2497 results about "Copper" patented technology

The invention discloses a high-strength silver-free copper-based brazing filler metal which is composed of P, Sn, Ni and Cu. The high-strength silver-free copper-based brazing filler metal is low in cost, safe, environmentally friendly and good in welding effect; through the adding of Sn and Ni, the melting point of brazing filler metal alloy is reduced, and the tensile strength and wettability of the brazing filler metal alloy are enhanced.

The present invention provides: a steel sheet which contains Ni, Cu and Sn, and has excellent chemical conversion treatability; and a component which includes said steel sheet.　A steel sheet and a component including the same according to the present invention are characterized by having a chemical composition containing, in mass %, 0.010-1.000% of Ni, 0.010-1.000% of Cu, and 0.003-1.000% of Sn, and by the emission intensities of Ni, Cu, and Sn in the surface layer of the steel sheet as measured by high-frequency glow discharge optical emission spectrometry satisfying the following relationships.　Ni: Surface layer maximum intensity / Bulk intensity ≤ 1.5 Cu: Surface layer maximum intensity / Bulk intensity ≤ 1.3 Sn: Surface layer maximum intensity / Bulk intensity ≤ 15

The invention provides a manufacturing method of an ultra-low dielectric loss high-speed copper-clad plate, which comprises the following steps of: constructing a physical coupling model of a multi-zone independent temperature control module and an electro-thermal conductivity adjusting layer based on the thickness of the copper-clad plate and a thermal response parameter of a resin system; space and time dynamic distribution of heating area power and heat conductivity is achieved; a dynamic thermal boundary regulation and control algorithm, finite element simulation and self-adaptive PID feedback are fused, real-time monitoring and deviation compensation of a temperature field are carried out through infrared thermal imaging and edge calculation, heating and heat dissipation strategies are cooperatively adjusted, a heat flow path can be actively guided, the uniformity of thermal stress distribution and the structural stability are achieved, and the method is suitable for large-scale popularization and application. And the thermal management efficiency of the copper-clad plate in a complex manufacturing environment is improved.

The invention provides an embedded substrate and a manufacturing method thereof. The manufacturing method specifically comprises the following steps: forming a conduction copper column and a shielding copper column on a first circuit layer of the substrate; pressing a second dielectric layer on the first circuit layer, the conduction copper column and the shielding copper column; mounting a component on the second dielectric layer; pressing the component into the second dielectric layer to enable the shielding copper column and the first circuit layer to surround the component; pressing a fourth dielectric layer on the second dielectric layer and the component, and curing the second dielectric layer and the fourth dielectric layer; forming an outer circuit layer on the fourth dielectric layer; and the outer circuit layer is in conducting connection with the conducting copper column, the shielding copper column and the terminal of the component. The shielding copper columns can reduce the deviation of the component in the extrusion process of the component and improve the yield, five surfaces of the embedded component are all provided with metal copper, and a good electromagnetic shielding effect can be achieved. Moreover, the second dielectric layer and the fourth dielectric layer are made of high-thermal-conductivity materials, so that heat can be quickly guided into the shielding copper columns, and the heat dissipation effect is obviously improved.

The invention relates to a bactericidal composition containing fluxapyroxad and thiediazole copper. The bacterial composition is compounded from fluxapyroxad and thiediazole copper in a binary mode, wherein a mass ratio of fluxapyroxad to thiediazole copper is (1-50) to (50-1); a mass fraction of fluxapyroxad and thiediazole in the preparation is 1%-80%, and the rest of the preparation is auxiliary components which are allowed to use and are acceptable in a pesticide. A dosage form of the bactericidal composition is missible oil, a suspending agent, wettable powder, a water dispersible granule, emulsion in water, microemulsion, a granule and a micro-capsule. The bactericidal composition is mainly used for controlling plant gray mold, peronospora and phytophthora germs.

