1262 results about "Geopolymer" patented technology

The invention provides geopolymeric compositions, which have controllable thickening and setting times for a wide range of temperatures and a large range of geopolymer slurry densities. The geopolymer slurry compositions have good mixability and pumpability, whilst the set materials develop good compressive strength and permeability. The invention discloses a method for preparing geopolymer for oilfield cementing applications. The geopolymeric compositions according to the invention comprises a suspension comprising an aluminosilicate source, a metal silicate, an alkali activator, lightweight or heavyweight fillers and a carrier fluid wherein the suspension of said geopolymeric composition is pumped in a well and allowed to set.

A geopolymer composite ultra high performance concrete (GUHPC), and methods of making the same, are provided herein, the GUHPC comprising: (a) a binder comprising one or more selected from the group consisting of reactive aluminosilicate and reactive alkali-earth aluminosilicate; (b) an alkali activator comprising an aqueous solution of metal hydroxide and metal silicate; and (c) one or more aggregate.

The invention provides geopolymeric compositions intended for use in carbon dioxide injection or production wells or storage reservoirs and preferably in a supercritical carbon dioxide conditions. The geopolymeric composition is formed from a suspension comprising an aluminosilicate source, a metal silicate, an alkali activator, a retarder and/or an accelerator and a carrier fluid wherein the oxide molar ratio M₂O/SiO₂ is greater than 0.20 with M an alkali metal.

The invention discloses a fibre reinforced coal ash based geopolymer foam material and a preparation method thereof. The fibre reinforced coal ash based geopolymer foam material disclosed by the invention comprises the following components in percentage by weight: 50-70% of aluminium silicon raw material, 5-15% of slag, 3-8% of inorganic fibre, 15-30% of liquid alkaline exciting agent, 0.2-2% of foaming agent, and 2.5-3.5% of foam stabilizer. The preparation method disclosed by the invention comprises the step of also adding the foam stabilizer while adding the foaming agent by adopting the liquid alkaline exciting agent by taking the inorganic fibre as the reinforcing agent, the slag as the Ca adjusting agent and other solid raw materials (such as coal ash, metakaolin and silica fume) as powder for providing aluminium silicon. The light foam material prepared by the invention has the characteristics of being high in intensity, small in size change rate, low in water absorption and the like in the event of having same volume weight and heat conductivity of the similar materials, and is applied to various applications.

The invention provides a geopolymer gel material for rush repairs and rush constructions, which is prepared by adding water to 13-17 percent by weight of exciting agent and 82-87 percent by weight of slag containing aluminosilicate. The slag comprises one or the combination of more of blast furnace slag, steel slag, coal ash and coal gangue, and the exciting agent comprises the following components in percentage by weight: 35-75 percent of SiO2, 0-55 percent of Na2O, 0-65 percent of K2O, 0-1 percent of CaO and 0-1 percent of SO3. The geopolymer gel material which has the characteristic of quick setting and hardening is prepared by using the industrial waste slag as a main raw material and matching the exciting agent, and the geopolymer gel material has excellent mechanical property and controllable setting time and can replace gel materials such as fast setting and hardening cement, and the like in the processes of rush repairs and rush constructions. The industrial solid wastes such as the blast furnace slag, the steel slag, the coal ash, the coal gangue, and the like containing the aluminosilicate series are used as main raw materials, metakaolin is not added and the raw materials do not need to be calcined, thus the invention has low energy consumption, less pollution, simple process, low cost, environmental protection and energy saving.

