223 results about "Natural polymers" patented technology

The invention relates to the technical field of polymer composite materials, and discloses a refining treatment method of a bamboo fiber ultra-nano micro powder and natural polymer blended material, which comprises the following steps: (a) premixing bamboo fiber ultra-nano micro powder and a deep eutectic solvent to obtain a premix and realize in-situ activation; (b) adding the premix and a natural polymer matrix from a main feed port of a double-screw extruder; and (c) in the melt blending process, adding a dynamic interface locking agent through a side feeding port arranged at the downstream of the main feeding port, and then extruding and granulating. A staged dynamic compatibilization process is adopted, a hydrogen bond network of bamboo fibers is destroyed by using a deep eutectic solvent to promote shearing dispersion of the bamboo fibers in the front section, and stable interface bonding is constructed in the rear section through a dynamic interface locking agent after dispersion is completed. The method synergistically solves the conflict between dispersion and interfacial compatibilization, so that the composite material has good comprehensive performance.

The invention relates to a cellulose-chitosan-based lithium ion battery diaphragm and a preparation method and application thereof.The preparation method of the diaphragm comprises the steps that gamma-polyglutamic acid and polyamide epichlorohydrin are adopted for modifying chitosan, the hydrophilicity and the liquid absorption capacity of the chitosan are improved, polyvinylpyrrolidone is adopted for coating the chitosan, and the hydrophilicity and the liquid absorption capacity of the chitosan are improved; pVP is replaced in ethanol soaking to form micropores, so that the porosity of the modified chitosan is improved. Amino groups and hydroxyl groups of the modified chitosan are combined with catechol of the polydopamine and hydroxyl groups of the hydroxy propyl cellulose through hydrogen bonds and covalent bonds to form a chitosan-cellulose-PDA interpenetrating network, and the diaphragm material suitable for the lithium ion battery is finally prepared by combining hot-pressing shaping. The preparation method has the advantages that the balance between the mechanical property and the ion conduction property of the diaphragm is realized through multi-component compounding by utilizing the biocompatibility and renewability of natural macromolecules (cellulose and chitosan).

Disclosed in the present invention are a gel having a regulatable free water content and morphology, a preparation method therefor, and the use thereof. The method comprises: S1, preparing a solution A from a natural polymer material; S2, mixing a small molecule material containing a positively charged polar group with the solution A to obtain a composite solution B; S3, mixing the composite solution B with a regulator to obtain a composite solution C, stirring same, then adding a condensing agent to the reaction system, and carrying out a curing crosslinking reaction; and S4, removing the regulator and the condensing agent to obtain the gel. By adjusting the concentrations of the natural polymer material and the regulator, gels having different morphologies can be prepared; the gel undergoes a physical process to remove hydrogen bond interaction between the gel and free water, so that the content of free water attached to the surface of the gel can be regulated, thereby regulating the physical and chemical properties of the gel. The gel of the present invention has regulatable morphology and controllable elastic modulus, and has many advantages such as good lubrication effect, good biocompatibility and biodegradability, capability of being biologically active, and capabilities of stimulating cell growth and accelerating wound repair.

The invention belongs to the technical field of vaccine adjuvants, and particularly relates to a water-in-oil-in-water adjuvant, a veterinary vaccine and a preparation method thereof.The water-in-oil-in-water adjuvant is prepared from, by weight, 0.5%-7.5% of a hydrophilic composite surfactant, 0.6%-9.8% of an oleophylic composite surfactant, 70%-85% of mineral oil and the balance water; and the mineral oil also comprises the following components in concentration: a reinforcing agent of 0.45-0.9 g / ml and a stabilizing agent of 2-6.9 g / L, wherein the water-in-oil-in-water adjuvant forms a gelatinous structure under the regulation of the stabilizer and is a non-Newtonian fluid of which the viscosity is not higher than 25cp; the adjuvant shows the non-flowing fluid characteristic through the stabilizer, the rheological property of the produced vaccine is enhanced, the stability of the vaccine is improved, on the premise that the hydrophilic surfactant and the oleophylic surfactant are balanced, the natural polymer enhancer is added, and on the premise that the adjuvant viscosity is reduced and granuloma side reaction is not prone to being generated, the stability of the vaccine is improved. Short-term immunity and long-term immunity can be induced at the same time, and the application of the water-in-oil-in-water adjuvant in the field of veterinary vaccines is expanded.

