The invention relates to the technical field of environmental
analytical chemistry, and discloses a
thymol phenolphthalein-TBPE double indicator-based
cyanide titration detection method and
system, and the method comprises the following steps: adjusting a
water sample to be detected to an alkaline pH interval to construct a detection matrix; the method comprises the following steps: introducing a double-indicator
system composed of
thymol phenolphthalein and tetrabromo
phenolphthalein ethyl ester according to a specific ratio into a detection matrix, and constructing a spectrum background for masking yellow interference of
sulfide by utilizing the blue color development characteristic of
thymol phenolphthalein; dropwise adding a
silver nitrate standard solution into the mixed
system to execute a complex reaction; according to the method, a spectrum background shielding field is constructed,
chromaticity response of a system in a specific
wave band is monitored in real time, and when a
chromaticity mutation signal from green to bluish violet is captured, a
titration end point is judged, and the
cyanide concentration is calculated. High-precision anti-interference detection on
cyanide in a complex high-
turbidity matrix is realized, and the sensitivity and accuracy of end point recognition are improved.