280 results about "Antimony" patented technology

The invention provides a preparation method of a barrier type antimonide infrared detector. The preparation method comprises the following steps: selecting a gallium antimonide substrate; a gallium antimonide buffer layer, an indium arsenide heavily-doped layer, a class II superlattice absorption layer and an aluminum-arsenic-antimony barrier layer are sequentially grown on the substrate in an epitaxial mode through a molecular beam epitaxy method; mechanically stripping the hexagonal boron nitride two-dimensional material, and transferring the stripped hexagonal boron nitride to the aluminum-arsenic-antimony barrier layer to form a Van der Waals heterojunction and composite barrier layer structure; depositing electrodes by using an ultraviolet lithography technology and a thermal evaporation mode to form one electrode arranged on the gallium antimonide buffer layer and the other electrode arranged on the boron nitride; a large-numerical-aperture micro-lens array is processed on a substrate, and the micro-lens array is composed of gallium antimonide cylinders with a phase modulation function; therefore, the antimonide medium-wave infrared detector with the composite barrier layer can be formed, the quantum efficiency is improved, the order of magnitude of dark current is reduced, and room-temperature medium-wave infrared detection can be realized.

The invention discloses a method for increasing the recovery rate of lead fire refining alkaline residues. The temperature of the roasting furnace is set to be 580-650 DEG C, after the actual temperature reaches the set temperature, the refined alkaline residues are conveyed into the roasting furnace, the rotating speed of the roasting furnace is controlled to be 0.5-1 circle / min, the amount of blown air is 2-5 m < 3 > / min, the materials are subjected to oxidizing roasting in the roasting furnace for 30-60 min, the temperature is reduced to 30-50 DEG C, and roasted sand materials are obtained; detecting the roasted product material to obtain the content of the S element; the roasted sand materials and corresponding auxiliary materials are put into a smelting furnace in batches, the temperature in the furnace is controlled to be 900-1100 DEG C, the smelting time is 2-3 h, and produced lead bullion is discharged after the smelting time is up; the auxiliary materials are prepared according to the input amount of a single-batch roasted product material and the content of the S element. The recovery rate of lead, tin, antimony and copper in the pyrorefining alkaline residues can be effectively increased, and the cost of smelting auxiliary materials is reduced.

The invention discloses a preparation method and application of a metal sulfide adsorbent for adsorbing iodine and methyl iodide. The preparation method comprises the following steps: uniformly mixing an antimony source, a sulfur source, a deep eutectic solvent, polyamine and water to obtain a mixed solution; and transferring the mixed solution into a high-pressure reaction kettle, sealing, carrying out hydrothermal reaction at 110-220 DEG C for 2-9 days, cooling to room temperature to separate out crystals, and filtering, washing and drying to obtain the metal sulfide adsorbent. The invention also discloses application of the metal sulfide adsorbent in adsorption of iodine and methyl iodide. The metal sulfide adsorbent disclosed by the invention has a good adsorption effect on iodine and methyl iodide, and compared with an ethylenediamine-oriented metal sulfide adsorbent, the diethylenetriamine-oriented metal sulfide adsorbent has higher adsorption capacity on iodine and methyl iodide.

The invention relates to the technical field of geological exploration, in particular to an X-ray fluorescence spectrometer and geological radar combined gold vein rapid positioning method, which comprises the following steps: S1, arranging an exploration survey line in a pre-selected exploration area; s2, along the same measuring line, measuring the content of the gold mineralization indication element in the earth surface or the shallow medium by using an X-ray fluorescence spectrometer, synchronously recording the position information of a measuring point, and generating element content spatial distribution data; the gold mineralization indicating element comprises at least one of arsenic As, antimony Sb and mercury Hg; s3, carrying out detection by using a geological radar along the same measuring line, obtaining a reflected wave signal of an underground medium, synchronously recording position information of a detection point, identifying fault zone and joint zone geological structure anomalous bodies through data processing, and generating geological radar space distribution data; through XRF and GPR data fusion, a CAI quantitative model is established to precisely delineate an ore prospecting target area, a hidden ore body is effectively identified, the exploration precision and efficiency are greatly improved, and the exploration cost is reduced.

