The invention provides a method for preparing a superfine
perovskite nanowire array by a
liquid phase method, which comprises the following steps of: carrying out asymmetric wettability modification on a micro-column template to obtain a surface with a hydrophobic top and a hydrophilic side wall, carrying out wettability modification on a target substrate, dropwise adding a
perovskite precursor solution on the micro-column template and covering the modified target substrate, and
drying to obtain the superfine
perovskite nanowire array. A perovskite solution is divided by the micro-column and limited in a square
capillary channel, along with volatilization of a
solvent, the capillary liquid bridge is directionally wetted, and superfine capillary liquid bridge trailing appears at the edge of a corner formed on the side wall of the micro-column and the surface of a substrate; and after the
solvent is completely volatilized, the superfine perovskite
nanowire array can be obtained on the substrate. According to the method, the
crystal quality and large-area manufacturing of the nanowires can be ensured by utilizing a bottom-to-top self-
assembly method, and meanwhile, the manufacturing cost of the superfine structure is also greatly reduced due to the reutilization of the template.