515results about How to "Improve mechanical stability" patented technology

The invention discloses a preparation method of a wear-regenerated super-hydrophobic durable anti-corrosion coating. The preparation method comprises the following steps: constructing a mechanical-sturdy super-hydrophobic coating with body phase consistency through reverse filling of a self-similar structure; wherein the oily binder solution is subjected to phase separation under the action of an alcohol solvent, is mixed with the fluorinated nanoparticles and is sprayed on the surface of a metal matrix to construct a self-similar super-hydrophobic coating, and a uniform dispersion liquid of the low-surface-energy nanoparticles and the high-hardness oily binder is sprayed on the surface of the self-similar super-hydrophobic coating; particularly, the self-similar structure of the super-hydrophobic coating can be effectively filled with the high-hardness oily binder due to the good oil absorbency of the oily binder, and finally the wear-regeneration durable super-hydrophobic anti-corrosion coating is formed; the wear regeneration durable super-hydrophobic anti-corrosion coating prepared by the method not only has excellent super-hydrophobicity, mechanical stability, chemical stability and anti-corrosion performance, but also has the advantages of special mechanical wear regeneration super-hydrophobicity and the like.

The invention provides a hydrogen production electrode doped with platinum, ruthenium, tin and praseodymium, a preparation method of the hydrogen production electrode and a water electrolysis hydrogen production device, and relates to the field of water electrolysis hydrogen production. The preparation method of the hydrogen production electrode doped with platinum, ruthenium, tin and praseodymium comprises the following steps: coating the surface of a conductive substrate with mixed powder; the conductive base material coated with the mixed powder is subjected to thermal oxidation treatment, the mixed powder comprises first metal powder, second metal powder and a pore forming agent, the first metal powder comprises Ni powder, and the second metal powder comprises Pt powder, Ru powder, Sn powder and Pr powder; and putting the structure subjected to thermal oxidation treatment into an alkaline solution, and activating to obtain the hydrogen production electrode doped with platinum, ruthenium, tin and praseodymium. The platinum, the ruthenium, the tin and the praseodymium are introduced into the hydrogen production electrode, so that the hydrogen evolution overpotential can be reduced. The hydrogen production electrode prepared by the method disclosed by the invention has relatively high catalytic activity, relatively high stability and a uniformly distributed porous structure, the electrolytic efficiency can be remarkably improved, and the service life of equipment is prolonged.

The invention discloses a photonic integrated circuit chip and a silicon optical integration platform, and aims to provide a specific waveguide structure on the photonic integrated circuit chip to realize efficient coupling with a common single-mode fiber, and meanwhile, a suspended structure is not introduced, so that the overall structure has relatively high mechanical stability. The method can pass high-temperature and high-humidity reliability test conditions of the photon integrated circuit chip, and is compatible with reflow soldering, silicon through hole and other processes.

The invention provides an asymmetric modified silicon dioxide particle doped sulfonated polyether ether ketone membrane and a preparation method and application thereof, the preparation method comprises the following steps: (1) under a heating condition, mixing surface hydroxylated silicon dioxide particles and paraffin, adding a first solvent, stirring, and cooling to obtain paraffin emulsion droplets; (2) mixing the paraffin emulsion droplets obtained in the step (1) with a sulfydryl-containing silane coupling agent, and reacting to obtain a mixture; and mixing the mixture with a hydrogen peroxide solution, and carrying out oxidation reaction to obtain the asymmetrically modified silicon dioxide particles, and (3) mixing the asymmetrically modified silicon dioxide particles and sulfonated polyetheretherketone, and drying to obtain the asymmetrically modified silicon dioxide particle doped sulfonated polyetheretherketone membrane. The asymmetric modified silicon dioxide particle doped sulfonated polyether ether ketone membrane provided by the invention is low in swelling property, relatively high in proton conductivity and relatively good in ion selectivity, and the performance of a flow battery can be improved when the membrane is used for the flow battery.

