2294 results about "High entropy alloys" patented technology

The invention discloses a high-entropy alloy bonding phase SiC hard composite material and a preparation method thereof, the SiC hard alloy composite material is a double-phase composite material and comprises SiC and high-entropy alloy, and the high-entropy alloy is AlMnCuiFeTi and AlZnCuFeTi. The proportion of the raw materials is 5 wt.%-20 wt.%. And the size of the SiC particles is 200 [mu] m. During preparation, firstly, the high-entropy alloy is prepared through mechanical alloying; after uniform mixing, a graphite mold is filled with the mixture for prepressing, the prepressing pressure is 10-50 MPa, and prepressing is conducted for 10-30 s; and then hot pressed sintering is carried out, the sintering pressure is 20-50 MPa, the sintering temperature is 1400-2000 DEG C, heat preservation is carried out for 10-90 min, and the high-entropy alloy bonding phase SiC hard alloy composite material is prepared. The liquid phase generated in the high-entropy alloy sintering process is used for reducing the sintering temperature, the organization structure is improved, and the hardness and toughness of the tungsten carbide hard alloy are improved.

The invention relates to the technical field of alloy coatings, and discloses a laser cladding high-entropy alloy coating and a preparation method thereof.The laser cladding high-entropy alloy coating is prepared from, by mass, 25%-45% of Fe, 15%-25% of Cr, 10%-20% of Ni, 5%-15% of Mn, 3%-10% of Al, 0%-5% of Ti, 1%-5% of a nanometer reinforcing phase and 0.1%-0.5% of a flow promoter. Lorentz force generated by an alternating electromagnetic field drives melt convection, so that the diffusion coefficient of segregation-prone elements such as Cr and Ni is increased, the ultrasonic cavitation effect is matched to crush dendritic crystals and promote dispersion of nanoparticles, the segregation index of the elements is reduced, a uniform nanocrystalline-amorphous composite structure is formed through the synergistic effect, and uniform distribution of elements in a molten pool is achieved.

The invention discloses a high-entropy alloy / nitrogen-doped carbon nano catalytic material and a preparation method and application thereof.The nano catalytic material comprises a high-entropy alloy composed of five non-noble metals including Fe, Co, Ni, Cu and Mn and nitrogen-doped carbon synthesized with the assistance of MOF, the non-noble metal high-entropy alloy serves as a main body material, the nitrogen-doped carbon serves as a carrier material, and the nitrogen-doped carbon serves as a carrier material. A non-noble metal high-entropy alloy is loaded on nitrogen-doped carbon to construct a novel nano catalytic material, and the novel nano catalytic material is used for activating peroxydisulfate to remove antibiotics in a water body. The catalyst has the advantages of excellent chemical stability, good reusability and the like and is a novel nano catalytic material with efficient catalytic performance and environment-friendly characteristics, and the preparation method has the advantages of being simple in operation process, green, environmentally friendly, economical, feasible and the like and can be used for large-scale preparation.

The invention belongs to the field of catalyst preparation, and provides a preparation method for rapidly synthesizing a self-supporting high-entropy alloy difunctional electrocatalyst through Joule heat. The prepared FeCuRu-coated Ni1Co1-TPA is benefited from rich active sites, and the high conductivity of effective electron transfer and transmission is achieved. The catalyst shows excellent HER and OER catalytic performance under an alkaline condition, and the current density of 500mA cm <-2 > can be realized by only needing overpotentials of 120mV and 350mV, which is superior to those of a standard noble metal catalyst Pt / C and RuO2. In addition, when the composite material is used as a bifunctional electrocatalyst for electrolyzing water, the composite material shows excellent catalytic activity for electrolyzing water. The method has important significance for realizing the social renewable development target and developing clean and sustainable energy resources to replace fossil fuel.

