2211results about "Microcapsule preparation" patented technology

The invention discloses crack-chloride ion double-triggered subsea tunnel corrosion-resistant concrete and a preparation method thereof, and relates to the field of subsea tunnel engineering materials. The concrete is prepared from the following components in parts by weight: 400 to 500 parts of Portland cement, 50 to 80 parts of fly ash, 60 to 100 parts of superfine mineral powder, 1000 to 1100 parts of coarse aggregate, 700 to 800 parts of fine aggregate, 140 to 160 parts of water, 10 to 20 parts of self-repairing microcapsules and 1 to 5 parts of a water reducing agent, the self-repairing microcapsule comprises a capsule wall material, a self-repairing material and a layered dihydroxyl composite metal oxide. A crack-chloride ion double-response system is constructed, and the limitation of traditional single trigger repair is broken through. When a crack with a certain width appears in the concrete, the capsule wall of the self-repairing microcapsule is broken to release the repairing component, so that effective filling of the crack is realized; and meanwhile, the layered double-metal hydroxide can directionally adsorb chloride ions to form a stable compound, so that the migration rate of the chloride ions is remarkably reduced.

The invention discloses water-based anti-forgery ink, a preparation method thereof, an obtained printed matter and application thereof, and relates to the technical field of printing forgery prevention. The water-based anti-forgery ink comprises the following components in percentage by mass: 15%-30% of water-based resin, 5%-20% of acrylic resin, 0.5%-10% of an auxiliary agent, 2%-5% of a first fluorescent developing substance, 3%-10% of a first microcapsule and the balance of water, a capsule core of the first microcapsule contains a second fluorescent color developing substance, a capsule shell is made of a first temperature-sensitive high polymer material, and the first temperature-sensitive high polymer material is subjected to reversible phase transformation at a first threshold temperature T1; the second fluorescent color-developing substance is different from the first fluorescent color-developing substance. According to the invention, multiple hidden anti-counterfeiting mechanisms are arranged and can be triggered under specific conditions, so that the cracking difficulty is increased; and the anti-counterfeiting verification requirements in some important occasions can be met.

The invention relates to the technical field of concrete materials, and discloses rapidly-reinforced high-performance sprayed concrete for an existing tunnel lining and a preparation method of the rapidly-reinforced high-performance sprayed concrete. The sprayed concrete is prepared from the following raw materials in parts by weight: 300 to 350 parts of low-calcium high belite sulphoaluminate cement, 80 to 100 parts of superfine slag powder, 3 to 8 parts of a trigger type activating agent, 5 to 15 parts of slow-release particles, 2 to 5 parts of nanogel, 800 to 900 parts of fine aggregate, 800 to 900 parts of coarse aggregate, 30 to 50 parts of copper-plated steel fiber, 0.8 to 1.2 parts of polypropylene fiber, 30 to 40 parts of a viscosity-adjusting accelerator, 10 to 20 parts of a water reducing agent and 160 to 180 parts of water. The sprayed concrete is high in compressive strength and good in durability, the double threats of chemical corrosion and chloride ion permeation / steel bar corrosion are cooperatively solved, and the requirement for rapid reinforcement of tunnels and underground engineering is met.

The invention relates to the field of oil storage microcapsules, and discloses a porous covalent organic framework oil storage microcapsule as well as a preparation method and application thereof. Under the catalysis of p-toluenesulfonic acid, 4, 4 ', 4' '-(1, 3, 5,-triazine-2, 4, 6-triyl) triphenylamine and trialdehyde phloroglucinol monomers are promoted to be subjected to condensation reaction in the repeated oscillation process, a product is purified to prepare a 4, 4', 4 ''-(1, 3, 5,-triazine-2, 4, 6-triyl) triphenylamine covalent organic framework, and by means of a periodic pore structure of the covalent organic framework, the covalent organic framework can be used for preparing the covalent organic framework. And the lubricating oil is adsorbed and stored and can be controllably separated out to provide lubrication during working, so that a high-performance self-lubricating effect can be realized. In addition, covalent organic frameworks are used as hard particles to be doped into a polymer matrix to modify the polymer matrix, so that the wear resistance of the polymer matrix can be greatly enhanced, and the performance of the self-lubricating bearing material is improved.