The invention discloses a high-voltage-resistant brominated flame-retardant polyamide composition and a preparation method thereof, and belongs to the technical field of flame-retardant materials. The composition comprises the following components in percentage by mass: 30-80 wt% of aliphatic polyamide, 10-30 wt% of a brominated flame retardant, 0.5-10 wt% of an antimony-based synergist, 0.5-10 wt% of aromatic zinc carboxylate, 0.5-5 wt% of hydroxyapatite, 0.1-50 wt% of a reinforcing agent and 0-5 wt% of other auxiliaries, the sum of the contents of all the components is 100 wt%, and the raw material components are subjected to melt blending processing through a single-screw or double-screw extruder. The invention provides the high-voltage-resistant brominated flame-retardant polyamide composition, the relative tracking index (CTI) of the high-voltage-resistant brominated flame-retardant polyamide composition is greater than 400V, and the high-voltage-resistant brominated flame-retardant polyamide composition has high-level flame retardance and cost effect.

The invention provides an electroplating solution and an electroplating method for preparing an antimony-containing tin-based alloy packaging bump structure. The content of antimony atoms in the bump structure is 0.1-8.0%; the electroplating liquid comprises tin (II), antimony (III), an inhibitor, methanesulfonic acid and an antioxidant; the concentrations of the tin (II), the antimony (III), the inhibitor, the methanesulfonic acid and the antioxidant in the electroplating solution are 15-60 g / L, 0.01-8.0 g / L, 0.5-15.0 g / L, 20-200 mL / L and 1.0-3.0 g / L in sequence. The electroplating solution can effectively realize co-deposition of tin ions and antimony ions, and the situation that the deposition rate is not matched in the deposition process due to the electrochemical characteristic difference of tin and antimony is overcome; the content of antimony atoms in the generated bump structure is 0.1-8.0%, and a small amount of metal antimony is added into a tin base, so that grains can be refined, the crystal face of a plating layer can be promoted to obtain excellent surface flatness, and the hardness of the plating layer can be effectively improved.

The invention relates to a preparation method of antimony pentafluoride, which comprises the following steps: preheating raw material gas nitrogen trifluoride, placing nitrogen trifluoride and antimony powder in a tubular furnace reactor made of a specific material, carrying out gradient heating reaction at 300-400 DEG C under the condition that the antimony powder is distributed by adopting a multi-layer nickel plate tiled structure, carrying out reaction for 10-40 seconds, and carrying out solid filtration through a filter after the reaction is completed, so as to obtain the antimony pentafluoride. And carrying out cold trap collection to obtain an antimony pentafluoride product. The diameter of the reactor is made of a nickel material or Monel to prevent corrosion of antimony pentafluoride, the number of tiled layers of nickel plates is r / 5-r / 10, the contact area is increased, the reaction yield is increased, and the utilization rate of the raw material nitrogen trifluoride is increased.

The invention discloses an antimony electrolyte impurity removal adsorbent as well as a preparation method and application thereof, and relates to the technical field of antimony electrolyte purification. The adsorbent is specially used for solving the problem that lead and bismuth ions similar to antimony in potential in the antimony electrolyte are difficult to deeply remove. The preparation method comprises the following steps: mixing sulfuric acid, deionized water, antimony oxide powder and hydrogen peroxide according to a specific mass ratio (1: (0.8-1.5): (0.5-1.5)), and controlling the liquid-solid ratio to be 8-15 mL / g to form a synthetic initial solution; then reacting for 0.5-4 hours under the condition of stirring at the temperature of 60-90 DEG C and the speed of 200-600 r / min; and finally, carrying out solid-liquid separation and drying at 55-110 DEG C for 1-12 hours. When the adsorbent is applied, the adsorbent is added into electrolyte according to the proportion of 500-5000 times of the total mass of lead and bismuth, reaction is performed for 1-6 hours under the conditions of 30-90 DEG C and 200-550 r / min, and deep purification can be realized after standing, settling and separating. The method is short in technological process, mild in condition, easy to operate, environmentally friendly and high in lead and bismuth removal rate, purified liquid can return to an electrolysis system, the saturated adsorbent can be regenerated and reused, and good economic benefits and application prospects are achieved.

