lifespan using the same are provided. The anode active material comprises complex material particles comprising silicon and graphite, a carbon layer covering the surface of the complex material particles, and a silicon-metal alloy formed between the complex material particles and the amorphous carbon layer.

A separator including at least a layer containing a fine particulate filler and a shutdown layer. The fine particulate filler includes a joined-particle filler that is in the form of a plurality of primary particles joined and bonded to one another. A non-aqueous electrolyte secondary battery including this separator exhibits improved safety, high performance and large current discharge capability particularly at low temperatures.

Disclosed is a negative active material for a rechargeable lithium battery that includes graphite particles, silicon micro-particles attached on the graphite particles and a carbon film partially or totally coated on the graphite particles.

A non-aqueous electrolyte secondary battery negative electrode material is provided wherein a negative electrode active material containing a lithium ion-occluding and releasing material which has been treated with an organosilicon base surface treating agent is surface coated with a conductive coating. Using the negative electrode material, a lithium ion secondary battery having a high capacity and improved cycle performance is obtainable.

A secondary battery includes a case, a rolled electrode assembly disposed within the case, and an electrode assembly fixing member receiving a portion of the rolled electrode assembly so that expansion and contraction of the rolled electrode assembly can be suppressed during charging and discharging operations of the battery, and deformation of the rolled electrode assembly caused by outer impact can be prevented. The electrode assembly fixing member comprises a cap fitted onto at least one of upper and lower ends of the rolled electrode assembly. The electrode assembly fixing member further comprises a gripper holding the rolled electrode assembly.

A negative active material, a negative electrode including the negative active material, a method of manufacturing the negative electrode, and a lithium battery including the negative electrode. The negative active material includes a composite including a non-carbonaceous material, carbon nanotubes (CNTs), and carbon nanoparticles. The carbon nanoparticles are formed by carbonizing a polymer of carbonizable monomers.

A nonaqueous electrolyte battery includes a flattened electrode group, a case, a positive electrode terminal and a negative electrode terminal. The positive electrode terminal is bent around one edge portion of the positive electrode terminal, curved toward the electrode group and reaches a sealed portion. The other edge portion of the positive electrode terminal extends from the case through the sealed portion. The negative electrode terminal is bent around one edge portion of the negative electrode terminal, curved toward the electrode group and reaches the sealed portion. The other edge portion of the negative electrode terminal extends from the case through the sealed portion. The positive electrode terminal satisfies formula (1) given below and the negative electrode terminal satisfies formula (2) given below:

t₂×W₂≧0.25 S_p  (1)

t₃×W₃≧0.25 S_n  (2)

A lithium rechargeable battery, which includes a separator having excellent mechanical strength such as elastic strength, swelling resistance, heat resistance, and peel strength. The lithium rechargeable battery includes a cathode, an anode, a separator for separating both electrodes from each other, and a non-aqueous electrolyte, wherein the separator includes a porous membrane formed of a ceramic material and a binder, and the binder has an elongation ratio of 200 to 300%.

A positive electrode material for non-aqueous electrolyte lithium ion battery (31, 41) of the present invention has an oxide (11) containing lithium and nickel, and a lithium compound (13) which is deposited on a surface of the oxide (11) and covers nickel present on the surface of the oxide (11). By this structure, it is possible to suppress decomposition of an electrolysis solution as much as possible and drastically reduce swelling of the batteries (31, 41).

A battery unit for a secondary battery that includes a positive electrode plate, a positive electrode tab, a negative electrode plate, a negative electrode tab, a separator, and short circuit preventing units, wherein the short circuit preventing units are formed on corresponding uncoated areas of the positive and negative electrode current collectors where the positive and negative electrode sheets are not formed, each short circuit preventing unit having a corresponding width greater than a width of the corresponding positive and negative electrode current collectors.