The invention relates to a burning-free geology polymer material of red mud coal ash and a preparation method thereof, belonging to the technical field of recycling inorganic nonmetal material and industrial solid waste. Kawazu mud powder and coal ash are taken as main substrate raw materials, building fine sands and building crushed stones are taken as aggregate, solid water glass powder is taken as alkali activator to prepare the burning-free geology polymer material of red mud coal ash. The raw materials comprise the following components based on parts by weight percent: 5-98% of the kawazu mud powder, 1-65% of the coal ash, 1-96% of the building fine sands and the building crushed stones, and 1-20% of the solid water glass powder. Counting the red mud+the coal ash+the building fine sands and the building crushed stones as 100%, the raw materials further comprise the following components based on parts by weight percent: 5-45% of water and 0.1-10% of calcium lignosulphonate. The preparation method comprises the steps of: dosing, mixing, aging, shaping, maintaining and drying, etc. The invention has the advantages of the high use ratio of industrial solid waste, the less pollution, the low energy composition and the simple operation of the preparation technology, and embodies the important meanings of environment protection, energy conservation and emission reduction.

The invention discloses inorganic artificial combining stone and a preparation method thereof. The artificial combining stone uses silicon acid-base solution to arouse metakaolin to react and generate geopolymer to serve as an inorganic cementing agent, and the artificial combining stone mainly contains the metakaolin, the silicon acid-base solution, natural stone aggregate, decoration aggregate, a thickening time control agent, inorganic pigment and fibers. The preparation method is firstly enabling the thickening time control agent and the inorganic pigment to be dissolved in the silicon acid-base solution to obtain mixed serous fluid, evenly blending the metakaolin, the natural stone aggregate, the decoration aggregate, the fibers and the mixed serous fluid, preparing the artificial combining stone through model entering or material distribution, vibration under the vacuum condition, molding in a pressing mode, maintaining, cutting, polishing, burnishing and surface protection. The artificial combining stone not only has decoration features which can be equal to that of resin artificial stone, but also is non-toxic, environment-friendly, low in cost, resisting in corrosion of most majority of acid-base salts, durable in high temperature and excellent in durable performance, obviously avoids whiting and saltpetering phenomena after a long time use, and is strong in pollution resisting capability.

The invention discloses a geopolymer grouting material and a preparation method thereof. An inorganic silicate composite material is prepared from 71-91 parts of mineral waste residues, 66-70 parts of coal ashes, 16-28 parts of alkali-activator and 0.5-1.6 parts of retarder; and then, the inorganic silicate composite material is mixed with water according to a proportion of 0.30-0.38 to prepare the geopolymer grouting material. The geopolymer grouting material disclosed by the invention has characteristics of being good in liquidity, high in early strength, free of shrinkage, good in durability, adjustable in setting time and strength. Compared with the conventional geopolymer polymer material, the material is a composite material formed by mixing various powder materials, and can be applied by adding water and stirring on the spot; the geopolymer grouting material is simple in preparation process, low in cost, convenient to operate, capable of being widely applied to cement concrete pavement slab bottom grouting, cement concrete pavement crack repairing, foundation bolt anchoring, equipment installing, pres-stressed bridge crack pouring, engineering repairing, reinforcing, and the like.

Geopolymer composite materials having low coefficient of thermal expansion are disclosed. The materials are useful in high temperature applications due to their low coefficient of thermal expansion and high strength. Also disclosed is a boron modified water glass geopolymer composition that is compatible with ceramic particulate material such as cordierite and fused silica. The geopolymer composite may be extruded to form structures such as honeycomb monoliths, flow filters or used as a plugging or skinning cement and may be fired at temperatures at or below 1100° C. Both the structures and the cement have high green and fired strength, a low coefficient of thermal expansion, and good acid durability. The cost of manufacturing objects using the material of the present invention is substantially reduced, in comparison with typically production methods of cordierite based bodies, due to the substantially shortened firing times.

The present invention generally relates to a geopolymer precursor dry mixture, geopolymer precursor package, a process of preparing a geopolymer composition, and a method of providing a geopolymer composition to a geopolymer composition preparation site.