The present invention provides a steel sheet containing Ni, Cu, and Sn, which has excellent chemical conversion treatability, and a part including the steel sheet. The steel sheet and parts including the steel sheet of the present invention have a chemical composition containing, in mass%, Ni: 0.010 to 1.000%, Cu: 0.010 to 1.000%, and Sn: 0.003 to 1.000%, and are characterized in that the emission intensities of Ni, Cu, and Sn in the surface layer of the steel sheet, measured by high-frequency glow discharge optical emission spectroscopy, respectively satisfy the following relationships: Ni: Maximum surface strength / bulk strength ≦ 1.5 Cu: Maximum surface strength / bulk strength ≦ 1.3 Sn: Maximum surface strength / bulk strength ≦ 15

The invention relates to the technical field of material corrosion and protection, discloses a TP2 copper corrosion behavior testing method based on temperature regulation and control, and aims to solve the problem that in the prior art, various physical and chemical parameters in the corrosion process are difficult to synchronously obtain under the same microscale, so that a local corrosion dynamics mechanism cannot be deeply revealed. The core of the system is a coaxial three-function composite probe integrated with thermal, acoustic and electrochemical sensing units, and the coaxial three-function composite probe is matched with a synchronous laser heating module and a multi-physical field synchronous control system. During testing, the probe scans on the surface of a sample, local thermal disturbance is applied to each pixel point, and the interface temperature, acoustic impedance and corrosion rate data of the point are synchronously collected. According to the invention, through high integration in structure and accurate synchronization in time, the space mismatch error of multi-source measurement is eradicated, and multi-physical field distribution images which are accurately corresponding to each other can be obtained in situ and losslessly.

The invention discloses a method for step-by-step impurity removal in crude copper fire refining, and belongs to the technical field of metallurgical technologies. The method comprises the following steps: (1) removing As and Sb in an oxidation stage: heating and melting crude copper, blowing oxygen, and adding an impurity remover to remove As and Sb impurities in the crude copper; (2) removing Pb and Ni in an oxidation stage: after the impurity removal agent is added in the step (1) for reaction, adding a composite impurity removal agent, continuously blowing oxygen, stopping blowing oxygen until the oxygen content in the melt is 0.6-0.8% by mass, and slagging off to remove Pb and Ni impurities; and (3) deoxidation in a reduction stage: after slagging-off in the step (2), adjusting the temperature of the melt to a reduction temperature, adding high-sulfur pulverized coal in twice, and removing oxygen in the melt to complete impurity removal. According to the method, the impurity removal agent and the impurity removal process are optimized, and the impurity removal effect of the crude copper is remarkably improved through the synergistic effect.

The invention discloses a preparation method of a high-strength, high-hardness and ablation-resistant CuWTaTeAl gradient nano composite material. The method comprises the following steps: 1, mechanically mixing Cu80Al20 spherical coated powder, Cu90W10 spherical coated powder, WTe2 alloy powder, Ta powder and Cu powder, and then carrying out ball milling and mixing; 2, performing SPS (spark plasma sintering); thirdly, after soaking treatment, multi-pass hot rolling deformation is carried out, and then quenching treatment is carried out; and 4, annealing heat treatment. The binary spherical coating powder, the alloy powder and the elementary substance powder are subjected to ball milling and mixing to achieve uniform distribution of all elements, high-melting-point W and Ta are added to improve the ablation-resistant temperature of the composite material, large-scale copper dendrite powder is added to form gradient distribution nanocrystals, the proportion of all the elements is controlled, the lattice distortion degree is increased, and the ablation-resistant temperature of the composite material is improved. The high-strength, high-hardness and ablation-resistant CuWTaTeAl gradient nano composite material is suitable for the fields of contacts, switches, electrical connectors, resistance welding electrodes and the like.

The invention discloses a method for separating, purifying and regenerating waste battery negative electrode powder, which belongs to the field of battery recycling and regenerating, and mainly comprises the following process steps of: ball-milling and screening waste battery negative electrode pieces into certain granularity, soaking the waste battery negative electrode pieces in alkali liquor and an impurity removal agent, and stirring for reaction and separation to obtain a negative electrode powder wet material and a copper ion solution; carrying out drying demagnetization and infrared irradiation treatment on the wet negative electrode powder to obtain regenerated negative electrode powder; and the copper ion solution is subjected to extraction, back extraction and reduction to obtain crude copper, and the crude copper is subjected to vacuum distillation to obtain an electronic-grade copper product. Wherein the impurity removal agent comprises an oxidizing agent, the oxidizing agent oxidizes elemental copper and forms soluble substances under the action of alkali liquor, and the excellent separation effect is achieved. The negative electrode powder treatment comprises infrared irradiation treatment, decomposition of an adhesive can be achieved through the dual effects of heat irradiation and heat conduction, the volume heating effect is formed through scattering, surface crusting is effectively avoided, the adhesive can be efficiently removed, and the quality and the recycling efficiency of the regenerated negative electrode powder are guaranteed.