The invention discloses a method for in-situ rapid growth of a dual-network hydrogel coating on the surface of a base material by a one-step method, which comprises the following steps: putting the base material with an adhesion initiation layer on the surface into a hydrogel precursor solution, and carrying out in-situ polymerization for 0.1-10 minutes under light irradiation, wherein the adhesion initiation layer comprises an adhesive compound based on a catechol group and a first photoinitiator, and the hydrogel precursor solution comprises a natural polymer containing tyrosine, an acrylic monomer, a cross-linking agent and a second photoinitiator, and wherein the first photoinitiator and the second photoinitiator are different from each other and are independently selected from a divalent ruthenium compound and a persulfate. Compared with the prior art, the natural / synthetic polymer double-network gel coating with biological activity and mechanical property can grow on the surfaces of different substrates more quickly and efficiently through a one-step method; and the base material, the surface of which is modified by the in-situ grown double-network hydrogel coating, obtained by the method can be applied to in-vivo medical apparatuses and instruments.

The invention discloses amphiphilic phosphorus-loaded biomass gel and a preparation method and application thereof, and the preparation method comprises the following steps: dissolving a hydrophilic natural polymer material in a solvent to form a uniformly dispersed biomass gel emulsion; activating the biomass gel emulsion by an activating agent A and an activating agent B to obtain pre-activated biomass gel emulsion; dissolving a long-chain alkyl material in water to form a uniformly dispersed emulsion, and uniformly mixing the uniformly dispersed emulsion with the pre-activated biomass gel to obtain a modified biomass gel emulsion; adding a phosphorus-containing solvent and a pore-foaming agent, and mixing to form a porous gel emulsion; after the porous gel emulsion and the biomass gel emulsion are fully mixed, a cross-linking agent is added for a cross-linking reaction. The gel obtained by the invention has an amphiphilic structure of a hydrophobic microcell and a phosphorus-containing hydrophilic group, can play a synergistic effect of electrostatic attraction and hydrophobic repulsion, and realizes selective separation and recovery of rare earth elements in water; the preparation method is simple, raw materials are green, and the method is suitable for large-scale production and has good application prospects.

The invention relates to an in-situ copolymerized and hybridized flocculant and a preparation method and an application method thereof, the in-situ copolymerized and hybridized flocculant comprises an inorganic metal, an organic monomer and a composite natural polymer material package, and the flocculant is formed by segmented in-situ polymerization of the inorganic metal, the organic monomer and the composite natural polymer material package, the inorganic metal is treated metal solid waste leachate; according to the preparation method, a segmented in-situ path of first induced polymerization and then skeleton hybridization is adopted; the application method adopts a one-step conditioning mode. Solid waste leachate is used as a reaction medium, an NVCL monomer is dissolved and polymerized to form an active long chain, then a natural polymer material bag is introduced to realize deep hybridization of space connection and chemical crosslinking, and the floc strength and filter pressing dehydration property in sludge flocculation treatment are improved through a synergistic mechanism. Rapid flocculation and deep dehydration under different mud properties are realized, and the green and environment-friendly properties are improved.

The application provides a formula system and a preparation method for improving the solubility and stability of ceramide NP, and belongs to the cosmetic field.The formula system comprises: an active ingredient, an emulsifier, a thickening agent and a solvent; the active ingredient is ceramide NP; the emulsifier comprises at least one of an anionic emulsifier, a natural polymer emulsifier, a non-ionic emulsifier and a phospholipid emulsifier; and the solvent comprises water, a polyhydric alcohol and an oil-soluble solvent.The formula system has an unexpected technical effect of greatly improving the stability of an oil-in-water cosmetic containing more ceramide NP by selecting suitable emulsifiers, thickening agents and solvents.