Disclosed is a high-durability protective layer compound pile. The structure of high-durability protective layer compound pile comprises: the compound pile is composed of a core bearing structure which is wrapped with a high-durability protective layer, the material of the protective layer adopts plastic or other modified products, asphalt and mortar or concrete, alkali activated material and the mortar or the concrete, geopolymer and the mortar or the concrete, reactive powder concrete, fiber reinforcement concrete base material, and resin mortar or concrete; The manufacturing and the construction can adopt six methods: firstly, site-casting can be performed to the protective layer and a core structure simultaneously; secondly, after the site-casting is performed to the protection wall of the protective layer, the site-casting is performed to the site-cast protective wall; thirdly, prefabrication is performed to the sleeve of the protective layer, and site-casting is carried out to the prefabricated sleeve of the site cast core structure of the sunk tube; fourthly, prefabrication is performed to the sleeve of the protective layer, the sleeve is taken as an outer mould plate to prefabricate the prefabricated sleeve of the core structure; fifthly, prefabrication is performed to the core structure, the core structure is taken as an inner mould plate to prefabricate the prefabricated sleeve of the core structure; and sixthly, site-casting is implemented to the protective layer and the core structure simultaneously.

The present invention provides a process for the preparation of self glazed geopolymer tile using fly ash and granulated blast furnace slag. In the process of the present invention, the granulated blast furnace slag is fine grounded and/or mechanically activated in conventional grinding mills or high-energy mills. The fly ash, which is found in powder form and fine powder of granulated blast furnace slag, is thoroughly mixed to make a homogenous mixture. The alkaline solution is added into the mixture to initiate the geopolymerization. The ratio of water to powder is optimised to obtain a consistent paste to be used for vibration casting. During the casting, the consistent paste flows inside the mould and the particles settles at mirror finished surface of mould, giving rise to dense and smooth surface.

A method of fracturing a reservoir comprising the steps of pumping a geopolymer precursor fluid through a wellbore into the reservoir at a fracture pressure, the geopolymer precursor fluid at the fracture pressure generates fractures in the reservoir, wherein the geopolymer precursor fluid is comprised of an amount of aluminosilicate, an amount of alkaline reagent, and a permeability enhancer, allowing the geopolymer precursor fluid to fill the fractures in the reservoir, shutting-in the wellbore at a wellbore pressure, the wellbore pressure maintains the geopolymer precursor fluid in the fractures, allowing the geopolymer precursor fluid to harden for a hardening time to form a geopolymer in the fractures, the geopolymer has a geopolymer matrix, the geopolymer matrix has a permeability, the geopolymer has a compressive strength, and reducing the wellbore pressure allows a reservoir fluid to flow from the reservoir through the geopolymer matrix of the geopolymer to the wellbore.

The invention provides geopolymeric compositions, which have controllable thickening and setting times for a wide range of temperatures and a large range of geopolymer slurry densities. The geopolymer slurry compositions have good mixability and pumpability, whilst the set materials develop good compressive strength and permeability. The invention discloses a method for preparing geopolymer for oilfield cementing applications. The geopolymeric compositions according to the invention comprises a suspension made of an aluminosilicate source, a carrier fluid, an activator taken from the list constituted by: a metal silicate, a metal aluminate, an alkali activator, or a combination thereof, and an aluminum containing compound taken in the list constituted of bauxite, aluminum oxide and aluminum salt and the suspension is a pumpable composition in oilfield industry and the suspension is able to set under well downhole conditions.

Shaped geopolymeric particles, fibers, and articles incorporating at least one geopolymer are provided; the geopolymeric particles, fibers, and articles having a structure that is solid, foamed, hollow or with one or more voids. Geopolymers are formed by alkali activation of an aluminosilicate and/or aluminophosphate material. The end-products are shaped as spheres, flakes, fibers, aggregates thereof or articles. Such products are formed at low temperatures; wherein forming includes processing using techniques such as spray drying, melt spinning, or blowing. The shaped geopolymeric particles and fibers have high chemical durability, high mechanical strength, application-targeted flowability and packing properties, and are specially suited for incorporating into composite materials, articles, and for use in cementitious, polymeric, paint, printing, adhesion and coating applications. Shaped geopolymeric particles, fibers and articles having voids, hollow or foam-like structures are formed by adding one or more blowing agents.

