469 results about "Natural polymers" patented technology

The invention provides an injectable short-fiber-based hydrogel tissue repair material with an electric response characteristic as well as a preparation method and application thereof, and the injectable short-fiber-based hydrogel tissue repair material with the electric response characteristic is prepared by taking a natural polymer material loaded with bioactive factors as a core layer material and a biodegradable material as a shell layer material through a coaxial electrostatic spinning technology. The method comprises the following steps: preparing short fibers with a core-shell structure, uniformly mixing the short fibers with a hydrogel matrix, injecting and filling a tissue defect part, and carrying out ultraviolet curing to form the tissue repair material. The injectable short-fiber-based hydrogel tissue repair material with the electrical response characteristic provided by the invention has piezoelectric characteristic and injectable characteristic, can generate electrical response through mechanical stimulation so as to promote cell proliferation and tissue repair, and also has controllable drug release capacity and good mechanical adaptability; the method is suitable for application scenes of complex tissue damage repair such as diabetes infected wound repair, articular cartilage repair, oral barrier membrane repair, abdominal wall defect repair and the like.

The invention relates to a poly-(2-oxazoline) epoxy derivative and application thereof, and belongs to the technical field of crosslinking. The invention provides a poly-(2-oxazoline) epoxy derivative, which is completely different from existing cross-linking agents such as 1, 4-butanediol diglycidyl ether (BDDE), divinyl sulfone, glycidyl methacrylate and the like in structure, and has the advantages that the structure is simple; the polymer can be used as a cross-linking agent for cross-linking natural high-molecular polymers such as polysaccharide (such as hyaluronic acid) and protein and synthetic high-molecular polymers such as polyethylene glycol and polyvinyl alcohol. Compared with an existing cross-linking agent, the poly-(2-oxazoline) epoxy derivative has the advantages that the poly-(2-oxazoline) epoxy derivative can be easily subjected to a cross-linking reaction with high-molecular polymers such as hyaluronic acid, the prepared cross-linked substances such as sodium hyaluronate gel are more stable and uniform, the performance of the prepared cross-linked substances is easier to regulate and control and the like, and the poly-(2-oxazoline) epoxy derivative has a great application prospect.

The invention relates to the technical field of water treatment, and particularly provides a polyaluminum chloride composite water treatment agent and a preparation method thereof, and the polyaluminum chloride composite water treatment agent comprises the following components in percentage by weight: 80-90% of polyaluminum chloride; 0.5%-2% of modified chitosan; 3%-8% of sodium lignosulphonate-Fe < 3 + > complex; 0.1%-0.5% of a pH regulator; wherein the modified chitosan is citric acid cross-linked chitosan, the deacetylation degree of the modified chitosan is not lower than 85%, and in the sodium lignosulphonate-Fe < 3 + > complex, the molar ratio of Fe < 3 + > to sodium lignosulphonate is 1: 3. Through the synergistic interaction of polyaluminum chloride and a natural polymer composite system, the design of an efficient, green and multifunctional water treatment agent is realized.

The invention discloses a high-valued graded utilization method of marine shells, and belongs to the technical field of comprehensive utilization of biological resources and preparation of functional materials. The method comprises the following steps: cleaning, air-drying and superfine grinding marine shell wastes such as abalone shells, and extracting water-soluble organic components in the marine shell wastes by adopting mild water extraction, so that the obtained extract is rich in protein, polysaccharide or small molecule peptide, has good biological activity, and can be used for preparing functional materials such as biomimetic mineralization, tissue repair and the like; extracted shell powder residues are subjected to heat treatment or chemical activation treatment and then compounded with natural polymer materials such as chitosan and sodium alginate, and the composite adsorbent which is loose in structure and large in specific surface area is prepared and can be used for removing dye, heavy metal, antibiotics and other water pollutants. According to the invention, separate utilization of organic components and inorganic framework materials in the marine shells is realized, and the method has the characteristics of environmental protection, efficient resource conversion and multifunctional application, and has a good industrial popularization prospect.

