4985 results about "Ammoniacal nitrogen" patented technology

Disclosed are: a catalyst which can exhibit an excellent catalytic activity and excellent durability for a long period in the wet oxidation treatment of waste water; a wet oxidation treatment method for waste water using the catalyst; and a novel method for treating waste water containing a nitrogenated compound, in which a catalyst to be used has a lower catalytic cost, the waste water containing the nitrogenated compound can be treated at high purification performance, and the high purification performance can be maintained. The catalyst for use in the treatment of waste water comprises an oxide of at least one element selected from the group consisting of iron, titanium, silicon, aluminum, zirconium and cerium as a component (A) and at least one element selected from the group consisting of silver, gold, platinum, palladium, rhodium, ruthenium and iridium as a component (B), wherein at least 70 mass% of the component (B) is present in a region positioned within 1000 [mu]m from the outer surface of the component (A) (i.e., the oxide), the component (B) has an average particle diameter of 0.5 to 20 nm, and the solid acid content in the component (A) (i.e., the oxide) is 0.20 mmol/g or more. The waste water treatment method uses a catalyst (a pre-catalyst) which is placed on an upstream side of the direction of the flow of the waste water and can convert the nitrogenated compound contained in the waste water into ammoniacal nitrogen in the presence of an oxidizing agent at a temperature of not lower than 100 DEG C and lower than 370 DEG C under a pressure at which the waste water can remain in a liquid state and a downstream-side catalyst (a post-catalyst) which is placed downstream of the direction of the flow of the waste water and can treat the waste water containing ammoniacal nitrogen.

The invention discloses a salt-tolerant microbial agent and a preparation method thereof. The microbial agent contains staphylococcus cohnii FSND-C, arthrobacter creatinolyticus FDN-1, flavobacterium mizutaii FDN-2, paracoccus denitrificans DN-3 and methylobacterium phyllosphaerae SDN-3. The microbial agent can achieve removal of ammonia nitrogen, total nitrogen and CODcr in the same reactor, has a good wastewater treatment effect, and can achieve short-cut nitrification and denitrification or simultaneous nitrification and denitrification while removing COD. Staphylococcus cohnii FSND-C can utilize various carbon sources, has certain salt tolerance, can be applied to the high-salinity wastewater treatment process, simultaneously can secrete a substance under environmental stimulus to enhance the flocculability of sludge, and further widens the application range of the microbial agent.

The invention belongs to the technical filed of agricultural microorganisms, particularly relating to separate and screen Pseudomonas stutzeri YZN-001 for degrading ammoniacal nitrogen, nitrate nitrogen and nitrous nitrogen in water body and application. The screened Pseudomonas stutzeri YZN-001 of the invention is preserved in China Center for Type Culture Collection (CCTCC), with the preservation number being CCTCC NO:M 209107. The strain can effectively degrade ammoniacal nitrogen, nitrate nitrogen and nitrous nitrogen in water body within the range of 20-37 DEG C, has no toxicity to chub, has good degradation function on ammoniacal nitrogen in water body at normal temperature, the microorganism of the invention is inoculated for 72 hours, the degrading ratios to ammoniacal nitrogen in domestic sewage and aquaculture wastewater are respectively up to 83.10% and 61.38%.

The invention relates to a device for ammonia nitrogen wastewater discharge reduction and ammonia nitrogen resource utilization and a method thereof, and belongs to the field of wastewater discharge reduction. The conventional steam blow-off method has high unit energy consumption (250-300 Kg steam/ton wastewater) in ammonia nitrogen wastewater treatment, thus resulting in very high ammonia nitrogen wastewater treatment cost. The inventive device comprises at least two stages of ammonia nitrogen stripping step and ammonia nitrogen reutilization step. The ammonia nitrogen wastewater to be treated is respectively fed into each stage of ammonia nitrogen stripping step, and the removal of ammonia nitrogen in wastewater is realized in ammonia nitrogen stripping tower and the resource utilization is realized in the ammonia nitrogen reutilization step. Except for the first stage of the ammonia nitrogen stripping tower requiring steam introduction, the steam required on other stages of ammonia nitrogen stripping tower is obtained by vaporization of a part of the tower bottom liquid in each tower by using the heat released via condensation of a part of steam in the upper stage tower and flash evaporation of the tower bottom liquid in the upper stage tower, so as to remarkably reduce steam consumption. The inventive device and method have the advantages of high ammonia nitrogen content wastewater treatment, low ammonia nitrogen content in wastewater after treatment, low steam consumption, and low treatment cost.