The invention relates to the technical field of daily chemicals, in particular to a color-protecting laundry detergent containing plant extracts and a preparation method of the color-protecting laundry detergent. The color-protecting laundry detergent is prepared from the following components in percentage by mass: 12.5 to 18.3 percent of natural anionic surfactant, 6.4 to 9.7 percent of nonionic surfactant, 3.2 to 5.8 percent of plant polyphenol extract, 3.0 to 5.2 percent of fiber affinity natural polymer, 2.1 to 4.0 percent of bio-based chelating aid, 1.8 to 3.5 percent of natural glycoside synergist, 0.9 to 2.3 percent of pH buffering agent, 0.6 to 1.4 percent of antioxidant plant essential oil and the balance of deionized water. The compound protease comprises alkaline protease, neutral protease and papain; the invention aims to solve the technical problems that the existing laundry detergent is poor in color protection effect, insufficient in environmental protection performance and large in damage to fabrics, and provides a laundry detergent product which takes natural plant extracts as core components and has an efficient color protection function.

This invention discloses a cross-linked copolymer coating for negative electrodes, its preparation method, and its application, relating to the field of solid-state battery negative electrode protection technology. The coating is formed by in-situ copolymerization of a precursor composition consisting of carbonate monomers with unsaturated double bonds, hydroxyl-rich natural polymer derivatives, lithium salts, and an initiator. The rigid cellulose skeleton in the copolymer regulates the degree of polymerization of the carbonate monomers through a hydrogen bond network, forming a protective layer with a rigid-flexible block structure, resulting in a uniform and dense SEI film. The hydrogen bond anchoring effect of high-density hydroxyl and carbonyl groups inhibits polycarbonate segment degradation and improves interfacial chemical stability. The three-dimensional hydrogen bond network endows the coating with excellent mechanical strength and flexibility, synergistically buffering volume changes and inhibiting lithium dendrite growth. This preparation process is simple and controllable, effectively reducing the probability of battery short circuits and improving safety performance and cycle stability.

The invention discloses biomimetic mineralized porous aerogel as well as a preparation method and application thereof, and belongs to the technical field of natural polymer-based composite materials. The preparation method comprises the following steps: dissolving sodium alginate powder in a weakly alkaline aqueous solution containing phosphate to obtain a uniformly dispersed precursor solution; freezing treatment is performed to form frozen gel with an ice crystal template structure; immersing the frozen gel into a solution containing calcium ions, and synchronously realizing crosslinking of a sodium alginate network and in-situ mineralization of hydroxyapatite at low temperature to obtain mineralized composite gel; finally, the mineralized composite gel is subjected to solvent replacement and normal-pressure drying treatment, and the biomimetic mineralized aerogel is prepared. According to the method, ionic crosslinking and in-situ mineralization are synergistically realized through a one-step method, the process is simple and efficient, expensive equipment is not needed, and the cost is low. The prepared aerogel has a rich pore structure, a high specific surface area and good biological activity, and has a wide application prospect in the fields of environmental adsorption materials, biological scaffold materials and the like.

The present application relates to the technical field of bamboo fiber composite material, in particular to a purification preparation method of bamboo fiber reinforced natural polymer composite material. The bamboo raw material is crushed and treated by steam explosion to obtain primary bamboo fiber; the primary bamboo fiber is sequentially subjected to organic solvent dewaxing treatment and oxidation system selective delignification treatment to obtain purified bamboo fiber; the purified bamboo fiber is treated in a tannin acid solution to form a polyphenol interface layer on the surface thereof; and a solution containing polyvalent metal ions is added to the treated bamboo fiber to form a coordination cross-linking interface layer on the surface of the bamboo fiber. The present application constructs a stable interface layer between the fiber and the natural polymer matrix. The interface layer can effectively transfer stress, significantly improve the tensile strength, bending strength and shear strength of the composite material, and solve the problem of weak interface and easy delamination of traditional natural composite materials.