The invention discloses a heat energy cyclic utilization control system and method for a copper-clad plate factory, and relates to the technical field of heat energy cyclic utilization. The heat energy cyclic utilization control system for the copper-clad plate factory comprises a heat energy circulation module, wherein high-temperature waste gas is introduced to perform efficient countercurrent heat exchange with low-temperature high-medium heat-conducting oil; the temperature-pressure dynamic model building module is used for building a temperature-pressure coupling function according to the thermal expansion and phase change characteristics of the medium and building a temperature-pressure dynamic model in combination with the basic equation and the temperature-pressure coupling function; the temperature and pressure coupling optimal control sequence determination module is used for solving an optimal control sequence in a prediction window through a rolling optimization algorithm; and the heat energy utilization module is used for inputting the high-temperature and high-medium heat conduction oil obtained by heating in the heat energy circulation module into a plurality of heat utilization devices according to the optimal control sequence. According to the method, the optimal control sequence in the prediction window is solved through the rolling optimization algorithm to dynamically adjust the operation parameters of the system, and the problem that the heat energy circulation efficiency is reduced in the prior art is solved.

The invention provides a method for preparing a copper ingot through waste copper refining, and belongs to the field of waste copper refining. The method comprises the following steps: sorting, crushing and drying a waste copper raw material to obtain a pretreated copper material; feeding the pretreated copper material into a cored power frequency induction furnace for melting; after the pretreated copper material is completely molten, adding a slag removing agent into the melt, then lowering the voltage, and salvaging slag after heat preservation; a magnetic refining agent is added into the melt obtained after slag fishing, stirring is carried out to adsorb impurity elements in the melt, then heat preservation and standing are carried out, and the magnetic refining agent is recycled; the refined melt is subjected to electromagnetic stirring and ultrasonic wave cooperative treatment, so that hydrogen and oxygen gas is deeply removed, and components are homogenized; and a slag conglomeration agent is added into the purified melt, stirring is conducted, slag is fished out after heat preservation, and casting is conducted to form an ingot. Therefore, deep and efficient removal of various types and trace harmful impurities (especially As, Pb, Sb and the like) in the waste copper is synergistically realized, and the metallurgical quality of final copper ingots is synchronously improved.

The invention discloses high-oxidation-resistance flaky silver-coated copper particles and a preparation method thereof, and relates to the technical field of silver-coated copper powder. The process comprises the steps of flaky copper powder preparation, copper powder pretreatment, silver coating plating and post-treatment. The surface of the copper powder is pretreated, and active sites on the surface of the copper powder are reduced; secondly, a zinc phosphate plated film is formed, full coverage of a silver layer is achieved by adding nano-silver to assist in a silver ammonia solution, meanwhile, micropores of the silver layer are filled, and the compactness of the silver-coated copper powder is improved; besides, the silver content of the silver-coated copper powder is controlled to be 8.7-14.6%, and the normal-temperature oxidation resistance of the silver-coated copper powder is improved, so that the optimal anti-oxidation effect is achieved, and performance deterioration caused by oxidation is reduced.

The invention discloses a method for improving performance of rare earth permanent magnet sintered neodymium iron boron grain boundary diffusion, and belongs to the technical field of rare earth permanent magnet materials. The method comprises the steps that a low-melting-point metal layer and a diffusion layer containing heavy rare earth elements are sequentially formed on the surface of a clean sintered neodymium-iron-boron magnet, and then vacuum diffusion heat treatment and tempering treatment are conducted. Wherein the low-melting-point metal layer comprises at least one of copper, aluminum, gallium and tin or an alloy of the copper, the aluminum, the gallium and the tin; the heavy rare earth element comprises at least one of dysprosium, terbium, holmium and gadolinium. The low-melting-point metal layer is preferentially diffused and wets the grain boundary in the heat treatment process, heavy rare earth elements are promoted to be deeply and uniformly diffused towards the interior of the magnet along the grain boundary, so that a heavy rare earth-rich shell layer is formed outside main phase grains of the magnet, and the intrinsic coercive force is improved; meanwhile, the low-melting-point metal forms a strengthening phase at the grain boundary, the brittleness of the magnet after diffusion is improved, the surface corrosion phenomenon is restrained, and collaborative optimization of the comprehensive performance of the magnet is achieved.