The invention discloses an advanced treatment system and method for high-concentration percolate in a comprehensive garbage disposal plant, belonging to the field of industrial waste water treatment. The system is formed by connecting a regulating tank, a coagulative precipitation tank, an upflow anaerobic sludge bed reaction tank, a primary anoxic and aerobic membrane bioreactor, advanced oxidation treatment equipment, a secondary anoxic and aerobic membrane bioreactor, nanofiltration membrane treatment equipment, an ozone contact tank and an active carbon filtering tower in sequence. According to the system, garbage percolate can be treated comprehensively, different pollutants in garbage percolate are treated in a classified way by combining physical, chemical and biological treatment,advanced treatment of garbage percolate is realized, and classified treatment for removing pollutants such as organic matters, heavy metals, ammonia, nitrogen and the like is performed, so that treated effluent strictly reaches the requirement of water pollution discharge degree limit in the Household Garbage Landfill Pollution Control Standard, the system runs stably for a long time, and treatment cost is lower than that of a secondary disc pipe reverse osmosis membrane process.

The invention discloses a novel compound microorganism living bacteria agent. The agent comprises probiotics such as pediococcus, saccharomyces, bacillus and the like, wherein the total bacterial quantity is above 107 colony-forming units (cfu)/gram. The invention further discloses a method for preparing the novel compound microorganism living bacteria agent and applications of the novel compound microorganism living bacteria agent in preparation of organic sewage purification additives, deodorization fly dispelling agents, degreasing agents, pipeline blockage removing agents, feed additives and microorganism disease prevention agents. The novel compound microorganism living bacteria agent has the comprehensive effects of high removal rates to ammonia nitrogen, total nitrogen and total phosphorus, small sludge residues, energy saving, environmental friendliness and the like and the characteristics of convenience in use, safety and quickness in function, no secondary pollution, benefits to ecological protection, low treatment cost, good comprehensive profit and the like.

The invention discloses a large-scaled culture method of high-concentration nitrosobacteria and application thereof. The method comprises the following steps of: (1) adding an enrichment culture solution with initial ammonia nitrogen mass concentration of 30-500mg/L in a reaction device with functions of stirring, heating and aeration; preparing activated sludge of a waste water treatment plant in activated sludge of 0.5-20% for primary inoculation to conduct the enrichment culture of the nitrosobacteria by 2-6d as a culture cycle, wherein extra ammonium salts and a growth promoter are added during the enrichment culture of the nitrosobacteria; (2) ending the culture when the concentration of NO2-N in the solution is accumulated to reach 70-95% of the concentration of total nitrogen; adding a flocculating agent for flocculation and sedimentation; and allowing to stand still to remove supernate, and then adding the enrichment culture solution to start the culture of the second cycle; and (3) continuously conducting 3-8 cycles of the enrichment culture to obtain the high-concentration nitrosobacteria. By adopting the nitrosobacteria to strengthen the bi-nitrification treatment of ammonia nitrogen contained waste water, the method has the advantages of high stress resistance, low cost and high efficiency and is suitable for the complicated treatment of ammonia nitrogen contained industrial waste water.

The invention discloses a enrichment method of nitrifying organism. The method adapts discontinuous activated sludge process by gradually improving ammonia nitrogen ph indicator in nutrient fluid to enrich. The main component of the enrichment nutrient fluid is inorganic salt comprising microelement Fe, Mg, Na, K and amortization liquor, in which inceptive concentration of NH(4)(+-N) is 100mg/L to 200mg/L, final concentration is 500mg/L to 1200mg/L and COD is less than or equal to 200mg/L. The method can restrain evidence the growth of sundry bacterium such as carbonizing bacterium, is propitious for nitrifying organism to become ascendency bacterium and resist more and more high ammonia nitrogen concentration, and finally disposing concentration of the ammonia nitrogen wasted water is up to 1200mg/L and high concentration ammonia nitrogen in wasted water can be reduce to less 10mg/L.