The invention discloses a formula, a coating and a method of a dual in-situ precipitation reinforced FeCoNiCr-based high-entropy alloy composite material with a low corrosion-wear synergistic effect. The Al-Co-Cr alloy material comprises the following components in atomic percent: 15 to 30 at% of Al, 10 to 25 at% of Co, 10 to 25 at% of Cr, 10 to 25 at% of Fe, 10 to 25 at% of Ni, 20 to 35 at% of Ti and 5 to 15 at% of C, the preparation method comprises the following steps: filling all metal powder and graphene powder into a ball-milling tank, adding grinding balls, filling argon, sealing, and ball-milling, so as to obtain mixed powder in which the surfaces of metal powder particles are uniformly coated with graphene. The high-entropy alloy composite material with high hardness, high wear resistance and high corrosion resistance is obtained by utilizing the solid solution strengthening effect and the multiple in-situ precipitation strengthening effect of micron-scale TiC and nano-scale precipitation B2. The prepared coating is uniform and compact in structure, is metallurgically bonded with a base material, and has excellent corrosion and friction resistance and low corrosion-wear synergistic effect.

The invention provides a high-performance nitrogen-containing hard alloy material based on a vanadium-titanium rare earth carbonitride solid solution and a preparation method of the high-performance nitrogen-containing hard alloy material, and belongs to the technical field of hard alloy cutting tool materials. Tungsten carbide of a hard phase is modified, meanwhile, the vanadium-titanium rare earth carbonitride solid solution and the boron quantum dot are introduced to modify the high-entropy alloy, through interaction of modified components, the hardness and transverse breaking strength of the hard alloy material are effectively improved, and meanwhile the phase granularity is reduced.

The invention discloses a metal oxide modified high-entropy alloy catalyst and a preparation method and application thereof, the metal oxide modified high-entropy alloy catalyst is a supported Ni-Ga-Cu-In-Zn-Fe high-entropy alloy catalyst with a mixed metal oxide of X, Mg and Al as a carrier, the metal X is Zr or Ce, preferably Zr; the catalyst is prepared through a one-step precipitation method, a co-precipitation and impregnation method or a two-step precipitation method by utilizing the characteristic that main body laminate composition and elements of a layered hydroxide (LDHs) material are adjustable; the metal oxide modified high-entropy alloy catalyst has the characteristics of high catalyst metal particle dispersity, high catalytic activity, good selectivity and long service life due to the introduction of ZrO2 or CeO2, and can reach a higher CO2 conversion rate in a relatively low temperature interval, so that the CO2 conversion rate and the single-pass yield of methanol are remarkably improved, and the catalyst has the advantages of low cost and high efficiency. Therefore, the utilization efficiency of carbon resources is improved, and the method has a good industrial application prospect.

The invention belongs to the field of rare earth magnetic materials, and particularly relates to a rare earth high-entropy alloy, an annular magnet and a preparation method of the rare earth high-entropy alloy. The invention discloses a rare earth high-entropy alloy, the component of which is (HEA-Re) 2Fe14B, HEA-Re is more than four of rare earth elements La, Ce, Pr, Nd, Y, Gd, Ho, Dy and Tb, and the content proportions of the rare earth elements are the same; meanwhile, the invention discloses a preparation method for preparing the annular magnet by adopting the rare earth high-entropy alloy through the steps of smelting, solution rapid quenching, annealing heat treatment, magnetic powder preparation, magnet pre-forming, hot pressing, thermal deformation and the like, and the prepared annular magnet. According to the annular magnet prepared through the components and the method, the magnetic performance and the mechanical performance are obviously improved, the content of high-price rare earth elements is reduced, and the cost is effectively saved.

The invention belongs to the technical field of powder metallurgy, and particularly relates to a titanium-based composite workpiece and a preparation method and application thereof. High-entropy alloy powder with fine granularity is preferably selected as reinforcing phase powder after being prepared by adopting a gas atomization method and subjected to vibration screening, the particle size of the reinforcing phase powder and internal crystal grains of particles are fine, and after the reinforcing phase powder and titanium alloy powder are uniformly mixed, hot isostatic pressing low-temperature sintering treatment is performed, so that the high-entropy titanium alloy is obtained. Fine grain structures in reinforced phase powder particles are reserved in the titanium-based composite master alloy bar, and then a secondary plasma rotating electrode method is used for preparing powder, so that the titanium-based composite powder with uniform components and smaller grain structures is obtained; after mixing, the homogenized titanium-based composite mother alloy bar is prepared into powder through a secondary plasma rotating electrode method, chemical components are further dispersed and homogenized, reinforcing phases are distributed in all titanium-based composite powder particles, and the reinforcing effect can be further improved through an unconventional surface contact type reinforcing mode.

