922 results about "Antimony" patented technology

The invention provides a preparation method of a barrier type antimonide infrared detector. The preparation method comprises the following steps: selecting a gallium antimonide substrate; a gallium antimonide buffer layer, an indium arsenide heavily-doped layer, a class II superlattice absorption layer and an aluminum-arsenic-antimony barrier layer are sequentially grown on the substrate in an epitaxial mode through a molecular beam epitaxy method; mechanically stripping the hexagonal boron nitride two-dimensional material, and transferring the stripped hexagonal boron nitride to the aluminum-arsenic-antimony barrier layer to form a Van der Waals heterojunction and composite barrier layer structure; depositing electrodes by using an ultraviolet lithography technology and a thermal evaporation mode to form one electrode arranged on the gallium antimonide buffer layer and the other electrode arranged on the boron nitride; a large-numerical-aperture micro-lens array is processed on a substrate, and the micro-lens array is composed of gallium antimonide cylinders with a phase modulation function; therefore, the antimonide medium-wave infrared detector with the composite barrier layer can be formed, the quantum efficiency is improved, the order of magnitude of dark current is reduced, and room-temperature medium-wave infrared detection can be realized.

The invention relates to the technical field of nodular cast iron, in particular to a silicon-molybdenum-chromium-nickel-niobium nodular cast iron material and a preparation method thereof. The material comprises the following chemical components in percentage by mass: 3.0%-3.5% of carbon, 4.3%-4.7% of silicon, 0.1%-0.3% of manganese, less than or equal to 0.05% of phosphorus, less than or equal to 0.02% of sulfur, 0.7%-1.0% of molybdenum, 0.6%-0.8% of chromium, 0.4%-0.7% of nickel, 0.3%-0.6% of niobium, 0.03%-0.06% of magnesium, 0.05%-0.1% of rare earth, 0.006%-0.012% of antimony and the balance of iron. The preparation method comprises the steps of smelting, first-time spheroidizing and inoculation, second-time spheroidizing, second-time inoculation and heat treatment in sequence. According to the obtained nodular cast iron material, the form of graphite and the number of graphite nodules are improved, carbon elements are separated out as many as possible in the form of high-carbon phase-spheroidal graphite, generation of pearlite is reduced, and the mechanical strength and high-temperature resistance of nodular cast iron are improved.

The invention discloses a sulphide ore flotation method which comprises the following steps: (1) carrying out ore grinding operation on sulphide ore to obtain ore pulp; (2) the pH value of the ore pulp is adjusted, then a pyrite inhibitor, a collecting agent and a foaming agent are sequentially added, flotation operation is conducted, and concentrate and tailings are obtained; the chemical structural formula of the pyrite inhibitor is as shown in formula (I). The flotation method preferably selects the pyrite inhibitor, can be widely applied to inhibition of pyrite, hemite and pyrrhotite in copper-sulfur separation, lead-zinc-sulfur separation and lead-antimony, molybdenum-bismuth and sulfur separation, can generate a strong inhibition effect on the pyrite and the pyrrhotite, has the characteristic of small dosage, is non-toxic and environment-friendly, can replace sodium cyanide for use, and has a wide application prospect. Meanwhile, the problems that the pH value of ore pulp is too high and the separation efficiency is low due to the fact that a large amount of lime is used can be effectively solved, and the grade and flotation recovery rate of target mineral concentrate are improved.

The invention discloses a method for recovering metal from high-nickel copper fire refining slag and application of the method, and relates to the technical field of metal metallurgy. Comprising the following steps: carrying out weak acid arsenic leaching on the copper fire refining slag to obtain arsenic-removed leaching slag and arsenic-containing copper liquid; copper removal is carried out on the arsenic-containing copper liquid to obtain a copper-containing material and copper-removed liquid, and arsenic precipitation is carried out on the copper-removed liquid; the arsenic-removed leaching residues are subjected to oxidation copper leaching to obtain copper leaching residues and a copper sulfate solution, and the copper leaching residues are subjected to reduction vulcanization smelting to obtain nickel matte, tin-antimony smoke dust and smelting residues. According to the method, the cost of separation of copper and arsenic in the raw materials can be reduced, the problem of furnace caking caused in the reduction smelting process is avoided, the obtained copper sulfate solution serves as electrolyte replenishing liquid to be applied to the copper electrolysis process, and the influence on the self-purification process of electrolyte is small. According to the method, nickel and copper are enriched in matte nickel through reduction vulcanization smelting, then copper-nickel separation is conducted through the post-treatment process, the post-treatment process is shorter, nickel recovery is achieved while copper recovery is guaranteed, and better economic benefits are achieved.

