A
medical device provided with at least a partial
surface coating of a
thermoplastic copolymer of
tetrafluoroethylene and perfluoroalkylvinylether that is free of cross-linking monomers and curing agents. The
fluoropolymer coating is preferably an amorphous
thermoplastic, is highly
inert and biocompatible, has elastomeric characteristics that provide desirable mechanical properties such as good flexibility and durability. These characteristics allow the
coating to be considered “functionally transparent” because it withstands mechanical deformations required for the
assembly, deployment, expansion, and placement of medical devices, without any
adverse effect on the mechanical and biological functionality of the coated device. Further, its inertness, derived from the perfluorocarbon structure, contributes to its functionally transparent nature. The
coating can be provided with various liquid or
solid additives, can be loaded with large quantities of additives including a wide range of therapeutic agents, and has excellent
drug elution characteristics when elutable additives are used. The desirable mechanical characteristics are surprising given the absence of cross-linking monomers and curing agents that would otherwise render such materials inadequately biocompatible. The perfluoroalkylvinylether may be perfluoromethylvinylether, perfluoroethylvinylether or perfluoropropylvinylether.