The invention provides a packaging container which comprises an outmost thermoplastic material layer, a core layer, an intermediate thermoplastic material layer, a blocking layer and an innermost thermoplastic material layer from outside to inside. The innermost thermoplastic material layer contains metalloscene catalyst polymerized linear low density polyethylene (MLLDPE) and low density polyethylene (LDPE), the MLLDPE has following parameters: average density of 0.88g / cm3-0.925g / cm3, melt flow index (190 DEG C, 2.16kg) of 5g / 10min-20g / 10min, peak melting point of 85 DEG C-130 DEG C, and expansion ratio of 1.2-1.8, and the LDPE has following parameters: average density of 0.90g / cm3-0.925g / cm3, melt flow index (190 DEG C, 2.16kg) of 5g / 10min-20g / 10min, peak melting point of 85 DEG C-110 DEG C, and expansion ratio of 1.2-1.8. A longitudinal sealing portion can realize quick thermal sealing during the process of manufacturing the packaging container, sealing intensity is high, and the manufactured packaging container is high in pass percentage and long in shelf life of liquid food.