The invention discloses a high-entropy alloy nanoparticle as well as application and a preparation method thereof, and belongs to the technical field of mature biological membrane removal. The high-entropy alloy nanoparticles comprise the following raw materials: metal powder Fe, Ni, Mn, Nb, Cu and Ag; wherein the molar ratio of Fe to Ni to Mn is 1: 1: 1; the molar ratio of Nb to Fe is x, the molar ratio of Cu to Fe is y, the molar ratio of Ag to Fe is z, x is larger than or equal to 1.0 and smaller than or equal to 12.0, y is larger than or equal to 0.5 and smaller than or equal to 1.5, and z is larger than or equal to 0.05 and smaller than or equal to 0.25. According to the high-entropy alloy nano-particles, the biological membrane removal effect is further enhanced through component regulation and control, and the high-entropy alloy nano-particles have excellent photothermal conversion capacity under sunlight irradiation, so that the biological membrane removal performance is more excellent; and an efficient and long-term stable biofilm removal effect can be realized by using a very small amount of high-entropy alloy nanoparticles.

The invention discloses a high-entropy alloy silicon carbide nanofiber composite material and a preparation method and application thereof, a high-entropy alloy is loaded on silicon carbide nanofibers, compared with a carbon fiber material carrier, SiC fibers can form a compact SiO2 protective layer in a high-temperature aerobic environment, further oxidation failure of the internal structure can be prevented, and the high-entropy alloy silicon carbide nanofiber composite material is prepared. And meanwhile, SiC also has relatively high high-temperature stability and weather resistance, so that the high-entropy alloy silicon carbide nanofiber composite material can stably work in an extreme high-temperature oxidation environment (such as a spacecraft thermal protection system and an engine tail gas pipeline) of over 1000 DEG C, and perfectly adapts to a high-temperature wave-absorbing scene.

The invention discloses an ultra-wideband carbon / boron doped high-entropy alloy wave-absorbing material which is prepared by adjusting Fe and Ni elements, adding Si and Al elements and doping a small amount of C or B. The specific component of the wave-absorbing material is (FeaCobSicAldNie) 100-xMx. In addition, the invention also discloses a preparation method of the wave-absorbing material, and the preparation method comprises the following steps: 1, high-entropy alloy smelting; 2, preparing high-entropy alloy spherical powder; 3, carrying out flaky treatment; and 4, stress relief annealing. On the basis of FeCoNi medium-entropy alloy, the content of the Fe element with low cost is increased, the content of the Ni element with high cost is reduced, the Si element and the Al element are added at the same time, then a small amount of non-metal C and B elements are doped to serve as interstitial atoms, lattice distortion is increased, the wave-absorbing performance and corrosion resistance are improved, and the ultra-wideband carbon / boron doped high-entropy alloy wave-absorbing material is obtained.

The invention discloses a rare earth oxide modified high-entropy hard alloy and a preparation method thereof. A high-entropy hard phase (high-temperature calcination), a high-entropy binding phase and rare earth oxide are adopted, grinding, pressing and air pressure sintering at the temperature of 1450-1550 DEG C are conducted, and the high-entropy hard phase is prepared from tungsten carbide, titanium carbide, zirconium carbide, yttrium carbide, manganese carbide, chromium carbide and molybdenum carbide; the high-entropy binding phase comprises the following components: cobalt and a CoCrFeNi-series high-entropy alloy; and the component of the rare earth oxide is Y2O3 or Nd2O3. The prepared rare earth oxide modified high-entropy hard alloy has the advantages of high strength, high compactness, high hardness, high wear resistance and the like.

The invention provides a high-entropy alloy tensile property prediction method and system based on molecular dynamics simulation, and belongs to the technical field of high-entropy alloy tensile property prediction. Molecular dynamics data are combined into a data set, and the data set is divided into a training set and an evaluation set; training and evaluating the dense connection neural network based on the training set and the evaluation set; calculating a potential function by using the evaluated dense connection neural network; based on an LAMMPS simulator, simulating the inter-atomic motion trail in the tensile fracture process of the high-entropy alloy; and predicting the tensile property of the high-entropy alloy according to the motion trail simulation result. According to the method, the tensile property of the high-entropy alloy can be accurately predicted on the basis of enhancing the generalization ability of the model.