The invention belongs to the technical field of compressed air energy storage, and discloses a salt cavern compressed air energy storage reservoir stability grade evaluation method and system, and the method comprises the steps: obtaining salt rock physical and mechanical parameters, stratum structure parameters and salt cavern internal structure parameters; selecting a stability evaluation index of the salt-cavern compressed air energy storage library; establishing a three-dimensional geomechanical model of the salt cavern energy storage library and performing simulation calculation; constructing an evaluation model; determining an index weight value of the stability of the salt-cavern compressed air energy storage library; calculating an evaluation grade; and adjusting and optimizing operation parameters of the salt cavern energy storage bank. According to the method, by providing a systematic quantitative analysis process and a unified evaluation index system, the accuracy and reliability of stability evaluation of the salt-cavern compressed air energy storage library are remarkably improved, and an important technical support is provided for development and application of a salt-cavern compressed air energy storage technology. Important technical support is provided for development and application of a salt cavern compressed air energy storage technology, and commercialization and large-scale development of the technology can be promoted.

The invention discloses an integrated optical diversity receiving device, solves the problem of high power consumption when the influence caused by phase distortion and light beam pointing error is corrected in the existing free space optical communication, and belongs to the field of optical communication. The method comprises the steps that free space light focused by a lens is received by a multimode / few-mode optical fiber; the multi-mode light beams received by the multimode / few-mode optical fiber enter the photon lantern; the photon lantern is coupled to the single-mode fiber array after mode demultiplexing; each light beam in the single-mode fiber array enters a polarization beam splitting rotary combiner through an edge coupler; the polarization beam splitting rotation combiner performs transverse electric wave (TE) and transverse magnetic wave (TM) mode separation on the entered light beam, then rotates the separated TM polarization state light to a TE polarization state, combines the rotated TE polarization state light and the separated TE polarization state light, and then enters the MZI network; the MZI network is used for realizing optical coherent beam combination; a control circuit controls the merging of the light beams in the MZI network.

The invention discloses an invisible appliance based on a transparent piezoelectric film and a design method thereof. A perioral muscle pressure sensor is installed on the lip / cheek lingual surface of teeth of the invisible orthodontic appliance, an occlusal force sensor is installed on the occlusal surface, and a tooth surface counter-acting force sensor is installed on the inner side tissue surface, so that dynamic changes of perioral muscle pressure, occlusal force and orthodontic force can be monitored in real time. The invisible orthodontic appliance provided by the invention integrates a sensor with high piezoelectric coefficient and high flexibility, has high sensitivity and accuracy, can be used for testing dynamic changes of orthodontic mechanics and evaluating the influence of perioral muscle pressure, occlusal force and the like on treatment during physiological processes of chewing, breathing, swallowing, language and the like of a patient; a doctor optimizes an orthodontic scheme through the PC terminal and pays attention to the association between oral functional mechanics and malocclusion, bad oral habits, bruxism, temporomandibular joint disorder and other diseases, and the efficiency and accuracy of oral health management are improved.

The invention discloses a sample adjusting device for a microbiological detection analyzer, and relates to the technical field of microbiological detection analysis, the sample adjusting device comprises a device main body, an inner cavity of the device main body is fixedly connected with a fixing plate, the fixing plate is fixedly connected with a servo motor, an output shaft of the servo motor is fixedly connected with a rotating disc, and the rotating disc is fixedly connected with a rotating shaft of the rotating disc. A crank is rotationally connected to the rotating disc, a loading table is rotationally connected to the end, away from the rotating disc, of the crank, a guide rail is fixedly connected to an inner cavity of the device body, and a first sample tube and a second sample tube are arranged on the loading table; in the process that the test tube moves to the position below the first sample tube and the second sample tube, a piston rod of a piston barrel moves, detection liquid in a liquid storage barrel is dropped into the test tube, meanwhile, the dropping quantity of the detection liquid can be adjusted and controlled, errors caused by different persons in manual operation are avoided, and the detection accuracy is improved. In addition, direct contact between operators and reagents and samples is reduced in the automatic process, and the risks of cross contamination and environmental pollution are avoided.