The invention discloses a device and a method for denitrification of single stage autotroph in low-cellulose nitrate (CN) high-ammonia nitrogen waste water. The device comprises a raw water tank, a water inlet pump, a reactor, a secondary sedimentation tank and a sludge reflux pump, wherein overcurrent holes are arranged in the water flow direction of the reactor in an up-and-down alternative form and connected with various grid chambers, an anoxic zone grid chamber is arranged at the front end of the reactor, and an aerobic zone grid chamber is arranged at the back end of the reactor; the anoxic zone grid chamber is provided with a stirrer and an agitator blade; the aerobic zone grid chamber is provided with the stirrer, the agitator blade, an aeration riser pipe and an intermediate perforated clapboard; and the aeration riser pipe is internally provided with an aeration head, and sponge filling material is filled below the intermediate perforated clapboard, wherein filling ratio is 30-50%. In the method, shortcut nitrification is achieved above the aerobic zone through low dissolved oxygen (DO is 0.5 <-1>mg/L) and free ammonia (FA) inhibition so that ammonia nitrogen is converted to nitrite nitrogen; and anoxicammoxidation biomembrane acts on the lower part of the aerobic zone, the nitrite nitrogen and ammonia nitrogen are converted to nitrogen, thereby achieving denitrification of autotroph. The method has the advantages of low oxygen consumption, less sludge output and no extra carbon source.

The invention relates to a process for leaching rare earth from ion-adsorption type rare earth ore without using ammonium salt. The process comprises the step of replacing ammonium salt by taking a mixture of calcium, magnesium and sodium salts as a leaching agent and taking non-ammonium salts, such as calcium hydroxide, magnesium hydrate or sodium hydroxide as a precipitator. According to the process disclosed by the invention, the ammonia nitrogen pollution problem in exploitation of ion-adsorption type rare earth is radically solved; environmental-friendly exploitation of the ion-adsorption type rare earth can be realized; the process disclosed by the invention has higher economic benefit and social benefit.

The invention concerns a way of synthesize stone using coal powder and its applying in removing nitrogen and phosphorus in the waste water. Get the coal powder as the material, add the material including aluminum, silicon, or fluorine which can saluted in the alkaline solution, after mixing, add metal alkaline solution and synthesize fei stone by water heating reaction, then change shape by metal salt aqua, we get the fei stone after separating solid and liquid. Change the fei stone to the grains and put them in the filtering bed, achieving to remove nitrogen and phosphorus. The invention solves the environment problem, economy the resource of nitrogen and phosphorus in the coal powder, no second pollution.

The invention relates to a biological denitrification method for salt-containing sewage, which comprises the following steps: adding a denitrification microbial inoculant into a biochemical sewage treatment system, and simultaneously starting the nitrification-denitrification biological denitrification treatment processes, wherein the sewage treatment temperature is 18-40 DEG C, the dissolved oxygen is 0.1-5 mg/L, and the pH value is 7.0-9.0. The denitrification microbial inoculant contains one or two of Staphylococcuscohnii FSDN-C, Arthrobactercreatinolyticus FDN-1 and Flavobacteriummizutaii FDN-2, and also contains one or two of Paracoccusdenitrificans DN-3 and Methylobacteriumphyllosphaerae SDN-3. The method provided by the invention can effectively treat high-salt-content sewage, enhances the adsorptivity and flocculence for sludge, has wide application range for wastewater quality and high impact resistance to salt-containing sewage, and obviously enhances the sewage treatment effect on the premise of removing pollutants, such as ammonia nitrogen, COD (chemical oxygen demand) and the like.

The invention discloses a biological disposing method of waste water through coupling the anaerobic ammonoxidation and methanation denitrification, which is characterized by the following: inoculating the particle sludge with methanation, denitrification and anaerobic ammonoxidation activity in the expansion grain sludge bed (EGSB); inoculating aerobic ammonoxidation bacteria in the biological aerating filter (BAF) or SHARON technique or SBR reactor; connecting the EGSB reactor and BAF or SHARON technique or SBR reactor; realizing the biological disposal of waste water through controlling pH value, temperature, dissolved oxygen, external reflow rate, load velocity, oxidizing reducing potential and organic COD density, ammonia nitrogen density.