The invention provides a sealing material for wet tissues as well as a preparation method and application of the sealing material. The sealing material comprises a hydrophobic oil phase and temperature-sensitive microspheres, the temperature-sensitive microspheres are dispersed in the hydrophobic oil phase to form a heterogeneous system; the temperature-sensitive microsphere is of a core-shell structure, and the core-shell structure comprises an inner core and an outer shell wrapping the inner core; the inner core comprises a temperature-sensitive cross-linked network and polysaccharide capable of being subjected to ionic cross-linking, and the shell is a porous shell body network and is formed by carrying out copolymerization reaction on a natural polymer derivative capable of being subjected to photo-crosslinking and a comonomer containing an active chemical group. The temperature-sensitive microspheres with core-shell structures are designed to cooperate with the hydrophobic oil phase, rapid hemostasis of dynamic and bleeding wet tissues is realized through a dual drainage mechanism of instantaneous drainage of the hydrophobic oil phase and active pumping of the temperature-sensitive inner core, and then stable chemical bonding is formed through cross-linking of the shell and tissue protein, so that the rapid hemostasis of the dynamic and bleeding wet tissues is realized. And the wet tissue is sealed.

The present disclose relates to a high-reactivity hydrogel particle and preparation method therefor and use thereof. The preparation method comprises the following steps: (1) performing polymerization reaction of double-bond modified polyethylene glycol, a modified natural polymer and an optional active functional monomer to obtain a gel; (2) smashing the gel to obtain a gel particle; and (3) performing enzymolysis reaction of the gel particle and an enzyme to obtain the hydrogel particle with reactivity. The double-bond modified polyethylene glycol has a double bond and a polyethylene glycol chain segment, the modified natural polymer has sulfydryl or a double bond, the active functional monomer is selected from a sulfydryl functionalized biological adhesive peptide or sulfydryl functionalized cholesterol, and the enzyme is an enzyme corresponding to the natural polymer. The obtained hydrogel particle has high reactivity and can be used for subsequent secondary crosslinking. The hydrogel particle also has good biocompatibility.

The invention discloses a high-strength self-lubricating three-layer nested medicine-carrying hollow cervical cerclage band with an auxiliary miscarriage prevention function and a preparation method of the cerclage band, and belongs to the technical field of medical instruments. Degradable polyester monofilaments are woven into a hollow round rope, and the hollow round rope and a medical curved needle are integrated; then carrying out polydopamine-polyethylene glycol double-layer modification on a copper-based metal organic framework (Cu-MOF), and loading active molecules; then mixing the drug-loaded Cu-MOF with collagen natural polymer sol, and uniformly filling the gel into the inner cavity of the round rope and forming a three-dimensional bracket through synchronous drawing type micro-perfusion and light-enzyme synergistic cross-linking; then constructing a transient hydrated lubricating layer on the surface; and finally carrying out ethylene oxide final sterilization to obtain a finished product. The cervical cerclage band device provided by the invention simultaneously provides degradable mechanical support, collagen scaffold induction and long-acting slow release regulation, has a low-friction implantation characteristic, and can be well used for preventing or treating middle and late abortion and premature delivery caused by cervical insufficiency.

The invention relates to the technical field of hemostatic materials, in particular to composite hemostatic gel as well as a preparation method and application thereof. The composite hemostatic gel is prepared from the following components in percentage by mass: 0.5 to 3 percent of carboxymethyl chitosan, 0.5 to 5 percent of trehalose, 1 to 10 percent of glycerol, 0.1 to 2 percent of carbomer, 0.1 to 2 percent of recombinant blood coagulation factor III, 0.005 to 0.05 percent of benzalkonium chloride and the balance of Tris-HCl buffer solution. Based on the synergistic effect of a natural high polymer material carboxymethyl chitosan and a bioactive component recombinant blood coagulation factor III, the gel constructs a'physical adsorption-blood coagulation activation 'dual hemostasis pathway, realizes a rapid and multi-mechanism hemostasis function, has antibacterial and repair promoting characteristics, can be widely applied to various bleeding scenes such as cutting wounds and surgical wounds, and has wide application prospects. The wound healing is effectively promoted.