The invention belongs to the field of hydrogen production by alkaline electrolyzed water, and particularly relates to a double-functional-group alkaline electrolyzed water composite diaphragm as well as a preparation method and application thereof. The preparation method of the double-functional-group alkaline electrolyzed water composite diaphragm comprises the following steps: S1, mixing nano ceramic particles with a modification liquid, and performing a modification reaction to obtain amino and sulfydryl double-functional-group modified nano ceramic particles, wherein the modification liquid contains an amino silane coupling agent and a sulfydryl silane coupling agent; the polymer supporting layer is placed in sulfonation liquid to be subjected to sulfonation modification reaction, and then a sulfonated polymer supporting layer is obtained; and S3, mixing the bifunctional group modified nano ceramic particles, a polymer, a pore forming agent and a first organic solvent to obtain a membrane casting solution, degassing the membrane casting solution, coating a sulfonated polymer supporting layer with the membrane casting solution to form a membrane, and performing phase inversion in a coagulating bath to obtain the bifunctional group alkaline electrolyzed water composite membrane. The double-functional-group alkaline electrolyzed water composite diaphragm provided by the invention is good in mechanical property, stable in performance, low in surface resistance and good in air tightness.

The invention discloses a semi-solid sodium-ion battery and a sodium-ion battery additive, and belongs to the technical field of energy materials, the general formula of the semi-solid sodium-ion battery is Na < x > (TM) O < 2 >, TM is one or a combination of transition metal ions, and x is more than or equal to 0.44 and less than or equal to 1.0; the semi-solid sodium-ion battery contains a sodium-ion battery additive, and the sodium-ion battery additive is a sulfide synthesized from a doped metal organic framework compound in a reducing atmosphere. The semi-solid sodium ion battery is prepared by adopting a method of combining sulfide and a small amount of liquid electrolyte, the sulfide is made of a loose and porous material, and holes are filled with the liquid electrolyte, so that the specific surface area and sodium ion transmission channels are increased, and the ionic conductivity is further increased. A reinforcing framework is introduced into the electrode plate, so that the mechanical strength of the electrode plate is improved, and the safety performance of the semi-solid sodium-ion battery is further improved.

A composite structure hollow anti-resonance optical fiber disclosed by the present invention comprises an outer cladding layer, a doping layer and an anti-resonance layer which are sequentially arranged from outside to inside, the anti-resonance layer comprises a plurality of glass nested combination tubes which are uniformly distributed along the circumferential direction, are tangent to the doping layer and are arranged at intervals, and the plurality of glass nested combination tubes surround to form an air fiber core. The glass nested combined pipe comprises an outer nested pipe of a circular structure and an inner nested pipe of an oval structure arranged in the outer nested pipe. The short half axis of the inner nested pipe is arranged in the radial direction of the optical fiber, and the outer ring, away from the air fiber core, of the inner nested pipe is tangent to the inner ring, away from the air fiber core, of the outer nested pipe. According to the invention, a multi-layer nested structure is adopted, and the anti-resonance effect is optimized through the cooperation of the doping layer and the anti-resonance layer with a special structure.

The invention discloses a coated titanium anode and an embedding preparation method thereof, and belongs to the technical field of coated titanium anodes, metal salt powder, an organic additive and inert filler are fully mixed to form embedding agent powder, the mass fraction of metal salt is 45-59%, the mass fraction of the organic additive is 1-5%, and the mass fraction of the inert filler is 40-50%; the sintering treatment is as follows: the pretreated titanium substrate is completely immersed in the embedding agent powder, the sintering temperature is 400-600 DEG C, the sintering time is 1-3 hours, and the heating rate is 5-10 DEG C / min. According to the method, low-temperature sintering is realized by precisely regulating and controlling the components and the proportion of the embedding medium and combining process parameters such as low-temperature sintering, and the damage to a titanium substrate is avoided; and meanwhile, the coating binding force of the titanium anode is improved, the service life of the titanium anode is prolonged, and technical innovation and industrial value are achieved.

The invention discloses a high-hardness polyurethane material and a preparation method thereof.The preparation method comprises the steps that a polyol solution and a phenylethylene solution are mixed according to the same proportion, and a prepolymer is formed; putting the prepolymer and an isocyanate solution into a reaction kettle for pre-pressing, and carrying out heating reaction at a preset temperature; in the heating process, reducing a pressure value set by the reaction kettle at a preset time interval, and reducing a heating temperature value to form a polyurethane prepolymer; mixing the polyurethane prepolymer with a mixture of melamine powder and an isocyanate solution, and uniformly mixing by stirring to obtain a polyurethane blank; and putting the polyurethane blank and the inorganic filler into a reaction kettle for secondary heating to obtain polyurethane in an initial state, and cooling the polyurethane in the initial state to obtain the high-hardness polyurethane material. The hardness, high temperature resistance and mechanical stability of the polyurethane material can be effectively improved, and the technical problem of insufficient hardness in the prior art is solved.