A subject for the invention is to improve the cycle characteristics of a high-capacity secondary battery containing an active material packed at a high density, by using a particulate active material having a low aspect ratio. The invention relates to a nonaqueous-electrolyte secondary battery comprising a negative electrode and a positive electrode each capable of occluding/releasing lithium, a separator, and a nonaqueous electrolyte solution comprising a nonaqueous solvent and a lithium salt, characterized in that the separator comprises a porous film made of a thermoplastic resin containing an inorganic filler, and at least either of the following is satisfied: the active material contained in the negative electrode is a particulate active material having an aspect ratio of from 1.02 to 3; and the active material contained in the positive electrode is a particulate active material having an aspect ratio of from 1.02 to 2.2.

A life of a secondary battery is extended, increase in a resistance when storing a secondary battery at an elevated temperature is prevented, and increase in a resistance during a charge-discharge cycle is prevented. A positive electrode active material comprising a lithium manganate and a lithium nickelate are used. The lithium manganate is a compound represented by the following formula (1) or the compound in which some of Mn or O sites are replaced with another element:

Li_1+xMn_2−xO₄  (1)

(in the above-shown formula (1), 0.15≦x≦0.24).

In a non-aqueous electrolyte secondary battery having a negative electrode containing Si as a negative electrode active material, a binder containing a non-crosslinked polyacrylic acid having a weight-average molecular weight of 300,000 to 3,000,000 is incorporated into a negative electrode molded article that constitutes the negative electrode, so as to prevent electrode decay resulting from expansion and contraction during charge/discharge, as well as to achieve high energy density and improved charge/discharge cycle characteristics.

The invention relates to an improvement in a cell which is normally susceptible to damage from overcharging comprised of a negative electrode, a positive electrode, and an electrolyte comprised of an overcharge protection salt carried in a carrier or solvent. Representative overcharge protection salts are embraced by the formula:

M_aQ

where M is an electrochemically stable cation selected from the group consisting of alkali metal, alkaline earth metal, tetraalkylammonium, or imidazolium groups, and Q is a borate or heteroborate cluster and a is the integer 1 or 2.

The positive electrode active material of a positive electrode includes a sodium-containing transition metal oxide (Na_aLi_bM_xO_2±α). The M includes at least two of manganese (Mn), iron (Fe), cobalt (Co), and nickel (Ni). For a negative electrode, a sodium metal or a metal that forms an alloy with sodium is used. A non-aqueous electrolyte produced by dissolving an electrolytic salt (sodium salt) in a non-aqueous solvent is used. Examples of the non-aqueous solvent may include a cyclic carbonate, a chain carbonate, esters, cyclic ethers, chain ethers, nitrites, amides and a combination thereof.

A cathode active material capable of increasing a capacity and improving high temperature characteristics or cycle characteristics, a method of manufacturing it, a cathode using the cathode active material, and a battery using the cathode active material are provided. In a cathode active material contained in a cathode, a coating layer is provided on at least part of a complex oxide particle containing at least lithium (Li) and cobalt (Co). The coating layer is an oxide which contains lithium (Li) and at least one of nickel (Ni) and manganese (Mn).

A lithium ion battery includes a cathode (10) having a plurality of nanoparticles of lithium doped transition metal alloy oxides represented by the formula LixCoyNizO2, an anode (20) having at least one carbon nanotube array (22), an electrolyte, and a membrane (30) separating the anode from the cathode. The carbon nanotube array includes a plurality of multi-walled carbon nanotubes (23). Preferably, an average diameter of an outermost wall of the multi-walled carbon nanotubes is in the range from 10 to 100 nanometers, and a pitch between adjacent multi-walled carbon nanotubes is in the range from 20 to 500 nanometers. In the carbon nanotube array, the lithium ions are able to intercalate not only inside the multi-walled carbon nanotubes, but also in the interstices between adjacent multi-walled carbon nanotubes. Thus a density of intercalation of the carbon nanotube array is significantly higher than that of graphite.

The use of lithium bis(oxalato)borate (LiBOB) as an additive in a lithium secondary battery provides improved battery performance such as long life, high capacity retention, and protection against overcharging.