605 results about "Surface energy" patented technology

This invention belongs to the field of marine antifouling, and specifically relates to a transparent, self-lubricating organosilicon hybrid antifouling coating with a negatively charged surface and its preparation method. The antifouling coating is obtained by a sol-gel reaction of modified nanocellulose, hydroxy acid, and functional fluorine / siloxane monomers; the mass ratio of the hydroxy acid to the modified nanocellulose is 10–100:1; the mass ratio of the functional fluorine / siloxane monomer to the modified nanocellulose is 10–300:1. This invention, based on a multi-element green antifouling strategy, constructs a material surface with negative charge, self-lubrication, and low surface energy. The prepared antifouling coating exhibits excellent transparency, mechanical properties, and static antifouling performance. This antifouling coating is environmentally friendly and has broad application prospects in the field of marine antifouling.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an oil-resistant interior material. The material comprises a porous base material layer, a fluorine-containing polymer and organic silicon resin blended oil-resistant functional layer and a micro-nano structure layer with a periodic micro-bulge array, surface modified nanoparticles are distributed in the functional layer in a gradient manner, and the micro-bulge surface is covered with a perfluoropolyether / fluorinated silicon dioxide composite coating; through a synergistic effect of a low-surface-energy oleophobic interface formed through chemical bonding and curing and a micro-structure capillary lifting effect, anti-permeation barrier of high-viscosity grease is realized, and meanwhile, mechanical wear resistance and thermal stability are improved by virtue of a nano-particle enhanced cross-linked network; and continuous imprinting and an ultraviolet-thermal dual-curing process are combined to achieve high-efficiency manufacturing with zero solvent residue, and finally the interior material with long-acting oil resistance, high environmental tolerance and industrial mass production feasibility is obtained.

The invention relates to the technical field of high polymer material processing, in particular to a blow molding method of a composite toughened film, which comprises the following steps: step 1, preheating matrix resin in preheating equipment; 2, feeding the mixed raw materials into a double-screw extruder for melt blending; 3, feeding the dried composite particles into a hopper of a single-screw blow molding extruder; 4, adjusting the air volume and the air pressure of the cooling system according to the monitoring result; and 5, the formed film pipe is folded into a flat shape through a guide component and led out through a traction roller, the traction speed and the extrusion speed are coordinated to control the traction ratio, corona treatment is conducted on the surface of the thin film to improve the surface energy, then rolling tension is controlled for rolling, and the rolling tension is controlled according to the elasticity and thickness of the thin film to prevent excessive stretching or loosening. The uniform distribution and proper compatibility of the composite toughening component improve the toughness of the film, and maintain the strength and barrier property of the film.

The invention discloses a cement-based surface super-hydrophobic coating as well as a preparation method and a use method thereof. The cement-based surface super-hydrophobic coating comprises a prime coating and a surface coating, the prime coating is a coupling agent modified fibrous clay / resin composite material, the surface coating is a coupling agent modified SiO2 / low surface energy substance modified resin composite material, the contact angle of the cement-based surface super-hydrophobic coating is 155-159 degrees, and the impact strength is 50-60 kg.cm. Fibrous clay and high-permeability alkali-resistant resin are mixed to serve as a bottom layer of the coating, silane modified SiO2 and a low-surface-energy substance modified resin material are compounded to serve as a surface layer, the surface layer is coated on the surface of a cement-based material, and a nanofiber structure of clay is combined with the high-permeability alkali-resistant resin, so that the coating is endowed with excellent toughness, adhesive force and alkali resistance; and the coating is endowed with super-hydrophobicity and wear resistance by virtue of a bulge structure formed by bonding dense SiO2 on the surface through resin.

The invention relates to a long-life room-temperature phosphorescent material and a preparation method and application thereof.According to the phosphorescent material, epoxy resin is doped with an epoxy prepolymer containing a fluorine-containing chain segment to serve as a host matrix, F-pi and pi-pi non-covalent synergistic interaction is formed between the host matrix and aromatic fluorescent guest molecules, the energy level difference of the excited state is adjusted, and the phosphorescent material is obtained. Intersystem crossing (ISC) and radiative transition rates are optimized, so that the phosphorescence lifetime and environmental adaptability are improved; a fluorine-containing chain segment introduced into a polymer system can be enriched on the surface of a material to form a needle-shaped structure, so that the surface energy of the material is remarkably reduced, the antifouling property is excellent, and additional functions of lyophobicity, transparency, chemical stability and the like are also realized while ultra-long room-temperature phosphorescence is realized; and cooperative enhancement and multifunctional integration of optical performance and surface performance are realized.

