9379results about How to "High reactivity" patented technology

This invention concerns a method for the preparation of polyurea elastomers, comprising: (a) reacting an amine chain extender with dialkyl maleate to form an aspartic ester, wherein the chain extender has a molar amount of amine groups that is less than the moles of dialkyl maleate; (b) blending the aspartic ester with one or more polyoxyalkyleneamines to prepare a resin blend; (c) contacting the resin blend with an isocyanate under conditions effective to form a polyurea elastomer. This invention also concerns a a polyurea elastomer, comprising the reaction product of (a) a resin blend containing one or more polyoxyalkyleneamine and an aspartic ester and (b) an isocyanate, wherein the aspartic ester in the resin blend comprises a reaction product of an amine chain extender and a dialkyl maleate, wherein the mole ratio of amine functionality in the amine chain extender to dialkyl maleate or fumarate is greater than 1:1.

High-surface-area carbon nanostructures coated with a smooth and conformal submonolayer-to-multilayer thin metal films and their method of manufacture are described. The preferred manufacturing process involves the initial oxidation of the carbon nanostructures followed by immersion in a solution with the desired pH to create negative surface dipoles. The nanostructures are subsequently immersed in an alkaline solution containing non-noble metal ions which adsorb at surface reaction sites. The metal ions are then reduced via chemical or electrical means and the nanostructures are exposed to a solution containing a salt of one or more noble metals which replace adsorbed non-noble surface metal atoms by galvanic displacement. Subsequent film growth may be performed via the initial quasi-underpotential deposition of a non-noble metal followed by immersion in a solution comprising a more noble metal. The resulting coated nanostructures may be used, for example, as high-performance electrodes in supercapacitors, batteries, or other electric storage devices.

The invention provides a method for preparing fluorine-containing sulphonyl (phosphoryl) imine and fluorine-containing sulphonyl (phosphoryl) imine alkali metal salt. The method comprises the following steps: taking one or two or more than two of Lewis acid, perfluoro-alkyl sulfuryl fluoride and perfluoro-alkyl acyl fluoride as a catalyst, catalyzing anhydrous hydrogen fluoride to react with chlorine-containing sulphonyl (phosphoryl) imine in a high-pressure kettle and then obtaining the fluorine-containing sulphonyl (phosphoryl) imine by depressurization distilling; taking Lewis base as a catalyst, catalyzing the anhydrous hydrogen fluoride to react with the chlorine-containing sulphonyl (phosphoryl) imine, then acting with different alkali metal carbonate and obtaining the correspondingfluorine-containing sulphonyl (phosphoryl) imine alkali metal salt. Compared with the prior art, the method has the characteristics of simple operation steps, mild reaction conditions, low cost, easyseparation and purification of the product, high purity and yield and the like and is suitable for industrialized mass production.

The invention discloses a polydopamine-based biofunction modification method. The method comprises the following steps of: soaking clean inorganic/metal materials in dopamine alkaline aqueous solution with a pH value of 7.2 to 10, introducing oxygen to fully oxidize the clean inorganic/metal materials to obtain a monolayer polydopamine modification layer, drying, placing the material in the air atmosphere at 50 to 200 DEG C, performing thermal oxidation to obtain a multi-layer firmly-combined high-reactivity polydopamine layer, and soaking the treated material into the amino-containing and sulfydryl-containing biofunctional molecular solution to obtain a firmly combined biofunction simulate modification layer on the surface of the materials. The polydopamine modification layer obtained bythe method has excellent anti-deformation performance, stability and reactivity, can directly react with amino or the sulfydryl in the biomolecule to immobilize the bioactive molecule on the surface by covalent bonds; moreover, the process is simple, the condition is mild, and the method is easy to implement.

The invention discloses a preparation method of a lithium ion battery ternary cathode material. According to the preparation method, full grinding is performed through a colloid mill to improve the reactivity of a precursor and a lithium salt and the uniformity of a mixed material; and a carbon chain organic additive is added in the process of grinding to improve the viscosity of a sizing material, inhibit raw material segregation in the process of drying, quickly balance the temperature of each part of a system in the process of high-temperature reaction and inhibit agglomeration among particles, so that a uniform-appearance and regular mono-crystal ternary cathode material is obtained. Meanwhile, the ternary cathode material is doped and subjected to surface coating modification, so that the structure of the material is stabilized, the side reaction between the material and electrolyte is inhibited, and the high-temperature cycle performance of the material is improved.