The present invention relates to the field of metal corrosion and protection, and specifically to a preparation method and application of a modified chitosan Schiff base corrosion inhibitor. The preparation method comprises six steps: (1) preparing a gel-like chitosan dispersion; (2) preparing an ethanol solution of 2,6-dimethyl-5-heptenal; (3) adding the gel-like chitosan dispersion; (4) adding the ethanol solution of 2,6-dimethyl-5-heptenal and conducting a Schiff base reaction; (5) rotary evaporation and dehydration of the reaction product; and (6) washing, filtering, and drying. The present invention utilizes 2,6-dimethyl-5-heptenal, a common food additive, as a modifier to condense with natural polymer chitosan to prepare an acid corrosion-resistant corrosion inhibitor, with a simple process and low production cost. The invention is applied to N80 steel sheets in a hydrochloric acid medium for corrosion protection, uses a low concentration, and effectively improves the corrosion inhibition rate of the corrosion inhibitor on metals. The invention is a green, environmentally friendly, economical, and efficient corrosion inhibitor with good promotion prospects.

The invention relates to the technical field of natural polymer material processing, and discloses a cross-linked composite chitosan solution which is composed of the following components in percentage by mass: 1%-5% of chitosan, 0.1%-5% of a cross-linking agent, 0.1%-5% of acetic acid and the balance of water, and the cross-linked composite chitosan solution is prepared from the following components in percentage by mass: 1%-5% of chitosan, 0.1%-5% of a cross-linking agent, 1%-5% of acetic acid and the balance of water. The cross-linking agent is one or more of glutaraldehyde, citric acid and epoxy chloropropane. According to the cross-linked composite chitosan solution and the preparation method of the chitosan fiber of the cross-linked composite chitosan solution, the adaptability of the cross-linked composite chitosan solution in a human body can be further improved and the immunoreaction can be reduced through a cross-linking reaction, so that the enhancement of the biocompatibility of the cross-linked composite chitosan solution can be ensured; by selecting different cross-linking agents and controlling the cross-linking degree, the biodegradation rate of the chitosan can be adjusted to a certain extent, so that the chitosan is more suitable for specific medical or environmental application requirements, and in addition, the water resistance of the chitosan can be remarkably improved through the cross-linking effect.

The invention provides an intelligent antibacterial konjac glucomannan composite film and a preparation method thereof. The intelligent antibacterial konjac glucomannan composite film is prepared by carrying out graft copolymerization on oxidized konjac glucomannan OKGM and amino-functionalized poly (N-isopropylacrylamide) PNIPAM-NH2 and then crosslinking with an antibacterial agent, the tail end of a molecular chain of the amino-functionalized poly (N-isopropylacrylamide) is provided with an amino group. The intelligent antibacterial konjac glucomannan composite film disclosed by the invention has temperature responsiveness, can control the release of an antibacterial agent according to environmental changes, ensures that the antibacterial agent is accurately released as required, and effectively prolongs the food preservation time and the food shelf life. The film is good in biocompatibility, has no obvious toxic reaction on human tissues and cells, and provides possibility for application in the field of biomedicine. Besides, the film has degradability, and the OKGM and the chitosan are natural high polymer materials and can be decomposed into harmless substances by microorganisms in the natural environment, so that the film meets the requirements of environmental protection and is beneficial to reducing environmental pollution.

The invention relates to the technical field of polymer composite materials, and discloses a refining treatment method of a bamboo fiber ultra-nano micro powder and natural polymer blended material, which comprises the following steps: (a) premixing bamboo fiber ultra-nano micro powder and a deep eutectic solvent to obtain a premix and realize in-situ activation; (b) adding the premix and a natural polymer matrix from a main feed port of a double-screw extruder; and (c) in the melt blending process, adding a dynamic interface locking agent through a side feeding port arranged at the downstream of the main feeding port, and then extruding and granulating. A staged dynamic compatibilization process is adopted, a hydrogen bond network of bamboo fibers is destroyed by using a deep eutectic solvent to promote shearing dispersion of the bamboo fibers in the front section, and stable interface bonding is constructed in the rear section through a dynamic interface locking agent after dispersion is completed. The method synergistically solves the conflict between dispersion and interfacial compatibilization, so that the composite material has good comprehensive performance.

