647 results about "Antimony" patented technology

The invention provides a preparation method of a barrier type antimonide infrared detector. The preparation method comprises the following steps: selecting a gallium antimonide substrate; a gallium antimonide buffer layer, an indium arsenide heavily-doped layer, a class II superlattice absorption layer and an aluminum-arsenic-antimony barrier layer are sequentially grown on the substrate in an epitaxial mode through a molecular beam epitaxy method; mechanically stripping the hexagonal boron nitride two-dimensional material, and transferring the stripped hexagonal boron nitride to the aluminum-arsenic-antimony barrier layer to form a Van der Waals heterojunction and composite barrier layer structure; depositing electrodes by using an ultraviolet lithography technology and a thermal evaporation mode to form one electrode arranged on the gallium antimonide buffer layer and the other electrode arranged on the boron nitride; a large-numerical-aperture micro-lens array is processed on a substrate, and the micro-lens array is composed of gallium antimonide cylinders with a phase modulation function; therefore, the antimonide medium-wave infrared detector with the composite barrier layer can be formed, the quantum efficiency is improved, the order of magnitude of dark current is reduced, and room-temperature medium-wave infrared detection can be realized.

The invention discloses a method for recovering metal from high-nickel copper fire refining slag and application of the method, and relates to the technical field of metal metallurgy. Comprising the following steps: carrying out weak acid arsenic leaching on the copper fire refining slag to obtain arsenic-removed leaching slag and arsenic-containing copper liquid; copper removal is carried out on the arsenic-containing copper liquid to obtain a copper-containing material and copper-removed liquid, and arsenic precipitation is carried out on the copper-removed liquid; the arsenic-removed leaching residues are subjected to oxidation copper leaching to obtain copper leaching residues and a copper sulfate solution, and the copper leaching residues are subjected to reduction vulcanization smelting to obtain nickel matte, tin-antimony smoke dust and smelting residues. According to the method, the cost of separation of copper and arsenic in the raw materials can be reduced, the problem of furnace caking caused in the reduction smelting process is avoided, the obtained copper sulfate solution serves as electrolyte replenishing liquid to be applied to the copper electrolysis process, and the influence on the self-purification process of electrolyte is small. According to the method, nickel and copper are enriched in matte nickel through reduction vulcanization smelting, then copper-nickel separation is conducted through the post-treatment process, the post-treatment process is shorter, nickel recovery is achieved while copper recovery is guaranteed, and better economic benefits are achieved.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 30 to 40% when calculated in accordance with Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.2% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+AI+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten ≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 35 to 55% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.635T to 1.670T.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.2% ≤ Manganese ≤ 0.24% 3.1% ≤ Silicon ≤ 3.5% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less from 30% to 35% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.645T to 1.660T.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.1% ≤ Manganese ≤ 0.2% 3.1% ≤ Silicon ≤ 3.6% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, is from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.64T to 1.66T.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.09% ≤ Manganese ≤ 0.15% 2.5% ≤ Silicon ≤ 3% 0.1 % ≤ Aluminum ≤ 0.5 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.25% 2.9% ≤ Silicon ≤ 3.4% 0.7% ≤ Aluminum ≤ 1.3 % 0.05% ≤ Nickel ≤ 1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 35% when calculated in accordance of Bertotti method.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.1% ≤ Manganese ≤ 0.3% 3.1% ≤ Silicon ≤ 3.8% 0.6% ≤ Aluminum ≤ 0.8% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 40 to 50% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.66T to 1.7T.

