The invention discloses a hydroxyapatite modified
bentonite material as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing a hydroxyapatite-
bentonite composite material by utilizing a
precipitation method, and modifying by utilizing
polyaluminum chloride, specifically, dropwise adding a
calcium nitrate tetrahydrate aqueous solution into an
ammonium dihydrogen
phosphate solution by utilizing a
peristaltic pump to react, adjusting the pH value by utilizing
ammonia water in the dropwise adding process, stirring at constant temperature to react, washing to be neutral by utilizing water and absolute ethyl
alcohol, and
drying to obtain n-HAP; adding the
bentonite solution into the
polyaluminum chloride solution, adjusting the pH value with NaOH, uniformly stirring, standing, carrying out suction
filtration, washing to be neutral, and
drying to obtain Al-B; the preparation method comprises the following steps: uniformly mixing n-HAP and Al-B, dispersing and stirring, adding
glutaraldehyde to carry out a cross-linking reaction, adjusting the pH value, stirring at a constant temperature, standing, aging, centrifugally washing and
drying to obtain the n-HAP / Al-B
composite material which is low in cost, large in adsorption capacity and high in stable regeneration performance, and the n-HAP / Al-B
composite material is applied to
fluorine ion-containing
wastewater, has a remarkable
fluorine removal effect and has a good application prospect.