4495 results about "Surface energy" patented technology

A bone adhesive application device has a pliable structure with an application surface upon which a bone adhesive may be applied. The application surface has a surface energy substantially equal to or less than a surface energy of the bone adhesive to reduce adhesion between the bone adhesive and the bone adhesive application device. The bone adhesive application device may be included in a kit for repairing bone defects having a bone adhesive formed from a reactive biocompatible polyurethane material. The bone adhesive may be applied to a bone defect by positioning the pliable structure over at least a portion of the bone defect, delivering the bone adhesive to the bone defect and removing the pliable structure from the bone adhesive.

Embodiments of the invention generally provide a method for depositing films or layers using a UV source during a photoexcitation process. The films are deposited on a substrate and usually contain a material, such as silicon (e.g., epitaxy, crystalline, microcrystalline, polysilicon, or amorphous), silicon oxide, silicon nitride, silicon oxynitride, or other silicon-containing materials. The photoexcitation process may expose the substrate and / or gases to an energy beam or flux prior to, during, or subsequent a deposition process. Therefore, the photoexcitation process may be used to pre-treat or post-treat the substrate or material, to deposit the silicon-containing material, and to enhance chamber cleaning processes. Attributes of the method that are enhanced by the UV photoexcitation process include removing native oxides prior to deposition, removing volatiles from deposited films, increasing surface energy of the deposited films, increasing the excitation energy of precursors, reducing deposition time, and reducing deposition temperature.

Embodiments of the invention generally provide a method for depositing films or layers using a UV source during a photoexcitation process. The films are deposited on a substrate and usually contain a material, such as silicon (e.g., epitaxy, crystalline, microcrystalline, polysilicon, or amorphous), silicon oxide, silicon nitride, silicon oxynitride, or other silicon-containing materials. The photoexcitation process may expose the substrate and / or gases to an energy beam or flux prior to, during, or subsequent a deposition process. Therefore, the photoexcitation process may be used to pre-treat or post-treat the substrate or material, to deposit the silicon-containing material, and to enhance chamber cleaning processes. Attributes of the method that are enhanced by the UV photoexcitation process include removing native oxides prior to deposition, removing volatiles from deposited films, increasing surface energy of the deposited films, increasing the excitation energy of precursors, reducing deposition time, and reducing deposition temperature.

Acrylic-based pressure sensitive adhesives are modified with a telechelic hydrocarbon oligomer. The oligomer comprises a hydrocarbon polymer chain or backbone and a functional end group, e.g., an oligomer prepared from a mono hydroxyl polybutadiene polymer and toluene diisocyanate. The oligomer attaches to the acrylic backbone of the polymer as a pendant group and in a preferred embodiment, the oligomer is mixed with the PSA shortly before the PSA is coated.

Embodiments of the invention generally provide a method for depositing films or layers using a UV source during a photoexcitation process. The films are deposited on a substrate and usually contain a material, such as silicon (e.g., epitaxy, crystalline, microcrystalline, polysilicon, or amorphous), silicon oxide, silicon nitride, silicon oxynitride, or other silicon-containing materials. The photoexcitation process may expose the substrate and / or gases to an energy beam or flux prior to, during, or subsequent a deposition process. Therefore, the photoexcitation process may be used to pre-treat or post-treat the substrate or material, to deposit the silicon-containing material, and to enhance chamber cleaning processes. Attributes of the method that are enhanced by the UV photoexcitation process include removing native oxides prior to deposition, removing volatiles from deposited films, increasing surface energy of the deposited films, increasing the excitation energy of precursors, reducing deposition time, and reducing deposition temperature.

