824 results about "Silver ion" patented technology

The invention relates to a polyurethane foam technology in the technical field of medical dressings, in particular to medical silver-containing porous polyurethane foam. The composite material comprises a foam matrix, the foam matrix adopts gradient layering design and comprises a matrix inner layer, a matrix middle layer and a matrix outer layer, the aperture of each layer is sequentially increased, the porosity is gradually increased layer by layer, the matrix inner layer is provided with randomly dispersed inner-layer hollow silver-loaded fibers capable of slowly releasing silver ions for bacteriostasis, the matrix middle layer is fixedly provided with pH response microcapsules, and the pH response microcapsules are fixed on the matrix outer layer. In an alkaline environment, antibacterial peptides are released for synergic antibiosis, and silver-loaded fibers in the outer layer of the matrix outer layer are arranged in the radial direction to form a flow guide channel and release silver ions. Through gradient layered design, different sterilization structures are added, the temperature-sensitive hydrogel layer covering the surface of the outer layer of the base body is matched, sterilization and seepage are managed through environmental changes, and the advantages of being excellent in antibacterial performance, high in seepage management capacity, intelligent in adjustment and the like are achieved.

The invention discloses silver powder with a high twin crystal ratio and a preparation method and application of the silver powder with the high twin crystal ratio. The preparation method comprises the following steps that S1, a carboxylic acid coordination agent is added into a silver source solution, and a silver precursor solution is obtained; sequentially adding a dispersing agent and an initiator into the reducing agent solution to obtain a reaction base solution; s2, a silver precursor solution is added into the reaction base solution for an oxidation-reduction reaction, then curing is conducted, and mixed mother liquor is obtained; s3, the mixed mother liquor is filtered, washed, dispersed and dried, and then the silver powder with the high twin crystal proportion is obtained; the initiator comprises one or more of sulfate, carbonate and nitrate; through the synergistic effect of the initiator and the carboxylic acid coordination agent, the silver ion release rate and the crystal nucleus preferential growth direction are regulated and controlled, the rapid feeding and curing technology is combined, the low supersaturation environment is constructed, the silver powder is induced to grow in the specific direction, and the twin crystal proportion is remarkably increased.

The invention relates to the technical field of material detection, in particular to a silver coating adhesive force detection method based on multi-frequency impedance imaging, which comprises the following steps: applying a dual-mode multi-frequency excitation signal to the surface of a silver coating through an attached microelectrode array, synchronously acquiring voltage-current response data, and generating a dual-mode multi-frequency impedance original data set; performing time-varying impedance phase-locked separation on the dual-mode multi-frequency impedance original data set, extracting a dynamic impedance component of a coating-matrix interface region, and reconstructing a three-dimensional sub-interface impedance distribution diagram; and outputting an adhesive force quantized value through an oscillation frequency-adhesive force conversion model according to the spatial oscillation frequency characteristics of the impedance phase in the three-dimensional sub-interface impedance distribution diagram. According to the invention, a double-phase-locked loop system is adopted to realize the time-varying component demodulation of the impedance response of the silver coating-matrix interface, the low-frequency dynamic impedance signal modulated by silver ion migration is effectively extracted, and the weak change of the interface bonding state is sensitively reflected.

The invention discloses a method for biologically leaching a retired ternary lithium battery positive electrode material under the catalysis of silver ions, which comprises the following steps of: (1) discharging, roasting, disassembling and grinding a retired ternary lithium battery to obtain ternary lithium battery positive electrode material powder; (2), Acidithiobacillus ferrooxidans is inoculated into the culture medium, and when the redox potential in a culture system is larger than or equal to 600 mV, a bacterial culture solution is obtained; and (3) adding the waste ternary lithium battery positive electrode powder into a bacterial culture solution, then adding a silver nitrate solution for leaching, and culturing for 3-7 days to obtain a biological leaching solution. According to the method, the biological leaching rate of metal is increased through silver ions, operation is easy and convenient to implement, the catalyst is simple and easy to obtain, the production cost is low, and environmental pollution is small, and the method has good application prospects.

