The invention discloses a polyimide woven cloth and a preparation method thereof. The materials of the polyimide woven cloth comprises 45-70% of polyimide fiber iron aramid wire, 10-25% of cashmere, 10-25% of wool, and 5-10% of other ingredients, wherein the other ingredients are at least one of the ingredients such as cotton, flax, tencel, modal, bamboo charcoal fiber, spun silk, silk, viscose rayon and polyester. The preparation method comprises the following steps of material synthesizing and choosing, flock dyeing, fiber mixing, fiber carding, doubling and twisting, panel knitting, finishing and the like. The polyimide woven cloth which is prepared by blending in different proportion has the advantages of being high in temperature resistance, strong in bursting resistance, fireproof, flame-retardant, ultraviolet-proof, soft, and anti-pilling. Compared with the conventional multi-function finishing fabrics, production technology and post-treatment technology are simplified greatly, and production efficiency is improved.