The invention provides a well wall heat insulation hollow microsphere and a preparation method thereof. A sealed vacuum cavity is formed in the well wall heat insulation hollow microsphere, a polymer layer is arranged on the surface of the well wall heat insulation hollow microsphere, the polymer layer is provided with cationic groups and anionic groups, and aerogel nano powder is embedded in the polymer layer. The invention also provides a preparation method of the well wall heat insulation hollow microsphere. The well wall heat insulation hollow microspheres have high compressive strength, and the heat conductivity coefficient is reduced; efficient well wall adsorption can be achieved through the synergistic effect of anion groups and cation groups, the defects that a traditional heat insulation material is prone to breaking, fast in heat conduction and ineffective in adsorption under the high-temperature and high-pressure environment of an ultra-deep well are overcome, and the material is suitable for an ultra-deep and ultra-deep oil and gas well drilling fluid system. A multistage pore heat insulation system is constructed through the zwitterionic polymer and the aerogel nano-powder, and a rough surface structure can be provided to assist the microspheres in adsorbing well wall rocks.

The invention discloses a multi-shell photo-thermal phase change microcapsule and a preparation method thereof, the multi-shell photo-thermal phase change microcapsule comprises a capsule wall and a capsule core, the capsule core is an organic phase change material, the capsule wall comprises a titanium dioxide layer, a graphene layer and a polydopamine layer, the graphene layer is located outside the titanium dioxide layer, and the polydopamine layer is located outside the graphene layer. The multi-shell photo-thermal phase change microcapsule disclosed by the invention can realize full-wave band capture, and is high in photo-thermal conversion efficiency and good in shell stability.

The invention relates to the technical field of road construction and maintenance, and discloses a multi-polymer modified emulsified asphalt in-situ cold recycling mixture and a preparation process thereof, the multi-polymer modified emulsified asphalt in-situ cold recycling mixture comprises the following components by weight: 600-680 parts of nano hybrid emulsified asphalt; 250 to 350 parts of plasma activated recycled aggregate; 15 to 30 parts of a microcapsule phase change catalyst; 5 to 10 parts of bio-based interface reinforcing fiber; and 3-8 parts of a rare earth doped curing accelerator. According to the invention, through multi-technology cross-scale fusion of a quaternary polymer rigid-flexible synergistic system, a gradient emulsification-vacuum self-assembly process, double-shell intelligent catalytic release and rare earth gradient distribution-magnetic field induced fiber arrangement, the bottlenecks of unbalanced high and low temperature performance, easy interface stripping, poor aging resistance, extensive process regulation and control and the like of a traditional asphalt material are overcome; and the strength and toughness-durability-self-adaption performance synergistic jump is realized.

The invention relates to the technical field of anti-counterfeiting materials, and particularly discloses a composite color-changing agent, anti-counterfeiting color-changing ink and a preparation method of the anti-counterfeiting color-changing ink. The composite color-changing agent is a composite microsphere with a core-shell-satellite structure, the core is a temperature-sensing color-changing microcapsule and is composed of a temperature-sensing color-changing core material and a polymer wall material, the shell is a transparent polymer shell and wraps the core through in-situ polymerization, the satellite is a light-sensing color-changing material and is embedded and fixed on the shell, and the shell is a transparent polymer shell and is embedded and fixed on the shell. According to the composite color-changing agent, the light-sensitive material and the temperature-sensitive material are compositely inlaid through the polymer shell, so that the problem of poor compatibility of the light-sensitive material and the temperature-sensitive material is solved, the stability and the production efficiency are improved, and the imitation difficulty is increased.