The invention discloses a method for preparing a super-hydrophobic antibacterial fabric with a photothermal effect. The method first loads a photothermal preparation on the surface of the fabric to impart photothermal properties, and then introduces a composite coating formed by hydrophobic silica nanoparticles and a silane coupling agent with an alkane chain to reduce the surface energy of the material and construct a micro-nanoscale rough structure, thereby preparing an antibacterial fabric with excellent photothermal and super-hydrophobic properties. The super-hydrophobic antibacterial fabric prepared by the invention has a fabric surface water contact angle of 158° and a surface temperature of 120°C under near-infrared light irradiation, showing excellent photothermal cycle stability and super-hydrophobic high temperature resistance. The super-hydrophobic antibacterial fabric has an antibacterial rate of over 99.0% under the synergistic effect of passive super-hydrophobic antibacterial adhesion and active photothermal sterilization, and has a wide antibacterial range and a long antibacterial life.

The invention relates to the technical field of material surface engineering, and discloses a plastic surface treatment process to solve the problems that in the prior art, a plastic surface coating is poor in adhesive force and single in function, and a traditional treatment method is not environmentally friendly. The process sequentially comprises the following steps: pre-treating a base material, and obtaining a clean and stress-free base material through ultrasonic cleaning and thermodynamic stress elimination; performing low-temperature plasma surface activation, performing physical bombardment and chemical modification on the plastic surface by utilizing plasma of specific process gas in a vacuum environment, introducing a large number of active functional groups, and remarkably improving the surface energy; and preparing and applying the functional nano coating, namely forming firm covalent bonds by using the coupling agent in a coating solution containing functional nano particles and a coupling agent and the anchor points, so that the chemical coupling of the functional coating and the plastic substrate is realized.

The present invention discloses a preparation method of a photothermal super-hydrophobic coating with excellent anti-icing / de-icing performance under a low temperature and high relative humidity environment, first by in situ growth of photothermal Cu-MOF nanoparticles on the surface of low thermal conductivity fibrous clay mineral nanoparticles, constructing a two-level nano- / nano-structured composite photothermal particle, which is then subjected to low surface energy modification and introduced into a low thermal conductivity binder, and a binder is induced to phase separate to form a micron-scale binder / low surface energy nanoparticle aggregate by a non-solvent, and finally a photothermal super-hydrophobic coating with a three-level micro- / nano- / nano-structure is constructed by spraying. The three-level micro- / nano- / nano-structure of the coating simultaneously gives the coating excellent photothermal performance and the Cassie-Baxter state stability of the droplet on the coating surface under a low temperature and high relative humidity environment, so that it has excellent passive anti-icing / frosting and active de-icing / defrosting performance in this environment. The low thermal conductivity of the coating further suppresses the heat exchange between the substrate-water droplets, so that the passive anti-icing / frosting performance of the coating is further improved. In addition, the present invention has the advantages of simple preparation method and large-area preparation, laying a solid foundation for the practical application of photothermal superhydrophobic anti-icing coatings.

The invention discloses a water-based single-component super-amphiphobic refrigeration coating, a coating and a preparation method of the coating, and relates to the technical field of coatings. 20-35 parts of a second filler; 5-10 parts of a third filler; 20-35 parts of a film-forming substance, 1-9 parts of an auxiliary agent and 3-50 parts of water; the first filler comprises fluorine-containing silane modified fumed silica; the second filler comprises at least one of long-chain silane modified precipitated barium sulfate, long-chain silane modified calcium carbonate and long-chain silane modified hollow glass beads; the third filler comprises an infrared emission filler treated by an organic silicon modifier. By modifying the filler, the purposes of stable dispersion and functional synergy of low-surface-energy substances and high-proportion inorganic nano filler in a water-based system are achieved.

