The invention relates to the technical field of high-molecular
polymer materials, in particular to a high-strength and high-
toughness polyelectrolyte conductive
elastomer as well as a preparation method and application thereof. The method comprises the following steps: mixing 3-
acrylamide-N, N, N-trimethylpropane-1-
ammonium bis (trifluoromethylsulfonyl)
amide, a cross-linking agent and a
photoinitiator to obtain a precursor solution, and carrying out an
ultraviolet irradiation reaction to obtain a
polyelectrolyte conductive
elastomer; and then putting into water for swelling process and deswelling process to obtain the high-strength and high-
toughness polyelectrolyte conductive
elastomer. The method is simple to operate and mild in reaction condition, the obtained high-strength and high-
toughness polyelectrolyte conductive elastomer does not contain liquid components, cations are fixed on a
polymer chain, anions are adsorbed around the cations under the action of charges, so that the problem of leakage does not exist, and the
microstructure of the elastomer contains a glassy hard phase and a high-elastic soft phase, so that the high-strength and high-toughness polyelectrolyte conductive elastomer is prepared. The
composite material has excellent mechanical properties of high strength and high toughness, and also has
ionic conductivity and good self-healing ability.