The invention discloses a multi-cable parallel connection anti-bias cable structure, and relates to the technical field of cables, the cable structure comprises a cable body, the cable body is provided with a mounting mechanism, the mounting mechanism comprises a circular ring groove, two circular pipes, a three-way pipe, a sealing plug and a clamping groove, and a rectangular block is fixed in the circular ring groove; according to the invention, the installation mechanism is arranged, so that the multi-cable parallel-connection anti-bias-current cable and the suspension wire can be conveniently installed in an overhead manner in the long-distance overhead laying process, that is, when the multi-cable parallel-connection anti-bias-current cable is subjected to long-distance overhead laying, a constructor can distribute and install the suspension wire and the cable at equal intervals; therefore, the situation that the service life of the cable is affected due to uneven stress of the cable is avoided, the using effect of the multi-cable parallel connection anti-bias-current cable is improved, and meanwhile the using efficiency of the multi-cable parallel connection anti-bias-current cable is improved.

The invention relates to a self-repairing invisible car cover and a preparation method thereof, and relates to the technical field of automobile material processing, and the self-repairing invisible car cover comprises the following components in parts by mass: 20-40 parts of fluorine-containing polyol, 15-30 parts of polyisocyanate, 5-10 parts of a composite chain extender, 10-20 parts of self-repairing microcapsules, 1-3 parts of an initiator and 30-50 parts of a solvent. The preparation method comprises the following steps: preparing a self-repairing coating; coating the surface of the transparent substrate with an adhesive to obtain an adhesive layer, and covering the adhesive layer with a release film to obtain a semi-finished automobile cover; and the self-repairing coating is applied to the face, away from the release film, of the semi-finished automobile cover, heating and curing are conducted, the semi-finished automobile cover with a self-repairing coating is obtained, the self-repairing coating is coated with a protective film, and the self-repairing invisible automobile cover is obtained after curing. The automobile cover has the effect of improving the self-repairing performance of the automobile cover, and the automobile cover has good weather resistance, tensile resistance and puncture resistance.

The invention belongs to the field of preparation processes of nano-porous materials, and relates to a method for preparing a silicon-based elastic aerogel phase-change thermal insulation material by an in-situ chemical method. A phase-change material with an oxygen-containing functional group on the surface is selected as a phase-change core material, a surfactant, deionized water, ethanol, a silicon precursor, acid, alkali and the phase-change core material are uniformly mixed and subjected to hydrolysis, polycondensation and other reactions, meanwhile, the phase-change core material and silicon-based aerogel are subjected to in-situ grafting combination in the process, and the silicon-based aerogel is prepared. The silicon-based elastic aerogel phase change thermal insulation material is prepared through sol-gel and supercritical drying. The invention innovatively provides an in-situ grafting method, and the constructed silicon-based elastic aerogel phase-change thermal insulation material integrates multiple functions of high thermal insulation property, elasticity, leakage prevention, high response rate and the like, has the advantages of low material cost and convenient preparation process, and is low in energy consumption and easy to realize large-scale production.

The invention relates to the field of electrochemical oxidation, and particularly discloses a preparation method of a co-doped modified Ti4O7 electrode, and the preparation method comprises the following steps: 1, mixing Ti4O7 powder, a metal source and a non-metal source, and carrying out ball milling to obtain mixed powder; and 2, adding a binder and an organic dispersant into the mixed powder, and carrying out ultrasonic treatment, heating and stirring, drying and sintering to obtain the co-doped modified Ti4O7 electrode. The co-doped modified Ti4O7 electrode prepared by the invention has excellent chlorine evolution and sterilization performance, and can be applied to purification treatment of wastewater containing ammonia nitrogen pollutants and long-acting maintenance of disinfection and sterilization of small water bodies such as circulating water, landscape water, ballast water and the like.