A fiber velvet comprising nano-size fibers or nanofibrils attached to micro-size fibers is disclosed. Methods of manufacturing the velvet as well as various uses of the velvet are also described. For example, the fiber velvet can be used as a thermal interface or as an adhesive material. The nanofibrils may be attached to a flat base or membrane, or may be attached to the tip portions of the micro-size or larger diameter fibers. Various attributes of the micro-size fibers and of the nano-size fibers, for example, geometry (e.g. size, length, packing density) material type (e.g. carbon, metal, polymer, or ceramic) and properties (e.g. conductivity, modulus, surface energy, dielectric constant, surface roughness) can be selected depending on the desired attributes of the fiber velvet. The nanofibrils have a diameter of less than about 1 micron, and may advantageously be formed from single walled and / or multi-walled carbon nanotubes.

A method of and device for controlled printing using liquid embossing techniques is disclosed. In accordance with the embodiments of the invention a stamp comprises a differentiated embossing surface with protruding and recessed surfaces to enhance the ability of the stamp to selectively displace liquid ink from a print surface and / or remove solvent from the liquid in a soft curing process. A stamp with differentiated surfaces is fabricated by selectively coating, or otherwise treating the protruding features, the recessed features, or a combination thereof, such that the surface energies and / or wettability of the protruding surfaces and the recessed surfaces are differentiated.

Embodiments of the invention generally provide a method for depositing films or layers using a UV source during a photoexcitation process. The films are deposited on a substrate and usually contain a material, such as silicon (e.g., epitaxy, crystalline, microcrystalline, polysilicon, or amorphous), silicon oxide, silicon nitride, silicon oxynitride, or other silicon-containing materials. The photoexcitation process may expose the substrate and / or gases to an energy beam or flux prior to, during, or subsequent a deposition process. Therefore, the photoexcitation process may be used to pre-treat or post-treat the substrate or material, to deposit the silicon-containing material, and to enhance chamber cleaning processes. Attributes of the method that are enhanced by the UV photoexcitation process include removing native oxides prior to deposition, removing volatiles from deposited films, increasing surface energy of the deposited films, increasing the excitation energy of precursors, reducing deposition time, and reducing deposition temperature.

A thermally conductive interface, which may be in the form of a double-sided, pressure sensitive adhesive tape, disposable intermediate a heat-generating source having a first heat transfer surface formed of a first material having a low surface energy, and a thermal dissipation member having a second heat transfer surface which is formed of a second material having a surface energy substantially higher than the surface energy of the first material, and which is disposable opposite the first heat transfer surface of the heat-generating source in a spaced-apart, heat transfer adjacency therewith. The interface includes a first pressure sensitive adhesive (PSA) surface which is bondable under pressure to at least a portion of the first heat transfer surface of the heat-generating source, and an opposing second pressure sensitive adhesive (PSA) surface bondable under pressure to at least a portion of the second heat transfer surface of the heat-generating source. The first PSA surface is presented from a layer of a thermally-conductive, first pressure sensitive adhesive composition, preferably silicone-based, having an affinity to the first heat transfer surface of the heat generating source. In turn, the second PSA surface is presented from a layer of a second pressure sensitive adhesive composition, preferably acrylic-based, different from the first composition and having an affinity to the second heat transfer surface of the thermal dissipation member. The interface is particularly adapted for bonding a plastic packaged electronic component to a metal heat sink.

A method for hydrophilifying the surface of a substrate by taking advantage of photocatalytic action. The substrate has a photocatalytic titania coating (10). The surface of the photocatalytic coating (10) bears the solid acid that increases a hydrogen bond component ( gamma Sh) in the surface energy in the solid / gas interface of the coating. Photoexcitation of the photocatalyst enhances the hydrogen bond component ( gamma Sh) in the surface energy of the photocatalytic coating (10), accelerating the physical adsorption of molecules of water in the atmosphere through a hydrogen bond (16) onto hydrogen atoms in a terminal OH group (12), bonded to a titanium atom, and a bridge OH group (14) on the surface of the coating. This results in the formation of a high density, physically adsorbed water layer (18) on the surface of the photocatalytic coating (10), thus permitting the surface of the substrate to be easily hydrophilified. The method is applicable to antifogging, antifouling, selfcleaning and cleaning of articles.

