The present application relates to the field of shoe leather production, and particularly relates to a production process of
fluorine-free dynamic waterproof suede shoe leather. First, the suede
microfiber base leather is soaked in a composite biological
enzyme preparation to remove surface impurities and open the
fiber gap, and then is treated by
helium-
oxygen mixed gas normal pressure
plasma to build micro-pits and active groups on the
fiber surface. Subsequently, the base leather is sequentially soaked in waterproof agents containing various modified substances, and a two-stage gradient
temperature and pressure padding process is adopted to realize the gradient distribution and crosslinking of the waterproof agent from inside to outside. Finally, a three-stage temperature oscillation
drying is adopted, the crosslinking reaction is triggered in the medium temperature section, the
siloxane chain is induced to directional arrangement to form a stress buffer layer in the high temperature section combined with mechanical oscillation, and the finished product is obtained through low temperature
polishing and setting. The process completely avoids
fluorine-containing compounds, solves the problem of easy
cracking of traditional waterproof leather in dynamic bending, and maintains the softness of suede. The process is suitable for high-end shoe materials, outdoor equipment and other fields.