The invention discloses a preparation method of a sandwich structure immunosensor based on surface enhanced Raman scattering and application of the sandwich structure immunosensor to detection of an anti-phospholipase A2 receptor antibody, and is characterized by comprising the following steps: sputtering silver ions on a cotton swab / ZIF-67 prepared by an in-situ growth method by adopting an ion sputtering method to obtain a cotton swab / ZIF-67 / Ag NPs composite material; the preparation method comprises the following steps: preparing an antigen solution, then adding the antigen solution into the antigen solution to obtain an immune substrate, adding a methylene blue aqueous solution into a silver nanoparticle solution for reaction, then connecting an anti-human PLA2R IgG antibody to obtain an immune probe, and finally dropwise adding a phosphate buffer solution containing an antibody to be detected onto the immune substrate, and dropwise adding the immune probe solution to the immune substrate adsorbed with the antibody to be detected to obtain the sandwich structure immunosensor based on surface enhanced Raman scattering. The method has the advantages of high sensitivity, good selectivity and strong stability.

The invention provides high-filling silver powder and a preparation method thereof, and belongs to the field of metal powder.The preparation method comprises the steps that a nano-silver solution is prepared, a dispersing agent and a first reducing agent are mixed to obtain a mixed solution, the nano-silver solution and the mixed solution are mixed in a constant-temperature stirring state to obtain a base solution, a second reducing agent solution and a silver nitrate solution are prepared respectively, and the high-filling silver powder is prepared. And under the constant-temperature stirring state, the second reducing agent solution and the silver nitrate solution are synchronously added into the base solution, a silver powder solution is obtained through reaction, the silver powder solution is subjected to washing, solid-liquid separation, drying and depolymerization shaping treatment, and the high-filling silver powder is obtained. Controllable preparation of the large-size sphericity silver powder is achieved by controlling the particle size and the adding amount of the nano-silver, regulating and controlling heterogeneous nucleation and growth sites of silver ions and inhibiting formation of multistage dendritic crystals, surface charges and steric hindrance effects of silver particles are optimized through the surface adsorption effect of the dispersing agent, the agglomeration phenomenon of the silver powder in the growth process is reduced, and the silver powder is prepared. And meanwhile, the silver powder is endowed with excellent flowability.

The invention relates to the technical field of food packaging, and discloses a composite preservative film as well as a preparation method and application thereof. The composite preservative film comprises a pectin film layer and a chitosan film layer which are arranged up and down, the pectin film layer contains an additive, the chitosan film layer contains lignin, and the additive is anthocyanin and / or an anthocyanin silver ion compound. The method comprises the following steps that S1, under the condition that a solvent exists, pectin and an additive are mixed I, then a pectin film layer is prepared through a tape casting method, and the additive is anthocyanin and / or an anthocyanin silver ion compound; in the presence of a solvent, chitosan and lignin are mixed II, and a chitosan film layer is prepared through a tape casting method; and S2, compounding the pectin film layer and the chitosan film layer to prepare the composite preservative film. The composite preservative film has antibacterial activity on various food spoilage bacteria and is high in oxidation resistance.

The invention relates to a metallized microbubble and a preparation method thereof, a construction method of a multifunctional composite probe, and a rapid bacterium capturing and sterilizing method, and belongs to the technical field of functional material preparation. The method aims at solving the technical problems that in the prior art, a metal coating on the surface of the hollow glass microbubble is not uniform, combination is not firm, and stability is poor. According to the technical scheme, the method is characterized by comprising the following steps: mixing surface-activated hollow glass microbubbles with a polyethyleneimine solution for reaction, and washing and drying to obtain polyethyleneimine-coated hollow glass microbubbles; then reacting with a single-stranded DNA buffer solution to obtain an intermediate product loaded with DNA; then introducing a silver nitrate solution to load silver ions on the surface of the compound; and finally, reducing through a sodium borohydride solution to prepare the metallized microbubbles. The metalized microbubbles prepared by the method can be used for constructing a multifunctional composite probe to realize efficient capture and synergistic antibiosis of targets such as bacteria.