The invention relates to the technical field of mine filling materials, and discloses a high-strength filling material for a mine and a preparation method, the high-strength filling material for the mine comprises 23.5-30 parts by weight of water, 50-64 parts by weight of chlorine-containing tailings, 5-16 parts by weight of pre-excited gelling slurry, and 2.5-6 parts by weight of a polyurethane cementing agent emulsion. The polyhydroxy sulfonic acid grinding aid prepared by the invention contains a plurality of hydroxyl groups and sulfonic acid groups, has stronger acting force with the surface of the slag and greater infiltration effect, and can be strongly adsorbed in microcracks on the surface of the slag after ball milling, so that the surface energy of slag particles is reduced, the dispersity of the slag particles is improved, and the specific surface area is increased; the activity of the slag powder can be stimulated to a greater extent, and the compressive strength of the filling material can be improved.

The invention discloses a halogen-free low-volatility anti-icing photo-thermal super-hydrophobic coating for the surface of a wind power blade and a preparation method thereof. The coating is prepared by compounding functionalized modified multi-walled carbon nanotubes, functionalized modified nano titanium nitride, polydimethylsiloxane / nano silicon dioxide modified epoxy resin and a curing agent. Wherein the multi-walled carbon nanotubes are subjected to amidation and dual functionalization of lauric acid and 3-aminopropyl triethoxy silane; the surface of the nano titanium nitride is uniformly modified through bionic polydopamine coating; hydroxyl-terminated polydimethylsiloxane and nano SiO are doped into an epoxy resin base material, so that the system is endowed with low surface energy and high weather-resistant binding force. After curing and film forming at room temperature for 24 hours or at 80 DEG C for 2 hours, the water contact angle is greater than or equal to 155 DEG C, the ice adhesion strength is less than or equal to 10 kPa, the photo-thermal temperature is greater than or equal to 40 DEG C, and the performance is not attenuated after 50 times of heating and cooling tests; and after 150-hour damp heat, 500-hour ultraviolet radiation, acid corrosion and abrasive paper friction, the coating does not blister or fall off. The coating disclosed by the invention is green and environment-friendly, low in curing energy consumption, high in photo-thermal temperature rise and strong in super-hydrophobic durability, and can be used for remarkably improving the long-term anti-icing capability of wind power blades in cold and high-humidity regions.

The invention relates to the technical field of intelligent sensing systems, in particular to an algorithm and system for avoiding water surface floating objects and improving monitoring precision based on radar water level monitoring, and the method comprises the following steps: collecting radar echoes, constructing spatial-temporal characteristics based on waveform asymmetry and coherent attenuation gradient, and calculating the spatial-temporal characteristics; according to the method, the central moments of the front edge and the rear edge of the echo are calculated, the waveform asymmetry is quantified, the dynamic stability is analyzed in combination with the attenuation gradient of the multi-time-lag coherence coefficient, the floating object interference is recognized from the double dimensions of the spatial form and the time memorability, and the actual water level is inverted. An effective scattering trailing interval is positioned, nonlinear approximation operation is performed on trailing data in combination with an index physical model, a shielded water surface energy distribution curve is reconstructed, a derivative zero point is solved, distance measurement deviation caused by floating objects is corrected, the real water level height is effectively restored, and the monitoring anti-interference capability and the data accuracy in a complex hydrological environment are improved.

The invention relates to a method for constructing a composite super-hydrophobic coating through double bonding. The preparation method comprises the following steps: taking a clean copper sheet which is not pretreated as a substrate, dipping the copper sheet in a suspension consisting of nanoparticles and sulfydryl-containing siloxane ethanol, taking out, washing, drying, dipping in a perfluoromercaptan ethanol solution, taking out, washing, and drying to obtain the copper-based super-hydrophobic surface coating. The coating prepared by the method has excellent super-hydrophobicity, icing resistance and stability. Different from an existing conventional preparation method, the method has the advantages that pretreatment operation such as abrasive paper polishing, strong acid etching or anodic oxidation does not need to be carried out on a copper sheet, and micro-nano roughening and low-surface-energy self-assembly can be completed on the copper surface only through two-step normal-temperature dipping. The method is simple in preparation process, mild in condition, free of expensive equipment, thin in coating thickness and small in influence on electric conduction and heat conduction of the copper substrate, intrinsic performance of copper can be reserved, the electric conduction / heat conduction characteristic of the copper substrate is considered, and the method has wide application value and prospects.