The invention relates to a double-layer coated silicon-carbon composite material, a preparation method thereof and a lithium ion battery. The preparation method comprises the following steps: adding a porous carbon precursor with a particle size D50 of 5-10 [mu] m into a chemical vapor deposition furnace, and introducing monosilane for 100-800 min for silicon deposition to obtain a silicon-carbon composite material; introducing acetylene gas, and reacting for 50 to 500 minutes to obtain a primary carbon-coated silicon carbon composite material; dissolving lithium nitrate in absolute ethyl alcohol, adding the primary carbon-coated porous silicon-carbon composite material, stirring and dispersing, dropwise adding an ammonium dihydrogen phosphate solution into the solution, and reacting at 60-80 DEG C for 1-3 hours; and carrying out suction filtration, cleaning and drying on the reacted material to obtain the porous silicon-carbon composite material with the double-layer coating structure. Through the double-layer coating structure, the electrochemical stability and mechanical stability of the material are improved, and meanwhile, the application scene of the silicon-carbon negative electrode material at low temperature is expanded.

The invention discloses a preparation method of a high-cycle-resistance water-based aluminum pigment, relates to the technical field of chemical materials, and aims to improve the cycle resistance of the aluminum pigment, and the preparation method comprises the following steps: adding silver type aluminum pigment slurry into a double-jacket reactor, dispersing with isopropanol, and stirring to obtain an aluminum pigment suspension; coating the surface of the aluminum pigment with a flexible organic polymer; and then carrying out secondary coating by using a rigid silane coupling agent. The invention further discloses the high-cycle-resistance water-based aluminum pigment prepared by the method and application of the high-cycle-resistance water-based aluminum pigment in automatic spraying of water-based automobile paint. According to the invention, a double-layer or even multi-layer coating system is adopted, the inner layer coats the aluminum pigment core with a flexible organic polymer such as polyvinyl butyral, the outer layer coats the aluminum pigment core with a rigid silane coupling agent, the inner layer provides buffering, the outer layer enhances protection, and the inner layer and the outer layer have a synergistic effect, so that the prepared pigment has very high deflation stability and mechanical stability; and the shear resistance is high.

The invention relates to the technical field of surgical robots, in particular to an RCM mechanism for cataract surgery and a corresponding surgical robotic.The RCM mechanism comprises a first active supporting rod, a second active supporting rod, a third active supporting rod and a fourth active supporting rod, the first end of the first active supporting rod is slidably arranged on a guide rail, the second active supporting rod comprises a telescopic part and a supporting rod part, and the second end of the telescopic part is hinged to a first base; the first end of the telescopic part is connected with the supporting rod part; the second end of the first driven supporting rod is connected with the first driving supporting rod through a sliding part, the first end of the supporting rod part is hinged to the first driven supporting rod, the second end of the second driven supporting rod is parallel to the first driven supporting rod, and the second end of the second driven supporting rod is hinged to the second end of the supporting rod part; the first end of the driven piece is hinged to the first end of the first driven supporting rod, and the second end of the driven piece is hinged to the first end of the second driven supporting rod; according to the surgical robot provided by the invention, the accuracy and safety of the surgery can be realized, and ophthalmologic surgeries such as cataract and the like can be carried out more quickly and noninvasively.

The invention relates to the technical field of hydrophobic flame-retardant materials, and discloses a method for preparing a super-hydrophobic flame-retardant flexible material from a water-dispersed nanocellulose compound, which comprises the following steps: preparing a nanocellulose suspension; synthesizing silicon dioxide nanoparticles; preparation of a precursor suspension: mixing SiO2 nanoparticles, methyltrimethoxysilane and the nanocellulose suspension in proportion, and carrying out a reaction to obtain the precursor suspension; preparing a polyvinyl alcohol solution; preparing a water-dispersible plant nano cellulose compound mixed solution, and freezing the water-dispersible plant nano cellulose compound mixed solution; and carrying out freeze drying treatment and heat treatment on the frozen material to obtain the super-hydrophobic flame-retardant flexible material. According to the method for preparing the super-hydrophobic flame-retardant flexible material by adopting the water dispersible nano-cellulose compound, the material preparation process is green and pollution-free, and the prepared flexible material has the characteristics of high elasticity, high oil absorbency, reusability, fire resistance, degradability and the like, and can be applied to various fields.