The invention discloses a Ti / IrO2-SnO2-SbO2 gradient active coating anode with low cost and high stability and a preparation process of the Ti / IrO2-SnO2-SbO2 gradient active coating anode. The gradient active coating is characterized in that the gradient active coating is composed of 3-5 layers, the total thickness is 5-15 microns, the thickness of each layer is 1-5 microns, the molar percentage content of iridium in a bottom layer is 0-5%, the sum of the molar percentage content of tin and antimony is 95-100%, the molar percentage content of iridium in a surface layer is 10-20%, the sum of the molar percentage content of tin and antimony is 80-90%, and the thickness of each layer is 1-5 microns. The molar percentage content of iridium from the bottom layer to the surface layer is sequentially increased from 2% to 10%, the molar percentage content of tin and antimony is sequentially reduced from 2% to 10%, and the total iridium loading amount in the gradient active coating is 0.05-0.2 mg / cm < 2 >. The preparation method comprises the three steps of titanium substrate pretreatment, precursor salt alcohol solution preparation and gradient active coating preparation. By adopting a gradient coating mode, the thermal stress between the coating and the titanium substrate in the preparation process is remarkably reduced, the consumption of noble metal is reduced, the oxygen evolution activity of the anode is improved, and the service life of the anode is prolonged. The method is simple to operate and low in cost, and has remarkable industrialization advantages.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.17% ≤ Manganese ≤ 0.4% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 25% when calculated in accordance of Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.21% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.63T to 1.66T.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 %, 0.15% ≤ Manganese ≤ 0.25%, 3.2% ≤ Silicon ≤ 3.8%, 0.7% ≤ Aluminum ≤ 1.3 %, 0 % ≤ Phosphorus ≤ 0.15 %, 0 % ≤ Sulfur ≤ 0.006 %, 0 % ≤ Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1%, 0% ≤ Titanium ≤ 0.1%, 0% ≤ Vanadium ≤ 0.1%, 0% ≤ Chromium ≤ 1%, 0% ≤ Molybdenum ≤ 0.5%, 0% ≤ Tungsten≤ 0.1%, 0% ≤ Cobalt ≤ 1%, 0% ≤ Arsenic ≤ 0.05%, 0.001% ≤ Calcium ≤ 0.01%, 0% ≤ Copper ≤ 1%,0.001% ≤ Nickel ≤ 0.01, 0 % ≤ Boron ≤ 0.05%, 0 % ≤ Lead ≤ 0.2%, 0% ≤ Tin≤ 0.2%, 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current loss in total iron loss less than 33 % when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.630T to 1.65T.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.3% 3.2% ≤ Silicon ≤ 3.8% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 30% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.66T to 1.69T.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 %, 0.15% ≤ Manganese ≤ 0.25%, 2.9% ≤ Silicon ≤ 3.4%, 0.8% ≤ Aluminum ≤ 1.1 %, 0 % ≤ Phosphorus ≤ 0.15 %, 0 % ≤ Sulfur ≤ 0.006 %, 0 % ≤ Nitrogen ≤ 0.09%,with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1%, 0% ≤ Titanium ≤ 0.1%, 0% ≤ Vanadium ≤ 0.1%, 0% ≤ Chromium ≤ 1%, 0% ≤ Molybdenum ≤ 0.5%, 0% ≤ Tungsten≤ 0.1%, 0% ≤ Cobalt ≤ 1%, 0% ≤ Arsenic ≤ 0.05%, 0.001% ≤ Calcium ≤ 0.01%, 0% ≤ Copper ≤ 1%, 0% ≤ Nickel ≤ 1%, 0 % ≤ Boron ≤ 0.05%, 0 % ≤ Lead ≤ 0.2%, 0% ≤ Tin≤ 0.2%, 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current loss in total iron loss less than 25% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.625T to 1.690T.

The invention provides a preparation method and application of a magnetic biochar adsorption material, and relates to the technical field of biochar adsorption materials. The adsorption material is prepared by taking three kinds of biomass including municipal sludge, straw and antimony ore waste residues as biochar sources and further loading magnetic nano gamma-Fe2O3 particles. In the process, by controlling the mass of the municipal sludge, the straw and the antimony ore waste residues, the composition and performance of the biochar base material in the adsorption material can be regulated and controlled, rich active sites in the sludge and the straw are fully utilized, loading of the magnetic nano gamma-Fe2O3 particles is achieved, and the adsorption efficiency is improved. A microfibril structure in the straw and a high-activity mesoporous carrier in the antimony ore waste residue not only can improve the load rate of the magnetic nano gamma-Fe2O3 particles to a certain extent, but also can be beneficial to diffusion and capture of heavy metal ions in the application process, so that the adsorption rate of the material to the heavy metal ions is improved on the whole.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.30% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.4% ≤ Aluminum ≤ 0.8 % 0.05% ≤ Tin≤ 0.15% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 25% to 35% when calculated in accordance of Bertotti method.

The invention discloses a low-carbon collaborative smelting method for an antimony-containing material, which adopts a technical route of oxygen-enriched side-blown smelting, oxygen-enriched side-blown reduction and top-blown oxidative volatilization to treat a mixed material of antimony concentrate and high-antimony anode slime, and adopts a mode of mixed blowing of a powdery raw material and oxygen-enriched air to prepare the low-carbon collaborative smelting method for the antimony-containing material. Compared with the prior art, reaction kinetic conditions of materials and oxygen when the materials are fed into the furnace are enhanced, advanced volatilization of sulfides and generation of antimony matte are effectively restrained, chemical reaction heat is fully absorbed by melt, heat excess in the smelting process is achieved, high-proportion antimony-containing secondary materials can be treated through the part of heat, and multi-material synergistic self-heating smelting is achieved. And meanwhile, Au and Ag are collected through crude antimony metal generated through reduction, high-quality antimony bletilla and high-concentration precious metal alloy can be produced through volatilization blowing, and short-process recovery of precious metal elements is achieved. The method is a brand-new technical route for widening the application range of raw materials, reducing cost and improving efficiency in antimony smelting plants.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.005 % 0.2% ≤ Manganese ≤ 0.3% 3.1% ≤ Silicon ≤ 3.6% 0.6% ≤ Aluminum ≤ 1 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of 18 recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 30% to 35% when calculated in accordance of Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.18% ≤ Manganese ≤ 0.5% 3.1% ≤ Silicon ≤ 3.8% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin ≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 34 % when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.60T to 1.65T.