According to the preparation method of the high-temperature-resistant durable super-hydrophobic powder coating, integrated powder coating particles are prepared by mixing through a tabletting-crushing-sieving technology, and finally, one end of a solid nano-material in the integrated powder coating particles is embedded into a bottom layer, and the other end of the solid nano-material protrudes out of the surface of the coating, so that a nano-fiber bridging interface strengthening structure is formed. According to the invention, the low surface energy material, the solid nano material and the thermoplastic film-forming resin are effectively combined together to construct firm and stable integrated powder coating particles, so that the overall performance is synergistically enhanced, and the protection capability of a micron-scale structure to a nano-scale structure is greatly improved; the solvent-free durable super-hydrophobic powder coating is directly prepared through electrostatic spraying, so that the technological process is simplified; the solid, solvent-free and environment-friendly super-hydrophobic powder coating is prepared, has excellent high-temperature resistance and super-hydrophobic performance, and has potential advantages in the aspect of anti-corrosion and anti-drag application of a heat distribution pipeline.

The invention discloses a water glass-based full-life super-amphiphobic radiation refrigeration block material, which is prepared from the following raw materials in parts by weight: 1.5 to 3 parts of C-F long-chain modified micro-nano particles, 0.5 to 1.5 parts of water glass-based binder, 0.1 to 0.3 part of nano silicon dioxide sol and 0.05 to 0.16 part of curing catalyst, the C-F long-chain modified micro-nano particles are obtained by sequentially carrying out silane coupling agent grafting modification and fluorosilane grafting modification on nano particles with high sunlight reflectivity and micro particles with high sunlight emissivity. The super-amphiphobic function is converted into a three-dimensional block material from a two-dimensional coating, stress distribution optimization and interface bonding energy improvement are achieved while the ultra-low surface energy characteristic is kept, the problems of optical performance degradation and the like caused by surface pollution of the radiation refrigeration material are effectively solved, the mechanical durability of the material is essentially improved, and the service life of the radiation refrigeration material is prolonged. And the radiation refrigeration system can maintain stable performance in the whole life cycle.

The invention belongs to the technical field of composite materials and radomes, and particularly relates to a layer structure of a radome body and a manufacturing method. The skin comprises a first skin layer, an interlayer, a second skin layer and a polyvinyl fluoride film layer which are sequentially arranged from top to bottom. Through collaborative design of a micro-nano composite structure and a low-surface-energy material, a self-cleaning surface skin layer with super-hydrophobicity, high wave transmission and weather resistance is constructed. Compared with a traditional fluorocarbon coating, the wave transmission rate is 60-70% and is improved by more than 25%, the signal transmission loss is remarkably reduced, and the harsh requirement for the wave transmission performance of the antenna housing is met. The cleaning cost of a traditional antenna housing can be saved by more than 80%, especially for high-altitude and complex-structure antenna housings, high-altitude operation or special equipment is not needed, and the maintenance safety risk is reduced. The replacement frequency of the radome caused by aging and abrasion of the coating can be reduced, and the overall life cycle cost of equipment is reduced.

The invention discloses a high-wear-resistance modified polypropylene material and a preparation process thereof. The material comprises the following components in parts by weight: isotactic polypropylene, a beta nucleating agent, a heterofunctional hexagonal boron nitride nanosheet, an elastomer, an antioxidant system and a surface migration accelerant, one side of the nanosheet is treated by amino silane, and the other side of the nanosheet is treated by fluorine-containing silane. The material is prepared through twin-screw melt blending granulation and injection molding, in the molding process, variable mold temperature is adopted, contact pressure is applied to the surface of a product to promote directional migration and orientation of nanosheets in a cortex area, and then annealing is conducted. The Janus structure and the surface migration accelerant cooperate to realize a fluorine-containing low-surface-energy self-lubricating surface layer with an outward surface; the beta nucleating agent induces beta crystal formation to improve toughness. The scheme has the advantages of simple process and easily available raw materials, and is suitable for polypropylene products with higher wear resistance requirements, such as automotive interiors and household appliance shells.