A urethane coating is formed by a reaction of a hydroxy-functional resin and a blocked isocyanate crosslinker. A method of catalyzing this reaction includes forming a polymeric ligand from the resin and/or the crosslinker. The method also includes incorporating a metal catalyst with the polymeric ligand to complex the metal catalyst with the polymeric ligand The method further includes reacting resin and the crosslinker to form the urethane coating

The invention belongs to the catalyst technical field, in particular to a ZSM-5 zeolite catalyst characterized by high ratio of silica and alumina as well as a preparation method and the application thereof. The catalyst, taking a pure silicon compound with activity as a silicon source, is made by a hydrothermal synthesis method by adding trace aluminum. The ratio of silica and alumina in the zeolite catalyst is over 1,000, sub-micron crystal particles with open channels have large surface area and good molecular diffusivity. The catalyst in the reaction of MTP has excellent catalytic activity, high selectivity of propylene, and high ratio of propylene and ethylene. The catalyst has simple regeneration method and good restoration of performance after regeneration.

The invention relates to coated optical fibers comprising soft primary coatings and to such primary coatings for protecting glass optical fibers having a sufficient high resistance against cavitation. In particular, the primary coatings have a cavitation strength at which a tenth cavitation appears (sigma10cav) of at least about 1.0 MPa as measured at a deformation rate of 0.20% min-1 and of at least about 1.4 times their storage modulus at 23° C. The coating preferably shows strain hardening in a relative Mooney plot, preferably has a strain energy release rate Go of about 20 J/m2 or more, and preferably has a low volumetric thermal expansion coefficient. The invention furthermore provides a method and apparatus for measuring the cavitation strength of a primary coating.

The invention discloses a preparation method of a super-retarding type polycarboxylate superplasticizer. The super-retarding type polycarboxylate superplasticizer comprises a copolymer and water serving as a solvent, wherein the copolymer comprises an unsaturated polyether macromonomer, an unsaturated carboxylic acid/anhydride mini-monomer, an unsaturated sulfonic acid mini-monomer and an unsaturated phosphonic acid mini-monomer; the pH is 6-7. According to the preparation method, a phosphonate structure capable of retarding is introduced into a water reducer molecular structure; the prepared super-retarding type polycarboxylate superplasticizer can be directly applied to the concrete which needs a relatively long setting time, and thus the process of compounding a retarder can be saved, the production efficiency can be improved, the obtained product is uniform and stable, and abnormal concrete setting time can be avoided.

The invention discloses a methane reforming catalyst for the production of hydrogen and a preparation method thereof, which more particularly relates to a Ni methane vapor reforming catalyst for the production of hydrogen which takes a nanometer cerium zirconium composite oxide as the carrier and the corresponding preparation method, and belongs to the methane reforming catalyst field. The catalyst comprises 5-30 wt% of active Ni, 0-10 wt% of noble metal catalytic promoter, 0-10 wt% of rare earth and/or the catalytic promoter of alkaline earth oxide, 50-95 wt% of nanometer cerium zirconium composite oxide carrier with the particle diameter of 5-20 nm. The invention is characterized by simple preparation method, high reactivity, strong anti carbon performance, good stability, low cost, etc.; when the invention is applied to the methane vapor reforming catalyst for producing hydrogen, the requirements of industrialization on catalyst reactivity and usage life can be satisfied. The invention can be largely applied in fuel cell-hydrogen area.

The invention provides a method for preparing hard polyurethane foam plastics from soybean oil. The method comprises the steps as follows: (1) carrying out epoxidation including the sub-steps of subjecting soybean oil and epoxidizing agent to reaction to obtain epoxidized soybean oil; (2) carrying out ring-opening reaction including the sub-steps of subjecting epoxidized soybean oil and nucleophilic reagent of reactive hydrogen to the ring-opening reaction of epoxy chemical bond in the presence of a catalyst to obtain mixed hydroxyl fatty acid glyceride; (3) carrying out alcoholysis and esterification including the sub-steps of adding alcohol, heating for alcoholysis to obtain mixed hydroxyl fatty acid monoester, i.e. soybean oil based polyol, and esterifying with organic acid and acid anhydride to generate polyester polyol; and (4) sequentially adding 80-150 weight parts of isocyanate, 0.3-4 weight parts of triethanolamine and 0.5-4 weight parts of foam stabilizer to 100 weight parts of soybean oil based polyol, intensively stirring, adding 0.5-3 weight parts of distilled water, and uniformly foaming while stirring at the high speed.