The invention relates to microcapsule phase change cooling liquid and a preparation method thereof, and belongs to the technical field of high polymer materials. The microcapsule phase change cooling liquid comprises the following components in parts by weight: 40-55 parts of ethylene glycol, 30-45 parts of deionized water, 5-14 parts of a core material, 3-6 parts of a wall material, 0.1-0.4 part of a dispersion stabilizer, 0.1-0.4 part of a corrosion inhibitor and 0.1-0.4 part of a modified antirust agent, the microcapsule phase change cooling liquid prepared by the invention not only has a good cooling effect, but also has excellent rust-proof and flame-retardant effects.

The invention belongs to the technical field of environmental protection of bioremediation wastewater, and discloses an immobilized adsorption microsphere, which is prepared from Bacillus spp., Candida utilis and European nitrosomonas through an immobilized embedding technology. The microspheres provided by the invention can effectively repair glutamic acid high ammonia nitrogen fermentation wastewater.

The invention belongs to the field of high polymer materials, and discloses a double-trigger programmable degradable PHA composition and a preparation method thereof. A cured film structure formed by the composition sequentially comprises an outer protective layer, a trigger layer and an inner functional layer from outside to inside, wherein the outer protective layer takes polyhydroxyalkanoate as a base material, a reversible cross-linked network is introduced into the outer protective layer, the trigger layer is provided with humidity and ion double-trigger microcapsules, and the inner functional layer is used for bearing functional auxiliaries. The cured film can maintain low permeability and mechanical stability before application. After application, under the synergistic effect of specific moisture and ions, the trigger layer is activated, so that the cured film is subjected to step-type improvement of moisture permeability in a preset time window, and a through hole is formed. And finally, integral disintegration is realized through physical structure failure. The technology can be applied to the fields of seed coating and the like, the activity of a biological base material can be ensured by adopting a low-temperature process with the temperature lower than 50 DEG C, and unification of stable protection before application and on-demand disintegration after application is achieved.

The invention discloses a multi-mode closed-loop feedback thumbtack needle electrical stimulation anti-depression system, belongs to the technical field of drug delivery systems, and particularly relates to collaborative treatment of acupoint stimulation and drug sustained release. The problems that in the prior art, cooperation of acupoint stimulation and medicine slow release cannot be achieved, and further improvement of the treatment effect is limited are solved. The system comprises an AI regulation and control module and a collaborative treatment module. The AI regulation and control module predicts treatment parameters; and the collaborative treatment module is used for carrying out collaborative treatment of acupoint electrical stimulation and skin administration on the patient based on the predicted treatment parameters. The multi-mode closed-loop feedback thumbtack needle electrical stimulation anti-depression system is suitable for collaborative treatment of acupoint stimulation and drug sustained release.

A magnetic nanoparticle composite microcapsule, and a preparation method therefor and the use thereof. The preparation method comprises: diluting concentrated ammonia water with absolute ethanol in which nano-Fe3O4 is dispersed, stirring same and adding ethyl orthosilicate, centrifuging same, and then performing washing to obtain Fe3O4 / SiO2 particles; dispersing same in anhydrous ethanol, then adding isopropanol containing tetrabutyl titanate, and performing a treatment to obtain Fe3O4 / SiO2 / TiO2 nanoparticles; adding polyurethane TDI prepolymer to the Fe3O4 / SiO2 / TiO2 nanoparticles, adding same to a core material, then dripping an emulsifier, and stirring same to obtain a core material emulsion; and heating same in a water bath, dropwise adding butanediol, and performing heating, stirring and vacuum filtration to obtain a magnetic nanoparticle composite microcapsule. By means of the loading with a core material having a repair function, the prepared magnetic microcapsule can actively repair damage to an insulating material caused by electrical and mechanical stress, thereby improving the reliability of a device.

A treatment composition that includes a treatment adjunct and a population of core / shell delivery particles, where the shell is made from an acid-treated chitosan and a cross-linking agent, where the acid-treated chitosan results from treating chitosan with a weak acid, or even a mixture of a strong acid and a weak acid. Related methods of making and using such compositions.