The invention provides a preparation method and application of coating enhanced nano silver powder. The preparation method comprises the following steps: S1, preparing nano silver by taking silver nitrate as a silver source and polyethyleneimine as a reducing agent; s2, carrying out coating modification on the nano-silver by adopting aniline and ammonium persulfate under an acidic condition; s3, modifying the polyaniline coated nano-silver by adopting chloroacetic acid to obtain chloroacetic acid modified polyaniline coated nano-silver; s4, preparing a modified graphene oxide dispersion liquid; s5, partially reducing the graphene oxide; s6, partially reduced graphene oxide is adopted to load the chloroacetic acid modified polyaniline coated nano-silver, polyaniline coating and reduced graphene oxide compounding are carried out, and the dispersity and stability of nano-silver particles are effectively improved. The oxidation state of polyaniline promotes the release of silver ions through an electron transfer effect, so that the antibacterial effect is enhanced; and the partially reduced graphene oxide synergistically accelerates the release of silver ions, so that the antibacterial property is further improved.

The invention discloses an AgVO material with modified vanadium dioxide doped with silver ions, a preparation method of the AgVO material and application of the AgVO material in an aqueous zinc ion battery. The silver ion doped modified vanadium dioxide AgVO material is prepared by the following steps: firstly, enabling vanadium pentoxide and anhydrous oxalic acid to react in water to obtain a clear dark blue solution; and then carrying out hydrothermal reaction on the dark blue solution and silver nitrate at 175-185 DEG C to obtain the silver vanadium oxide composite material with a nanofiber bundle microstructure, wherein the silver vanadium oxide composite material is formed by doping silver ions on the surface and inside of a VO2 material. The silver ion doped modified vanadium dioxide AgVO material provided by the invention has a nanofiber bundle microstructure, and an aqueous zinc ion battery taking the silver ion doped modified vanadium dioxide AgVO material as a positive electrode active material has excellent capacity, cycling stability and rate capability and excellent electrochemical performance.

The invention provides an automobile lining material with sterilization and peculiar smell removal functions and a preparation method of the automobile lining material. The material for the automobile lining comprises a surface layer, a functional layer and a bottom layer which are sequentially arranged, wherein the functional layer is obtained by performing surface treatment on a fabric through an MOF-lysozyme material. Silver-based ZIF is formed by silver ions and dimethylimidazole, the characteristics of large specific surface area, adjustable aperture and high crystallinity of a traditional MOF material are reserved, and the silver-based ZIF has a certain antibacterial effect due to the silver ions, so that the antibacterial characteristic of a functional layer is enhanced; as the silver-based ZIF has the characteristics of large specific surface area and large aperture, more lysozyme can be covalently grafted, and the silver-based ZIF still has excellent broad-spectrum antibacterial performance; the silver-based ZIF material and the lysozyme synergistically enhance the bactericidal ability of the functional layer, so that the effects of long-acting sterilization, good antibacterial effect and peculiar smell elimination are achieved, the air quality in a vehicle is further improved, and a healthier and fresher riding environment is provided for passengers.

The invention belongs to the technical field of metal powder materials, and particularly relates to a preparation and surface modification method of silver-coated copper powder. Comprising the following steps that copper powder activated through a mixed acid solution and a dispersing agent are dissolved in ethyl alcohol, and copper powder turbid liquid is obtained; dropwise adding the silver complexing solution into the copper powder turbid liquid under the condition of water bath heating for reaction to obtain silver-coated copper powder turbid liquid; then, a reducing agent solution is dropwise added into the silver-coated copper powder turbid liquid, silver ions in the solution are further reduced, solid-liquid separation, washing and drying are conducted, and primary silver-coated copper powder is obtained; and finally, the silver-coated copper powder is subjected to surface modification, and the dispersity of the silver-coated copper powder is improved. The preparation method of the silver-coated copper powder provided by the invention is simple in process, and in the chemical oxidation reduction process, the prepared silver-coated copper powder is compact in silver coating, complete in coating, low in resistivity and good in oxidation resistance by regulating and controlling the concentration of silver ions and the complexing agent, the reaction temperature, the type of the dispersing agent, the dripping rate and the type of the surface modifier.