The application belongs to the technical field of metallurgy, and relates to a method for efficiently purifying and directionally removing oxygen and impurities from a precious antimony alloy, which comprises the following steps: S1, after the precious antimony alloy is melted, an arsenic-tellurium removal agent is added, and smelting is performed at 600-610 DEG C to obtain a pre-impurity removal alloy melt and an arsenic-tellurium residue; the arsenic-tellurium removal agent is a mixture of sodium hydroxide and sodium nitrate; S2, the pre-impurity removal alloy melt obtained in step S1 is heated to 620-640 DEG C, a reducing agent is added, and smelting is performed to obtain an arsenic alkali residue and a refined antimony alloy; the reducing agent is a mixture of antimony sulfide and sodium hydroxide; S3, the arsenic-tellurium residue obtained in step S1 and the arsenic alkali residue obtained in step S2 are ball milled, leaching and filtration are performed to obtain a filtrate and a filter residue; S4, the filtrate obtained in step S3 is mixed with sulfuric acid, and after reaction, a neutralization residue and a neutralization liquid are obtained. By introducing the efficient arsenic-tellurium removal agent and the reducing agent, the content of antimony in the arsenic alkali residue is significantly reduced, and the direct recovery rate of antimony and the recovery rate of tellurium are effectively improved.

The invention provides a preparation method of high-purity antimony, and belongs to the technical field of high-purity metal materials. The preparation method of the high-purity antimony comprises the following steps that a crude antimony raw material is added into a cylindrical container, then the cylindrical container is placed in an induction heating coil, and under the conditions that the induction power is 30-150 kW, the change frequency is 2-15 kHz and the rotating eddy current is in the clockwise direction, the crude antimony raw material is subjected to induction melting, and gathering the impurities at the edge, parallel to the section circle of the cylindrical container, of the molten antimony, cooling, and removing the impurities to obtain the high-purity antimony. According to the preparation method of the high-purity antimony, the purity of the crude antimony raw material can be rapidly and effectively improved.

The invention discloses an iron-mud-based environmental functional material based on an electrochemical-ferrate synergistic effect as well as a preparation method and application of the iron-mud-based environmental functional material. The material is derived from an iron sludge byproduct generated in the process of cooperatively treating wastewater by electrochemical oxidation and ferrate. Due to the influence of active oxygen species, electric field action and local pH gradient in an electrochemical system, the forming process of the iron mud is different from that of conventional chemical precipitation, the obtained material has an amorphous and high-specific-surface-area unique structure and is endowed with remarkable oxidation capacity, and cooperation of oxidation and adsorption functions is achieved. The material disclosed by the invention can be used for efficiently removing anion pollutants such as arsenic, antimony and phosphate in a water body. According to the invention, solid wastes generated by a combined process are converted into a high-performance adsorption material, so that the resource utilization of treating wastes with wastes is realized, the comprehensive operation cost of the advanced oxidation process is effectively reduced, and the method has good environmental and economic benefits and application prospects.

The invention belongs to the technical field of medicine detection, and particularly relates to an ICPMS (Inductively Coupled Plasma Mass Spectrometry) detection method for element impurities in theophylline. The linear test solution, the blank solution and the theophylline test solution are subjected to ICPMS detection, the content of element impurities in the theophylline test solution is calculated according to an internal standard curve method, and the element impurities are one or more of cadmium, lead, arsenic, mercury, cobalt, vanadium, nickel, lithium, antimony or copper. The method is good in reproducibility and stability, high in accuracy and high in precision.

Systems and methods for forming an antimony containing film on a substrate. Related structures and films are also disclosed. The antimony films are be formed by a plasma enhanced atomic layer deposition process. The antimony films can be utilized as underlayers in EUV lithography processes.

The invention discloses a process for rapidly removing impurity arsenic in crude antimony by using a refining pot, which comprises the following steps: adding crude antimony produced by a copper removal furnace into the refining pot, melting, then removing slag, blowing oxygen, and adding a proper amount of arsenic removal agent to produce an arsenic-removed antimony alloy; compared with the prior art, the method has the beneficial effects that arsenic in the materials can be rapidly removed, the smelting production efficiency is improved, the production cost is reduced, and conversion of intermediate products is accelerated.

