The application belongs to the technical field of
polymer materials and
engineering, and discloses a preparation method of a
phosphate cross-linked organic porous
uranium extractant. A
phenylacetylene is cross-linked with 1,4-dithioerythritol through a
click chemistry reaction by using a photo-induced cross-linking method. Compared with common mercaptans, 1,4-dithioerythritol contains an adsorption group. The cross-linking reaction is carried out under the condition that the ratio is 1:3 and the
light irradiation time is 1h. An
organic polymer PCM with a porous structure is synthesized. After the synthesized
polymer is subjected to Soxhlet extraction for 48h, the
polymer is modified by phosphating with
phosphorus oxychloride to prepare a porous polymer containing a
phosphate group. After the synthesized polymer is subjected to Soxhlet extraction for 48h and is dried, a purple black
powder P-PCM is obtained. The target polymer can be synthesized only through three steps of reactions. The polymer preparation is relatively simple under the photo-induced cross-linking, which is of great significance to improving the
uranium adsorption capacity. The preparation is simple, the reaction is stable, the safety is high, and the cost is low through the
click chemistry reaction.