The invention discloses a paper-based composite film, which adopts a four-layer structural design, and the outer layer is an ultraviolet shielding layer formed by coating TiO2 with lignin; the transition layer is composed of 32-64 PLA / PBAT alternating microlayers, and the multiple alternating transition layers form a zigzag gas barrier path; ag-coated ZIF-8 nanoparticles are loaded on the paper base layer, so that long-acting antibiosis is realized by slowly releasing silver ions; and the inner layer adopts a PPC / PBS blend to support the heat sealing layer with adjustable heat sealing strength. According to the preparation process, a gradient micro-layer structure is constructed through a multi-runner co-extrusion die head and a layer multiplier, silver ions are loaded to ZIF-8 through an ultrasonic-vacuum impregnation process, the hydroxyl density of the surface of the paper base layer is improved through plasma treatment, good interlayer strength is achieved, ester bond crosslinking is induced in a pre-irradiation mode, and the product is prepared. The paper-based composite film has ultraviolet shielding, gradient blocking, slow-release antibacterial and controllable heat sealing performance, the interface bonding strength of a traditional paper-based composite film is greatly improved, all components are biodegradable, and the paper-based composite film is suitable for packaging of food, medicine and the like.

The invention discloses a silver particle modified and carbon coated lithium manganese iron phosphate positive electrode material and a preparation method thereof, and relates to the technical field of materials.The preparation method comprises the steps that a lithium source, an iron source, a manganese source and a phosphorus source are mixed and dissolved, and a mixed solution is obtained; adding a silver ion solution into the mixed solution, and carrying out a first hydrothermal reaction to obtain a reaction solution; mixing the reaction liquid with a carbon source and a reducing agent, carrying out a second hydrothermal reaction, and separating a solid phase to obtain a precursor; and sintering the precursor to obtain the lithium iron manganese phosphate positive electrode material. In the hydrothermal reaction stage, silver ions can inhibit rapid growth of high-energy crystal faces, and finally more high-energy crystal faces are exposed. And in the sintering stage, silver ions are reduced into simple substances to modify the carbon layer, a carbon-metal composite conductive network is formed, and the conductivity of the carbon layer is improved. The preparation method is simple and convenient to operate, can quickly and efficiently form the nanoscale lithium manganese iron phosphate positive electrode material with relatively good electrical properties and [001] crystal face orientation, and has a relatively good application prospect.

The invention belongs to the technical field of metal surface treatment, and discloses a high-uniformity metal surface silver plating process and a corrosion-resistant treatment method thereof.The high-uniformity metal surface silver plating process comprises the following steps that firstly, pretreatment is conducted; step 2, activating treatment; step 3, pre-plating a bottom layer; step 4, electrosilvering; step 5, post-processing; according to the method, pre-plating of the bottom layer and electroplating of silver are combined, a layer of thin nickel or copper is pre-plated firstly, and then electroplating of silver is performed, so that the binding force and uniformity of the silver plating layer are effectively improved, and in the electroplating process, the mode of stirring and circulating the electroplating liquid is adopted, so that silver ions in the electroplating liquid are uniformly distributed, and the uniformity of the plating layer is improved; and a thin aluminum oxide protective film is deposited on the surface of the silver plating layer by adopting a chemical vapor deposition technology, so that the corrosion resistance of the silver plating layer is further improved.

The invention relates to the technical field of titration detection in analytical chemistry, in particular to a thymol phenolphthalein-TBPE composite indicated cyanide high-precision detection method which comprises the following steps: step 1, after a water sample to be detected is distilled and separated, adjusting the pH value of distillate to a strong alkaline environment required by thymol phenolphthalein color development; 2, adding a composite indicator containing thymol phenolphthalein and tetrabromo phenolphthalein ethyl ester, wherein the mass ratio of the two components in the composite indicator is determined through a color change sensitivity optimization experiment; step 3, titrating with a silver nitrate solution, and judging an end point according to three-order color mutation: the initial state is light yellow, the intermediate state is green, and the end point state is purple red; and 4, adding an auxiliary masking agent before titration, and blocking the reaction between the auxiliary masking agent and silver ions by preferentially complexing interference ions. By optimizing the ratio of the composite indicator and using the masking agent, interference of other substances can be effectively prevented, and accurate detection of cyanide is ensured.