The antimony smelting dust collecting device comprises a dust collecting hopper, an air inlet pipe and an air outlet pipe, a filter cylinder is installed in the dust collecting hopper through a framework, an air guide ring is arranged on the inner wall of the dust collecting hopper, the air inlet pipe is communicated with the air guide ring, and a plurality of air inlet holes are evenly formed in the side wall of the air guide ring in the circumferential direction. The two sides of the air inlet are provided with flow guide plates which are arranged in a sequence needle mode or an anticlockwise mode, and an air inlet channel is formed between the two flow guide plates. By the adoption of the antimony smelting dust collecting device, accumulation of dust on the filter cylinder is reduced.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 30 to 40% when calculated in accordance with Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.2% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+AI+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten ≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 35 to 55% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.635T to 1.670T.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.2% ≤ Manganese ≤ 0.24% 3.1% ≤ Silicon ≤ 3.5% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less from 30% to 35% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.645T to 1.660T.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.1% ≤ Manganese ≤ 0.2% 3.1% ≤ Silicon ≤ 3.6% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, is from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.64T to 1.66T.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.09% ≤ Manganese ≤ 0.15% 2.5% ≤ Silicon ≤ 3% 0.1 % ≤ Aluminum ≤ 0.5 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method.

The invention belongs to the technical field of photomultipliers, particularly relates to a photocathode, and discloses a high-sensitivity high-temperature photomultiplier photocathode with long service life and a preparation method thereof. According to the method for preparing the high-temperature photoelectric cathode in a sandwich mode, firstly, a K3Sb bottom layer is evaporated, then Na activation is carried out, and finally, a K3Sb surface layer is evaporated, so that alkali metal Na is buried in the K3Sb layer, a sandwich structure is formed, metal antimony and alkali metal K and Na are fully reacted, the chemical proportion of the cathode is optimized, the sensitivity of the cathode is improved by more than one time, and the sensitivity of the cathode reaches more than 50 microamperes / lm. Alkali metal adsorbed by the antimony beads is removed by electrifying, and an annular heating device is designed to locally heat the tube wall of the high-temperature tube and a fixed ceramic chip in the high-temperature tube so as to remove alkali metal adsorbed on the surface of the high-temperature tube, so that the damage of the alkali metal to the photoelectric cathode at high temperature is avoided, the preparation of the cathode with the service life of more than 400 hours is realized, and the service life is prolonged by more than 3 times.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.25% 2.9% ≤ Silicon ≤ 3.4% 0.7% ≤ Aluminum ≤ 1.3 % 0.05% ≤ Nickel ≤ 1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 35% when calculated in accordance of Bertotti method.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.1% ≤ Manganese ≤ 0.3% 3.1% ≤ Silicon ≤ 3.8% 0.6% ≤ Aluminum ≤ 0.8% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 40 to 50% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.66T to 1.7T.

The invention discloses a Ti / IrO2-SnO2-SbO2 gradient active coating anode with low cost and high stability and a preparation process of the Ti / IrO2-SnO2-SbO2 gradient active coating anode. The gradient active coating is characterized in that the gradient active coating is composed of 3-5 layers, the total thickness is 5-15 microns, the thickness of each layer is 1-5 microns, the molar percentage content of iridium in a bottom layer is 0-5%, the sum of the molar percentage content of tin and antimony is 95-100%, the molar percentage content of iridium in a surface layer is 10-20%, the sum of the molar percentage content of tin and antimony is 80-90%, and the thickness of each layer is 1-5 microns. The molar percentage content of iridium from the bottom layer to the surface layer is sequentially increased from 2% to 10%, the molar percentage content of tin and antimony is sequentially reduced from 2% to 10%, and the total iridium loading amount in the gradient active coating is 0.05-0.2 mg / cm < 2 >. The preparation method comprises the three steps of titanium substrate pretreatment, precursor salt alcohol solution preparation and gradient active coating preparation. By adopting a gradient coating mode, the thermal stress between the coating and the titanium substrate in the preparation process is remarkably reduced, the consumption of noble metal is reduced, the oxygen evolution activity of the anode is improved, and the service life of the anode is prolonged. The method is simple to operate and low in cost, and has remarkable industrialization advantages.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.17% ≤ Manganese ≤ 0.4% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 25% when calculated in accordance of Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.21% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.63T to 1.66T.