The invention belongs to the technical field of preparation of phosphorus removal agents, and particularly relates to a composite phosphorus removal agent and a preparation method and application thereof. The composite phosphorus removal agent comprises a honeycomb carrier and microspheres, the microspheres are loaded on the honeycomb carrier; the microspheres are prepared from the following raw materials: polyvinylidene fluoride particles, graphene oxide, ZrOCl2 and phosphorus-accumulating bacteria. The composite phosphorus removal agent comprises a honeycomb carrier, microspheres and microcapsules, wherein the microspheres and the microcapsules are loaded on the honeycomb carrier; capturing phosphate radicals in a water body by the microspheres and carrying out biological phosphorus removal and adsorption phosphorus removal; the honeycomb carrier also has the effect of adsorbing phosphate; and the two synergistically remove phosphate in the water body, so that the phosphorus removal effect of the phosphorus removal agent is improved, and the burden of the water body is not increased.

The invention relates to the technical field of water-stable layer materials, in particular to a microcapsule self-repairing ardealite water-stable layer material and a preparation method and application thereof.The preparation method comprises the following steps that S1, ardealite, slag powder and a modified coagulant are mixed in a mixer, and a preliminary modified mixture is obtained; s2, adding double microcapsules into the primary modified mixture to obtain a secondary modified mixture; s3, adding deionized water into the modified mixture obtained in the step S2, and stirring and mixing to obtain a modified wet mixture; and S4, injecting the modified wet mixture into a mold, vibrating to remove bubbles, standing at room temperature, and demolding and curing for 25-28 days to obtain the microcapsule self-repairing phosphogypsum water-stable layer material. Through the synergistic effect of the double microcapsules and the modified coagulant, the integrated function of rapid coagulation, self-repairing and toughness enhancement is achieved, it is guaranteed that a strength framework is rapidly formed in a high-humidity environment, meanwhile, immediate repairing can be provided for micro-damage, and the toughness and crack resistance of the material are macroscopically improved.

The invention relates to the technical field of controlled-release microcapsules, and particularly discloses a pH-responsive mold-targeted controlled-release essence microcapsule for daily chemicals and a preparation method thereof.The preparation method comprises the following steps that S1, chitosan is dissolved with an acid solution, a catalyst and a pH sensitive reagent are added under the protective atmosphere for a reaction, and a pH-responsive graft copolymerization product is obtained through separation and purification; s2, mixing the pH response graft copolymerization product, a cross-linking agent and a mould targeting reagent for reaction, and dialyzing and purifying to obtain a microcapsule wall material; and S3, emulsifying essence by using an emulsifier, and then adding a defoaming agent, the microcapsule wall material, the sodium tripolyphosphate aqueous solution and a pH regulator to prepare the pH-responsive mold-targeted controlled-release essence microcapsule for daily use. The microcapsule integrates specific recognition targeting ability and pH response release ability to mould, and can accurately release natural essence with bacteriostatic and aromatic functions at the mould breeding part of clothes, so that the dual effects of bacteriostasis and aroma retention are realized.

The invention provides a perfluoroethanone microcapsule and a preparation method thereof, and belongs to the technical field of fire extinguishing materials, the perfluoroethanone microcapsule comprises a core and a shell layer; the core comprises perfluorohexanone and fumed silica; the shell layer comprises isophorone diisocyanate, diethylenetriamine and a chlorine-containing monomer, and the isophorone diisocyanate, the diethylenetriamine and the chlorine-containing monomer are subjected to an interfacial polymerization reaction to form a polyurea-polyurethane hybrid network; the mass ratio of the shell to the core of the microcapsule is 1: (5-20); the anhydrous microcapsule core is constructed through an oil-in-oil type anhydrous interfacial polymerization system, so that the hydrolysis side reaction is fundamentally avoided, the microcapsule has higher stable encapsulation efficiency, and the reliability and long-term effectiveness of the product in the storage and use processes are ensured.