The invention relates to a preparation method of a multilayer alloy net electrode for hydrogen production by alkaline electrolysis of water and the multilayer alloy net electrode, and the preparation method comprises the following steps: firstly, selecting an alloy electrode net material, then etching the alloy electrode net, and carrying out electrochemical etching by taking the alloy electrode net as an anode and an inert electrode as a cathode and using 0.5-5M acid liquor to prepare the multilayer alloy net electrode. The preparation method comprises the following steps: sequentially overlapping a first layer of pure nickel net with the mesh number of 80-200 and a second layer of etched alloy electrode net with the mesh number of 40-80 and a third layer of etched alloy electrode net with the mesh number of 20-40, carrying out vacuum sintering at 800-1400 DEG C for 2-5 hours, and finally stirring and drying in a polyethyleneimine aqueous solution. Compared with the prior art, the obtained electrode has the advantages of being low in cost, high in catalytic activity, fast in bubble removal, high in durability and stability and the like, effectively solves many problems of an existing alkaline water hydrogen production electrode, has a wide application prospect in the field of alkaline water electrolysis hydrogen production, can remarkably improve the water electrolysis efficiency and is beneficial to large-scale industrial production.

The invention provides a manufacturing method of a heat sink strip for a high-density interconnected printed circuit board. S1, heat dissipation strips I are manufactured on the core plate; s2, carrying out electroplating treatment on the manufactured heat dissipation strip I, so that the heat dissipation strip I is completely filled with electroplating copper; s3, manufacturing the core board into a laminated board; s4, manufacturing a heat dissipation strip II on the laminated board; s5, carrying out electroplating treatment on the manufactured heat dissipation strip II, so that the heat dissipation strip II is completely filled with electroplating copper; the size of the heat dissipation strip I can be designed according to the shape and size of the heating element, so that the heat dissipation strip I is in large-area contact with the heating element, and heat generated by the heating element is absorbed more uniformly; the heat dissipation strip II is connected with the heat dissipation strip II after being filled with electroplating copper, the heat dissipation strip II and the copper layer in the laminated board form a continuous copper heat dissipation area penetrating through the whole laminated board, and the copper heat dissipation area is good in heat conduction effect and can also play a role in auxiliary supporting. Therefore, the mechanical stability of the whole printed circuit board and the elements adopting the printed circuit board is better, and the risk of damage caused by external force is also reduced.

The invention relates to a titanium carbide thin film material, a preparation method and a zinc ion hybrid capacitor, and the preparation method of the titanium carbide thin film material comprises the following steps: mixing titanium carbide nanosheets with an aqueous solution of ammonium salt, carrying out ultrasonic treatment, carrying out solid-liquid separation, and taking the supernatant liquid to obtain an intercalated titanium carbide nano colloid; adding a water-soluble salt into the intercalated titanium carbide nano colloid, reacting, carrying out solid-liquid separation, washing with water, and drying to obtain titanium carbide aerogel; and carrying out compression molding on the titanium carbide aerogel to obtain the titanium carbide film material. The super-wrinkled titanium carbide film prepared through a nanosheet distortion strategy has obviously improved compression resistance. Under the pressure of 1MPa, the microstructure of the electrode material does not change. In addition, the titanium carbide thin film material has lower tortuosity and can be directly used for constructing an electrode, ion transmission can be accelerated, the dynamic performance of the electrode is remarkably improved, and the requirement for high-quality load application is met.

The invention relates to the technical field of special polymer functional membranes, and discloses a polybenzimidazole gas separation membrane as well as a preparation method and application thereof, the polybenzimidazole gas separation membrane has an interpenetrating network-shaped pore structure, and the polybenzimidazole gas separation membrane has a nanoscale pore structure. The pore size distribution of the nanoscale pore structure is 0.1-30 nm, and the average pore size of the nanoscale pore structure is 1-80 nm. The polybenzimidazole gas separation membrane has an interpenetrating network-shaped pore structure and a nanoscale pore structure, so that the polybenzimidazole gas separation membrane has relatively high gas selectivity and permeability coefficient and also has relatively good mechanical properties.