The invention relates to the field of photomultiplier tube processing, and discloses an antimony bead evaporation source quantitative founding device and method, the antimony bead evaporation source quantitative founding device comprises a founding tool and a vacuum system connected with a bell jar above the device, the founding tool is provided with a groove for accommodating antimony powder, and quantitative founding of antimony beads of different specifications is realized by controlling the volume of the antimony powder groove; the melting tool is used for heating antimony powder through a heating part at the bottom of the melting tool; the exterior of the melting tool is evenly wound with a nickel wire, and the invention further discloses an antimony bead evaporation source quantitative melting method which comprises the following steps that S1, the nickel wire is wound and fixed, specifically, the purified nickel wire is evenly wound on the melting tool, and the nickel wire is fixed to the middle position of an antimony powder groove through a wire groove. The antimony powder is degassed and purified in a high-vacuum state, the antimony beads are molten in a high-purity argon atmosphere, the purity of an antimony bead evaporation source is guaranteed, in addition, the antimony powder quantitative loading tool is adopted, and the antimony beads are produced in batches with high specification consistency.

The invention discloses a preparation method of an acidic antimony ore wastewater heavy metal adsorbent. The preparation method comprises the following steps: S1, preparing a pasty uniform sodium alginate aqueous solution; s2, adding electrolytic manganese residues to form a first solution; s3, adding an APS initiator solution to obtain a second solution; s4, adding a sodium hydroxide solution and an AA solution to obtain a third solution; s5, adding an AM solution to obtain a fourth solution; s6, adding an MBA solution to obtain a fifth solution; and carrying out a cross-linking reaction under water culture, washing with water until the product is neutral, and drying. The invention further provides the heavy metal adsorbent for the acidic antimony ore wastewater. The heavy metal adsorbent is prepared by adopting the preparation method. The invention further provides application of the heavy metal adsorbent for the acidic antimony ore wastewater. The heavy metal adsorbent is applied to removal of lead and antimony heavy metals in the acidic antimony ore wastewater. The invention not only provides a new material for adsorbing lead and antimony heavy metals in the acidic antimony ore wastewater, but also provides a new way for high-value recycling of the electrolytic manganese residues.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 %, 0.15% ≤ Manganese ≤ 0.25%, 3.2% ≤ Silicon ≤ 3.8%, 0.7% ≤ Aluminum ≤ 1.3 %, 0 % ≤ Phosphorus ≤ 0.15 %, 0 % ≤ Sulfur ≤ 0.006 %, 0 % ≤ Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1%, 0% ≤ Titanium ≤ 0.1%, 0% ≤ Vanadium ≤ 0.1%, 0% ≤ Chromium ≤ 1%, 0% ≤ Molybdenum ≤ 0.5%, 0% ≤ Tungsten≤ 0.1%, 0% ≤ Cobalt ≤ 1%, 0% ≤ Arsenic ≤ 0.05%, 0.001% ≤ Calcium ≤ 0.01%, 0% ≤ Copper ≤ 1%,0.001% ≤ Nickel ≤ 0.01, 0 % ≤ Boron ≤ 0.05%, 0 % ≤ Lead ≤ 0.2%, 0% ≤ Tin≤ 0.2%, 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current loss in total iron loss less than 33 % when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.630T to 1.65T.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.3% 3.2% ≤ Silicon ≤ 3.8% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 30% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.66T to 1.69T.