The invention provides a method for recycling valuable metal from germanium-antimony-tellurium alloy waste. The method comprises the three steps of surface treatment, chlorine reaction and compartment condensation and discharging. Oxidation films on the surfaces of the waste materials are removed through surface treatment, and the subsequent chlorine reaction efficiency is improved; then a self-made chlorination-step condensation integrated device is utilized, germanium, antimony and tellurium react with chlorine at the high temperature to generate gaseous chloride, step-by-step condensation separation is achieved through partition temperature control based on the boiling point difference of tellurium tetrachloride, antimony pentachloride and germanium tetrachloride, and target products are collected respectively; and finally, introducing inert gas to purge residual chlorine, and discharging safely. The method has the advantages of short process flow, no need of complex wet process steps and low equipment investment; metal chlorides are efficiently separated through the integrated device, and recovery is thorough; and the pyrogenic process is mainly adopted, no wastewater is generated, only tail gas is treated in a compliance manner, and the method is environment-friendly. Compared with a traditional wet process, the method has the remarkable advantages of high efficiency, low cost, environment friendliness and the like.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.009 % 0.25% ≤ Manganese ≤ 0.6% 1% ≤ Silicon ≤ 2.5% 0.15% ≤ Aluminum ≤ 0.3 % 0.05% ≤ Tin≤ 0.15% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 50% when calculated in accordance of Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.05% ≤ Manganese ≤ 0.15% 2.5% ≤ Silicon ≤ 3.1% 0.26% ≤ Aluminum ≤ 0.7 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method.

The invention discloses a method for increasing the recovery rate of lead fire refining alkaline residues. The temperature of the roasting furnace is set to be 580-650 DEG C, after the actual temperature reaches the set temperature, the refined alkaline residues are conveyed into the roasting furnace, the rotating speed of the roasting furnace is controlled to be 0.5-1 circle / min, the amount of blown air is 2-5 m < 3 > / min, the materials are subjected to oxidizing roasting in the roasting furnace for 30-60 min, the temperature is reduced to 30-50 DEG C, and roasted sand materials are obtained; detecting the roasted product material to obtain the content of the S element; the roasted sand materials and corresponding auxiliary materials are put into a smelting furnace in batches, the temperature in the furnace is controlled to be 900-1100 DEG C, the smelting time is 2-3 h, and produced lead bullion is discharged after the smelting time is up; the auxiliary materials are prepared according to the input amount of a single-batch roasted product material and the content of the S element. The recovery rate of lead, tin, antimony and copper in the pyrorefining alkaline residues can be effectively increased, and the cost of smelting auxiliary materials is reduced.

The invention discloses a preparation method and application of a metal sulfide adsorbent for adsorbing iodine and methyl iodide. The preparation method comprises the following steps: uniformly mixing an antimony source, a sulfur source, a deep eutectic solvent, polyamine and water to obtain a mixed solution; and transferring the mixed solution into a high-pressure reaction kettle, sealing, carrying out hydrothermal reaction at 110-220 DEG C for 2-9 days, cooling to room temperature to separate out crystals, and filtering, washing and drying to obtain the metal sulfide adsorbent. The invention also discloses application of the metal sulfide adsorbent in adsorption of iodine and methyl iodide. The metal sulfide adsorbent disclosed by the invention has a good adsorption effect on iodine and methyl iodide, and compared with an ethylenediamine-oriented metal sulfide adsorbent, the diethylenetriamine-oriented metal sulfide adsorbent has higher adsorption capacity on iodine and methyl iodide.

The invention provides a method for comprehensively recovering valuable metals from liquid purified by an antimony-based adsorbent, and belongs to the field of hydrometallurgy. The method comprises the following steps: (1) primary electrodeposition copper removal; (2) primary purification and impurity removal; (3) secondary electrodeposition copper removal; (4) secondary purification and impurity removal; (5) diffusion dialysis; (6) neutralizing to remove iron; (7) nickel precipitation by oxalic acid; and (8) roasting to obtain the high-purity nickel oxide powder. The treated object is the copper electrolyte subjected to purification and impurity removal through the antimony-based adsorbent, and the content of arsenic, antimony and bismuth impurities is remarkably reduced. By means of the method, it can be guaranteed that the quality of electric copper reaches the A-level copper standard, meanwhile, generation of highly toxic H3As gas is avoided, the comprehensive utilization efficiency of valuable metal resources in purified liquid is high, and the method is suitable for industrial application of copper electrolyte purification.