The present invention is directed to a template having a body including a surface with first and second regions. The first region has first wetting characteristics for a given material and the second region has second wetting characteristics for the given material. The first wetting characteristics differ from the second wetting characteristics. Specifically, the first region is formed from a surface treatment layer with a first surface energy to provide the first wetting characteristics. The second region is exposed portions of the body, typically quartz of fused silica, having a second surface energy associated therewith. The second surface energy is greater than the first surface energy to provide the second region with the second wetting characteristics.

Invention performs an assay to determine presence or quantity of specific analyte in fluid sample. Representative device has two separate flow paths established sequentially in device with a single user activation step. First flow path delivers sample, and conjugate soluble binding reagents to solid phase. If analyte is present, an analyte:conjugate complex is formed and immobilized. Sample volume delivered by first path determined by absorbent capacity of solid phase, and not by amount of sample added to device. User need not measure sample volume. Sample / conjugate mixture is prevented from entering second flow path because capillary and surface energy of second flow path prevent it from being wetted by this mixture. Second flow path allows wash reagent to remove unbound conjugate and sample from solid phase to the absorbant, and optionally deliver detection reagents. Adaptable for many formats including, sandwich immunoassays, colloidal gold, sol particle, heterogeneous generic capture, and competitive assays.

According to an aspect of the present invention, long term medical articles are provided which include the following: (a) first and second body contacting (e.g., tissue and / or body-fluid contacting) porous polymeric layers; (b) a polymeric barrier layer disposed between the first and second porous polymer layers; and (c) a reinforcement element. According to another aspect of the present invention, tubular medical articles for long term implantation are provided, which comprise: (a) a reinforcement element; (b) a blood contacting porous polymeric layer having a surface energy ranging between 20 and 30 dynes / cm disposed over an inner surface of the reinforcement element; and (c) an additional porous polymeric layer formed over an outer surface of the reinforcement element.

A biosensor for analyzing specific components in an introduced liquid sample by reaction of the liquid sample with a reagent comprises a cavity into which the liquid sample is introduced, an air hole communicating from the cavity to outside, and a water repellent part having a water repellency at 43 mN / m or less in surface free energy and provided to at least a portion around the outlet of the air hole. By the water repellent part around the air hole, the liquid sample can be prevented from flowing out through the air hole, thereby achieving a high-accuracy measurement.

The invention belongs to the technical field of a new chemical material, and in particular relates to a high-durability super-hydrophobic self-cleaning coating material and a preparation method thereof. The coating material of the invention is prepared by curing and drying nanoparticles with photo-catalytic activity, a low-surface-free-energy polymer and a cross-linking agent at the room temperature, wherein the low-surface-free-energy polymer consists of one or more of polysiloxane fluoride, dimethyl silicone polymer and polyphenylene methyl siloxane, which contain active groups, such as hydroxyl alkoxy group, carbon-carbon double bond, silanol group, siloxy group, and the like; the cross-linking agent is hydrogen-containing silicone oil or aminosilane; and the mass content of the photo-catalytic nanoparticles in the coating ranges from 10 to 60 percent. The coating is formed into a micro-nanostructure by nanoparticle self-organization; a super-hydrophobic self-cleaning coating with lotus effect is prepared from the coating and a cross-linked filming matrix with low surface energy; the persistence of a lotus-shaped super-hydrophobic characteristic of the coating is realized by using the photo-catalytic decomposition characteristic of an organic pollutant for the nanoparticles; and thus the material is suitable for large-area construction and has high weathering resistance andprominent self-cleaning characteristic.

Pressure-sensitive adhesives are prepared from (meth)acrylate esters of 2-alkyl alkanols. The adhesives are characterized by exhibiting an overall balance of adhesive and cohesive characteristics and exceptional adhesion to low surface energy substrates.

