The invention relates to a method of a low cost
selenide van thin film and the fast
selenium sulfuration heat treatment to prepare the
solar cell, which can be used in the nm
selenide paint roll
coating or the electrodeposit method to prepare the
selenide van film, through the vacuum flash
selenium sulfuration heat treatment, the high efficiency
cadmium-free
thin film solar cell or the photovoltaic integrated module. The thin film
cell adsorption layer
band gap is in the v-shaped distribution, and the flash
selenium sulfuration heat treatment causes the CuSe in the porous loose thin film fusing, soaking,
liquid phase serving the reaction growth of the CIGS film
crystal and the self densification of the film with the In4Se3, reactive
sputtering In2Se3 or In2S3 to neutralize the excessive CuxSe adsorbed by the film
surface layer, going on splashing the micro excessive In2S3 to generate n-high-ohmic
resistor Cu(In<1-y>Gay)<3>(SxSe<1-x>)<5> thin film
cell shallow burying, then reacting the splashing deposit n-type In(OH,S) / ZnS(O,OH) / Zno(S) buffer layer with the i-layer, linking the slashing transparent conductive film / and laserprocessing collecting ellectrode to complete the preparation of the thin film
cell.