The invention provides a high-entropy alloy intermediate layer for GH5188 instantaneous liquid phase diffusion bonding and a bonding method of the high-entropy alloy intermediate layer, and relates to the technical field of metal welding, the high-entropy alloy intermediate layer is composed of Co, Ni, Cr, Al, Ta, Ge, Zr and Y according to the atomic ratio of 25: 20: 20: 15: 10: 5: 3: 2, and the element purity is larger than 99.99 wt.%. The invention further provides the bonding method of GH5188 instantaneous liquid phase diffusion bonding. The high-entropy alloy intermediate layer is arranged in the middle of the base metal GH5188 and is arranged in the vacuum diffusion welding furnace for welding, and compared with conventional instantaneous liquid-phase diffusion bonding, formation of brittle compounds can be inhibited, and improvement of the comprehensive performance of an interface is facilitated.

The invention relates to a preparation method of a seawater wear and corrosion resistant high-entropy alloy coating, and belongs to the technical field of coating preparation and treatment. The preparation method comprises the steps that matching calculation is conducted according to the chemical formula FeCrCoMnSix of the high-entropy alloy, Fe, Cr, Co, Si and Mn-Fe alloy powder are weighed, and x is equal to 0.1-1; the weighed powder is mixed and then subjected to ball milling, and a mixture is obtained; mixing the mixture with an adhesive, coating the mixture on a substrate to form a plurality of prefabricated layers, distributing the prefabricated layers on the substrate in parallel, and then drying the coated substrate; under the protection atmosphere of inert gas, the dried base body coated with the prefabricated layer is subjected to multi-channel laser cladding; and then annealing treatment is conducted, and the high-entropy alloy coating is obtained. According to the method, the seawater corrosion resistance and wear resistance of the high-entropy alloy coating are improved by adjusting the content of the Si element, utilizing the laser cladding technology and further performing annealing treatment.

The invention belongs to the technical field of high-performance cutter coatings, and relates to a cross-scale bionic gradient coating design method based on a multi-principal-element high-entropy system, which comprises the following steps: sequentially forming a high-entropy alloy plastic layer, a high-entropy alloy / high-entropy ceramic tough layer and a nanocrystalline high-entropy ceramic superhard layer on the surface of a cutter matrix, and constructing a gradient transition structure; the method comprises the following steps: matching a high-entropy alloy plastic layer with a tool matrix binding phase, optimizing a high-entropy alloy / high-entropy ceramic tough layer material, improving interface binding force, optimizing gradient transition design by adopting thermal-mechanical coupling calculation, constructing an atomic model, simulating and optimizing a microstructure based on molecular dynamics, and establishing a finite element model to simulate thermal cycle and mechanical load. The interface performance is optimized, a mathematical model is constructed through a BP neural network and a particle swarm optimization algorithm, and gradual transition design of the tool base body and the coating is achieved. The problems that the tool coating interface is high in brittleness, insufficient in adhesiveness, limited in thermal stability and the like are solved, and the bonding performance of the coating interface and the stability and durability of the coated tool are improved.

The invention discloses a laser additive manufacturing method for an aluminum / titanium alloy gradient structure, and belongs to the technical field of laser additive manufacturing. The laser additive manufacturing method comprises the steps that TiNbVZr or TiNbV high-entropy alloy powder is used for preparing the high-entropy alloy transition layer on the surface of titanium alloy through the laser additive manufacturing process, and then the aluminum alloy layer is prepared on the surface of the high-entropy alloy transition layer through the laser additive manufacturing process. According to the preparation method, the aluminum / titanium alloy gradient structure with high performance is prepared by combining optimization of the intermediate transition layer of the high-entropy alloy with two preferable components with a laser additive manufacturing technology, and the problems of interface cracking and low bonding strength of the current aluminum / titanium alloy can be effectively solved.