The invention discloses a super hydrophobic anti-icing coating and a preparation method thereof, and is realized by preparing a fluorine contained acrylic resin and combining the fluorine contained acrylic resin with organosilicon resin and nano particles. In a scheme of the invention, the fluorine contained acrylic resin has small surface energy and strong hydrophobicity. The organosilicon resin utilizes effect of -CH3 on a surface thereof and small polarity to substantially reduce contact angle hysteresis. The fluorine contained acrylic resin can crosslink and solidify with the nano particles and active groups in the organosilicon resin to form a composite network. The invention can overcome defects of complex technology, high costs and unsuitability for large scale usage of an ordinary method for preparing a super hydrophobic coating; and the prepared coating can realize super hydrophobic anti-icing effect through a regular spraying method.

Disclosed is a process for modification of a substrate so as to form an ultrahydrophobic surface on the substrate. Also disclosed are surface-modified substrates that can be formed according to the disclosed processes. The process includes attachment of a multitude of nano- and / or submicron-sized structures to a surface to provide increased surface roughness. In addition, the process includes grafting a hydrophobic material to the surface in order to decrease the surface energy and decrease wettability of the surface. The combination of increase surface roughness and decreased surface energy can provide an ultrahydrophobic surface on the treated substrate.

The present invention provides a water based, low VOC super hydrophobic coating composition that can be used to make wet and dry dirt repellent surfaces to keep the surfaces clean for a reasonable period of time. The coating utilizes hydrophobic nanoparticles dispersed in water. This treatment produces a virtually transparent coating releasing very little or no VOC compounds whereas previous coatings of comparable hydrophobicity release up to 99 percent VOC compounds. The coating can be applied by a simple, single application method and the super hydrophobic property can be achieved by drying at room temperature for 5 to 10 minutes. A preferred coating can be easily removed and renewed when desired. The aqueous hydrophobic self cleaning coating composition that can be applied by conventional methods such as by spraying the composition onto a surface creating a wet and dry dirt repellent coating on the surface. The hydrophobic self cleaning coatings are used on exterior automotive and boat surfaces, and in many other applications, to produce a self cleaning surface, reduce adherence of dirt and contaminants to a treated surface, and reduce drag in some applications providing an energy savings. The coating solves the problem of poor resistance to UV light, opaque appearance, and / or abrasion found in previous coatings of similar nature. A preferred coating has good resistance to UV light and some resistance to abrasion. Clear, nearly transparent and translucent coatings are produced as compared to conventional coatings of comparable hydrophobicity which are typically white or opaque. The coating can be applied by a single and easy spraying method and the super hydrophobic property can be achieved by drying the film by evaporation of the solvent wetting solution and water based carrier at ambient temperature for 5 to 10 minutes. Embodiments of the hydrophobic self-cleaning coating composition can be produced resulting in a clear coating or in some cases a translucent dirt repellant film or coating on painted material, plastic, metal, glass, ceramic, fiberglass or a polymer substrate. The coating typically utilizes hydrophobic nanoparticles of fumed silica and / or titania wetted by a hydrophilic solvent such as acetone for no VOC applications, or with mineral spirits, alcohol or a light distillate if VOC are not a consideration, together with a selected surfactant typically having an HLB value in a range of from 9 to 13.At least one preferred coating composition comprising an effective amount of a treated fumed silica wetted with a solvent and dispersed in water, upon drying, resulted in a coated surface providing a contact angle of at least 165 degrees and a surface energy below 12 dynes / centimeter as compared to water having a contact angle of from 65 to 80 degrees on a noncoated surface. The composition imparts a degree of hydrophobicity to a surface so that the surface will have a tilt angle of sliding of less than 2 degrees as compared to water on a noncoated surface having a tilt angle of sliding of 90 degrees or higher. The coating composition is removed by washing with a detergent or applying pressure to the coating wiping same from the treated surface. Exposure to water in the form of rain or snow does not remove the coating composition.