The invention relates to the technical field of ecological restoration, in particular to an ecological restoration composite material and a preparation method thereof. Comprising a base material: 30-70 parts of a natural polymer material or a degradable synthetic polymer material; reinforced fibers: 5-40 parts of natural fibers or degradable synthetic fibers; a functional additive: 10-40 parts of at least one of a water-retaining agent, an organic fertilizer, a microbial carrier and a soil conditioner; a plant growth promoter: 1-15 parts of humic acid, a seaweed extract, a trace element fertilizer or an antagonistic antibacterial agent; a binder: 0 to 15 parts of a degradable polymer binder; and 5-15 parts by weight of water. According to the invention, the biodegradability of the material is ensured, the mechanical strength is improved and the overall performance of the composite material is enhanced by optimizing the combination of base materials, pretreating the reinforced fibers, achieving the synergistic effect of the multifunctional additive and efficiently loading the plant growth promoter; the ecological restoration composite material provides long-term support for plant growth.

The invention relates to a cellulose-chitosan-based lithium ion battery diaphragm and a preparation method and application thereof.The preparation method of the diaphragm comprises the steps that gamma-polyglutamic acid and polyamide epichlorohydrin are adopted for modifying chitosan, the hydrophilicity and the liquid absorption capacity of the chitosan are improved, polyvinylpyrrolidone is adopted for coating the chitosan, and the hydrophilicity and the liquid absorption capacity of the chitosan are improved; pVP is replaced in ethanol soaking to form micropores, so that the porosity of the modified chitosan is improved. Amino groups and hydroxyl groups of the modified chitosan are combined with catechol of the polydopamine and hydroxyl groups of the hydroxy propyl cellulose through hydrogen bonds and covalent bonds to form a chitosan-cellulose-PDA interpenetrating network, and the diaphragm material suitable for the lithium ion battery is finally prepared by combining hot-pressing shaping. The preparation method has the advantages that the balance between the mechanical property and the ion conduction property of the diaphragm is realized through multi-component compounding by utilizing the biocompatibility and renewability of natural macromolecules (cellulose and chitosan).

Disclosed in the present invention are a gel having a regulatable free water content and morphology, a preparation method therefor, and the use thereof. The method comprises: S1, preparing a solution A from a natural polymer material; S2, mixing a small molecule material containing a positively charged polar group with the solution A to obtain a composite solution B; S3, mixing the composite solution B with a regulator to obtain a composite solution C, stirring same, then adding a condensing agent to the reaction system, and carrying out a curing crosslinking reaction; and S4, removing the regulator and the condensing agent to obtain the gel. By adjusting the concentrations of the natural polymer material and the regulator, gels having different morphologies can be prepared; the gel undergoes a physical process to remove hydrogen bond interaction between the gel and free water, so that the content of free water attached to the surface of the gel can be regulated, thereby regulating the physical and chemical properties of the gel. The gel of the present invention has regulatable morphology and controllable elastic modulus, and has many advantages such as good lubrication effect, good biocompatibility and biodegradability, capability of being biologically active, and capabilities of stimulating cell growth and accelerating wound repair.