The invention discloses a fire extinguishing microcapsule and a preparation method thereof, and belongs to the technical field of fire extinguishing. The fire extinguishing microcapsule comprises a capsule core and a capsule shell, wherein the capsule core comprises a water-based fire extinguishing agent and a fluorine-based fire extinguishing agent which are mutually insoluble; the capsule shell is coated outside the capsule core; wherein the mass ratio of the water-based fire extinguishing agent to the fluorine-based fire extinguishing agent is K1, and K1 is larger than or equal to 0.5 and smaller than or equal to 2. The fluorine-based fire extinguishing agent is preferentially gasified to break through the capsule shell to be released due to the characteristics of low boiling point and high vapor pressure so as to quickly block the chain reaction of combustion, the water-based fire extinguishing agent is secondarily released after being heated and expanded, continuous cooling is realized through vaporization heat absorption, self-driven staged release is realized by utilizing the physical property difference of the fluorine-based fire extinguishing agent and the water-based fire extinguishing agent, and the overall fire extinguishing efficiency of the fire extinguishing microcapsule is improved.

The invention belongs to the technical field of coating self-repairing, and relates to a preparation method of a modified urea formaldehyde microcapsule containing a drying oil repairing agent. Preparing the microcapsule by using a two-step in-situ polymerization method, wherein the microcapsule mainly comprises a capsule core and a capsule wall. Wherein the capsule core is a dry oil repairing agent, and the capsule wall is urea-formaldehyde resin copolymerized and modified by melamine. According to the microcapsule provided by the invention, the defect that the dry oil core material is easy to leak is overcome through a simple modification process while high repairability endowed by the dry oil capsule core is considered, and the storage life of a microcapsule product coated with the dry oil in an air environment is greatly prolonged.

The invention discloses a self-repairing synchronous grouting material and a preparation method thereof, and belongs to the technical field of grouting materials. The self-repairing synchronous grouting material comprises a cement base material, a microbial capsule and chitosan calcium salt, the concrete comprises the following raw materials in parts by mass: 7-12 parts of Portland cement, 20-28 parts of fly ash, 40-55 parts of quartz sand, 20-30 parts of water, 2-7 parts of bentonite, 1-5 parts of microbial capsules and 1-5 parts of chitosan calcium salt. The self-repairing synchronous grouting material disclosed by the invention is combined with a microorganism self-repairing technology, and mineral substances such as calcium carbonate and the like can be generated through metabolic activity of microorganisms when the material has cracks, so that the cracks are automatically filled, and expansion of the cracks on the surface of a concrete material can be effectively prevented; the grouting material can continuously repair microcracks caused by environmental changes or construction stress in the long-term use process, and the integrity and stability of the structure are kept.

To provide hollow particles in which the dielectric dissipation factor is decreased, and the performance stability in high-humidity environment is improved. Hollow particles comprising a shell, which contains a resin, and a hollow portion surrounded by the shell, wherein the hollow particles have a void ratio of 50% or more; wherein the shell contains a polymer as the resin, and a content of a crosslinkable monomer unit is 60% by mass or more in 100% by mass of all monomer units of the polymer; and wherein an aqueous dispersion of the hollow particles, which is obtained by dispersing the hollow particles with a volume of 0.35 cm3 in 100 mL of deionized water, has a pH of 6.5 or more and 7.5 or less and a conductivity of 50 μS / cm or less.