The invention discloses a method for detecting heavy metal trivalent antimony ions / hexavalent chromium ions in an environment based on a color developing agent, and belongs to heavy metal ion detection.The method comprises the following steps that a sample to be detected is taken, and acid liquor is added to adjust the pH value of the sample to be detected; adding a color developing agent and a surfactant into the to-be-detected solution, mixing, and standing; after full reaction, the absorbance is measured through a spectrophotometric method, the measured absorbance value of the trivalent antimony ions / hexavalent chromium ions corresponds to the standard curve, and the concentration of the trivalent antimony ions or hexavalent chromium ions in the to-be-measured sample is obtained. Sb < 3 + > / Cr < 6 + > reacts with a color developing agent to generate a stable orange complex, and the stable orange complex has the characteristics of low detection limit and high sensitivity to trivalent antimony ions and hexavalent chromium ions. In addition, the method does not depend on large instruments and equipment, and is simple, efficient and convenient to operate.

The invention relates to the technical field of geological exploration, in particular to an X-ray fluorescence spectrometer and geological radar combined gold vein rapid positioning method, which comprises the following steps: S1, arranging an exploration survey line in a pre-selected exploration area; s2, along the same measuring line, measuring the content of the gold mineralization indication element in the earth surface or the shallow medium by using an X-ray fluorescence spectrometer, synchronously recording the position information of a measuring point, and generating element content spatial distribution data; the gold mineralization indicating element comprises at least one of arsenic As, antimony Sb and mercury Hg; s3, carrying out detection by using a geological radar along the same measuring line, obtaining a reflected wave signal of an underground medium, synchronously recording position information of a detection point, identifying fault zone and joint zone geological structure anomalous bodies through data processing, and generating geological radar space distribution data; through XRF and GPR data fusion, a CAI quantitative model is established to precisely delineate an ore prospecting target area, a hidden ore body is effectively identified, the exploration precision and efficiency are greatly improved, and the exploration cost is reduced.

A preparation method of 5N high-purity antimony comprises the following steps: (1) hydrolysis: taking ethylene glycol antimony as a raw material, and carrying out pyrohydrolysis pretreatment to obtain antimony trioxide; (2) biological reduction: uniformly mixing antimony trioxide with an organic catalytic reduction covering agent, and carrying out reduction smelting to prepare 4N antimony; and (3) vacuum distillation: the 4N antimony is subjected to two-stage vacuum distillation, namely first-stage high-temperature vacuum distillation and second-stage low-temperature vacuum distillation, and the 5N high-purity antimony is obtained. According to the method, an ethylene glycol antimony product is adopted as a raw material and subjected to hydrolysis-biological reduction and multi-field synergistic enhanced vacuum distillation to obtain 5N high-purity antimony, the total amount of impurity elements of the product is controlled to be 10 ppm or below, the content of key impurity elements As is controlled to be 1 ppm or below, the content of Pb is controlled to be 0.2 ppm or below, the content of Bi is controlled to be 0.2 ppm or below, the content of Cu is controlled to be 0.05 ppm or below, and the content of Fe is controlled to be 0.5 ppm or below.

The invention discloses a high-antimony lead production process based on lead refining alkaline residues, and belongs to the technical field of lead bullion refining alkaline residues. Through carbonization treatment after urea intercalation and urea decomposition and escape, more pores and larger interlayer spacing are left, so that the specific surface area of anthracite is increased, porous anthracite is obtained, and the specific surface area of the anthracite is increased; the porous anthracite is subjected to secondary intercalation by using nano calcium oxide, the obtained modified porous anthracite is larger in interlayer spacing and larger in surface area, a large amount of nano calcium oxide is uniformly attached to the surface of the anthracite, the reaction activity is remarkably improved, and an enlarged pore structure is beneficial to gas diffusion, so that the reduction reaction efficiency of the anthracite is improved; the zeolite-based modified asphalt powder is used as a binder, and zeolite particles can fill micro pores and cracks in the asphalt, so that the void ratio is reduced, the compactness of the asphalt is improved, and the bonding strength is improved; the lead product prepared through the production technology is high in purity, the antimony recovery efficiency is high, meanwhile, the amount of generated slag is small, and the content of lead in the slag is low.