The invention discloses a bionic cross-linked film-forming repair dressing containing mussel mucoprotein and a preparation method of the bionic cross-linked film-forming repair dressing, and relates to the technical field of medical instruments. The bionic crosslinking film-forming repair dressing containing the mussel mucoprotein is prepared from the following components in parts by weight: 30 to 40 parts of bionic crosslinking agent, 25 to 35 parts of humectant, 10 to 20 parts of natural high polymer material, 1 to 10 parts of mussel mucoprotein, 1000 parts of purified water and 5 to 15 parts of pH regulator. PEG-DOPA is formed through cross-linking, the DOPA content and stability are remarkably improved, the adhesion-repair-anti-inflammatory effect of mussels mainly depends on the dopa content, the effect of the dressing is remarkably enhanced through improvement of the DOPA content and stability, the dressing is more convenient to use through the flexibility change of a film, the dressing is more suitable for dynamic and wet wounds, and the application range of the dressing is widened. The medicine has a remarkable effect on chronic ulcer and burn.

The invention discloses a coal gasification slag-based aerogel porous material and application thereof, and belongs to the field of compounds of non-metallic elements. The preparation method comprises the following steps: by taking regional bulk coal-based solid waste-coal gasification slag and a self-gelling natural polymer material as raw materials, pretreating the coal gasification slag to remove heavy metal ions, then preparing dispersion liquid from the coal gasification slag and a self-gelling natural polymer material solution, and carrying out first freeze drying to obtain a solidified material; then, soaking by using a cross-linking agent to form cross-linked aerogel, fully soaking the cross-linked aerogel by using a tert-butyl alcohol solution, and performing freeze drying for the second time to obtain the coal gasification slag-based aerogel porous material. The prepared composite aerogel has super-hydrophilicity, excellent water absorption and water retention properties and excellent photo-thermal conversion performance. Due to the characteristics, the composite aerogel can be used as a soil water-retaining agent or a soil conditioner; or is used as an interface evaporation material for treating high-salinity wastewater.

The invention discloses hydrogel for ulcers and a preparation method thereof.The hydrogel is obtained through a cross-linking reaction with polyphenol substance modified gelatin, aldehyde natural polymers and methacrylate gelatin as frameworks, and the hydrogel has injectability and can be injected to oral ulcers or pressure ulcers, and the hydrogel can also be used as a hydrogel for ulcers or oral ulcers or pressure ulcers or oral ulcers or pressure ulcers or pressure ulcers or pressure ulcers or pressure ulcers or pressure ulcers or pressure ulcers or pressure ulcers or pressure ulcers or pressure ulcers or pressure ulcers. The hydrogel can be prepared into a sheet shape to be applied to the ulcer surface, has good biocompatibility, compression resistance, wet adhesion, angiogenesis promotion, hemostasis, inflammation resistance and oxidation resistance, and is beneficial to healing of oral ulcers and pressure ulcers.

The invention relates to a method for improving the strength properties of a nonwoven material. The method includes forming a nonwoven web comprising cellulose-based fibers, and optionally drying the nonwoven web. A strength composition is applied to the nonwoven web. The strength composition comprises (i) a glyoxalated polyacrylamide and (ii) a natural polymer selected from the group consisting of non-charged and cationically charged polysaccharides, non-charged and cationically charged polysaccharide derivatives, and any mixture thereof. The invention also relates to the nonwoven material obtained and to the use of the strength composition.

The invention relates to the field of agricultural biochemical engineering and plant protection, and particularly discloses a liquid film-forming agent for preventing crops from freezing injury due to late spring coldness and a preparation method of the liquid film-forming agent. The film-forming agent is prepared from carboxymethyl chitosan, sodium carboxymethyl cellulose, kasugamycin, brassinolide, glycol and glycerol mixed dihydric alcohol, Tween 80 and deionized water according to a specific proportion. The preparation method comprises the key processes of step-by-step dissolution, mixing, functional component addition and the like. Organic fusion of physical barrier, ice nucleus inactivation and physiological regulation is realized through multiple action mechanisms of natural polymer composite film forming, biopesticide targeted sterilization, plant hormone induced cold resistance and dihydric alcohol synergistic antifreezing. The product can provide efficient protection at a low temperature of-4 DEG C, significantly reduces the frost damage rate, has the characteristic of 28-day natural rapid degradation, and solves the technical bottlenecks of single function, difficult degradation and poor environmental compatibility of a traditional film agent.