The invention discloses a self-repairing geopolymer grouting material as well as a preparation method and application thereof, and belongs to the technical field of underground engineering structures and rock mass grouting, leaking stoppage and reinforcement materials. The self-repairing geopolymer grouting material is prepared from the following components in parts by mass: 1 part of grouting powder base material, 0.01 to 0.1 part of self-repairing microcapsule and 0.5 to 1.5 parts of water, the self-repairing microcapsule comprises a geopolymer microcapsule and a microbial microcapsule in a mass ratio of (0.5-1.5): 1. The obtained grouting material has high impermeability, dynamic deformation adaptability and multi-scale self-repairing capability. In the elastic stage, the shell of the geopolymer microcapsule absorbs deformation energy and delays the cracking of the matrix; in the damage stage, the geopolymer microcapsules are broken to release the repairing agent, and crack diffusion energy is dissipated through chemical bond recombination; and in the repairing stage, the calcium carbonate / geopolymer composite phase forms a new energy loss interface, so that the material still has relatively low permeability after strain cyclic loading, and the repairing effect is improved.

The invention discloses a fire extinguishing microcapsule and a preparation method thereof, and belongs to the technical field of fire extinguishing. The fire extinguishing microcapsule comprises a capsule core and a capsule shell, and the raw material for preparing the capsule core comprises a water-based fire extinguishing agent; the capsule shell comprises an interfacial polymerization layer and a UV curing layer which are sequentially arranged from inside to outside, and the water-based fire extinguishing agent is wrapped in the interfacial polymerization layer. On one hand, the interfacial polymerization layer is a film formed through interfacial polymerization reaction, namely, the interfacial polymerization layer is formed by utilizing the hydrophilicity of the water-based fire extinguishing agent and the lipophilicity of the capsule shell, so that the sealing performance and the flexibility are improved; and on the other hand, the UV curing layer is formed by curing the raw materials for preparing the capsule shell through cross-linking under ultraviolet irradiation, so that the impact resistance and the deformation resistance of the capsule shell can be enhanced, and the mechanical strength and the high temperature resistance of the capsule shell are improved. In addition, the UV curing layer on the outer side and the interfacial polymerization layer on the inner side are sequentially formed in stages, the mechanical strength of the capsule shell is improved, and meanwhile the possibility of permeation loss of the water-based fire extinguishing agent is reduced.

The invention provides low-viscosity high-wear-resistance vehicle engine oil and a preparation method thereof, and belongs to the technical field of engine oil. According to the preparation method, an ionic liquid group is introduced through a reaction, a nano interlayer compound is constructed by combining surface modification of a metal-ionic liquid complex and silicon dioxide nanoparticles, and a microcapsule structure is formed through coating of a urea-formaldehyde prepolymer; the ionic liquid group provides a low friction coefficient and thermal stability, the silicon dioxide nanoparticles provide physical isolation and wear-resistant protection, and the microcapsules realize controlled release and dynamic repair of the lubricating components; a skeleton polymer is prepared through a reaction of polyamidoamine and epoxy chloropropane so as to provide abundant active sites, and oxidation resistance is improved through a synergistic effect of the skeleton polymer, hindered phenol and calixarene; by combining oleic acid modified nanoparticles, the dispersity and the wear resistance are enhanced, and meanwhile, dynamic protection is provided on a friction interface; the synergistic effect prolongs the service life of the engine oil and improves the high-temperature stability of the engine oil.

The present application relates to the technical field of melamine phase change microcapsule preparation, and particularly relates to a melamine phase change microcapsule preparation device and method based on microfluidic technology; the technical scheme: a melamine phase change microcapsule preparation device and method based on microfluidic technology, comprising an aqueous solution tank, an aqueous phase liquid inlet pump, a first valve, a pressure regulator, an oil phase liquid inlet assembly, a liquid mixing assembly, a reaction assembly and a collection assembly; compared with the traditional melamine phase change microcapsule preparation method, the melamine phase change microcapsule prepared by the intermittent method has the problems of poor quality stability, low performance reproducibility, low production efficiency and low cost, etc.; the melamine phase change microcapsule preparation method adopts a microfluidic device integrating temperature control, liquid mixing and chemical reaction, etc., and by connecting the liquid inlet pump at different places, various components can be introduced and polymerization reaction can be carried out in the process of preparing the melamine phase change microcapsule.