The application provides an antimony-based composite negative electrode material and a preparation method and application thereof, and relates to the technical field of new energy batteries.The preparation method provided by the application comprises the following steps: mixing antimony metal powder with amorphous carbon, ball-milling, drying and calcining to obtain an antimony-based intermediate; performing acidification treatment on the surface of carbon nanotubes to obtain acidified carbon nanotubes, dispersing the acidified carbon nanotubes in an organic sodium modified solution, stirring, filtering, drying to obtain modified carbon nanotubes; mixing and dispersing the antimony-based intermediate, sodium polyacrylate and the modified carbon nanotubes to obtain a suspension, and then performing spray drying to obtain the antimony-based composite negative electrode material.The preparation method provided by the application can improve the problem of performance decline caused by the capacity attenuation of the antimony metal due to the huge volume expansion in the process of deintercalating sodium ions, and effectively improves the electrochemical performance of the antimony-based negative electrode material.

The invention discloses a method for recovering copper from high-arsenic matte and enriching arsenic and lead. The method comprises the steps that the high-arsenic matte and quartz sand are fully mixed according to a first set proportion and then added into a smelting furnace; natural gas and oxygen are continuously introduced into the smelting furnace for a heating smelting reaction, air is continuously blown in the heating smelting reaction process, and slag is discharged once every set time; and after slagging is completed, limestone is added to remove arsenic, meanwhile, the temperature in the smelting furnace is gradually increased to 950 DEG C, the temperature in the smelting furnace is kept at 950 DEG C till the content of arsenic in the materials is smaller than 1%, at the moment, arsenic enters smoke, and ash is produced after dust collection. According to the method provided by the invention, the high-arsenic matte obtained through treatment in a lead smelting enterprise can be recycled in a targeted manner, so that lead, antimony, gold, silver, arsenic and the like in the high-arsenic matte are recycled after being classified, and the aims of deeply treating the high-arsenic matte and enriching and extracting various valuable metal elements in a classified manner are fulfilled.

Non-grain-oriented electrical steel sheet, having a thickness of 0.30 mm to 0.38 mm and a composition comprising the following elements, expressed as weight percent: 0.0001% ≤ Carbon ≤ 0.007% 0.09% ≤ Manganese ≤ 0.15% 2.6% ≤ Silicon ≤ 2.95% 0.1% ≤ Aluminum ≤ 0.5% Phosphorus ≤ 0.15% Sulfur ≤ 0.006% Nitrogen ≤ 0.09% 0% ≤ Tin ≤ 0.04% and may contain one or more of the following optional elements: 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten ≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0% ≤ Boron ≤ 0.05% 0% ≤ Lead ≤ 0.2% 0% ≤ Antimony ≤ 0.2% wherein the remaining composition consists of iron and unavoidable impurities caused by processing, wherein the microstructure of the steel sheet consists of ferrite, comprising 80% to 100% recrystallized microstructure and 0% to 20% non-recrystallized microstructure in area fractions, wherein the average grain size of the recrystallized microstructure is 20 to 110 micrometers, and exhibiting a percentage of eddy current losses in the total iron losses, measured at 1 T and 400 Hz according to standards IEC 60404-2, of 35% to 45%, calculated according to the Bertotti method.

The invention relates to the technical field of adsorbent materials, and discloses a CoMn2O4 spinel adsorbent and a method for removing trivalent antimony in a water body by using the CoMn2O4 spinel adsorbent. The adsorbent is prepared by adopting a co-precipitation and low-temperature thermally induced crystallization synergetic green process: dissolving cobalt salt and manganese salt according to a stoichiometric ratio, dropwise adding a sodium hydroxide solution for co-precipitation, washing an obtained precursor, and drying at 80-120 DEG C under normal pressure for 12-48 hours to directly obtain the adsorbent. According to the method, the spinel material with low crystallinity, high specific surface area and rich surface hydroxyl is controllably synthesized by regulating and controlling the concentration of the precipitator and the drying condition, and the problems of active site loss and high energy consumption caused by traditional high-temperature calcination are avoided. When the composite material is used for treating wastewater containing trivalent antimony, antimony ions can be efficiently removed through the adsorption effect under the appropriate pH condition, excellent adsorption capacity is shown, the technology is simple, cost is low, safety is good, and an efficient and stable adsorption material and a feasible method are provided for water body antimony pollution treatment.