The disclosure relates to a method and a device for the production of an optical element from a curable material by using an additive manufacturing technology. According to the disclosure, this method comprises: A—providing a curable material; B—curing said curable material inside sliced outlines (C1) whose geometry are determined according to the geometry of said optical element, said optical element comprising at least: a first volume element (V1) and a second volume element (V2), by forming the first volume element (V1) by irradiating the curable material with at least a first curing surface energy (E1) with a first light depth penetration value within the curable material (Dp1), and forming the second volume element (V2) by irradiating the curable material with at least a second curing surface energy (E2) with a second light depth penetration value within the curable material (Dp2), wherein said second light depth penetration value within the curable material (Dp2) is different from the first light depth penetration value within the curable material (Dp1).

The invention provides a composite acrylic acid low-surface-energy antifouling coating, a preparation method and application, and belongs to the technical field of marine antifouling materials, the composite acrylic acid low-surface-energy antifouling coating comprises a three-layer composite structure, the three-layer composite structure comprises a bottom layer, a middle layer and a surface layer from bottom to top, the bottom layer is capsaicin-loaded polymethyl methacrylate, and the middle layer is a polymethyl methacrylate surface layer. The bottom layer is made of capsaicin, the middle layer is made of pressure-sensitive adhesive activated by oxygen plasma, the surface layer is made of dihydroxyl-terminated polydimethylsiloxane, the mass ratio of the bottom layer to the middle layer to the surface layer is (23-25): 1: (23-25), and the mass content of capsaicin in the bottom layer accounts for 5.82-5.75% of the total mass; based on the bonding strength change of the pressure-sensitive adhesive generated by oxygen plasma jet and the capsaicin for effectively inhibiting biological growth, polyacrylic acid is used as a self-polishing reservoir to continuously release an environment-friendly antifouling agent; the pressure-sensitive adhesive adheres to the polydimethylsiloxane layer through the adhesive force change generated by oxygen plasma to achieve the low-surface-energy antifouling effect, synergistic gain is achieved, the composite material intervenes into the biological fouling process from multiple aspects, and the composite material copes with the marine biological fouling process jointly.

The invention relates to a method for measuring wafer surface energy in hybrid bonding based on a chemically modified probe. The method comprises the following steps: carrying out surface pretreatment on an atomic force microscope probe and a wafer sample; constructing same functional group modification layers on the surfaces of the microscope probe and the wafer sample; the bending sensitivity, the elastic coefficient and the curvature radius of the probe are calibrated; acquiring a force-distance curve based on interaction between the probe covered by the functional group modification layer and the surface of the wafer sample, and calculating initial adhesion work based on the force-distance curve; and performing error correction on the initial adhesion work by using the surface energy measured by a contact angle method of a standard wafer sample, and establishing a quantitative mapping relation between the corrected adhesion work and the bonding strength. Compared with the prior art, the method has the advantages that the probe is subjected to functional group modification, the adhesive force of the surface of the sample is measured through the functionalized probe, and the surface energy of the wafer sample in mixed bonding is calculated in mixed bonding, so that the subsequent bonding strength of the sample is estimated.

The invention provides a method for improving the blackness of a blue phase of a TPV material, and belongs to the technical field of the blackness of the TPV material.The method comprises the steps that modified carbon nanotubes and a titanate coupling agent are mixed for ball-milling surface treatment, the specific surface area change rate is used as a key control parameter, the optimal grinding time is calculated in combination with a surface energy density mechanism equation, and the blackness of the blue phase of the TPV material is improved. A gradual dispersion process of premixing, double-rotor internal mixing and single-screw extrusion is adopted, real-time parameter adjustment and dispersion state prediction are performed by applying a dispersion optimization model, and an upper-layer model taking maximization of blue phase blackness as a target and a lower-layer model taking optimization of grinding time matching as a target are established for game optimization; the optimal process parameter combination is obtained through multi-round iteration until convergence, finally ideal dispersion and optical performance matching of the carbon nanotubes in the TPV material are achieved, and the technical problem that the blackness of the blue phase of the TPV material is not high enough is solved.