The invention belongs to the technical field of catalyst preparation, focuses on a high-entropy alloy nanowire catalyst, and mainly relates to a preparation method and application of an AuCuAgPtNi catalyst. A one-pot wet chemical method is innovatively adopted, a 4-aminopyridine solvent and metal precursors of gold, copper, silver, platinum and nickel are fully and evenly mixed and placed in an oil bath pot at the temperature of 90 DEG C, then a reducing agent ascorbic acid is rapidly added, after specific reaction time, washing, drying and other operations are sequentially carried out, and the high-entropy alloy nanowire AuCuAgPtNi catalyst can be successfully prepared. The preparation method disclosed by the invention has the remarkable advantages of simple process, simple steps, convenience in operation and the like. In an alkaline environment, the prepared nanowire-shaped high-entropy alloy AuCuAgPtNi catalyst shows extremely excellent catalytic activity and selectivity for catalytic degradation of waste plastic polylactic acid, the waste plastic can be efficiently upgraded and converted into pyruvic acid, a new way is opened up for resource utilization of the waste plastic, and the application prospect is wide. The method has a wide application prospect in the fields of environmental protection and resource recovery.

Embodiments relate to system and methods involving use of a technique for managing a database for producing a material composition having a thermodynamic phase. The technique can include: receiving a binary phase diagram for each material to be used as a component of a high-entropy alloy (HEA); using one or more active learning machine learning techniques for generating a feature, the feature including: a primary feature that is representative of a probability that an HEA will exhibit a solid solution phase and / or an intermetallic phase, and a physics-based feature that is representative of a factor related to formation of a desired intermetallic HEA phase; encoding the primary feature and the physics-based feature; generating an output representation of a HEA alloy composition and phase of a predicted materials composition; and selecting a HEA composition and phase that will meet a material design criterion.

The invention provides a high-entropy-titanium-aluminum alloy and a laser melting deposition preparation method thereof, and relates to the technical field of alloy preparation. According to the method, the high-entropy-titanium-aluminum alloy is prepared through laser melting deposition, and the laser melting deposition has the advantages of being large in temperature gradient and high in cooling speed, so that the prepared material is small in crystal grain, compact in structure and excellent in mechanical property. The titanium-aluminum alloy and the high-entropy alloy are compounded, the overall strength of the alloy is improved, and due to the fact that the titanium-aluminum alloy is low in density, the overall density of the alloy can be reduced, and the requirement for light weight is met. According to the method, the final high-entropy-titanium-aluminum alloy components are changed by changing the powder feeding rates of different powder materials, compared with a laser melting deposition mode that powder with different contents is mixed and then put into a powder feeding barrel, the process of weighing the powder and mechanically mixing the powder is omitted, the method is more flexible in design, and the method is suitable for large-scale industrial production. Alloys with different components can be prepared in batches, and the efficiency is obviously higher than that of a mechanical powder mixing method.

The invention discloses a connecting method of an FGH99 double-radial-plate turbine disc based on a nanocrystallization high-entropy alloy middle layer, and belongs to the technical field of welding. A high-entropy alloy middle layer is adopted, nanocrystallization treatment is combined to optimize a microstructure, the nanocrystallization high-entropy alloy middle layer is arranged between an upper FGH99 double-radial-plate turbine disc and a lower FGH99 double-radial-plate turbine disc, diffusion connection is conducted in a vacuum diffusion welding furnace, and the welded FGH99 double-radial-plate turbine disc is obtained. Low-damage solid-phase diffusion bonding is achieved at the welding temperature lower than the solid solution temperature of base metal; meanwhile, the nanocrystallization interlayer structure promotes element diffusion, the diffusion welding period can be greatly shortened, the problems of grain coarsening and performance degradation of a heat affected zone caused by long-time heat preservation in a traditional technology are solved, the technical bottleneck of cooperative regulation and control over the strength and toughness of a high-temperature alloy complex component connection interface is broken through, and the application prospect is wide. And a high-reliability solution is provided for efficient manufacturing of the double-radial-plate turbine disc of the aero-engine, and the double-radial-plate turbine disc is particularly suitable for the long-service-life service requirement under the working conditions of extreme high temperature and cyclic loads.