The invention discloses a long-acting analgesic compound as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing a mixed solution containing a polymer, a local anesthetic, a non-steroidal anti-inflammatory drug and a solvent into drug-loaded microspheres through an electrostatic spraying technology; the preparation method comprises the following steps: dissolving poloxamer and a natural polymer material in water to obtain a hydrogel solution; and uniformly mixing the drug-loaded microspheres and a hydrogel solution to prepare the long-acting analgesic compound. The long-acting analgesic compound comprises drug-loaded microspheres and hydrogel, the long-acting analgesic compound and the hydrogel are both of a three-dimensional porous network structure, the drug-loaded microspheres are evenly dispersed in the hydrogel, and the drug-loaded microspheres are of a solid spherical structure. The advantages of electrostatic spraying microspheres and hydrogel are combined, the preparation method is mild in condition and simple in process, and the preparation process is non-toxic and harmless; the long-acting analgesic compound has the advantages of thermosensitivity, injectability, high drug loading rate and the like, and can be effectively applied to preparation of analgesic products.

The invention belongs to the technical field of chemical modification of natural polymer materials, and particularly relates to a modified cellulose adhesive and a preparation method thereof. The modified cellulose adhesive is prepared from the following components in parts by weight: 50 to 70 parts of modified cellulose-based emulsion, 10 to 20 parts of VAE (Vinyl Acetate Ethylene) composite emulsion, 5 to 8 parts of rosin water emulsion, 3 to 8 parts of cross-linking agent and 2 to 5 parts of plasticizer, the modified cellulose is obtained by grafting an epoxy hypophosphite compound and a fluorine-containing pentaphenyl alkynyl dicarboxylic acid compound with a nano cellulose solution; according to the prepared modified cellulose adhesive, targeted improvement of waterproofness, durability and bonding strength is achieved through molecular design.

The invention discloses a multifunctional coating with a compact-porous double-layer structure on the surface of magnesium alloy and a preparation method, and belongs to the technical field of biological materials. According to the multifunctional coating, magnesium alloy serves as a substrate, a compact layer and a porous layer are sequentially stacked from the substrate to the outside, and the compact layer is composed of two-dimensional transition metal carbide / nitride, calcium silicate nanowires and a positively charged polymer. The porous layer is composed of copper-containing complex / biopolymer composite fibers, mineralized silk fibers loaded with bioactive metal ions and astragalus polysaccharide on the surface, and natural polymers. According to the multifunctional coating with the compact-porous double-layer structure prepared on the surface of the magnesium alloy, the porous layer on the surface layer has a unique porous structure, growth and proliferation of osteoblasts can be well promoted, meanwhile, the multifunctional coating has the characteristics of pressure resistance, bacteria resistance and oxidation resistance, the compact layer on the bottom layer can improve the corrosion resistance of the magnesium alloy, and the service life of the magnesium alloy is prolonged. The coating is particularly suitable for surface coating of magnesium alloy implant materials and can be used in the field of medical instruments.

The invention provides a method for preparing vaterite type nanoscale calcium carbonate with ardealite as a raw material and application of the method, and relates to the technical field of inorganic nano-material preparation.The method comprises the following steps that firstly, efficient dissociation of calcium ions in the ardealite is achieved through a phase transfer method, then digestion treatment is conducted on a leaching solution, and the leaching solution is obtained; a crystal morphology regulating agent is further introduced to construct a mineralized microenvironment, and then through a carbon dioxide carbonization reaction, vaterite type nano-scale calcium carbonate with a specific average particle size (200-400 nm) is prepared. According to the preparation method, natural high polymer materials such as collagen are introduced in the preparation process to serve as green crystal form guiding agents, so that the coordination effect of the natural high polymer materials and calcium ions can be utilized, the crystal morphology can be effectively regulated and controlled, and the biocompatibility of the nano material is improved; and the application possibility of calcium carbonate in the biomedical fields of drug carriers, bone repair materials and the like is expanded.