The invention belongs to the technical field of chemistry and chemical industry and functional materials, and relates to a method for preparing a metal mesh which has special wetting properties and is used for oil-water separation. The method adopts simple wet-method chemical etching technology, nano-scale microscopic bulges are prepared on the surface of a metal mesh with micron-grade pore diameters, and then a compound which does not contain fluorine and has low surface energy is modified on the surfaces of the microscopic bulges. For the surface of the prepared material, a contact angle of a water drop is more than 150 degrees, and a contact angle of oil is close to 0 degree. Due to the specific wetting properties, the material can allow the oil to pass through the metal mesh smoothly, but the water cannot permeate through the metal mesh completely, so that the property of effectively separating oil-water mixtures is realized. Particularly, the specific wetting properties of the surface of the material can keep stable in acid solution, alkali solution and salt solution, and thus the functional metal mesh can be excellently applied in aspects of metal corrosion prevention and the like. A mesh membrane does not contain the fluorine, and has the advantages of simple preparation method, high permeability of pore space and good oil-water separation effect, and corrosion resistance.

A thermally conductive interface, which may be in the form of a double-sided, pressure sensitive adhesive tape, disposable intermediate a heat-generating source having a first heat transfer surface formed of a first material having a low surface energy, and a thermal dissipation member having a second heat transfer surface which is formed of a second material having a surface energy substantially higher than the surface energy of the first material, and which is disposable opposite the first heat transfer surface of the heat-generating source in a spaced-apart, heat transfer adjacency therewith. The interface includes a first pressure sensitive adhesive (PSA) surface which is bondable under pressure to at least a portion of the first heat transfer surface of the heat-generating source, and an opposing second pressure sensitive adhesive (PSA) surface bondable under pressure to at least a portion of the second heat transfer surface of the heat-generating source. The first PSA surface is presented from a layer of a thermally-conductive, first pressure sensitive adhesive composition, preferably silicone-based, having an affinity to the first heat transfer surface of the heat generating source. In turn, the second PSA surface is presented from a layer of a second pressure sensitive adhesive composition, preferably acrylic-based, different from the first composition and having an affinity to the second heat transfer surface of the thermal dissipation member. The interface is particularly adapted for bonding a plastic packaged electronic component to a metal heat sink.

The present invention belongs to the field of mnacromolecule, relating to the fluorine-containing polyester of low surface energy and the preparation method of the fluorine-containing polyester. The polyester has the following chemical structure (1): wherein R f C is the straight chain of 2 - 21 C or the branch-chain pseudo-perfluoroalkyl; R1, R2 is the alkyl, aryl, or naphthenic base of the C1-C8; E is -(CH2) m-; formula (3) or formula (4); R' is H or the straight chain or the branch-chain alkyl under C4; m is an integer between 0 or 10. The polyester preparation method is that dibasic acid or the correspondent diester, dihydric alcohol and perfluoroalkane, which are 0.05 percent to 10 percent of the total material weight, are fused and polymerized under vacuum condition. The polyester preparation method at the pseudo-perfluoroalkyl sealed end is simple, and is of good drainage and oil dredging properties. The present invention can be widely used in antifouling coatings, and is of important development and application value.

The invention belongs to the technical field of functional materials, and particularly relates to a micro-nano coating material with low surface energy and a preparation method thereof. The preparation method comprises the following steps of mixing composite microspheres with micro sodium structure and hydrophobic nature, matrix resin with contact angle more than 90 degrees with coating film, solvent, powder, and additive, and adopting a co-mixing method, an in-situ emulsion polymerizing method, an in-situ solution polymerizing method, an in-situ concentration and polymerizing method, an in-situ addition and polymerizing method and the like, so as to prepare the coating material with micro-nano structure; performing spraying, brushing, roll coating, photo-etching, 3D (three-dimensional) printing, mechanical processing and the like, drying and curing at the temperature of 0 to 1000 DEG C, and coating the coating material with micro-nano structure onto different matrix surfaces, so as to obtain the micro-nano coating material with low surface energy and groove structure. The micro-nano coating material has the advantages that the preparation technology is simple, the coating hardness is high, the water-resistant property is good, the adhesion force to different matrix surfaces is strong, and the micro-nano coating material can be used for self-cleaning, resistance-reducing, denoising, anti-icing and other functional materials.