The invention discloses a dynamically migratable low-surface-energy polymer modifier and a preparation method thereof, the polymer main chain of the low-surface-energy polymer modifier comprises a temperature-sensitive dynamic structure, and the polymer chain end group of the low-surface-energy polymer modifier is a fluorinated structure. The low-surface-energy polymer modifier disclosed by the invention is co-mixed with matrix resin through a conventional processing and mixing means in a standard production process, and migrates to the surface of a material in a processing heat treatment and use process, so that multiple effects of water resistance, pollution resistance, dust prevention, anticoagulation, antithrombus, antibiosis, self-cleaning and the like can be achieved; the modifier not only can achieve an excellent low surface energy modification effect, but also has no influence on the performance of matrix resin. The invention further discloses a low-surface-energy blending composition containing the low-surface-energy polymer modifier and application of the low-surface-energy blending composition.

The invention relates to the technical field of hydrophobic materials, in particular to a water-based acrylate emulsion based on structured hydrophobic particle modification as well as a preparation method and application of the water-based acrylate emulsion. The industrial problems that hydrophobic particles are prone to agglomeration and the hydrophobic effect is not lasting are solved. According to the emulsion, long-chain alkyl silane modified silicon dioxide serves as a structured hydrophobic phase, in-situ hybridization is carried out on the structured hydrophobic phase, a hydrophobic silane coupling agent, an acrylate monomer and the like through a semi-continuous emulsion polymerization method, and a stable micro-nano rough structure and a low-surface-energy surface are successfully constructed in a coating. According to the preparation method, a physical hydrophobic structure and chemical hydrophobic components are ingeniously combined, the prepared emulsion is good in stability, the water contact angle after film forming can reach 110 degrees or above, and the emulsion has excellent static hydrophobic and dynamic moisture-resistant performance and has wide application prospects in the fields of buildings, textiles, leather and the like.

The invention relates to the technical field of coatings, in particular to a double-layer super-hydrophobic passive daytime radiation cooling coating and application thereof. The super-hydrophobic passive daytime radiation cooling coating is developed through a two-step spraying process. And the bottom layer is formed by combining a high refractive index TiO / Al2O3 composite material and modified polydimethylsiloxane. The top layer employs high band gap SiO to mitigate ultraviolet absorption and combines unmodified PDMS to ensure high thermal emissivity and low surface energy. By accurately controlling the particle size distribution and concentration gradient between the two layers of structures, the optimized SPDRC coating shows excellent optical performance, the solar reflectivity is 93.2%, and the mid-infrared thermal emissivity is 95.4%. Under the direct irradiation of the sun, the temperature reduction of 10 DEG C is obviously lower than that of the environment, and the radiation cooling power of 125 Wm <-2 > is realized. In addition, the coating has a water contact angle of 155 degrees, has strong super-hydrophobicity, can ensure excellent self-cleaning performance and long-term durability, and is suitable for actual outdoor application of building cooling.

The invention discloses a preparation method of a wear-resistant super-hydrophobic coating with double covalent bonding interfaces, which comprises the following steps: (1) sequentially adding deionized water, ammonia water and halloysite into absolute ethyl alcohol, continuously stirring under a water bath condition, then slowly dropwise adding tetraethoxysilane into the mixture, keeping high-speed stirring, and cooling to room temperature; nano silicon dioxide particles are generated on the surface of the halloysite in situ, and HNTs-SiO2 micro-nano particles are formed; (2) slowly dropwise adding a low-surface-energy substance into the mixed solution in which the micro-nano particles are generated in the step (1), and continuously stirring in a water bath to obtain a super-hydrophobic suspension; collecting precipitates after solid-liquid separation, and then drying, grinding and screening to obtain super-hydrophobic composite particles; and (3) dispersing waterborne polyurethane resin and the super-hydrophobic composite particles in the step (2) in deionized water containing a nonionic surfactant, uniformly mixing to obtain a coating, spraying the obtained coating on the surface of a substrate, and curing to obtain the wear-resistant super-hydrophobic coating.