The invention provides a water-based suspension pesticide composition. The water-based suspension pesticide composition comprises the following components: a solvent deionized water; based on the mass of the solvent, the core-shell structure active particles account for 0.5-20w%; based on the mass of the solvent, 0.01-5w% of a suspension stabilizer; the core-shell structure active particles are humidity response microspheres resistant to acid and alkali, the core-shell structure active particles are used, intermolecular acting force is reduced, particle agglomeration is reduced, dispersity of active ingredients is improved, a natural polymer material is adopted as a shell, biocompatibility is good, biodegradability is achieved, pollution to the environment is reduced, and the core-shell structure active particles are environmentally friendly. Meanwhile, the PEG-PCL block copolymer is introduced, so that the pesticide release rate can be accurately controlled according to the environment humidity change, and the pesticide utilization rate is increased. Moreover, the chitosan-sodium alginate composite gel of the particle shell layer is stably and slowly released in neutral and weakly alkaline soil, in acidic and strongly alkaline environments, the microspheres are prevented from collapsing, the stability of the particle slow-release system in soil with different PH values is improved, and the application range of the active particles is expanded.

The invention relates to an application of carboxylated chitin or carboxylated chitosan in promoting insect-killing fungi to prevent and treat diseases and insect pests. Research finds that carboxylated chitin or carboxylated chitosan can significantly promote spore germination and hypha growth of insecticidal fungi, also can significantly enhance stress resistance of the insecticidal fungi, significantly enhance toxicity of the insecticidal fungi to pests, improve ultraviolet resistance and high temperature resistance of the insecticidal fungi, and improve the insecticidal activity of the insecticidal fungi. The invention also finds that the carboxylated chitin or chitosan can effectively inhibit the growth of Xanthomonas oryzae pv. Oryzae. Therefore, the carboxylated chitin or the carboxylated chitosan can be used for preparing a product for enhancing the insecticidal fungus effect and a product for preventing and treating the rice bacterial leaf blight, and the prevention and treatment of plant diseases and insect pests are realized. In addition, carboxylated chitin and carboxylated chitosan are derived from natural polymer materials, have the characteristics of safety, no toxicity, biodegradability, environmental friendliness and the like, are environment-friendly and economical, and have wide application prospects and market values.

The invention relates to the technical field of water treatment, and discloses a silicon powder conditioner and a preparation method thereof, the silicon powder conditioner comprises 20-40% of an inorganic coagulant, 5-15% of an organic polymer coagulant, 3-10% of a natural polymer coagulant aid, 10-25% of a demulsifier, 2-8% of a synthetic coagulant aid, and the balance of water. The demulsifying agent is compounded with various coagulants and coagulant aids, the demulsifying agent preferentially destroys an oil-water interfacial film, releases wrapped silicon powder and eliminates the'colloid protection 'effect of oil stains on the surface of the silicon powder, and the inorganic and organic coagulants rapidly perform electrical neutralization and adsorption bridging on exposed silicon powder particles to form floc which is good in settling performance and easy to filter. Meanwhile, the inorganic coagulant provides positive charges and efficiently neutralizes the microfine silicon powder with negative charges; cPAM with high molecular weight and PDADMAC with strong cations form long-chain bridging and patching effects, so that fine particles with the particle size of 1-5 microns are specially captured, and meanwhile, larger-particle silicon powder is improved to form floc which is easy to filter; the natural polymer further increases the volume and density of the floc, and prevents the floc from being broken under shearing.

The invention discloses a protective coating treating agent, a protective coating treating fluid, modified forage and a preparation method and application thereof, and belongs to the technical field of ecological engineering. The protective coating treating agent comprises a first component, a second component and a third component in a mass ratio of 10: (0.5-2.5): (1-3), the first component is a natural polymer film-forming material; the second component is a plant-derived functional anti-degradation agent; and the third component is a natural mineral particle reinforcing agent. The protective coating treating agent containing the components is prepared into a protective coating treating fluid, and then the protective coating treating fluid is coated on the surface of forage to form a protective coating, so that the aging resistance of the straw checks in environments of high temperature, strong ultraviolet rays, sand erosion and microbial erosion can be remarkably improved, the service life of the straw checks is prolonged, and the service life of the straw checks is prolonged. And the operation and maintenance cost of ecological restoration engineering is reduced. The straw checkerboard with the protective coating can be widely applied to ecological engineering construction such as treatment of railways, highways and sand source areas in arid and windy sand areas.

