The invention provides an
online analysis method of primary loop
boric acid, and belongs to the technical field of
boric acid detection. The method comprises the following steps: firstly, diluting a
water sample with demineralized water, dropwise adding a
methyl red indicator, and carrying out acid solution
titration; when acid solution
titration reaches a first end point,
mannitol and
phenolphthalein indicators are added for alkaline solution
titration, and when acid solution titration reaches a second end point, a C alkaline solution and a V alkaline solution are recorded; and finally, calculating the concentration of
boric acid according to the sampling amount V0 of the
water sample, the C alkali solution and the V alkali solution. The two indicators are respectively used in the two continuous titration processes, the indicator added for the first time can indicate the arrival of the first titration end point, and the indicator added for the second time does not interfere with the arrival of the second titration end point indicated by the indicator for the second time. According to the method, for judging the titration end point of
methyl red, the design of double
light source detection is adopted, and the titration end point of which the pH value is equal to 5.2 + / -0.2 is determined by calculating the
absorbance value of the double light sources.