The application discloses a water-retaining agent with salt resistance and urease inhibition, and a preparation method and application thereof, and belongs to the technical field of water-retaining in agriculture and forestry. The water-retaining agent is prepared from the following raw materials in mass parts: 100 parts of monomers, 3-10 parts of anionic natural polymer derivatives, 0.1-0.5 parts of cross-linking agents, 5-15 parts of modified lithium saponite or modified bentonite, and 0.1-1 parts of initiators; wherein the monomers are one or more of acrylic acid, acrylic acid salt or acrylamide; and the modified lithium saponite or modified bentonite is obtained by modifying lithium saponite or bentonite by quaternary ammonium salt natural polymer derivatives. The water-retaining agent has high water absorption ratio and salt water absorption ratio, can maintain stable water absorption and water retention performance in a high-salt environment, can delay the urea hydrolysis rate and reduce nitrogen loss, can realize synchronous application of the water-retaining agent and fertilizer, and can simplify farm operations.

The invention provides a preparation method of acacia gum nano-composite hydrogel. The preparation method comprises the following steps: S1, mixing an acacia gum aqueous solution with a free radical initiator, and then sequentially adding acrylonitrile, CuFe2O4 nanoparticles and a cross-linking agent into the mixture to obtain the acacia gum nano composite hydrogel. The acacia gum nano-composite hydrogel combines the characteristics of a natural polymer, a synthetic polymer and inorganic nanoparticles, and is an effective adsorbent for removing heavy metals in an aqueous solution, the prepared magnetic hydrogel is treated by hydroxylamine hydrochloride, so that a nitrile group is converted into an amidoxime group to serve as a bidentate ligand, and the adsorption capacity of the hydrogel is improved. The existence of CuFe2O4 in the acacia gum nano-composite hydrogel makes the recoverable magnetic hydrogel possible, the recoverable magnetic hydrogel can be easily removed from an aqueous solution and regenerated, and after three continuous cycles, the recoverable magnetic hydrogel still has high heavy metal adsorption capacity.

The invention discloses a biomass waste-based compost fertilizer for improving saline-alkali soil and a preparation method thereof, and belongs to the technical field of fertilizer preparation, the compost fertilizer comprises the following raw materials: a biomass waste basic mixture, charcoal, desulfurized gypsum, zeolite powder, hydroxyapatite, sodium lignin sulfonate, EDTA-metal chelate and polyaspartic acid; the biomass waste base mixture comprises animal waste, crop straw and agricultural product processing by-products. On the basis of a biomass waste resource utilization concept, the compost fertilizer with a multi-mechanism synergistic effect is constructed through precise compatibility of components such as the biochar, the desulfurized gypsum, the zeolite, the hydroxyapatite, the natural polymer and the metal chelate and optimization of a two-stage fermentation and aging process, and aims to break through the bottleneck of the prior art. An innovative solution is provided for green and sustainable improvement of the saline-alkali soil.

The application discloses a degradable organic-inorganic composite film and a preparation method and application thereof, and belongs to the technical field of composite materials. The method comprises the following steps: (1) preparing a calcium phosphate nanocluster precursor by using an organic amine stabilizer, a calcium source, a phosphorus source and an organic solvent, and further separating the calcium phosphate nanocluster; (2) mixing the calcium phosphate nanocluster and a natural polymer material to prepare a uniformly dispersed emulsion, wherein the natural polymer material comprises carboxymethyl chitosan and an alginate, and film is prepared by using the emulsion; in the film preparation process, an evaporation-induced self-assembly process occurs, the calcium phosphate nanocluster is phase changed into crystalline rod-shaped hydroxyapatite nanocrystals, and the natural polymer material is combined, so that the degradable organic-inorganic composite film is obtained. The mechanical property of the organic-inorganic composite film is adjustable, the organic-inorganic composite film can be directly degraded in soil, and has a wide application prospect in the fields of packaging, agriculture, medical treatment and the like.