The invention relates to the technical field of biological medicines, in particular to a soluble skin-adhering microneedle for delivering an inactivated enterovirus vaccine as well as a preparation method and application of the soluble skin-adhering microneedle. Sodium hyaluronate is adopted as a film forming material to wrap an enterovirus 71 type (EV71)-coxsackie virus A16 (CA16) type bivalent inactivated vaccine antigen, and a needle body layer of the soluble microneedle is formed; the substrate layer is prepared from a pullulan material, so that the microneedle patch with a stable overall structure is formed. The technology provided by the invention is completed in a clean environment, and the vaccine patch which is qualified through sterility detection is obtained. The soluble microneedle disclosed by the invention has good antigen stability under the condition of 2-8 DEG C. In animal experiments, the microneedle is attached to the skin surface of a mouse for skin-adhering immunization, a strong immune response reaction can be induced, good immunogenicity is shown, and a novel, safe and effective vaccine delivery way is provided for prevention and control of the infantile hand-foot-and-mouth disease.

The invention provides a spinel oxide catalyst as well as a preparation method and application thereof. According to the present invention, the spinel oxide catalyst has the hollow nano-tubular structure, and comprises NiCo2O4 particles, and the specific surface area of the catalyst is large by means of the hollow nano-tubular structure, such that more reaction active sites are provided, and electrolyte diffusion and gas desorption during the water electrolysis oxygen evolution process are easily achieved. Through research, the spinel oxide catalyst has excellent OER electrocatalytic activity. Meanwhile, the catalyst also has relatively small charge transfer resistance, good reaction kinetics and cycling stability.

The invention provides a dopamine hybrid ligand ZIF-8 / gelatin composite aerogel and a preparation method and application thereof, and belongs to the field of composite aerogel and preparation thereof.The growth rate of ZIF-8 nanocrystals is accurately controlled through dopamine hybrid coordination metal ions, stable ZIF-8-DA hybrid crystals are formed, and the stability of the aerogel is improved. The crystal not only solves the problem that the traditional MOF material is easy to aggregate particles, but also retains abundant chemical functional groups; furthermore, the ZIF-8-DA and a gelatin matrix are compounded by adopting a multi-crosslinking strategy and a freeze-thaw treatment technology to obtain the composite aerogel with a unique three-dimensional porous microstructure, so that the mechanical strength and the structural stability of the composite aerogel are remarkably improved, and the composite aerogel shows better heat-insulating and flame-retardant properties; the composite aerogel material prepared by the scheme has excellent heat insulation and flame retardant properties, and is suitable for high-energy-consumption fields such as building energy conservation, industrial heat management and environmental flame retardance.

The invention discloses a preparation method of an efficient and stable TiNi alloy-based porous composite structure electro-catalysis electrode, and relates to a preparation method of an electro-catalysis electrode. The invention aims to solve the problem that the existing hydrogen evolution electro-catalysis electrode cannot simultaneously have high hydrogen production efficiency, low cost and excellent stable performance. The preparation method comprises the following steps: 1, pretreating the sodium metaaluminate pore-forming agent; 2, ball-milling and mixing; (3) preparing a porous TiNi-based alloy; and 4, compounding a catalytic active layer. The method is used for preparing the efficient and stable TiNi alloy-based porous composite structure electro-catalysis electrode.

The present invention discloses a dietary fiber that can be used for weight management and has high expansion in gastric juice, and its preparation and application. The dietary fiber is composed of a three-dimensional network structure and a support structure interlaced. The three-dimensional network structure is generated by a condensation reaction of a polycarboxylic acid and a cellulose derivative. The structure has limited expansion capacity in gastric juice, and may lose resistance to gastric pressure or gastric acid erosion after expansion, so it is relatively weak in prolonging gastric retention. Therefore, the present invention introduces anionic polysaccharides, cationic polysaccharides, and inorganic calcium salts as support structures, so that the dietary fiber maintains a high expansion force in gastric juice, and at the same time, the mechanical strength and stability are significantly enhanced, providing a long-lasting feeling of fullness to the gastrointestinal tract. This innovative design is expected to play an important role in weight loss and diet control, and provide potential benefits for patients with obesity, obesity syndrome and diabetes.