The invention relates to the technical field of PI
fiber function modification, and discloses a modified PI
fiber, a preparation method and a
polyimide film based on the modified PI
fiber, and specifically, the surface of the modified PI fiber is grafted with a
carbon nanotube /
carbon black hybrid conductive network through covalent bonds; the network is constructed by bridging a multifunctional connecting agent containing alkenyl, hydroxyl and a
quaternary ammonium salt functional group, the hydroxyl of the connecting agent and an acylating chlorination
carbon nanotube form an
ester bond, the
quaternary ammonium salt group electrostatically adsorbs
carbon black, and the residual alkenyl and sulfhydrylated PI fiber are subjected to a sulfhydryl-
alkene click reaction under the
initiation of
ultraviolet light to realize covalent
grafting. The modified fiber is used as a functional filler, water-soluble
polyamide acid is used as a film-forming matrix, and the flexible
composite film is prepared through vacuum
filtration and thermal imidization. The
electromagnetic shielding effectiveness of the thin film in the
X wave band reaches 37dB or above, and the tensile strength is gt; the elongation at break is gt; the cable has the advantages of high shielding performance, excellent
mechanical strength and excellent flexibility.