The invention belongs to the field of functional composite fabrics, and provides a mosquito-repellent thermoplastic polyurethane composite fabric and a preparation method thereof.According to the mosquito-repellent thermoplastic polyurethane composite fabric and the preparation method thereof, the design that mosquito-repellent microcapsules of a core-shell structure are dispersed in a thermoplastic polyurethane hot melt adhesive layer is adopted, a microcapsule core layer comprises mosquito-repellent active ingredients such as icaridin, deet or dimethyl phthalate, and the mosquito-repellent active ingredients are dispersed in a thermoplastic polyurethane hot melt adhesive layer; the shell layer is made of a polyurea material and is prepared through an interfacial polymerization method, high-load stable dispersion and controllable dot matrix film forming of the microcapsule in a hot melt adhesive system are achieved, the content of the microcapsule can reach 0.5-15 wt%, the particle size is controlled to be 0.1-2.0 m, the drug loading capacity reaches 10-60 wt%, the problem that the mosquito-repelling microcapsule is prone to damage and failure in the high-temperature melting mixing and hot-pressing compounding process is solved, and the mosquito-repelling microcapsule has good application prospects. The prepared composite fabric is high in mosquito repelling rate, still keeps an effective mosquito repelling function after being washed for multiple times, and has a wide application value.

The invention discloses a method for preparing a cordyceps culture medium by taking polygonatum kingianum as a culture medium, and relates to the technical field of culture medium preparation. The method comprises the following steps: performing enzymolysis treatment on a polygonatum kingianum raw material to obtain enzymatic hydrolysate rich in micromolecular nutrition; active components of polygonatum kingianum are extracted to prepare microcapsules with response release characteristics; preparing at least two kinds of 3D biological printing ink by utilizing the enzymatic hydrolysate and a component containing the microcapsule and a polygonatum kingianum material which is not subjected to enzymolysis; the ink is constructed into a three-dimensional culture medium with a layered or gradient structure layer by layer through a 3D printing technology and is solidified, the culture medium prepared by the method can realize gradient distribution of nutrients and programmed release of active ingredients, and an optimized microenvironment is provided for growth of cordyceps sinensis, so that the culture efficiency, yield and quality of cordyceps sinensis are effectively improved.

This invention discloses an ultra-high toughness multifunctional self-assembled C-S-H gel material and its preparation method. The ultra-high toughness multifunctional self-assembled C-S-H gel material includes a stacked core-shell structure layer, which is composed of core-shell structure particles. The core-shell structure particles have hydrated calcium silicate nanoparticles as the core and polyacrylic acid-acrylamide copolymer as the shell. The obtained ultra-high toughness multifunctional self-assembled C-S-H gel material has high toughness, good tensile deformation properties, and temperature-sensitive effect.

The invention relates to a preparation method and application of a silicon-based biodegradable essence microcapsule, and the preparation method of the silicon-based biodegradable essence microcapsule comprises the following steps: S1, uniformly mixing oily essence and a silicon-based mesoporous material to obtain an oil phase; dissolving an emulsifier in water to obtain a water phase; s2, mixing the oil phase and the water phase, and homogenizing to obtain an emulsion; and S3, adding a diisocyanate compound and polypropylene carbonate into the emulsion, and carrying out a stirring reaction to obtain the silicon-based biodegradable essence microcapsule. A silicon-based mesoporous material is introduced in the process of preparing the essence microcapsule by taking polypropylene carbonate as a wall material, a synergistic wrapping system of the essence microcapsule is constructed, and the volatile essence is subjected to double-layer protection by utilizing a mode of combining physical adsorption and chemical crosslinking embedding, so that the fragrance retention time of the essence is prolonged, and the fragrance retention time of the essence is prolonged. Meanwhile, the embedding rate of the microcapsule can be effectively improved, and the application of the essence microcapsule in actual production can be promoted by combining the biodegradable characteristic of the polypropylene carbonate.