26257results about "Other chemical processes" patented technology

A vacuum insulating panel may include: a first substrate; a second substrate; a plurality of spacers provided in a gap between at least the first and second substrates, wherein the gap is at pressure less than atmospheric pressure; a pump-out / evacuation tube extending at least partly into an aperture in one of the substrates; and a pump-out / evacuation tube seal. The pump-out / evacuation tube seal may include at least one of: (a) from about 20-80 wt. % tellurium oxide, the tellurium oxide comprising TeO4 and TeO3, wherein the pump-out tube seal comprises more TeO3 than TeO4 by wt. %; and / or (b) tellurium oxide and from about 10-50 wt. % vanadium oxide, wherein the pump-out tube seal by wt. % comprises more tellurium oxide than vanadium oxide, and wherein the vanadium oxide comprises VO2 and V2O5, and wherein more V in the pump-out tube seal is in a form of VO2 than V2O5. A substantially donut-shaped laser beam may be used to heat pump-out tube material in order to form a pump-out tube seal.

A vacuum insulating panel may include: a first substrate; a second substrate; a plurality of spacers provided in a gap between at least the first and second substrates, wherein the gap is at a pressure less than atmospheric pressure; a seal provided between at least the first and second substrates, the seal including a first seal layer and a second seal layer, wherein, for at least one location of the seal, the first seal layer has a first width and the second seal layer has a second width, wherein the first width of the first seal layer may be from about 2-20 mm, more preferably from about 3-10 mm, and possibly from about 4-8 mm.

The invention belongs to the field of biochar adsorbing materials, and relates to a method for preparing modified biochar with aquatic plant waste and hematite. The method includes the following steps: (1) naturally drying aquatic plants prior to crushing to obtain aquatic plant powder; (2) crushing the hematite to obtain hematite powder; (3) weighing the hematite powder prior to putting the hematite powder into deionized water, and performing ultrasonic treatment to obtain suspension; (4) weighing the aquatic plant powder, soaking the aquatic plant powder in the suspension, and stirring and drying to obtain fully mixed aquatic plant and hematite mixture; (5) weighing the fully mixed aquatic plant and hematite mixture, putting the mixture in a batch-type atmosphere furnace, and feeding nitrogen into the furnace; performing temperature programming to the target temperature, and maintaining final-temperature pyrolysis; after the pyrolysis process is finished, obtaining the target product, namely the modified biochar. The modified biochar has strong adsorbability in nitrate and phosphate, high in stability and reusable.

To provide a compound, an acid generator, a resist composition, and a resist pattern forming method which reduce an environmental load, achieve higher sensitivity, and can form a resist pattern excellent in lithographic characteristics.SOLUTION: The resist composition, which generates an acid upon exposure and whose solubility in a developer changes by the action of an acid, contains: a base component (A) whose solubility in a developer changes by the action of an acid; an acid generator component (B) which generates an acid upon exposure; and an acid diffusion controller component (D). The acid generator component (B) contains a compound represented by general formula (b1-1) described in the specification.SELECTED DRAWING: None

A method of making a vacuum insulating panel, the vacuum insulating panel comprising a first glass substrate, a second glass substrate, a plurality of spacers provided in a gap between at least the first and second glass substrates, and a seal provided between at least the first and second glass substrates, the seal comprising a first seal layer and / or a second seal layer. The method may include laser heating, using a laser beam from a continuous wave near-IR laser, seal material in order to form the first seal layer; wherein the laser heating may include causing the laser beam to move at a lateral speed of from about 5-70 mm / second relative to the substrates and the first seal material so that the laser beam at least partially passes through at least one of the glass substrates and impinges upon at least the second seal layer in order to heat the second seal layer and fire and / or sinter the first seal material thereby forming the first seal layer.

A method of making a vacuum insulating panel including a first substrate, a second substrate, a plurality of spacers provided in a gap between at least the first and second substrates, and a seal provided between at least the first and second substrates, the seal comprising a first seal layer, and optionally second and / or third primer layer(s). The method may include at least one of: (i) laser heating, using a laser beam from a laser, the first seal material for firing and / or sintering the first seal material to form the first seal layer, in a manner that causes TeO4>TeO3 in the first seal material to transform into TeO3>TeO4 due to said laser heating, whereby an amount of TeO4 decreases and an amount of TeO3 increases due to said laser heating, and / or (ii) laser heating in a manner that causes V2O5>VO2 in the first seal material to transform into VO2>V2O5 due to said laser heating whereby an amount of VO2 increases and an amount of V2O5 decreases due to said laser heating, so that after said laser heating the first seal layer comprises more VO2 than V2O5 by wt. %.