The invention discloses a method for increasing the recovery rate of lead fire refining alkaline residues. The temperature of the roasting furnace is set to be 580-650 DEG C, after the actual temperature reaches the set temperature, the refined alkaline residues are conveyed into the roasting furnace, the rotating speed of the roasting furnace is controlled to be 0.5-1 circle / min, the amount of blown air is 2-5 m < 3 > / min, the materials are subjected to oxidizing roasting in the roasting furnace for 30-60 min, the temperature is reduced to 30-50 DEG C, and roasted sand materials are obtained; detecting the roasted product material to obtain the content of the S element; the roasted sand materials and corresponding auxiliary materials are put into a smelting furnace in batches, the temperature in the furnace is controlled to be 900-1100 DEG C, the smelting time is 2-3 h, and produced lead bullion is discharged after the smelting time is up; the auxiliary materials are prepared according to the input amount of a single-batch roasted product material and the content of the S element. The recovery rate of lead, tin, antimony and copper in the pyrorefining alkaline residues can be effectively increased, and the cost of smelting auxiliary materials is reduced.

A sorting system conveys a heterogeneous mixture of material pieces past an XRF system and a vision system. A classification of a material piece is changed to a high copper content aluminum alloy when the XRF system classifies the material piece as a low copper content aluminum alloy and the vision system determines that the material piece is a thin strip material piece. The reclassified material piece is then sorted accordingly.

The invention discloses a high-specific-gravity and high-toughness tungsten-nickel-copper material and a preparation method thereof, and belongs to the technical field of non-ferrous metal materials. The material comprises the following components in percentage by mass: 6-15% of nickel; 2-5% of copper; 2-5% of manganese, and the balance tungsten and inevitable impurities. The preparation method of the material comprises the following steps: preparing materials (pure tungsten powder, pure nickel powder, pure copper powder and pure manganese powder), mixing the powder, pressing, sintering, and carrying out recrystallization annealing heat treatment. In the burdening step, two kinds of tungsten powder with different particle size grades are selected and added, and the gradient particle size ratio is adjusted. By adding the strengthening element manganese, combining the gradient particle size ratio and enhancing interface bonding, the high specific gravity and high strength of the material are kept, meanwhile, excellent toughness can be kept, and the material is suitable for aerospace gyroscope rotors and balance weight parts, electronic industry precise instrument parts, medical instrument ray shielding materials and national defense military industry kinetic energy armor-piercing weapon parts.

The invention discloses a method for recovering iron in tailings of copper separation from copper smelting slag through combination of microwave-assisted oxidizing roasting and magnetic separation, and belongs to the technical field of metallurgical solid waste resource utilization. The method comprises the steps that high-temperature copper smelting slag is subjected to water quenching, crushing and ore grinding, flotation and copper removal to obtain tailings containing silicon iron, after a calcium-based additive is added for ball milling and mixing, microwave oxidizing roasting is conducted under the oxygen-enriched condition, roasting products are subjected to high-gradient magnetic separation after crushing and ore grinding, and iron ore concentrate and magnetic separation tailings are obtained. According to the method, the strong wave-absorbing characteristic of fayalite is utilized, the roasting temperature and energy consumption are reduced through microwave heating, iron-silicon separation is achieved through a calcium-based additive, and iron is recycled through magnetic separation in one step. The final magnetic separation iron recovery rate reaches 85% or above, the iron ore concentrate grade exceeds 60%, magnetic separation tailings can be used as building materials, the process is simple, the cost is low, environment friendliness is achieved, the defects of a traditional process are overcome, and high-value utilization of solid waste is achieved.