The invention relates to a method for controlling the axial resistivity of a crystal bar and the crystal bar, and the method comprises the steps: carrying out the equal-diameter growth of a first crystal bar according to a preset equal-diameter parameter, measuring the axial resistivity of the first crystal bar, and drawing a change curve of the axial resistivity of the first crystal bar; calculating the unevenness of the axial resistivity of the first crystal bar; when the unevenness of the axial resistivity of the first crystal bar is greater than or equal to 17%, the evaporation of the antimony element is promoted or inhibited by adjusting the pressure parameter aiming at different change stages of the axial resistivity, so that the concentration of the antimony element in the silicon solution is adjusted; the risk that the reduction trend of the axial resistivity of the crystal bar is large due to the fact that the concentration of the antimony element in the silicon solution is high is reduced, and the risk that the increase trend of the axial resistivity of the crystal bar is large due to the fact that the concentration of the antimony element in the silicon solution is low is also reduced, namely, the difference value between the maximum resistivity and the minimum resistivity is reduced; and thus, the nonuniformity of the axial resistivity is reduced.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 %, 0.15% ≤ Manganese ≤ 0.25%, 2.9% ≤ Silicon ≤ 3.4%, 0.8% ≤ Aluminum ≤ 1.1 %, 0 % ≤ Phosphorus ≤ 0.15 %, 0 % ≤ Sulfur ≤ 0.006 %, 0 % ≤ Nitrogen ≤ 0.09%,with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1%, 0% ≤ Titanium ≤ 0.1%, 0% ≤ Vanadium ≤ 0.1%, 0% ≤ Chromium ≤ 1%, 0% ≤ Molybdenum ≤ 0.5%, 0% ≤ Tungsten≤ 0.1%, 0% ≤ Cobalt ≤ 1%, 0% ≤ Arsenic ≤ 0.05%, 0.001% ≤ Calcium ≤ 0.01%, 0% ≤ Copper ≤ 1%, 0% ≤ Nickel ≤ 1%, 0 % ≤ Boron ≤ 0.05%, 0 % ≤ Lead ≤ 0.2%, 0% ≤ Tin≤ 0.2%, 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current loss in total iron loss less than 25% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.625T to 1.690T.

The invention provides a preparation method and application of a magnetic biochar adsorption material, and relates to the technical field of biochar adsorption materials. The adsorption material is prepared by taking three kinds of biomass including municipal sludge, straw and antimony ore waste residues as biochar sources and further loading magnetic nano gamma-Fe2O3 particles. In the process, by controlling the mass of the municipal sludge, the straw and the antimony ore waste residues, the composition and performance of the biochar base material in the adsorption material can be regulated and controlled, rich active sites in the sludge and the straw are fully utilized, loading of the magnetic nano gamma-Fe2O3 particles is achieved, and the adsorption efficiency is improved. A microfibril structure in the straw and a high-activity mesoporous carrier in the antimony ore waste residue not only can improve the load rate of the magnetic nano gamma-Fe2O3 particles to a certain extent, but also can be beneficial to diffusion and capture of heavy metal ions in the application process, so that the adsorption rate of the material to the heavy metal ions is improved on the whole.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.30% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.4% ≤ Aluminum ≤ 0.8 % 0.05% ≤ Tin≤ 0.15% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 25% to 35% when calculated in accordance of Bertotti method.

The invention discloses a method for reducing the grade of lead in crude bismuth. The method comprises the following steps: 1) melting the crude bismuth; 2) oxidizing and refining to remove arsenic and antimony; 3) adding alkali to remove tellurium; and 4) removing lead by using quartz sand, namely controlling the temperature of the bismuth pot to be 350-400 DEG C, introducing compressed air, positively and negatively stirring for 8-9 hours in different directions by using a stirrer, adding the quartz sand while stirring to enable the generated lead silicate to float on the surface, and removing slag manually to obtain the lead-removed bismuth. According to the method, no waste gas is produced in the lead removal process, the field operation environment is friendly, the energy consumption is greatly reduced, and the lead removal cost is greatly reduced; according to the method, quartz sand is adopted to remove lead, and a proper reaction temperature is matched, so that not only can the formation of lead silicate be effectively promoted, but also the formation of bismuth silicate can be effectively inhibited, further the lead removal effect can be effectively improved, the lead grade is reduced, and the bismuth grade is improved; the quartz sand is not easy to decompose in the reaction process, the utilization rate of the quartz sand is high, the cost of removing lead from crude bismuth is reduced, and the method is suitable for large-scale production.