A method of making a vacuum insulating panel, the vacuum insulating panel including a first glass substrate, a second glass substrate, a plurality of spacers provided in a gap between at least the first and second glass substrates, and a seal provided between at least the first and second glass substrates, the seal comprising a first seal layer. The method may include: providing first seal material for the first seal layer in a location at least partially between at least the first and second glass substrates; laser heating, using a laser beam from a continuous wave near-IR laser, the first seal material in order to form the first seal layer; wherein said laser heating may comprise using the laser beam, having a size of from about 2-15 mm, so that the laser beam at least partially passes through at least one of the glass substrates to fire and / or sinter the first seal material thereby forming the first seal layer, in a manner so that the first seal layer a density of from about 2.8-4.0 g / cm3; and after forming the first seal layer, evacuating the gap to a pressure less than atmospheric pressure.

A vacuum insulating panel includes first and second substrates (e.g., glass substrates), a hermetic edge seal, a pump-out port, and spacers sandwiched between at least the two substrates. The gap between the substrates may be at a pressure less than atmospheric pressure to provide insulating properties. The vacuum insulating panel may include a multi-layer edge seal structure, including at least one layer including boron oxide (e.g., B2O3 or any other stoichiometry).

Described are storage and dispensing systems and related methods, for the storage and selective dispensing germane a reagent gas from a vessel in which the reagent gas is held in sorptive relationship to a solid adsorbent medium at an interior of a storage vessel and wherein the methods and dispensing systems provide dispensing of the reagent gas from the storage vessel with a reduced level of atmospheric impurities contained in the dispensed reagent gas.

Described herein are sorbents functionalized with polyamines having oxygen-containing units selected from carbonyl units, hydroxyl units, and combinations thereof, methods of making same, and methods of using same.

The invention relates to serratia marcescens XJ108 and application thereof, and belongs to the technical field of microorganisms. The serratia marcescens XJ108 is preserved in the China General Microbiological Culture Collection Center (CGMCC), the preservation number is CGMCC No.29557, the preservation date is January 10, 2024, and the address of the preservation institution is No.3, Yard 1, Beichen West Road, Chaoyang District, Beijing. The invention also provides application of the serratia marcescens XJ108 in acid environment, alkaline environment, high salinity environment and high chemical fertilizer environment soil tolerance and plant growth promotion. The serratia marcescens XJ108 provided by the invention has certain biological safety; meanwhile, the plant growth promoting function is achieved; and various extreme soil environments can be tolerated.

The invention relates to the technical field of land improvement, in particular to an alginic acid type multifunctional long-acting soil conditioner and a preparation method and application of the alginic acid type multifunctional long-acting soil conditioner. The core particle layer comprises an organic material, nano silicon, calcium magnesium polyphosphate, magnesium hydride, ammonium borate, rhamnose and an adhesive, and the slow release layer comprises clay minerals and alginate; the mass ratio of the clay mineral to the alginate to the organic material to the calcium magnesium polyphosphate to the nano silicon to the magnesium hydride to the ammonium borate to the rhamnose to the binder is controlled within a certain range. The soil conditioner provided by the invention is good in slow release performance, can release effective components durably and slowly, and has multiple effects of improving soil quality, providing nutrition, promoting crop growth, improving resistance and the like; the problems of soil acidification, heavy metal pollution, micro-plastic pollution, pesticide pollution, antibiotic pollution and the like in agricultural production can be effectively solved.

The invention provides a heteroatom-doped porous carbon material for carbon dioxide adsorption as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, drying and crushing waste biomass to obtain raw material powder; s2, mixing the raw material powder with an activating agent, and fully grinding to obtain a mixture of the raw material powder and the activating agent powder; s3, dissolving one or more heteroatom sources in hot deionized water to obtain a hot solution, pouring the mixture of the raw materials and the activator powder in the step S2 into the hot solution, and heating and stirring until water is evaporated; s4, performing high-temperature carbonization on the mixture finally obtained in the step S3 in an anoxic environment; and S5, cleaning and drying the product in the step S4 to obtain the heteroatom-doped porous carbon material. The heteroatom-doped porous carbon material disclosed by the invention has a highly developed pore structure, and the porous carbon prepared by taking the waste biomass as a precursor is used as a carbon dioxide adsorbent, so that high-value utilization of waste biomass resources is realized.