The invention relates to a compound microecological preparation used to purify aquaculture water in the field of aquiculture, a preparation form and a preparation process thereof; the preparation is composed of photosynthetic bacterium, bacillus subtilis, denitrifying bacterium, coagulant aid and auxiliary components; the preparation form is composed of an inner layer and an outer layer, wherein, the outer layer comprises bacillus subtilis, denitrifying bacterium and coagulant aid, and the inner layer comprises solid photosynthetic bacterium particles. The invention breaks through the prior theory that people keeps using nitrite bacteria and nitrobacteria to solve the problem of the accumulation of ammonia nitrogen and nitrite in the aquaculture water in the control of aquaculture water, introduces an advanced SHARON theory in wastewater treatment, integrates the characteristics of the aquaculture water quality, purifies the aquaculture water with denitrifying bacteria strains as the main bacteria strains, can quickly and effectively reduce the content of NH3 and NO2- in the aquaculture water, is not inhibited by the concentration of the NO2-, and effectively reduces the oxygen consumption in the aquaculture water.

The invention provides complete equipment and process for processing coal tar wastewater, and belongs to the technical field of environmental conservation. The process comprises the following steps of: adopting different removal principles according to different physicochemical properties of heavy oil, light oil and emulsified oil; scientifically and orderly removing the heavy oil, light oil and emulsified oil through three sets of environmental conservation equipment such as a multi-stage oil separator, an oil-water separator and an air floating tank gradually; combining a micro electrolysis reactor with a five-section integrated oxidization device; and firstly destroying a benzene ring by microelectrolysis, and then strongly oxidizing various organic matters through an oxidant, so that the COD (chemical oxygen demand) and the chromaticity are greatly reduced. Ammonia nitrogen can be efficiently removed by a denitrification system; the denitrification system is low on requirements of pH value and temperature, and low in operation cost; the denitrification system is arranged behind the five-section integrated oxidization device; the reaction change of power of hydrogen is fully considered; and the complete equipment complies with the scientific principle, and can be used for reducing feeding of acid and alkali, and lowering the operation cost.

The present invention discloses a short-cut nitrification-denitrification microbial agent. The microbial agent contains Arthrobacter creatinolyticus FDN 1, Flavobacterium mizutaii FDN 2, Paracoccus denitrificars DN 3 and Methylobacterium phyllosphaerae SDN3. The preservation register numbers of the four strains respectively are CGMCC No.3657, CGMCC No.3659, CGMCC No.3658 and CGMCC No.3660. With the microbial agent, the ammonia nitrogen removing, the total nitrogen removing and the CODcr removing in the same reactor can be achieved, the wastewater treatment effect is good, and the microbial agent is especially suitable for the purification treatment of the wastewater containing the ammonia nitrogen so as to really achieve the short-cut nitrification-denitrification or simultaneous nitrification and denitrification.

The invention discloses a method for preparing an aerobiotic nitrifier immobilizing vector, and belongs to the field of water treatment. The method comprises the steps of: firstly, carrying out acid washing on thermally modified attapulgite; adsorbing the nitrifier using the nanometer grade attapulgite; carrying out rapid inclusion by using the mixture gel of polyvinyl alcohol (PVA) and sodium alginate (SA); dropping the mixture into a crosslinking agent to soak for 24 hours using a granulator to obtain an immobilized nitrifier pellet; and finally, repeatedly washing the immobilized nitrifier pellet for three times using normal saline to obtain a vector particle. By taking advantage of pretty large specific surface area and pretty strong adsorption performance of the modified attapulgite, an adsorption vector which is conductive to the growth and reproduction of the aerobiotic nitrifier is prepared; the modified attapulgite is capable of ammonia and nitrogen adsorption, and can increase the ammonia and nitrogen removal rate in water; the carrier particle composited from the modified attapulgite and a macromolecular material can improve the activity and ammonia and nitrogen removal capacity of denitrification microorganisms; and the repeated use rate of the carrier is high.