The invention discloses a double-gradient high-temperature-resistant high-entropy alloy wear-resistant layer and an ultrasonic-assisted laser cladding preparation method thereof, and belongs to the technical field of metal material coatings and surface modification. A proper amount of refractory element W with anti-oxidation and solid solution strengthening effects is introduced into a CoCrFeNi high-entropy alloy coating, an ultrasonic-assisted laser cladding process is adopted, the wear-resistant layer with the grain size and the precipitated phase volume fraction in a gradient structure from exterior to interior is prepared, local stress concentration caused by W aggregation in the laser cladding process is improved, and the wear-resistant performance of the CoCrFeNi high-entropy alloy coating is improved. And the metallurgical bonding strength of the cladding layer and the matrix is improved, and the high-temperature friction and wear resistance of the cladding layer is enhanced. The cladding layer is fine and compact in structure, in gradient distribution, good in mechanical property and excellent in high-temperature wear resistance. The method is easy to operate and low in cost, and an effective method is provided for improving highly coordinated regulation of process-structure-performance and preparing the novel high-temperature-resistant high-entropy alloy wear-resistant layer.

The invention relates to the field of additive manufacturing nano precipitated phase reinforced refractory high-entropy alloys, in particular to an additive manufacturing nano precipitated phase reinforced refractory TiNbVAlSix high-entropy alloy. The high-entropy alloy comprises the following chemical components by atomic percent: 45-55% of Ti; 15%-25% of Nb; v, 15%-25%; 8%-15% of Al; and 0-9% of Si. The alloy is prepared through a laser directional energy deposition additive manufacturing method, precipitation of a nano Ti5Si3 phase at the grain boundary and in grains is promoted through addition of the Si element, microstructure characteristics of a disordered BCC phase, an ordered B2 phase and the nano Ti5Si3 phase are formed, and the content of the nano Ti5Si3 phase is in direct proportion to the content of the Si element. The high-entropy alloy has the performance characteristics of light weight and high strength, can meet the requirements of part of aerospace parts, and has important value for development and application of TiNbVAl and related light refractory high-entropy alloy systems.

The invention discloses a preparation method of FeCoNiMnAl series high-entropy alloy powder with wave absorbing performance, which comprises the following steps: (1) uniformly mixing iron powder, cobalt powder, nickel powder, manganese powder and aluminum powder to obtain alloy raw material powder; (2) adding the alloy raw material powder, absolute ethyl alcohol and grinding balls into a ball milling tank, and carrying out high and low rotating speed alternate ball milling under the protection of inert gas; (3) after ball milling is finished, the alloy raw material powder obtained after ball milling is subjected to vacuum drying, grinding and smashing, and an intermediate product A is obtained; (4) adding a sodium hydroxide solution into the intermediate product A, and performing corrosion modification by adopting a water bath heating method; after the water bath is finished, washing a solid product obtained by solid-liquid separation to be neutral to obtain an intermediate product B; and (5) carrying out vacuum drying on the intermediate product B, and grinding and crushing. The FeCoNiMnAl series high-entropy alloy powder prepared by the preparation method disclosed by the invention has relatively excellent wave absorbing performance under the condition that the thickness is relatively small.

The invention discloses a preparation method and an application of an S and N co-doped small-nano-size high-entropy intermetallic compound. 2, 2 '-bithiophene is simultaneously used as a metal ligand and a sulfur source to be applied to synthesis of the high-entropy intermetallic compound, and sulfur atoms in the substance can form a complex with metal ions, so that a metal precursor can be uniformly and firmly distributed on the surface of a commercial carbon carrier, and formation of the high-entropy intermetallic compound in the subsequent annealing process is facilitated; the S and N co-doped high-entropy alloy intermetallic compound catalyst synthesized by the invention has excellent electrochemical performance in a fuel cell, and particularly has remarkable performance in the aspect of stability; wherein the mass activity of the S and N co-doped high-entropy alloy intermetallic compound PtCuNiCoFe / C-SN (PCNCF-SN) catalyst under the condition of 0.9 V (vs.RHE) reaches 2.7 A * mg <-1 > Pt, which is more than 12.3 times of that of commercial Pt / C; and in the aspect of stability, the mass activity can still be kept at 65% or above after 100000 circles of accelerated durability.