The invention relates to the technical field of adsorbents, and particularly discloses an aluminum oxide type adsorbent and a preparation method thereof.The preparation method comprises the following steps that lanthanum salt, cerium salt and a polyethylene glycol aqueous solution are mixed to be uniform, then the mixture is mixed with gamma-Al2O3 to be uniform, pH is adjusted, standing is conducted, solid-liquid separation is conducted, drying and roasting are conducted, and a double-doped carrier is obtained; dispersing the double-doped carrier in a mixed solution containing 2-methylimidazole, ferric salt and zinc salt, adjusting the pH value, carrying out heating reaction, solid-liquid separation and drying in an inert atmosphere, grinding to obtain powder, and carrying out molding treatment on the powder to obtain a composite carrier; uniformly mixing the Ag modified molecular sieve with silica sol, coating the surface of the composite carrier with the mixture, and drying to obtain an adsorbent precursor; dipping an adsorbent precursor in the dispersion liquid, and after dipping, solid-liquid separation and drying, reactivating to obtain the aluminum oxide type adsorbent; the prepared adsorbent can synergistically and efficiently remove multiple impurities and is excellent in corrosion resistance.

The invention belongs to the field of biochar material preparation technology and application, and discloses a preparation process of modifier-doped ferromagnetic biochar and a method for adsorbing organic pollutants by using the modifier-doped ferromagnetic biochar. Aiming at the problems of complex modification process, low adsorption efficiency, difficulty in recovery and the like of the existing biochar, the scheme comprises the following steps: mixing corncob serving as a raw material with ferric nitrate and carbonate / bicarbonate according to a mass ratio of 2: 1: 1, grinding, calcining for 2-4 hours in an inert atmosphere at 600-700 DEG C, and cleaning and drying to obtain the magnetic biochar. According to the process, through the synergistic effect of double modifiers, carbonate is decomposed at high temperature to form pores to increase the specific surface area, ferric nitrate is pyrolyzed to generate Fe3O4 to endow the magnetic recovery performance, and structure optimization and function enhancement are synchronously achieved. When being applied to adsorption, the biochar treats organic pollutants according to the dosage of 10-15 mg / 100 mL under the conditions that the pH value is equal to 7 and the temperature is 20-30 DEG C, efficient adsorption is achieved through pore filling, the conjugation effect and the iron complexing effect, and the magnet can be separated and recycled within 30 seconds. The method is suitable for environmental treatment of various organic pollutants.

The invention belongs to the technical field of soil fertilizers, and particularly relates to a soil conditioner and a preparation method thereof. Wherein the soil conditioner is prepared from the following raw materials in parts by weight: 30 to 40 parts of modified charcoal, 20 to 30 parts of microbial complexing agent, 15 to 25 parts of humic acid and 1 to 5 parts of biological enzyme; according to the microbial complexing agent, dopamine grafted and modified nano silicon dioxide and hydroxyapatite form a composite shell, pseudomonas aeruginosa and bacillus subtilis are wrapped, and the microbial complexing agent has the functions of protecting microorganisms, adsorbing heavy metals and slowly releasing phosphorus elements; the modified biochar is compounded with the attapulgite through acid-base treatment to form a porous structure with physical inlaying and chemical functional groups synergistic, so that the adsorption and fixation capability on heavy metals and organic pollutants is remarkably improved; the biological enzyme accelerates organic phosphorus conversion, and enzymatic hydrolysate provides a phosphorus source for microorganisms, promotes microorganism breeding, effectively increases the content of available phosphorus in soil, and enhances the stability of a remediation system.

The invention discloses a microbial agent and a method for repairing cadmium-polluted rice field soil by using the microbial agent, relates to the technical field of repairing cadmium pollution of rice field soil, and solves the problem that the cadmium metal enrichment capacity of duckweed is limited due to the fact that the duckweed has certain endurance capacity to cadmium stress. The microbial agent comprises bacillus subtilis ATCC6633 and pseudomonas aeruginosa ATCC27853, and the mass ratio of the bacillus subtilis ATCC6633 to the pseudomonas aeruginosa ATCC27853 is 2: 1, and the method comprises the following steps: step 1, spreading the microbial agent on the surface layer of cadmium-polluted rice field soil, then mixing the microbial agent with the rice field soil, raking the rice field soil, adjusting the water-holding capacity of the rice field soil, applying a base fertilizer, and irrigating the rice field. According to the method, the cadmium tolerance of the duckweed can be promoted, so that the enrichment capacity of the duckweed on cadmium is promoted, the remediation capacity of the duckweed on cadmium-polluted soil is improved, the cadmium content in the soil can be reduced, and the content of metal cadmium in rice is also reduced through a competitive cadmium absorption way.