The invention discloses injectable oxygen-carrying and medicine-carrying microbubble composite hydrogel with immunoregulation performance and a preparation method of the injectable oxygen-carrying and medicine-carrying microbubble composite hydrogel, and belongs to the field of tissue damage treatment. The preparation method comprises the following steps: carrying out a reaction on hyaluronic acid HA and dipalmitoyl phosphatidyl ethanolamine DPPE to construct a microbubble monomer DPPE-HA; the preparation method comprises the following steps: fully dissolving DPPC (dipalmitoyl phosphatidylcholine), DPPE-HA (dipalmitoyl phosphatidylcholine) and a therapeutic drug into a solvent, introducing oxygen and carrying out mechanical oscillation to obtain oxygen-carrying and drug-carrying microbubbles; the oxygen-carrying and drug-carrying microbubbles are uniformly doped into a vinyl modified natural polymer solution, and the oxygen-carrying and drug-carrying microbubble composite hydrogel is formed through photo-crosslinking. The obtained injectable microbubble hydrogel can be used for treatment of different tissue injuries, including wound repair and burn treatment, osteochondral injury repair, cardiovascular disease treatment and nerve injury repair, in addition, the injectable microbubble hydrogel can also be applied to the fields of cosmetic plastic surgery, skin regeneration and the like, and has a wide clinical application prospect.

The invention relates to the technical field of natural polymer material processing, in particular to a high-strength cellulose membrane and a preparation method thereof.The preparation method comprises the following steps that a solvent is prepared from an alkaline aqueous solution and a stabilizer to dissolve cellulose, and a cellulose solution is obtained after filtering and defoaming; the cellulose solution is regenerated in a salting-out bath after being extruded through a slit, and a carbonate solution or a mixed salt solution of carbonate and sulfate is selected as the salting-out bath; and washing, drafting and drying the regenerated product to obtain the high-strength cellulose membrane. Carbonate and sulfate ions in the salting-out bath can polarize hydrated water molecules around cellulose molecular chains, destroy hydrogen bond interaction between the cellulose molecular chains and water and water molecules and interfere hydrophobic interaction of the cellulose molecular chains, so that the water molecules are discharged from the cellulose molecular chains; the interaction among hydroxyl groups on a cellulose skeleton is enhanced, compact and uniform nanofibers are formed, and the mechanical property of the film is remarkably improved.

The invention belongs to the technical field of vaccine adjuvants, and particularly relates to a water-in-oil-in-water adjuvant, a veterinary vaccine and a preparation method thereof.The water-in-oil-in-water adjuvant is prepared from, by weight, 0.5%-7.5% of a hydrophilic composite surfactant, 0.6%-9.8% of an oleophylic composite surfactant, 70%-85% of mineral oil and the balance water; and the mineral oil also comprises the following components in concentration: a reinforcing agent of 0.45-0.9 g / ml and a stabilizing agent of 2-6.9 g / L, wherein the water-in-oil-in-water adjuvant forms a gelatinous structure under the regulation of the stabilizer and is a non-Newtonian fluid of which the viscosity is not higher than 25cp; the adjuvant shows the non-flowing fluid characteristic through the stabilizer, the rheological property of the produced vaccine is enhanced, the stability of the vaccine is improved, on the premise that the hydrophilic surfactant and the oleophylic surfactant are balanced, the natural polymer enhancer is added, and on the premise that the adjuvant viscosity is reduced and granuloma side reaction is not prone to being generated, the stability of the vaccine is improved. Short-term immunity and long-term immunity can be induced at the same time, and the application of the water-in-oil-in-water adjuvant in the field of veterinary vaccines is expanded.