The invention discloses an antimony electrolyte impurity removal adsorbent as well as a preparation method and application thereof, and relates to the technical field of antimony electrolyte purification. The preparation method comprises the following steps: mixing antimony pentoxide and deionized water according to a certain proportion, preparing a slurry at a certain temperature and within a certain reaction time, or further modifying antimony pentoxide by using one or a mixed solution of concentrated sulfuric acid and hydrogen peroxide, and filtering and drying the mixed slurry to obtain the novel active polyhydroxy antimonic acid. During application, the novel active polyhydroxy antimonic acid adsorbent is added into electrolyte according to the proportion of 500-5000 times of the total mass of lead, bismuth and arsenic, reaction is performed for 1-6 hours under the conditions of 30-90 DEG C and 200-550 r / min, and deep purification can be realized after standing, settling and separating. The method is short in technological process, mild in condition, easy to operate, environmentally friendly and high in lead, bismuth and arsenic removal rate, purified liquid can return to an electrolysis system, the saturated adsorbent can be regenerated and reused, and the method has good economic benefits and application prospects.

Double-rolled non-grain-oriented electrical steel sheet, having a thickness of 0.28 mm to 0.32 mm and having a composition comprising the following elements, expressed as weight percent: 0.0001% ≤ Carbon ≤ 0.007% 0.2% ≤ Manganese ≤ 0.24% 3.1% ≤ Silicon ≤ 3.5% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15% Sulfur ≤ 0.006% Nitrogen ≤ 0.09% 0.01% ≤ Chromium ≤ 1% 0.01% ≤ copper ≤ 1% and may contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten ≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0.001% ≤ Nickel ≤ 0.04% 0% ≤ Boron ≤ 0.05% 0% ≤ Lead ≤ 0.2% 0% ≤ Tin ≤ 0.2% 0% ≤ Antimony ≤ 0.2% wherein the remaining composition consists of iron and unavoidable impurities caused by processing, wherein the microstructure of the steel sheet consists of ferrite, comprising 80% to 100% recrystallized microstructure and 0% to 20% non-recrystallized microstructure in area fractions, wherein the average grain size of the recrystallized microstructure is 20 to 110 micrometers, and exhibiting a percentage of eddy current losses to the total iron losses, measured at 1 T and 400 Hz according to standards IEC 60404-2, of 30% to 35%, calculated according to the Bertotti method, and simultaneously a magnetic polarization at 5000 A / m (J50) of 1.645 T to 1.660 T.

The application relates to an ultrasonic treatment method of high-impurity copper anode slime. The ultrasonic treatment method is realized through hierarchical ultrasonic strengthening and synergistic leaching. In the first-stage leaching, hydrogen peroxide-oxygen-rich air composite oxidants are combined with ultrasonic cavitation effects to realize efficient oxidation leaching of arsenic, antimony and bismuth; in the second-stage leaching, sulfuric acid-sodium sulfite mixed leaching agents are used to remove harmful impurities such as arsenic, antimony and bismuth under ultrasonic strengthening, and to efficiently enrich valuable metals such as gold, silver, selenium and tellurium, so that the treatment period is shortened, energy consumption and reagent consumption are reduced, resource comprehensive utilization is improved, and the method is suitable for efficient separation and resource recovery of high-impurity copper anode slime containing refractory impurities such as arsenic, antimony and bismuth and valuable metals such as gold, silver, selenium and tellurium.

The utility model relates to the technical field of drying equipment, in particular to a high-purity antimony particle drying device which comprises a drying box body, a filter and an air return cavity, one side of the drying box body is connected with the filter, the other side of the drying box body is connected with the air return cavity, an air inlet is formed in the side, connected with the filter, of the drying box body, and an air outlet is formed in the upper portion of the side, connected with the air return cavity, of the drying box body. The upper part of the air return cavity is provided with an air return port and connected to an air return pipeline; a heating cavity is formed in one side of an air inlet of the filter, heating pipes protected by non-metal materials are uniformly arranged in the heating cavity, and temperature measuring points are arranged in the heating cavity; a drying machine is mounted outside the drying box body, is connected with the air return pipeline and is provided with a water outlet; the heating cavity supplies air through an air feeder. According to the high-purity antimony particle drying device, by reasonably designing the number proportion of the air inlet holes and the air outlet holes, a multi-layer tray placing structure and the layout of the heating pipes, the flowing path and heat distribution of hot air flow in the drying box body are optimized.