A direct air capture (DAC) of CO2 system includes a reaction reactor having a solid, amine-functionalized sorbent configured to sequester CO2 from air; an in-situ dual-function device configured as a CO2 conversion reactor and an exchange fluid regeneration device; and the exchange fluid, recirculating between the reaction reactor and the dual-function device, configured to capture the sequestered CO2 from the solid sorbent in the reaction reactor and release the captured CO2 in the conversion reactor, the exchange fluid including one or more amino acids.

The invention discloses a preparation and regeneration method of an iron-aluminum-lanthanum-based composite fluorine removal agent, relates to the technical field of fluorine removal agent preparation, and aims to solve the problem that the performance of an existing fluorine removal agent needs to be improved. The preparation method comprises the following steps: weighing raw materials according to a molar ratio of iron ions to aluminum ions to lanthanum ions of 1: 1: 1, fully stirring and dissolving the raw materials in deionized water at room temperature, and making the volume constant to prepare a clear mixed solution; adding excessive triethanolamine into the mixed solution, dropwise adding a nitric acid solution, adjusting the pH value of the mixed solution to 3.0-4.0, continuously stirring at room temperature, and fully reacting to obtain a precursor solution; continuously heating and stirring the precursor liquid at 150 DEG C for dehydration to obtain organic group brown fluffy precursor powder; fully grinding the precursor powder, and calcining to obtain a gray powdery iron-aluminum-lanthanum-based composite fluorine removal agent; the method is simple, the prepared fluorine removal agent is large in adsorption capacity and short in reaction time, most of the adsorption capacity can be recovered through simple acid pickling, operation is easy, the service life is long, and the regeneration cost is low.

The invention relates to a deicing super-hydrophobic coating based on MXene, a coating, a preparation method and application of the coating. The coating comprises the following components in percentage by mass: 2%-5% of a super-hydrophobic modified MXene photo-thermal material, 2%-5% of epoxy resin, 0.5%-1.5% of an epoxy resin curing agent, 0.5%-1.5% of PDMS, 0.05%-0.15% of a PDMS curing agent and 80%-90% of a diluent. Wherein the super-hydrophobic modified MXene photo-thermal material is MXene powder treated by fluorine-free long-chain silane, and the super-hydrophobic modified MXene photo-thermal material is a super-hydrophobic modified MXene photo-thermal material. MXene with excellent photo-thermal conversion performance is used as a photo-thermal material, fluorine-free long-chain silane is used for performing low-surface-energy hydrophobic modification on the MXene material, environmental pollution caused by perfluorinated or polyfluorinated organic compounds is avoided, photo-thermal performance and super-hydrophobic performance are integrated, the advantages of a super-hydrophobic coating and a photo-thermal coating are integrated, and the application prospect is wide. The deicing super-hydrophobic coating based on MXene can be used for passive ice prevention and active photo-thermal deicing.

The invention provides a microbial solidified sand barrier and a preparation method thereof, a cementing liquid and a microbial liquid are respectively added into aeolian sandy soil, the aeolian sandy soil is treated by a microbial induced calcium carbonate precipitation technology, and then the aeolian sandy soil is dried and solidified at a high temperature to obtain the microbial solidified sand barrier. The aeolian sandy soil is a basic material, the microbial liquid contains active microorganisms capable of inducing calcium carbonate precipitation, and the cementing liquid provides a calcium source and promotes a precipitation reaction. The cementing liquid comprises a soluble calcium source and urea, the microbial liquid is bacillus pasteurii liquid, calcium carbonate precipitation is induced in the aeolian sandy soil by means of metabolic activity of specific microorganisms, so that sandy soil is solidified, a firm sand barrier is formed, more efficient and environment-friendly wind and sand control is achieved, the wind erosion resistance of the aeolian sandy soil can be remarkably improved, and the service life of the aeolian sandy soil is prolonged. A new solution is provided for wind and sand disaster prevention and control in arid and semi-arid areas, and the defects of an existing sand stabilization technology are effectively overcome.