This application relates to an anti-icing coating, its preparation method, and its application, belonging to the field of protective coating technology. The anti-icing coating comprises a superhydrophobic self-cleaning coating and a hydrophobic and oleophobic layer stacked together. The superhydrophobic self-cleaning coating includes first SiO2 nanoparticles and fluorosilane. The hydrophobic and oleophobic layer includes second SiO2 nanoparticles, nanocellulose, chitosan nanoparticles, and a binder. The use of natural polymer materials such as nanocellulose and chitosan nanoparticles in the hydrophobic and oleophobic layer results in lower cost and better environmental friendliness. The superhydrophobic self-cleaning coating achieves superhydrophobic properties through the synergistic effect of a nano-dispersion system and a "papillary" micro-nano rough structure. The hydrophobic and oleophobic layer further enhances the coating's hydrophobic and oleophobic properties and surface lubricity, significantly reducing the adhesion of ice to the coating surface.

The invention provides three-dimensional interconnected porous skeleton structure carbon aerogel as well as a preparation method and application thereof, and belongs to the technical field of electrode materials. The green deep eutectic solvent is used for cellulose modification, and efficient carboxylation can be realized under the condition that a crystal structure is not damaged, so that the dispersity and the compatibility with conductive components are improved. The MOF template is used as a sacrificial template, a porous structure is formed through induction in carbonization, and the conductivity of the material is improved through the metal center effect; a three-dimensional network is constructed by using a gelatinizing agent, so that the gel strength is improved, and the aerogel skeleton forming is ensured. According to the method, the carbon aerogel is prepared by combining carboxylation of the deep eutectic solvent, doping of the natural polymer gelatinizing agent and regulation and control of the MOF soft template, and the structure of the carbon aerogel and the electrochemical performance of the carbon aerogel in a three-electrode system are remarkably improved by utilizing the synergistic effect of the three components.

The present disclosure relates to a method for modifying the shape of permeable fibers, such as keratinous fibers, enabling in particular styling of mammalian hair fibers. The method comprises applying to the fibers a composition comprising a natural polymer and a fatty agent, both being water-insoluble and jointly polymerizable, and a water-soluble hygroscopic agent, all afore-said ingredients being small enough to permit their penetration within the fibers; leaving the composition on the fibers for sufficient time so that at least part of said materials penetrate within the fibers; and curing the water-insoluble ingredients to internally form a shapeable polymer capable of maintaining the fibers in a desirable shape. Compositions adapted for such method and kits allowing to prepare the same are also disclosed.

The invention discloses a composite artificial cavity / membrane tissue and a preparation method thereof. The composite artificial cavity / membrane tissue is formed by compounding a synthetic high-molecular material and a natural high-molecular biological material, and the synthetic high-molecular material is selected from more than one of silicone, synthetic high-molecular hydrogel and an acrylic polymer. The natural polymer biological material is selected from more than one of an acellular matrix scaffold material, a non-acellular matrix and non-acellular collagen. The composite artificial cavity / membrane tissue provided by the invention has the advantages of good healing after transplantation, high biomechanical strength, low immunogenicity, smooth surface and the like.

The application belongs to the technical field of bio-based packaging materials, and particularly relates to a novel double-layer composite film and application thereof. The novel double-layer composite film comprises the following steps: reacting palmitic anhydride and carboxymethyl cellulose to obtain carboxymethyl cellulose palmitate; adding a pH-sensitive natural dye indicator to obtain carboxymethyl cellulose palmitate nanoemulsion containing a pH-sensitive substance; then loading a natural polymer material to prepare a film material; finally adding the film material to the carboxymethyl cellulose palmitate to prepare a composite film, thereby obtaining the novel double-layer composite film. The double-layer composite film can be self-emulsified without adding a surfactant, and has the ability to load functional indicator (pH-sensitive color indicator) substances; meanwhile, the barrier performance of the film material, such as a chitosan film, to water vapor and oxygen is improved, and the double-layer composite film has a very promising application in food or fruit preservation. The method provided by the application is not only green in raw materials, but also uses a flow casting method, which can be applied to industrial production and has a good application prospect.