The invention belongs to the technical field of comprehensive utilization of metallurgical and chemical resources, and discloses a method for improving the productivity of magnet powder and sulfuric acid by adding pyrite in copper smelting. According to the method, a heat release rate, SO2 generation kinetics and an iron oxide phase change path are synergistically optimized by constructing a gradient blending mechanism of pyrite and an in-furnace oxygen potential directional oxidation regulation and control system. The method is characterized in that on the basis of real-time feedback of the molten pool temperature, the flue gas SO2 concentration and the slag phase FeO activity, the pyrite blending rate, the granularity and the carrier gas oxygen concentration are dynamically regulated and controlled in a staged mode; a reduction microenvironment in which logpO2 is approximately equal to-11 is created on a slag-sulfonium interface, and growth of Fe3O4 crystal nucleus is promoted; and the flue gas cooling and acid-making gas inlet stability is optimized. According to the method, the capacity of the magnet powder and the capacity of the sulfuric acid are synchronously improved, the stability and the high efficiency of the copper smelting main process are guaranteed, and an engineering-oriented technical path is provided for comprehensive utilization of resources of copper smelting enterprises.

The invention belongs to the technical field of copper bar machining, and particularly relates to a copper bar continuous machining device and method.The copper bar continuous machining device comprises a vertical cabinet, a machining area is arranged on the vertical cabinet, a welding mechanism and a fixing mechanism used for copper bar fixing and transposition are arranged in the machining area, and an isolation hood with an upward opening is fixedly arranged on the lower side of the machining area; and a connecting pipe connected with external vacuumizing equipment is arranged on one side of the isolation hood. In the welding pressurization process, the two long edge sides of the end of the copper bar can be automatically and effectively supported and limited, lateral plastic flow generated by the copper bar under vertical pressure is directly restrained, it is ensured that the width of the end of the copper bar meets the preset precision requirement, the welding quality of the end of the soft copper bar is ensured, and the production efficiency is improved. A closed welding environment composed of the isolation cover and the sealing plate is arranged and matched with external vacuumizing equipment, the possibility that the high-temperature surface of the copper bar makes contact with oxygen to generate an oxide layer is eradicated, and welding failure caused by oxide inclusions is avoided.

The application discloses a beneficiation separation method for high-copper and low-zinc high-sulfur polymetallic ore, which comprises the following steps: A, after crushing the raw ore, ball milling and grading are performed, the sand is returned to the ball mill, and the overflow product is fed into a copper roughing process; B, copper roughing is performed; C, the roughing concentrate is subjected to copper cleaning process to obtain copper concentrate, and the roughing tailings are fed into a copper scavenging process; D, copper scavenging is performed, the scavenging tailings are subjected to grading, the sand is returned to the ball mill, and the overflow product is fed into a zinc roughing process; E, zinc roughing is performed, the roughing concentrate is subjected to zinc cleaning process to obtain zinc concentrate, and the roughing tailings are subjected to zinc scavenging process to obtain zinc tailings. The application efficiently realizes the separation of copper concentrate and zinc concentrate by fully utilizing the mineral particle size distribution characteristics, introducing a particle size grading system and improving the flotation reagent, and has the technical characteristics of high separation yield, easy operation, stable separation index and the like.

The invention discloses a neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and a preparation method thereof, and relates to the technical field of neodymium-iron-boron magnet preparation, and the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet comprises the following preparation raw materials: 170-175 kg of PrNd (praseodymium-neodymium alloy), 25-30 kg of BFe (iron white copper), 1-5 kg of Co (cobalt), 0.1-2 kg of Cu (copper), 1-5 kg of Zr (zirconium), 0.1-1 kg of Ga (gallium) and 380-420 kg of Fe (iron). According to the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and the preparation method thereof, the 54H sintered neodymium-iron-boron magnet is prepared through a double-alloy technology with neodymium, iron and gallium as auxiliary alloy without adding dysprosium, terbium and other scarce type heavy rare earth elements, and performance optimization and cost optimization of the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet are achieved.