The invention discloses a method for in-situ rapid growth of a dual-network hydrogel coating on the surface of a base material by a one-step method, which comprises the following steps: putting the base material with an adhesion initiation layer on the surface into a hydrogel precursor solution, and carrying out in-situ polymerization for 0.1-10 minutes under light irradiation, wherein the adhesion initiation layer comprises an adhesive compound based on a catechol group and a first photoinitiator, and the hydrogel precursor solution comprises a natural polymer containing tyrosine, an acrylic monomer, a cross-linking agent and a second photoinitiator, and wherein the first photoinitiator and the second photoinitiator are different from each other and are independently selected from a divalent ruthenium compound and a persulfate. Compared with the prior art, the natural / synthetic polymer double-network gel coating with biological activity and mechanical property can grow on the surfaces of different substrates more quickly and efficiently through a one-step method; and the base material, the surface of which is modified by the in-situ grown double-network hydrogel coating, obtained by the method can be applied to in-vivo medical apparatuses and instruments.

The invention relates to the technical field of adhesive preparation, in particular to an epoxy resin-based paper adhesive and a preparation method thereof, and the epoxy resin-based paper adhesive is prepared from the following raw materials in parts by weight: 40-55 parts of an epoxy resin matrix, 18-29 parts of a bio-based reinforcing system, 15-25 parts of a recovery adaptation system and 10-15 parts of a toughening system; the epoxy resin matrix is composed of bisphenol A epoxy resin and epoxidized soybean oil. According to the invention, bio-based modified epoxy resin and natural polymer partially replace petrochemical raw materials, carbon footprint is significantly reduced, the defect of insufficient water resistance of a biological material is made up through a nanocellulose composite enhancement technology, and a thermo-sensitive polyvinyl alcohol and initiator system is introduced, so that the binder can be rapidly stripped under mild conditions during recovery, and the recovery rate of the binder is increased. According to the scheme, high bonding strength is kept, meanwhile, comprehensive optimization of recoverability, environmental adaptability and cost effectiveness is achieved, and reliable technical support is provided for green upgrading of the corrugated paper industry.

The invention belongs to the field of hydrogel material preparation, and particularly relates to high-strength gelatin-curdlan hydrogel and a preparation method thereof. The preparation method of the high-strength gelatin-curdlan hydrogel comprises the following steps: preparing a gelatin aqueous solution and a curdlan dimethyl sulfoxide solution, heating, uniformly mixing and slowly cooling the two solutions to obtain organic gel, removing an organic solvent from the organic gel, drying, and swelling the dry gel in water by absorbing water to obtain the high-strength composite hydrogel. Two natural polymers are used as raw materials, curdlan is driven to form a nanofiber structure in gelatin through high-temperature rapid mixed annealing and solvent conversion, the hydrogel with the interpenetrating network structure of nanofibers is formed, and the composite hydrogel has higher strength and higher biocompatibility compared with pure gelatin hydrogel and can be used for preparing the hydrogel with the interpenetrating network structure. The obvious application prospect is realized in the field of biomedical materials.

The invention discloses a soil-improving growth-promoting modified lignin soil conditioner and a preparation method thereof, and belongs to the technical field of high polymer materials and soil improvement. The modified lignin soil conditioner comprises an agent A, an agent B and an agent C, the agent A is a cationic modified lignin polymer and is prepared by graft copolymerization of lignosulfonate and a cationic monomer in a free radical initiation mode; the agent B is lignin controlled-release particles and is prepared by wrapping an amino acid amphoteric regulator in the cationic modified lignin polymer and another negative charge natural polymer through electrostatic intercalation self-assembly; the agent C is at least one of citric acid, lactic acid, itaconic acid, fulvic acid, wood vinegar, maleic acid, maleic anhydride and polyacrylic acid. The soil conditioner disclosed by the invention has the advantages of low cost, environment friendliness and efficient repairing performance, and an innovative solution is provided for agricultural soil improvement.