The invention discloses a method for recovering precious metal from refining wastewater, and relates to the technical field of wastewater resourceful treatment. Comprising the following steps: adding a porous carbon-based composite material into the acidic silver-containing refining wastewater, and stirring for adsorption to obtain an adsorption solution; the porous carbon-based composite material adsorbing the silver ions is recycled in a filtering or centrifugal separation mode; the porous carbon-based composite material adsorbing the silver ions makes contact with a desorption agent, desorption treatment is conducted, and a regenerated porous carbon-based composite material and a silver-containing desorption solution are obtained through separation; and a reducing agent is added into the silver-containing desorption solution, and silver ions are reduced into elemental silver to be recycled. The precious metal silver in the refining wastewater is recovered by adopting an adsorption method, and the recovery rate of the silver is relatively high.

The present invention discloses a tellurium-lead-lithium oxide glass powder for BC cell N-region conductive paste and its preparation method, belonging to the field of photovoltaic silver paste. The glass powder adopts components with high Pb, Te, and Li: aTeO2 - bPbO - cLi2O - dBi2O3 - eWO3 - fZnO - gSiO2 - hNa2O; where a + b + c + d + e + f + g + h = 1, 0.2 < a < 0.4, 0.1 < b < 0.4, 0.1 < c < 0.25, 0 < d < 0.1, 0 < e < 0.1, 0 < f < 0.1, 0 < g < 0.1, 0 < h < 0.05, and a + b > 0.5, and the ratio of c to h is (3 - 10):1. By controlling the specific Pb, Te, and Li contents and the specific Li / Na ratio in the present invention, a strong corrosion effect on the poly layer of the cell is achieved, enabling more silver ions dissolved in the glass liquid to recrystallize on the surface of the silicon wafer, thereby achieving good ohmic contact.

The invention discloses silver-coated copper particles, a preparation method thereof and application of the silver-coated copper particles in sintering slurry. The invention belongs to the field of sintered materials. The problem that in the prior art, the sintering temperature of high-temperature welding flux is high is solved. According to the silver-coated copper particles, a multi-step chemical synthesis method is adopted, firstly, silver-coated copper particle suspension is prepared, and then a silver complexing solution, a second chelating agent solution and a complexing agent solution are used for regulating and controlling the release and reduction rate difference of silver ions, so that gradient structure evolution of a silver layer from a compact structure to a porous structure is achieved; the surfaces of the silver-coated copper particles have multistage pore structures, so that the contact resistance among the particles can be effectively reduced, the sintering initial temperature is effectively reduced, the problem of poor oxidation performance of the copper particles is solved, the use amount of silver is reduced, the manufacturing cost is reduced, the ion migration path length is increased, and the electromigration life is prolonged; the prepared silver-coated copper particles greatly meet the requirements of the current electronic packaging field for novel welding materials, and have remarkable social benefits and economic benefits.

The invention discloses an antibacterial polyolefin composite pipe and a preparation method thereof, and belongs to the technical field of polymer pipes. The antibacterial polyolefin composite pipe comprises an inner layer and an outer layer, wherein the inner layer comprises the following components in parts by mass: 88-95 parts of polypropylene random copolymer, 3-6 parts of an antibacterial agent, 3-6 parts of a compatilizer and 0.1-1 part of an antioxidant; the antibacterial agent comprises silver ions and an antibacterial carrier, and the antibacterial carrier comprises sulfonated graphene oxide and a metal type imidazolate skeleton. The antibacterial agent is introduced into the inner layer, the antibacterial agent is compounded by an antibacterial carrier and silver ions, precipitation of silver can be effectively slowed down, the initial antibacterial effect of the polyolefin composite pipe is guaranteed, meanwhile, the antibacterial durability of the polyolefin composite pipe is improved, breeding of microorganisms such as bacteria can be effectively inhibited under the actual working condition of tap water, and the service life of the polyolefin composite pipe is prolonged. Therefore, a pipeline system of the polyolefin composite pipe is suitable for conveying drinking water for a long time.

The invention relates to a biosensor, an outer membrane of the biosensor and a preparation method and application of the outer membrane. The outer membrane of the biosensor comprises a polymer molecule with a thiourea group, and the polymer molecule is obtained by reacting and polymerizing a polymer containing a pyridine group and a monomer containing the thiourea group, that is, the thiourea group of the monomer is combined with the pyridine group in the polymer through the action of a chemical bond; the outer membrane of the biosensor is provided with a thiourea group, so that the thiourea group is utilized to generate an adsorption effect on silver ions, seepage of the silver ions in the reference electrode is prevented, the biocompatibility of the biosensor is improved, and the toxicity is reduced.