The invention discloses a low-carbon collaborative smelting method for an antimony-containing material, which adopts a technical route of oxygen-enriched side-blown smelting, oxygen-enriched side-blown reduction and top-blown oxidative volatilization to treat a mixed material of antimony concentrate and high-antimony anode slime, and adopts a mode of mixed blowing of a powdery raw material and oxygen-enriched air to prepare the low-carbon collaborative smelting method for the antimony-containing material. Compared with the prior art, reaction kinetic conditions of materials and oxygen when the materials are fed into the furnace are enhanced, advanced volatilization of sulfides and generation of antimony matte are effectively restrained, chemical reaction heat is fully absorbed by melt, heat excess in the smelting process is achieved, high-proportion antimony-containing secondary materials can be treated through the part of heat, and multi-material synergistic self-heating smelting is achieved. And meanwhile, Au and Ag are collected through crude antimony metal generated through reduction, high-quality antimony bletilla and high-concentration precious metal alloy can be produced through volatilization blowing, and short-process recovery of precious metal elements is achieved. The method is a brand-new technical route for widening the application range of raw materials, reducing cost and improving efficiency in antimony smelting plants.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.005 % 0.2% ≤ Manganese ≤ 0.3% 3.1% ≤ Silicon ≤ 3.6% 0.6% ≤ Aluminum ≤ 1 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of 18 recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 30% to 35% when calculated in accordance of Bertotti method.

The invention provides high-strength corrosion-resistant structural steel and a preparation method thereof. The high-strength corrosion-resistant structural steel is composed of the following components in percentage by mass: 0.12-0.15% of C; 0.3 to 0.50 percent of Si; 1.8 to 2.0 percent of Mn; 0.05% to 0.06% of Nb; 0.12% to 0.15% of Ti; 0.75 to 1.0 percent of Cr; 0.8 to 1.0 percent of Ni; 0.25 to 0.50 percent of Cu; 0.10% to 0.20% of Mo; 0.10% to 0.20% of Sb; the content of Als is 0.015 to 0.035 percent; n < = 0.00060%; o < = 0.00015%; h < = 0.0015%; less than or equal to 0.015% of S; p is less than or equal to 0.018%; the balance is Fe and residual impurity elements in the smelting process. By adjusting the element components and the content of the element components in the high-strength corrosion-resistant structural steel, on the basis that traditional chromium, nickel, molybdenum and copper are added to improve corrosion-resistant elements, trace antimony elements and titanium elements are added, on one hand, a large amount of dispersed TiC is separated out to generate second-phase strengthening, and the strength is improved; on one hand, formation of Fe3C is inhibited, and toughness is improved; the corrosion-resistant steel plate is suitable for the working condition of a coal mine and the high-salt and high-humidity environment containing sulfur, chlorine and other acid media.

The invention discloses a method for harmlessly preparing ceramsite by removing arsenic and antimony from arsenic-alkali leaching residues. The method comprises the following steps: mixing matrix components containing arsenic alkali leaching residues, quartz sand and alumina powder with a solid carbonaceous regulator, adding water to make pellets, and roasting the pellets to obtain the arsenic alkali leaching residues. According to the method, removal and recovery of arsenic and antimony in the arsenic-alkali leaching residues can be realized by using the same process while ceramsite is prepared, the problem that the arsenic-alkali leaching residues cannot be completely digested due to high toxicity and high alkalinity is solved, and meanwhile, volatile arsenic and antimony can be recovered and returned to an antimony smelting main system by cooling and capturing smoke dust; according to the method, waste of valuable metal and pollution of arsenic are avoided, low-cost and high-value treatment of the arsenic alkali leaching residues is achieved, the prepared ceramic particles are high in strength and small in density and can be applied to the fields of building materials and the like, and the method is short in process, low in cost and capable of achieving industrial application.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.18% ≤ Manganese ≤ 0.5% 3.1% ≤ Silicon ≤ 3.8% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin ≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 34 % when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.60T to 1.65T.