The invention is suitable for the technical field of alloy material analysis, and provides a TME composite algorithm-based high-entropy alloy performance prediction method and a TME composite algorithm-based high-entropy alloy performance prediction system, and the method comprises the steps of firstly obtaining hardness characteristic data set information of a target alloy, and then inputting the hardness characteristic data set information into a trained multi-layer perceptron model, and performance prediction result information can be quickly and accurately generated. According to the method, the advantages of the converter model, the multi-layer perceptron model and the egret swarm optimization algorithm can be combined, the precision of high-entropy alloy performance prediction is effectively improved, the prediction cost and the calculation amount are reduced, the prediction precision and the generalization ability of the model are enhanced, and the method is suitable for performance prediction of various high-entropy alloys and has wide application prospects. Efficient application of the prediction model under different alloy components and process conditions is ensured, and reliable technical support and reference are provided for research, development and application of the high-entropy alloy.

The invention relates to a low-density AlNbTaTiZr refractory high-entropy alloy and a preparation method thereof, belongs to the technical field of metal materials, and solves the problem that a refractory high-entropy alloy material obtained by adopting a vacuum arc melting technology in the prior art is difficult to ensure relatively high strength, good plasticity and relatively low density at the same time. The preparation method of the low-density AlNbTaTiZr refractory high-entropy alloy comprises the following steps that S1, raw materials are prepared, and mixed powder is prepared according to the designed molar ratio; s2, alloy ingots are prepared, and the mixed powder is subjected to vacuum melting to obtain the alloy ingots; s3, the alloy ingot is subjected to vacuum melting, and an alloy cast ingot is obtained; and S4, the alloy cast ingot is subjected to heat treatment, and an initial-state sample is obtained. According to the low-density AlNbTaTiZr refractory high-entropy alloy and the preparation method thereof provided by the invention, the obtained alloy material is relatively low in density, relatively high in yield strength, excellent in plasticity and relatively wide in application range.

The invention belongs to the field of metal processing, and relates to an in-situ self-generated NiMoCoAlTi high-entropy alloy toughened metal ceramic material and a preparation method thereof. According to the invention, Ti (C, N) ceramic is used as a matrix, Ni, Mo, Co, Al and Ti are directly added as binders, and spark plasma coupling high-frequency induction sintering is carried out to obtain the high-temperature-resistant ceramic. The preparation method comprises the following steps: firstly, mixing Ti (C, N), Ni, Mo, Co, Al and Ti, then carrying out ball milling and drying to obtain powder, and carrying out spark plasma coupling high-frequency induction sintering. The method is beneficial to improving the mechanical property of the material, saves the preparation time of the high-entropy alloy powder, and has the advantages of being simple in preparation method, convenient to operate and the like. The obtained titanium carbonitride-based metal ceramic has higher toughness and hardness and excellent antifriction and wear-resisting properties, and can be used for manufacturing high-precision numerical control machine tool guide rails and other wear-resisting and corrosion-resisting parts.

The invention discloses a graphene modified high-entropy alloy particle reinforced titanium-based composite material and a preparation method and application thereof. According to the composite material, titanium or a titanium alloy serves as a titanium matrix, and graphene is modified on the surface of a high-entropy alloy and serves as a reinforced phase together with the high-entropy alloy to be distributed at the grain boundary of the titanium matrix. In the microstructure of the material, the surface of the high-entropy alloy is modified with graphene, the interface of the high-entropy alloy and a titanium matrix and the solid solution degree of the high-entropy alloy in the titanium alloy matrix are regulated and controlled, and the graphene reacts with the matrix to generate titanium carbide to jointly reinforce the titanium alloy matrix with the high-entropy alloy. According to the preparation method, the graphene is modified on the surfaces of the high-entropy alloy particles by adopting a three-dimensional rotary mixing method, the problem that impurities are easily introduced in a conventional ball milling method is solved, and the graphene-modified high-entropy alloy particle reinforced titanium-based composite material block is obtained through sintering or laser 3D printing forming. The material has high strength and high plasticity, has excellent comprehensive mechanical properties, and can be applied to the fields of aerospace, ships and naval vessels and the like.