The invention provides an UV curing coating, a wear-resistant and antifouling coating layer and a mobile phone protection film containing the wear-resistant and antifouling coating layer. The coating comprises, in parts by weight, 10-95 parts of a first prepolymer, 5-60 parts of a second prepolymer, 0.05-8 parts of a polysilazane-based polymer, 0.05-8 parts of a fluorine-containing aid, 1-15 parts of a photoinitiator and 100-300 parts of a solvent, wherein the first prepolymer is a urethane acrylate prepolymer with a functionality degree of 4-8; the second prepolymer is an acrylate prepolymer with a functionality degree of 9-18. The wear resistance of the coating layer formed after curing the UV curing coating can be improved by the first prepolymer and the second prepolymer with high functionality degrees, improvement for the wear resistance of the coating layer and prolonging for the service life of the coating layer are benefited due to the adding of the polysilazane-based polymer and a polar compound, and the good antifouling performance of the coating layer can be ensured, and the reduction of the antifouling performance of the coating layer can be suppressed due to the fluorine-containing aid. The coating layer has both good antifouling performance and wear resistance.

The invention provides an edible collagen food packaging film and a preparation method thereof. The preparation method comprises the following steps: firstly, stirring a 5-30wt% collagen solution and a 0.1-3wt% modifier solution at the temperature of 30-60 DEG C to react for 30-60 minutes, thus obtaining a compound solution; then adding a plasticizer and an auxiliary additive into the compound solution, then continuing to stir for 20-40 minutes at the temperature of 30-60 DEG C so as to obtain a mixed solution; and pouring the mixed solution in a die, molding, drying for 5-15 hours at the temperature of 40-80 DEG C, so as to obtain the edible collagen food packaging film. The edible collagen food packaging film has the advantages of better mechanical property, better heat stability, better moisture barrier property, safety, effectiveness and no side effect; wastes can be degraded and do not cause environment pollution; and the edible collagen food packaging film can be widely applied to the fields of various food packaging and medicament packaging, and has a good market application prospect.

The invention discloses an environmentally-friendly type solvent-free impregnating resin and a preparation method thereof. The impregnating resin comprises: 100 parts by weight of one or more high heat-resistant unsaturated polyester resins, 0 to 100 parts by weight of one or more modified epoxy resins, 50 to 200 parts by weight of one or more novel reactive diluents, 0.1 to 1 parts by weight of one or more polymerization inhibitors, 1.5 to 3.8 parts by weight of one or more initiators and 0 to 2 parts by weight of one or more auxiliary agents. Under the same work conditions, a baking time of the solvent-free impregnating resin is less than about one third of a baking time of the existing conventional solvent-free type impregnating resin utilized for middle and low voltage motors and transformers, and an energy consumption of the solvent-free impregnating resin is lower than about 25% of an energy consumption of the existing conventional solvent-free type impregnating resin middle and low voltage motors and transformers.

The utility model relates to a water-based acrylic resin paintand the manufacturing method. The basic ray materials comprise acrylic monomer, styrene monomer, initiator, cosolvent, and active solvent. The utility model is characterized in that the acrylic monomer comprises acrylic derivative with hydroxyl; the cosolvent is ether alcohol solvent; the active solvent is butyl carbonate ethylene derivative active solvent; the initiator is peroxide initiator; and the neutralizer is Amine neutralizer. The resin is manufactured through two-step process. In the first step, water-based acrylic resin prepolymer is manufactured and is then manufactured into resin latex through inner emulsification on the second step. The product is of long storage time and is of no added emulsifier. Under the room temperature, the product can cross-link with water-based isocyanate curing agent to form membrane. The utility model is of excellent membrane, good water resistance, anti-scrubbing property, chemical resistance and sullying resistance.

The invention provides a cobalt-based compounded catalyst and preparing method and application thereof, comprising a carrier component and a metal component; the carrier uses spherical powder Al2O3; the metal component comprises a first metal component Co; a second metal component is one of Ce, La and Zr; a third metal component is one of Pt, Ru, Rh and Re; the weight percentage of each metal component in the finished catalyst is as follows: the first metal component is 10-35%; the second metal component is 0.5-10%; the third metal component is 0.05-3%; and the rest is aluminum oxide carrier. The invention is cobalt-based compounded catalyst with the diesel oil and paraffin as the main products; and the catalyst is applied for slurry bubble column reactor or continuous-stirring reactor with simple preparing method, less selectivity in methane, high reacting activity and good selectivity in C5+.