A method for improving the accuracy of pH value detection using an antimony-based pH electrode, belonging to the field of pH value detection technology, includes: measuring the dissolved oxygen concentration of the test solution; comparing this dissolved oxygen concentration with the dissolved oxygen concentration of the standard buffer solution used during pH sensor calibration; when the two dissolved oxygen concentrations differ, dissolved oxygen potential compensation is required: multiplying the difference between the two dissolved oxygen concentrations by a dissolved oxygen concentration compensation coefficient to obtain a dissolved oxygen potential compensation value; and using this dissolved oxygen potential compensation value to compensate the electrode potential of the antimony-based pH electrode in the test solution, thereby achieving accurate pH value measurement. This invention improves the measurement accuracy of the antimony-based pH electrode and the accuracy of in-situ pH value monitoring results through dissolved oxygen potential compensation.

This invention belongs to the field of metallurgical technology and relates to a method for preparing crude cadmium from cadmium-containing flue dust, comprising the following steps: S1, neutral leaching of cadmium-containing flue dust with deionized water to obtain filter residue and filtrate 1; then acid leaching of the filter residue with sulfuric acid to obtain lead slag and filtrate 2; S2, mixing filtrate 1 and filtrate 2, adding an oxidant and iron salt for primary purification to obtain arsenic-antimony slag and filtrate 3; adding zinc powder twice to filtrate 3 for secondary purification to obtain copper-nickel slag and filtrate 4; S3, concentrating filtrate 4 to obtain cadmium-rich solution, then aging at 70-85℃; subsequently cooling to 50-65℃, adding polyethylene glycol, and adding aluminum-magnesium alloy powder under high-speed stirring for a displacement reaction; after the reaction, obtaining filtrate and crude cadmium. This invention deeply removes impurities such as arsenic, antimony, and lead from cadmium-containing flue dust and obtains high-purity, dense crude cadmium particles with the aid of morphology modifiers, high-speed stirring, and aluminum-magnesium alloy powder.

The present application belongs to the field of metallurgy, and relates to a method for producing antimony white by directly oxidizing crude antimony, comprising the following steps: S1, mixing crude antimony with crude antimony alloy, and reacting under an oxygen-containing atmosphere, to obtain oxidized slag and a melt after the reaction is completed; S2, adjusting the temperature of the melt, and then introducing compressed air to react, to produce antimony trioxide-containing flue gas, and to obtain antimony oxide slag after the reaction is completed. The present application makes full use of impurities such as sodium sulfide, sodium hydroxide and sodium thiosulfate contained in crude antimony, and innovatively uses these components for arsenic removal reaction, which not only avoids the cumbersome steps of adding various auxiliary materials in the traditional process, but also enables the original sodium sulfide, sodium hydroxide and sodium thiosulfate in the crude antimony to fully play a synergistic role, showing excellent performance in arsenic removal effect, thus simplifying the process flow, significantly reducing the production cost, and realizing the dual improvement of economic benefit and process efficiency.

The application discloses a zinc powder automatic control method, device and system for antimony salt purification process, which comprises the following steps: constructing a copper and cobalt removal fitting model, calculating the optimal potential setting value by using a particle swarm algorithm and setting the potential setting value; updating the potential setting value by using a fuzzy algorithm and a case reasoning method; constructing a three-dimensional fuzzy rule according to the difference between the current potential measurement value and the potential setting value, generating a zinc powder adjustment amount, adding the current zinc powder addition amount to obtain a new zinc powder amount setting value, writing the new zinc powder amount setting value into a DCS system on line, and controlling the automatic feeding device to add zinc powder. The above steps are repeated to achieve stable potential control and realize the minimum zinc powder consumption. The zinc powder automatic control method for the antimony salt purification process, which automatically adjusts the zinc powder addition amount according to the potential fluctuation, realizes accurate control of the zinc powder addition amount, effectively reduces the zinc powder consumption in zinc hydrometallurgy, and reduces the production cost in the antimony salt purification process.