The invention discloses a method and a device for simultaneously carrying out wastewater treatment and power generation by using a photocatalysis associated microbial fuel cell technology. The device takes conductive glass coated with an n-type semiconductor photocatalyst film as an outside wall of a cathode chamber and takes conductive glass coated with an n-type semiconductor photocatalyst film as an outside wall of an anode chamber, a conductive filler respectively connected on the outside walls of the cathode chamber and the anode chamber is used as an electrode of a microbial fuel cell. The conductive filler is a carbon fiber rope for microbial growth. Denitrifying bacteria and nitrifying bacteria are respectively cultivated at the cathode and anode of the microbial fuel cell, and mainly used for the degradation of organic matters and the removal of ammonia nitrogen. Under the irradiation of ultraviolet light, electrons flow from the anode to the cathode, so that the anode has strong oxidability, and the cathode has strong reducibility. In the invention, the functions of microbial fuel cells and a photocatalysis technology are mutually associated, so that the wastewater treatment cost is low, and the generating capacity is large.

The invention provides a technology and a method for treating urban sewage by three-section short-cut nitrification/ anaerobic ammonia oxidation, and belongs to the technical field of biological treatment of sewage. A raw water tank, an organic substance removal sequencing batch reactor (SBR), a first regulating water tank, a short-cut nitrification SBR (provided with an on-line monitoring and feedback control system), a second regulating water tank and an autotrophic nitrogen removal up-flow anaerobic sludge bed/ blanket (UASB) reactor are sequentially connected in series in the technology; and the sludge is separated according to the sludge age, so that the contradiction between denitrification and phosphorus removal sludge age is solved. By applying the real-time control technology of the short-cut nitrification SBR to the autotrophic nitrogen removal technology, the problems that the half short-cut of low ammonia nitrogen short-cut nitrification in continuous flow is difficult to maintain, the concentration ratio of ammonia nitrogen to nitrous in the effluent is difficult to control and the like are solved. By successfully applying the anaerobic ammonia oxidation technology todeep denitrification treatment of the domestic sewage, urban sewage treatment with high efficiency and low energy consumption is realized.

The invention relates to a method of economically recycling phosphor from excess sludge. The method comprises the following steps: (1), pre-treating the excess sludge; (2), carrying out alkaline hydrolysis on the excess sludge, wherein the alkaline hydrolysis is carried out by a single-stage alkaline hydrolysis method or a two-stage alkaline hydrolysis method; measuring concentration of orthophosphate and ammonia nitrogen in liquid supernatant; and (3), adding magnesium salt aqueous liquor with a Mg/P molar ratio of 0.8-2, stirring and reacting for 10 minutes-120 minutes, gravitationally or centrifugally separating precipitates, naturally drying the precipitates to obtain a magnesium ammonium phosphate crude product. Organic substances remained in the liquid supernatant can be used for producing methane by anaerobic fermentation or supplementing a carbon source by a reflux wastewater treatment system, also can be used for supplementing alkalinity needed for an anaerobic unit, so that comprehensive utilization of excess sludge is facilitated. The method disclosed by the invention has the advantages that nutrient elements in the sludge are comprehensively utilized, process is simple, and phosphor can be recycled by only adding the magnesium salt; and meanwhile, ammonia nitrogen can be partly recycled without regulating pH, and the obtained magnesium ammonium phosphate crude product can be used for producing fertilizers.

The invention relates to the field of drinking water treatment, in particular to a reaction device for deep treatment of drinking water and a method for deep treatment of the drinking water by a water factory. In order to realize the goal of transforming the conventional drinking water treatment process into the deep treatment process, the reaction device and the method adopt the scheme that (1) a static mixer and a coagulation reaction pool are not changed; (2) a sedimentation pool is transformed into an ultrafiltration membrane pool; (3) a medium water pool and a lifting pump used for waterlifting are additionally arranged at the back end of the ultrafiltration membrane pool; (4) a main ozone oxidization pool is in additional arrangement; and (5) an original sand filter pool is transformed into a particular active carbon filter pool. The coagulation and the ultrafiltration are combined, particular colloid and macromolecular organic matters in the water are removed, difficult-to-degrade pollutants are damaged through ozone oxidization, in addition, the macromolecular organic matters are converted into middle and small molecular weight organic matters, and organic matters and pollutants such as ammonia nitrogen and the like in the water are further reduced through the absorption of particular active carbon and the biological degradation of microbes grown on the surface.