The invention discloses protective glass, an isolating agent, application of the isolating agent and display equipment, the protective glass comprises a glass body and an isolating membrane layer arranged on at least one surface of the glass body, the isolating membrane layer can inhibit alkali precipitation reaction of soda-lime glass, especially alkali precipitation reaction on the back surface of the glass, and the isolating membrane layer can inhibit alkali precipitation reaction of the soda-lime glass, especially alkali precipitation reaction on the back surface of the glass. And the surface energy difference of the back surface of the glass can be eliminated, so that the whole surface energy becomes more uniform. The protective glass is good in optical transparency, clear in imaging, high in glossiness, low in Ra roughness and high in Rsm roughness, the problem of poor watermarks of a whole machine can be solved, and the protective glass can be adopted for improvement as long as soda-lime glass is used in other industries.

The invention belongs to the technical field of tempered glass preparation, and particularly relates to impact-resistant self-cleaning tempered glass and a preparation method thereof. Epoxy acrylate, a repairing agent, an oil-phase solvent, a photoinitiator, polyvinyl alcohol and an acrylamide sulfonic acid derivative are adopted as raw materials, a self-repairing microcapsule is obtained through mixing, emulsification and UV polymerization, a hydrophobic modified microcapsule is obtained through modification of aluminum phosphate and a low-surface-energy substance, the hydrophobic modified microcapsule is mixed with water-borne epoxy resin to obtain a coating mixed solution, the coating mixed solution is applied to the surface of glass, and the surface of the glass is coated with the self-repairing microcapsule. And drying and cooling to obtain the toughened glass with the coating. The toughened glass has good impact resistance, self-repairing performance and self-cleaning performance.

The invention relates to the technical field of coatings, and discloses a wear-resistant super-hydrophobic coating and a preparation method thereof. The wear-resistant super-hydrophobic coating prepared by the invention is prepared by taking the waterborne polyurethane emulsion as a main raw material, adding the hydrophobic modified organic silicon, the wear-resistant agent, the defoaming agent and other auxiliaries and stirring, and the coating not only has excellent adhesive force and wear resistance, but also has a super-hydrophobic effect; wherein the introduction of the hydrophobic modified organic silicon improves the bonding strength and wear resistance of the coating to a base material, and the introduction of the low-surface-energy fluorine element and the-Si-O-Si chain segment improves the hydrophobicity of the coating and endows the coating with super-hydrophobicity.

The invention provides a method for preparing a uranium dioxide single crystal by using a molten salt method and the obtained uranium dioxide single crystal, aiming at solving the problem that the growth of different crystal faces cannot be controlled when the uranium dioxide single crystal is prepared by using an existing fluxing agent method. The method comprises the following steps: in the presence of a reducing agent and a surface active substance, heating U3O8 powder in molten salt to a heat preservation temperature, preserving heat, and then cooling and growing to obtain the uranium dioxide single crystal, wherein the surface active substance is SiO2 (silicon dioxide), GeO2 (germanium dioxide), V2O5 (vanadium pentoxide) or Na2WO4 (titanium dioxide). According to the method, U3O8 is taken as a raw material, a molten salt fluxing agent is combined, the reducing agent is used for reducing U3O8 and growing the UO2 crystal, and the preferred crystal face of UO2 in the nucleation and growth processes is effectively controlled by selecting a proper surface active substance and changing the surface energy of UO2 in the nucleation and growth processes, so that the UO2 single crystal with the preferred crystal face and an ordered structure is obtained.

The application discloses a composite current collector based on a PP-based film / PET-based film and a production process, which comprises the following steps: S1, base film pretreatment; S2, physical modification treatment; S3, double-layer intermediate transition layer preparation; and S4, metal layer preparation. The physical modification constructs a micro-nano rough structure on the surface of the base film through plasma etching, removes impurities in a weak boundary layer, increases the contact area by 3-5 times, provides a basis for the mechanical occlusion of the transition layer and the metal layer, and introduces a small amount of oxygen-containing polar groups to preliminarily increase the surface energy; and the transition layer is a composite structure of a silane coupling agent and a Cr layer, is combined with the polar groups of the base film through Si-O-C covalent bonds, is connected with the coupling agent and the Cr layer through Cr-N coordination bonds, and is embedded into rough pits through Cr atoms to form a dual action of mechanical anchoring and chemical bridging, so that the peeling strength of the metal layer and the base film is greatly increased through the cooperation of the two, and the mechanical requirement of long-term cycling of a lithium battery is met.