The invention relates to the technical field of comprehensive utilization of non-ferrous metal smelting waste residues, and discloses a harmless treatment and valuable metal recovery method for arsenic-alkali residues, which comprises the following steps: carrying out selective leaching and antimony separation on the arsenic-alkali residues, and precipitating antimony by using solubility product difference to obtain arsenic-containing alkali filtrate; carrying out gradient carbonization crystallization under oxidation-reduction potential clamping on the filtrate, converting sodium carbonate into sodium bicarbonate crystals under the constraint of specific potential by utilizing the salting-out effect of pentavalent arsenic in a saturated sodium bicarbonate solution, separating out the sodium bicarbonate crystals, and filtering and separating to obtain a sodium bicarbonate product and arsenic-rich mother liquor; according to the method, through a coupling mechanism of potential clamping and gradient carbonization crystallization, the solubility difference of arsenic and alkali is constructed, the salting-out effect is utilized, the arsenic-alkali co-dissolution balance is broken on the premise that exogenous foreign ions are not introduced, and the arsenic-rich mother liquor is subjected to terminal mineralization to generate arsenic-containing mineral precipitates. Efficient separation and recovery of antimony and sodium carbonate and deep solidification of arsenic are realized.

The invention relates to a novel functional material for X-ray protection, in particular to a liquid metal flexible shielding material and a preparation method and application thereof. The material comprises liquid metal and solid metal, the liquid metal serves as a solvent to be filled in gaps of the solid metal, the liquid metal is gallium, gallium indium, gallium indium tin, gallium indium tin zinc or mercury, and the solid metal is selected from one or more of indium, tin, gold, platinum, iridium, zirconium, niobium, molybdenum, ruthenium, osmium, rhenium, rhodium, tungsten, antimony, palladium, tantalum, hafnium, lutetium, lead, ytterbium, thulium, bismuth, silver, erbium, holmium, dysprosium, terbium, gadolinium, samarium, neodymium, lanthanum, praseodymium, cerium and europium. On the basis of compounding of the liquid metal solvent and the solid metal solute based on the liquid metal combinatology, the liquid metal and the solid metal are jointly used for protecting X-ray radiation, the comprehensive performance of X-ray protection is improved, and meanwhile the variety and number range of selectable metal elements is widened.

This invention relates to the field of chemical process technology, specifically to a method for preparing sodium hexafluoroantimonate. The preparation method includes the following steps: (1) adding antimony trioxide, hydrogen fluoride aqueous solution, and sodium fluoride into a reaction vessel, stirring and heating, introducing a fluorine-nitrogen mixed gas, and then refluxing the reaction; (2) filtering and then flash evaporation concentration; (3) subsequently cooling and crystallizing at 0~15℃, and centrifuging to obtain sodium hexafluoroantimonate crystals. The preparation method provided by this invention can achieve fluorination, oxidation, and salt formation in one step simultaneously, with a simple process route and a significant reduction in steps; using low-concentration fluorine gas as an oxidant and fluorine source, the atom utilization rate is high, the reaction rate is fast, the raw material consumption is close to the stoichiometric ratio, the final product has a trivalent antimony residue of ≤0.01%, and the product purity is as high as 99.9%; combined with flash evaporation concentration, hydrogen fluoride and mother liquor recovery and recycling process, it can reduce raw material consumption and waste liquid discharge, thereby improving product yield and reducing production costs.

The invention relates to the field of ore smelting, in particular to antimony-containing ore smelting equipment integrating crushing and screening and a smelting process. The antimony-containing ore smelting equipment comprises a smelting furnace, a platform is arranged at the top of the smelting furnace, a material opening upwards penetrates through the platform, a circular-truncated-cone-shaped core body is erected on the platform, and a plurality of fixed crushing blocks are arranged on the surface of the outer ring of the core body; each fixed crushing block is fixed on the core body through a bolt, and the fixed crushing blocks can be detached and replaced after being seriously abraded; the core body is covered with a cover plate matched with the core body in shape, the cover plate is erected on the platform, the outer ring of the cover plate is fixedly connected with a gear ring, the gear ring is erected on the platform through a supporting frame, the gear ring and the cover plate are rotationally connected to the supporting frame, the gear ring is meshed with a gear, the gear is driven by a gear motor, and the cover plate can rotate around the axis of the core body. A plurality of movable crushing blocks are arranged on the inner surface of the cover plate and can be connected to the cover plate according to the assembly mode of the fixed crushing blocks.