[Problem] To provide an organic-inorganic hybrid coating film which contains a large amount of silver ions, copper ions, and zinc ions, which has an excellent antibacterial / antiviral function, antifungal function, and a deodorization function, which makes it possible to reliably eliminate germs, various viruses, various mold fungi and which makes it possible to reliably remove unpleasant odors. [Solution] A organic-inorganic hybrid coating film that is a glass coating film which contains silicon oxide (SiO2) as a base, wherein in the coating film, glass particles are electrically conductive glass which includes at least one type of ion from among silver ions (Ag+), copper ions (Cu2+), and zinc ions (Zn2+), and the glass particles include glass which contains, as a base, at least one oxide from among vanadium oxide (V2O5), tungsten oxide (WO3), and molybdenum oxide (MoO3), and phosphorus oxide (P2O5).

The present invention provides a method for preparing silver-coated copper powder, which relates to the technical field of metal powder preparation. This preparation method directly prepares a copper core by chemical reduction method, then uses electroless plating method to grow a silver layer on its surface, and finally uses jet milling to improve the density of the powder. In the present invention, reducing agents with different reduction effects are added twice to reduce copper sulfate, which reduces the initial reaction rate, makes the whole reaction stable, and improves the sphericity of copper crystal nuclei. At the same time, sulfate radicals in the reaction system can form silver sulfate precipitation with silver ions in the subsequent reaction, further slowing down the reduction rate of silver ammonia complex ions and enabling the dense growth of the silver layer. At the same time, the unreacted completely glucose remaining in the reaction system can continue to reduce silver ammonia complex ions when silver ammonia solution is added dropwise later. By strictly controlling the growth rate of silver powder from crystal seeds to particles, the present invention reduces the structural defects caused by rapid growth and improves the performance of the final product.

A silver ion sterilizing liquid preparation system comprises a water inlet pretreatment system and a silver ion sterilizing liquid generation system, the water inlet pretreatment system comprises a water inlet channel, a water outlet channel and a filtering device, the water inlet channel is communicated with a raw water source, and the filtering device is communicated with the water inlet channel and the water outlet channel; filtering the raw water source to generate filtered water; the silver ion sterilizing liquid generating system is used for reacting with the filtered water to generate silver ion sterilizing liquid; the silver ion sterilizing liquid generating system comprises a silver ion generating water tank and a silver ion sterilizing liquid storage tank; an electrolysis device is arranged in the silver ion generation water tank and comprises a silver anode and a silver cathode, the silver ion generation water tank is communicated with the water outlet channel, the filtered water enters the silver ion generation water tank, and the silver anode and the silver cathode are subjected to an electrolytic reaction to generate a silver ion sterilizing solution; the silver ion sterilizing liquid storage tank is communicated with the silver ion generating water tank so as to store silver ion sterilizing liquid generated in the silver ion generating water tank, and the silver ion sterilizing liquid preparation system further comprises a control system; the control system is used for adjusting the water flow path and starting and stopping of the inlet water pretreatment system and the silver ion sterilization liquid generation system according to the liquid level and the electrolysis time.

This invention discloses a method for preparing ultrafine spherical silver-coated copper powder. A dense film is formed on the surface of copper powder using a specific activator, and this film can quickly form a complex with silver ions in the solution. At the same time, under the action of a specific reducing agent, silver ions are reduced to fine silver nanoparticles and adsorbed on the surface of copper powder. Silver ions in the solution form a dense silver layer on the surface of copper powder through two-dimensional nucleation, resulting in silver-coated copper powder with high density, high conductivity, and high oxidation resistance.