The invention discloses a crystallizer slag entrapment detection method, a medium and equipment. The crystallizer comprises a copper plate, the copper plate comprises two narrow faces which are oppositely arranged, a plurality of thermocouples are arranged on each narrow face in the height direction of the copper plate at intervals, and every two thermocouples which are oppositely arranged on the two narrow faces form a thermocouple set. Acquiring a detection temperature deviation value of the two thermocouples of at least one thermocouple group; and if the at least one detection temperature deviation value is larger than or equal to a preset temperature deviation threshold value, and the duration when the at least one detection temperature deviation value is larger than or equal to the temperature deviation threshold value is larger than or equal to a preset duration, it is determined that the risk that the casting blank entraps slag exists in the steel plate. The detection accuracy of the slag entrapment of the casting blank can be improved, and the detection cost is low.

The invention discloses a preparation method and application of a low-temperature photovoltaic welding strip, and belongs to the technical field of energy conservation and environmental protection. According to the technical scheme, the method comprises the steps that a metal precursor is dissolved in an alcoholic solution, and a nano reinforced phase is prepared through regulation and control of a surfactant, ultrasonic treatment and aging calcination; the composite solder is prepared through argon smelting according to 1-6 parts of Sn, Bi, Ag, Ni, Cu, Ge, the modified glass powder and the nano reinforced phase; 99.95% electrolytic copper is subjected to vacuum melting and cold rolling to form a copper strip; the surface roughness is controlled through alkali washing degreasing and acid washing micro-etching; immersing the preheated copper strip into a molten pool for plating; and carrying out heat preservation and rosin protection treatment. According to the method, low-temperature welding at the temperature of 150-220 DEG C is achieved, an Ag-Sn intermetallic compound layer is formed after welding, the pull-off strength retention rate of a welding spot is larger than or equal to 80% after 200 times of thermal cycles, and the method is suitable for interconnection of crystalline silicon photovoltaic battery pieces.

The invention discloses a preparation method of a high-quality solid welding wire. The preparation method comprises the following steps of S1, raw material selection and pretreatment, S2, a drawing forming process, S3, surface treatment, S4, aftertreatment and finishing, S5, quality detection and control and S6, packaging and storage. Before work starts, raw materials are selected, low-carbon steel is selected, the purity of S is controlled to be smaller than or equal to 0.010%, the purity of P is controlled to be smaller than or equal to 0.015%, the size is controlled to be phi 5.5-6.5 mm, then oxide skin is removed through sulfuric acid for 5-10 min, after flushing is conducted through high-pressure water, residual acid is neutralized through alkali liquor, corrosion is prevented, then hot air drying is conducted at the temperature of 100-120 DEG C, it is guaranteed that no water exists on the surface, and the low-carbon steel is obtained. According to the method, the raw materials are pretreated, so that the cleanliness of the raw materials is improved, the production quality of the thick solid welding wire is improved, then the raw materials are smelted after being pretreated, and then a mixture of rare earth, deoxidized silicon, alloy vanadium and copper phosphorus tungsten carbide is added according to different environment requirements so as to increase the variety of the welding wire.

The invention discloses high-performance bridge steel and a production method thereof, and belongs to the technical field of ferrous metallurgy. The bridge steel comprises the following chemical components in percentage by mass: 0.09%-0.11% of carbon; silicon: less than or equal to 0.55%; 1.4%-1.6% of manganese; less than or equal to 0.018% of phosphorus; sulfur: < = 0.005%; 0.15% to 0.20% of niobium; less than or equal to 0.08% of vanadium; 0.006% to 0.03% of titanium; 0.01 to 0.02 percent of chromium; 0.01% or less of nickel; less than or equal to 0.3% of copper; 0.01% to 0.045% of aluminum; less than or equal to 0.3% of molybdenum; not more than 0.008% of nitrogen; and the balance of iron and inevitable impurities. According to the high-performance bridge steel and the production method thereof, by optimizing the component design and the production process, production of the bridge steel with high strength, low yield ratio, high toughness and good welding performance can be achieved.