The invention relates to a tea garden acidic soil conditioner, which is prepared from the following raw materials in parts by weight: 10 to 15 parts of alkaline conditioning materials, 10 to 30 parts of honey pomelo waste fruit fermented organic fertilizers, 4 to 6 parts of alkali modified biochar, 2 to 4 parts of biostimulant, 3 to 5 parts of graft modified chitosan, 0.25 to 0.6 part of dicyandiamide, 0.5 to 1 part of complex microbial inoculants, 0.25 to 0.5 part of binding agents and 0.006 to 0.012 part of trace element substances. The alkaline conditioning material is a mixture of magnesium-containing mineral substances and shell powder in a mass ratio of 10: (2-5); the graft modified chitosan is obtained by grafting and modifying chitosan through an unsaturated phosphorus-containing monomer and an unsaturated nitrogen-sulfur-containing monomer, and the grafting rate is 20-30%; the biostimulant comprises mineral source fulvic acid, magnesium sulfate, monopotassium phosphate and a seaweed extract. The tea garden acidic soil conditioner provided by the invention can effectively improve tea garden soil, so that the yield and quality of tea leaves are obviously improved.

The invention relates to the technical field of environmental materials and water treatment, in particular to a graphene amino silica gel composite adsorbent for heavy metal wastewater treatment and a preparation method thereof.The graphene amino silica gel composite adsorbent is prepared from # imgabs0 nanoparticles, an amino-functionalized silicon dioxide coating layer, carboxylated reduced graphene oxide, a polydopamine modification layer and tetraethyl orthosilicate; the coating is prepared from the following raw materials: 3-aminopropyltriethoxysilane, 3-mercaptopropyltrimethoxysilane, N-((4-vinyl benzyl) amino) diacetic acid, chitosan, beta-cyclodextrin, hexadecyl trimethyl ammonium bromide, polyethylene glycol, L-ascorbic acid, 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide. The composite adsorbent shows excellent adsorption performance on various heavy metal ions, and the adsorption performance is far higher than that of traditional adsorption materials and existing composite adsorbents.

The invention discloses composite modified pig manure and sludge biochar, relates to the technical field of modified biochar, and mainly comprises pig manure and sludge. The invention also provides a preparation method of the compound modified pig manure and sludge biochar, pig manure and sludge are mixed and pyrolyzed to prepare the pig manure and sludge biochar, and the pig manure and sludge biochar is modified by sulfuric acid and a magnesium chloride solution to prepare the compound modified pig manure and sludge biochar. According to the composite modified pig manure and sludge biochar provided by the invention, pig manure and sludge are subjected to carbonization modification through a composite modification technology, so that heavy metal cadmium pollution is efficiently removed, and meanwhile, a new way is provided for resource utilization of organic wastes.

The invention relates to a negative-wear super-wear-resistant current-carrying friction pair material which is a conductive lubricating film which is constructed in situ and stably exists under a current-carrying friction condition, and the current-carrying friction pair material is composed of Ga-based liquid metal, a Mo coating and an Al alloy bolt. Through cooperation of friction pair materials, a friction interface reaction is adjusted to generate a conductive lubricating film, and excellent lubricating and wear-resisting properties are achieved; in a large voltage and current range, the average friction coefficient is always maintained to be 0.25 or below, the existence of the lubricating film enables the surface to present negative wear, and the average negative wear rate is 1.28 * 10 <-6 > mm < 3 > / Nm or above. The obtained material is suitable for application in the field of electric contact industry and provides lubrication and wear protection for the surfaces of mechanical parts.

The invention discloses a zeolite adsorption and desorption integrated treatment system, and particularly relates to the field of zeolite separation treatment, and the zeolite adsorption and desorption integrated treatment system comprises a process sensing module, a dynamic partition control module, a global optimization control module and a cooling regeneration module. According to the zeolite adsorption and desorption integrated treatment system, the problem of blind operation in the traditional technology is solved through the process sensing module, a data basis is provided for dynamic partition, the intelligent monitoring level is improved, and the performance of an adsorbent is fully exerted; the problem of non-uniform heat and mass transfer of a bed layer is effectively solved through the dynamic partition control module, the desorption heat utilization efficiency is improved, and meanwhile, the service life of an adsorbent is prolonged; a dynamic optimization function is constructed through the global optimization control module, energy consumption, solvent recovery income and stability are comprehensively considered, self-adaptive adjustment of operation parameters is achieved, the energy consumption is reduced while the processing efficiency is guaranteed, and the environmental benefits are remarkably improved.