The invention provides a preparation method of silver-coated copper powder, and belongs to the technical field of metal powder treatment. The used copper particle suspension contains a complexing agent, so that the activity of the copper particles can be reduced, the reaction rate of reduction coating can be reduced when a silver-ammonia complexing solution is added, and a compact silver layer slowly and uniformly grows on the surface of each copper particle; the reduction of the activity of the copper particles slows down the replacement reaction of silver ions and copper, and the situation that the coating surface is rough and loose due to the generation of overlarge silver particles is avoided; the silver grows slowly and compactly, so that the surface of the coated silver layer is smooth and compact on the basis of lower usage amount of the silver source; the preparation method is simple in process, low in silver content and low in production cost, and the coated silver layer is smooth and compact in surface.

The present invention discloses a method for preparing silver powder and a nanostructure on the surface of the silver powder. The preparation method comprises the following steps: (1) mixing micron silver powder, a nanosilver seed solution, an organic solvent, and a binder to form a mixture solution; preparing a complex silver ion solution and a reducing agent solution; wherein the binder is an organic acid containing a carbon-oxygen double bond and a hydroxyl group, and the complex silver ion solution is a silver ion solution containing a complexing agent, wherein the silver ions exist in a complexed state; (2) mixing the complex silver ion solution, the reducing agent solution, and the mixture solution to react, so that newly generated silver is formed on the surface of the micron silver powder and wraps the surface of the micron silver powder; (3) after the reaction is completed, separating and obtaining silver powder, washing, filtering, and drying to obtain a silver powder product. The present invention achieves a higher coverage rate of subsequent surface nanostructured silver powder by all-round coating of silver particles, thereby obtaining a silver powder product with high sintering activity.

The invention provides application of a silver modified AFX molecular sieve in xenon and krypton gas separation, and belongs to the technical field of gas separation. According to the invention, silver ions with electronegativity are introduced into AFX molecular sieve pores through ion exchange, selective adsorption of xenon is realized through the AFX topological molecular sieve subjected to Ag exchange so as to enrich xenon, and excellent separation of xenon and krypton is finally realized. The xenon and krypton adsorption isotherm of the silver modified AFX molecular sieve under the condition of 25 DEG C is tested, and the IAST (ideal adsorption solution theoretical value) of the molecular sieve is analyzed to be 36.5 through a static adsorption curve; according to the method disclosed by the invention, a dynamic penetration test is carried out under trace Xe and Kr concentrations by simulating the waste gas subjected to UNF post-treatment, and the dynamic capacity of Xe is calculated to be 104 mmol kg <-1 >, which is superior to that of other reported materials.

The invention relates to the technical field of food packaging, in particular to a bacteriostatic aluminum foil material for a meal box and a preparation method thereof. The material is subjected to aluminum foil surface activation, then is sequentially impregnated in a sol impregnation liquid and an outer layer coating liquid, is subjected to dip coating, and finally is subjected to ultraviolet curing to obtain a multi-layer composite structure. The middle layer is made of an aminated organic silicon material and is firmly combined with the aluminum base material and the outer layer resin through chemical bonds, so that the adhesive force of the coating is remarkably improved. The outer coating is added with a phenyl triazole modified layered double hydroxide loaded nano-silver antibacterial agent, so that slow release and efficient broad-spectrum antibacterial property of silver ions are realized, the thermal stability is improved, and reliable performance under a high-temperature condition is ensured. The multilayer design and multiple antibacterial mechanisms have a synergistic effect, the problems of poor antibacterial durability, insufficient adhesive force, low heat resistance and the like of a traditional lunch box aluminum foil material are effectively solved, meanwhile, food safety is considered, and the aluminum foil material is suitable for the field of modern high-requirement food packaging.

The invention belongs to the technical field of antibacterial agents, and particularly relates to a preparation method of a nano-zinc oxide composite silver ion antibacterial agent, which comprises the following steps: 1, synthesizing nano-zinc oxide by a sol-gel method; 2, loading silver ions to the sodium zirconium phosphate by adopting an ion exchange method to obtain silver-loaded sodium zirconium phosphate; and 3, compounding the nano-zinc oxide and the silver-loaded sodium zirconium phosphate by adopting a liquid phase method to obtain the nano-zinc oxide composite silver ion antibacterial agent. According to the invention, the antibacterial mechanisms of zinc oxide and silver ions are different, and a synergistic antibacterial mechanism exists when zinc oxide and silver ions are compounded, so that the obtained composite antibacterial agent has more excellent antibacterial performance.