The invention discloses an efficient and uniform electroplating manufacturing method of a thick copper plate. The efficient and uniform electroplating manufacturing method comprises the following steps: step 1, carrying out chemical oil removal treatment and micro-etching coarsening on a substrate; step 2, carrying out pre-impregnation treatment and manufacturing a mask; 3, a pulse electroplating device is adopted for carrying out edge auxiliary electroplating on the plate edge, and 4, plating solution closed-loop regulation and control are carried out, specifically, a regulation and control system is provided, the regulation and control system comprises a plating solution regulation and control device and an automatic compensation module, and a PLC control system controls the automatic compensation module to quantitatively supply additives according to the difference between a detection value and a required value. According to the method, the electric field intensity of the edge and the center of the substrate is balanced, the thickness uniformity of the copper layer is remarkably improved, and the thickness difference between the edge and the center is reduced; and the deposition rate stability of pulse electroplating is ensured. And meanwhile, the working efficiency is improved, the electroplating time is shortened, the energy consumption is reduced, the dosage of an electroplating additive is reduced, the service life of an electroplating solution is prolonged, the binding force of a copper layer and a substrate is improved, practicability is high, and high popularization significance is achieved.

The invention provides high-stability double-layer core-shell coated pure copper silver-substituted conductive paste and a preparation method thereof, and belongs to the technical field of electronic special materials. The copper-resistant coating comprises the following components in percentage by mass: 82%-90% of antioxidant copper powder with a double-layer core-shell structure, 3%-6% of bismuth-boron-zinc lead-free low-melting-point glass powder, 3%-7% of a modified epoxy resin compound organic carrier, 2%-5% of a gradient volatilization compound solvent and 0.5%-2% of a special compound additive for copper. Through the double-layer core-shell copper powder design of inner-layer nano-silver passivation and outer-layer organic composite coating and in cooperation with a liquid-phase synergistic anti-oxidation system, the volume resistivity after slurry curing is smaller than or equal to 3.5 * 10 <-5 > omega.cm, the resistivity change rate after 1000-hour damp-heat aging at 85 DEG C / 85% RH is smaller than or equal to 10%, the normal-temperature storage period without opening a tank is larger than or equal to 6 months, direct curing can be conducted in the conventional air atmosphere of 120-160 DEG C, and the high-temperature-resistant copper paste can be applied to the field of high-temperature storage. The silver paste is completely compatible with production and application production lines of existing silver paste, equipment transformation is not needed, the comprehensive cost is reduced by more than 80% compared with pure silver paste, and the silver paste can be widely applied to the fields of PCBs, membrane switches, flexible electronics, photovoltaic back electrodes, LED packaging and the like.

The invention discloses a temperature rise verification method for welding reliability of a copper bar, relates to the technical field of copper bars, and provides the following scheme aiming at the problems that potential and developing hidden defects proposed in the background technology cannot be identified and potential safety hazards are buried due to the fact that obvious temperature abrupt change is possibly not caused in the test period. Comprising the steps of sample selection and pretreatment: selecting a to-be-tested copper bar welding part, performing nondestructive testing (such as ultrasonic testing or X-ray testing) on the sample, observing defects such as air holes, slag inclusion, cracks and incomplete penetration, removing obviously unqualified samples, and pretreating the sample, including surface cleaning and stress relief annealing. According to the invention, the artificial intelligence technology is deeply integrated into the traditional temperature rise test process, so that the characteristic mode can be identified when a tiny hot spot is just formed and the overall temperature rise is not caused to exceed the standard, the early intelligent diagnosis of hidden defects is realized, the fault hidden danger is eliminated in the bud state, and the accuracy of the detection result is improved at the same time.

The application relates to the technical field of primary and secondary fusion complete ring network boxes, in particular to a high-reliability primary and secondary fusion complete ring network box, which comprises a box body, a ring network cabinet installed in the box body and a plurality of ventilation openings arranged around the box body. The primary and secondary fusion complete ring network box can utilize the phase-change material filled in the heat preservation box to absorb the external radiant heat and the residual heat of the equipment in the box during the day and stably store the heat, and the heat is conducted through the heat-conducting copper plates in the heat increasing and dew removing assembly at night, is then directionally transmitted to the inner wall of the box through a plurality of heat dissipation copper sheets, and the first temperature insulation cover wraps the rest of the side surfaces of the heat dissipation copper sheets, so that the heat loss to the air in the box or the outside of the box is prevented, the heat is forced to act on the inner wall, the temperature of the inner wall is prevented from being reduced below the dew point of the air, dew is prevented from being formed on the surfaces of the secondary elements and cable joints, hidden dangers such as the decrease of insulation performance and the corrosion of elements are effectively avoided, and the overall operation reliability is ensured.