The invention discloses magnetic modified biochar, a preparation method and application of the magnetic modified biochar to adsorption of micro-plastics, and belongs to the technical field of biochar. The method comprises the following steps: pretreating industrial hemp straws, pyrolyzing at 700 DEG C in a nitrogen atmosphere to obtain original biochar, activating with potassium hydroxide, and continuously pyrolyzing in the nitrogen atmosphere to obtain activated biochar powder; soaking the obtained activated charcoal powder in an iron nitrate nonahydrate solution, mixing and stirring, drying and pyrolyzing, washing and drying to obtain the magnetic modified charcoal. Compared with traditional biochar, after the activated biochar is subjected to impregnation-pyrolysis treatment, Fe < 3 + > is introduced into the formed magnetic modified biochar, so that the specific surface area, the pore diameter, the adsorption performance and the magnetism are improved; meanwhile, in the application process of adsorbing the micro-plastics, a magnet can be used for separating the magnetic modified charcoal adsorbent from the micro-plastics, and the effects of recycling and cyclic regeneration are achieved.

The invention relates to the technical field of soil conditioners, and particularly discloses an intelligent controlled-release core-shell alginate soil conditioner and a preparation method thereof.The conditioner is of a core-shell-layer three-layer structure and comprises a core layer, a middle shell layer and an outer layer, the three layers account for 30%, 40% and 30% of the total weight respectively, and the core layer mainly comprises improved alginate and nutrients; the middle shell layer mainly comprises chitosan and a microbial preparation; and the outer layer mainly comprises modified charcoal and magnetic nano # imgabs0 #. The preparation method comprises the four steps of core layer preparation, middle shell layer coating, outer layer coating and forming post-treatment, and multiple functions of accurate nutrient supply, efficient heavy metal fixation and soil microenvironment regulation and control are achieved through a core-shell-layer three-layer structure design and a pH / temperature / microorganism triple response mechanism by adopting a coaxial electronic injection and layer-by-layer self-assembly technology; the fertilizer has a remarkable improvement effect on sandy soil and saline-alkali soil, and the organic matter increasing rate reaches 40%.

The invention relates to a crown ether covalent organic framework material as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a crown ether monomer and an amino monomer in an o-dichlorobenzene solvent, adding a catalyst acetic acid aqueous solution, and uniformly dispersing to form a reaction solution; the method comprises the following steps: freezing a reaction solution through a liquid nitrogen bath, vacuumizing, filling nitrogen, carrying out a heating reaction, and carrying out post-treatment operations such as washing and drying on a reaction product, so as to obtain the crown ether covalent organic framework material BADT-DB18C6-COF. The crown ether covalent organic framework material is formed by condensation of a crown ether aldehyde monomer and an amino monomer, the crown ether monomer is 4, 4 ', 4' ', 4 '''-(6, 7, 9, 10, 17, 18, 20, 21-octahydrodibenzo [B, K] [1, 4, 7, 10, 13, 16] hexaoxacyclo octadecene-2, 3, 13, 14-tetrayl) tetrabenzaldehyde, and the crown ether monomer is 4, 4 ', 4' ', 4'''-(6, 7, 9, 10, 17, 18, 20, 21-octahydrodibenzo [B, K] [1, 4, 7, 10, 13, 16] hexaoxacyclo octadecene-2, 3, 13, 14-tetrayl) tetrabenzaldehyde. The amino monomer is 4 ', 5'-bis (4-aminophenyl)-[1, 1 ': 2', 1 ''-terphenyl]-4, 4''-diamine. The crown ether covalent organic framework material BADT-DB18C6-COF prepared by the invention is mainly used as an adsorbent, is used for adsorbing and recovering uranium, thorium and americium ions from a solution, shows good adsorption capacity on radionuclides U-238, Th-232 and Am-243, and is particularly suitable for the field of spent fuel post-treatment in the nuclear industry.

Provided is a polishing composition capable of realizing high polishing removal rate on an object to be polished. The polishing composition provided by this invention is used for polishing an object to be polished. The polishing composition includes water, sodium permanganate as an oxidant, and a transition metal salt different from the oxidant. The polishing composition includes the oxidant in an amount of more than 10 wt %. In some preferable embodiments, the transition metal salt is an oxo-transition metal salt, or a multi-nuclear transition metal complex including a transition metal and one or both of oxygen and hydrogen. The polishing composition can be preferably used in polishing an object formed of a high-harness material having a Vickers hardness of 1500 Hv or higher.