Multi-functional materials which have a photocatalytic layer with a photocatalytic function disposed on the surface of a base through an amorphous binder layer 6 interposed therebetween. Photocatalytic particles of the photocatalytic layer are joined together by a surface energy or solid-state sintering. The photocatalytic layer may have a structure in which fine particles fill interstices defined between photocatalytic particles or a structure in which no fine particles fill interstices defined between photocatalytic particles. A metal such as Ag, Pt, or the like may be fixed or not fixed to surfaces of the photocatalytic particles. A lower layer of the photocatalytic layer is embedded in the binder layer such that an intermediate layer is formed between the binder layer and the photocatalytic layer, the intermediate layer including components of the binder and photocatalytic layers in varying concentrations therethrough.

Methods of creating patterns on substrates are presented, and articles of manufacture resulting therefrom. One method comprises applying a first surface energy modifier to an applicator to form a coating on the applicator; contacting the coating with a receiving member, the receiving member having a topography, the coating only contacting and remaining on at least some protrusions; exposing the first modified receiving member to a second surface energy modifier, thereby forming a second modified receiving member having surface modified recesses; applying a composition comprising a polymeric material to the second modified receiving member, the composition substantially conforming to the topography of the surface modified protrusions and the surface modified recesses; and contacting the composition-coated, surface modified protrusions with a substrate for a time and under conditions sufficient to transfer the polymeric material on protrusions to the substrate. Because the surface energy of the sidewalls is lower than that on the protrusions, polymer dewetting from the sidewalls is promoted, which makes the polymer film discontinuous along the edges of patterns. Therefore, inked polymer patterns from the protrusions of the mold show very smooth edges and smaller dimensions compared to that of the mold.

The invention provides a super-hydrophobic nanometer transparent coating and a preparation method thereof and belongs to the technical field of super-hydrophobic paint. The method includes the steps that firstly, a first category of inorganic nanometer particles are added into an organic solution, and ultrasonic dispersion is performed; secondly, dispersing agents and a second category of inorganic nanometer particles are added, and ultrasonic dispersion is performed so that a dispersion solution can be obtained; crosslinking agents and additives are added in the dispersion solution, ultrasonic dispersion is performed, finally, low-surface energy polymers are added, mixtures are evenly mixed, and transparent and clear super-hydrophobic paint is obtained; the surface of a solid base materials is coated with the transparent and clear super-hydrophobic paint, and the super-hydrophobic nanometer transparent coating is obtained through low-temperature thermal drying and curing. The super-hydrophobic performance of the super-hydrophobic nanometer transparent coating prepared through the method is excellent, the contact angle can be 160 degrees, the rolling angle is 1-7 degrees, the super-hydrophobic nanometer transparent coating can be sprayed to the surfaces of most of common materials, the morphology of the surfaces of the materials are not changed, and the application prospects and the application potency are very wide.

A process for preparing nano water paint comprising the steps of: A. Modifying the chemical property on the surface of nano particles by hydroxylation for forming hydroxyl groups at high density on the surface of the nano particles; B. Forming self-assembly monolayers of low surface energy compounds on the nano particles by substituting the self-assembly monolayers for the hydroxyl groups on the nano particles for disintegrating the clusters of nano particles and for forming the self-assembly monolayers homogeneously on the surface of the nano particles; and C. Blending or mixing the nano particles having self-assembly monolayers formed thereon with organic paint to form nano water paint.

There is provided a process for forming an organic electronic device. The process includes the steps: forming a first layer, which includes an electrically conductive material and a fluorinated acid polymer, the first layer having a first surface energy; forming a second layer over the first layer, the second layer having a second surface energy which is greater than the first surface energy; removing selected portions of the second layer, resulting in uncovered areas of the first layer; forming a third layer over the uncovered areas of the first layer. There are also provided electronic devices made using the process.