The invention discloses a polymer electrolyte, a preparation method thereof and a battery, and the preparation method of the polymer electrolyte comprises the following steps: dissolving a polymer containing a nucleophilic functional group in a polar solvent to obtain a first polymer solution; dissolving a natural high-molecular polymer in a polar solvent to obtain a second polymer solution; mixing the first polymer solution and the second polymer solution to form a double-polymer solution; adding a cross-linking agent into the double-polymer solution, casting, standing and curing to obtain a polymer film; immersing the polymer membrane in a polar solvent for removing the residual cross-linking agent and the non-cross-linked polymer and carrying out soaking swelling absorption, and then freeze-drying at a temperature of-55 DEG C to-35 DEG C, so that pores are formed in the polymer membrane to form a porous polymer membrane; and soaking the porous polymer membrane to absorb electrolyte containing lithium salt, and standing to obtain the dual-network polymer electrolyte. The ionic conductivity of the polymer electrolyte is effectively improved.

The invention belongs to the technical field of biomedical materials, and discloses a conductive composite scaffold of a bionic nerve orientation structure and a preparation method of the conductive composite scaffold of the bionic nerve orientation structure, and the conductive composite scaffold of the bionic orientation structure is formed by compounding a structural layer and a functional layer, the structural layer is an oriented nanofiber membrane (made of a natural high-molecular polymer containing amino and a synthetic high-molecular polymer), the functional layer is ionic conductive hydrogel (made of a natural high-molecular polymer containing amino and a natural high-molecular polymer containing carboxyl), and the structural layer and the functional layer are compounded through the action of an amido bond; the amido bond is formed by reacting amino of the oriented nanofiber membrane with carboxyl of the ionic conductive hydrogel under an acidic condition; the preparation method comprises the following steps: compounding the structural layer and the functional layer by using glacial acetic acid by adopting a chemical cross-linking method to prepare the conductive composite nerve scaffold with the bionic orientation structure. According to the invention, electric signal transmission between cells can be realized, and the efficiency of damaged nervous tissue repair is improved.

The invention discloses a composite shell layer fire extinguishing microcapsule and a preparation method thereof, and belongs to the field of fire extinguishing agent preparation, the first shell layer of the composite shell layer fire extinguishing microcapsule is polyurethane resin, the shell layer can be preliminarily formed at the temperature of 0-10 DEG C, and then the temperature is gradually increased to improve the compactness of the shell layer, so that core material escape caused by temperature rise can be reduced; therefore, the yield of the microcapsules is improved, and the quality of the microcapsules can be ensured; the second shell layer adopts gelatin, chitosan, sodium alginate and other natural polymers as raw materials, glutaraldehyde, triethylamine, calcium chloride and other curing agents are correspondingly used, a compact film is formed outside the first shell layer, the compactness of the overall shell layer of the fire extinguishing microcapsule is further improved, the application performance of the fire extinguishing microcapsule is guaranteed, and the fire extinguishing microcapsule has the advantages of being safe, environmentally friendly and excellent in fire extinguishing performance on the whole.

The invention discloses amphiphilic phosphorus-loaded biomass gel and a preparation method and application thereof, and the preparation method comprises the following steps: dissolving a hydrophilic natural polymer material in a solvent to form a uniformly dispersed biomass gel emulsion; activating the biomass gel emulsion by an activating agent A and an activating agent B to obtain pre-activated biomass gel emulsion; dissolving a long-chain alkyl material in water to form a uniformly dispersed emulsion, and uniformly mixing the uniformly dispersed emulsion with the pre-activated biomass gel to obtain a modified biomass gel emulsion; adding a phosphorus-containing solvent and a pore-foaming agent, and mixing to form a porous gel emulsion; after the porous gel emulsion and the biomass gel emulsion are fully mixed, a cross-linking agent is added for a cross-linking reaction. The gel obtained by the invention has an amphiphilic structure of a hydrophobic microcell and a phosphorus-containing hydrophilic group, can play a synergistic effect of electrostatic attraction and hydrophobic repulsion, and realizes selective separation and recovery of rare earth elements in water; the preparation method is simple, raw materials are green, and the method is suitable for large-scale production and has good application prospects.