The invention discloses a method for preparing a manganese slag-based geological polymer binder comprising: (1) the solid components of the materials are manganese slag and kaolin; the liquid components are water glass, water and activator. (2) the manganese slag is dried till the moisture content is less than 1%, and is milled in a ball mill till the specific surface is 400-600m<2>/kg, the kaolin is calcined at 900 DEG C till the kaolin becomes metakaolin, and is milled till the specific surface is 500-700<2>/kg. (3) the activator is added into the water glass solution and is mixed uniformly with water to get a water glass solution with a water glass modulus value of 1.5-3.5 and a water glass baume of 35-45 degrees. (4) the mixed solution prepared by the step (3) is added into the mixed powder of managese and metakaolin micropowder, is stirred and moulded after uniform mixture and maintenance. The preparation method has advantages of simple technology, no pollution during the preparation process, good gelling property and strong anti-seawater erosion property using industrial waste residue.

The invention discloses fly ash geopolymer concrete. The concrete is prepared by taking fly ash and metakaolin as base materials, taking one or more than two of sodium hydroxide, potassium hydroxide, sodium silicate and potassium silicate as well as water glass as alkaline activators, and adding modified ceramic microsphere particles, polymer fibers, coarse aggregates, fine aggregates and water. The fly ash geopolymer concrete has good mechanical properties, high durability and high corrosion resistance.

The invention provides a fly ash based geopolymer. The fly ash based geopolymer comprises a dry powder phase and water, of which the mass ratio is 20:3, wherein the dry powder phase comprises the following components in parts by weight: 60-85 parts of fly ash, 0-25 parts of silica fume, 10 parts of solid sodium silicate, 5 parts of industrially pure sodium hydroxide and 0.05-0.12 part of sodium tripolyphosphate. The fly ash based geopolymer can replace cement to prepare engineering materials such as concrete, mortar and the like, and is expected to be applied in the fields such as utilization of high-strength thermal mortar, high temperature resistant reinforcement materials, corrosion-resistant concrete structures and industrial wastes, rapid repairing materials, high-strength and high-performance materials, and the like. Meanwhile, the industrial waste fly ash can be largely and efficiently utilized; the fly ash based geopolymer has great significance on saving of resources, saving of energy sources and protecting of the environment. A preparation method of the fly ash based geopolymer is also simultaneously provided.

The invention discloses a porous material of phosphate-based geopolymer and a preparation method thereof. The preparation method comprises the following steps of: adopting metakaolin, alumina (or aluminium hydroxide), phosphoric acid and water as raw materials, adopting aluminium powder as a foaming agent and under a lower temperature ( 50-90 DEG C) preparing the porous material which adopts geopolymer material as a skeleton and has good properties. By testing the properties of the porous material, the result shows that the porous material has compression strength of 2.0 to 15.0MPa, apparent porosity of 30 percent to 70 percent, volume density of 0.40cm to 1.0g/cm and high-temperature resistance of more than 1300 DEG C; and the porous material with different properties and porous structures can be obtained by controlling molar ratio of Al/Si and P/Al and reaction conditions. The invention has simple technique and low cost and is expected to be applied in the fields of insulating materials, waste gas absorbing materials, sewage filtering materials, energy absorbing materials, insulating and encapsulating materials, military, aerospace and the like.

The present invention relates to geopolymer compositions, methods of producing the compositions, and uses thereof. The geopolymer compositions broadly are comprised of a geopolymer binder and an aggregate and, once cured, can exhibit compressive strengths in excess of that of Portland cement-based concrete formulations. The geopolymer composition of the present invention adheres to most surfaces and can b used in the formation of a mortarless building block, floor screed, bench, building block brick, support column or pre-molded column, beam, paving stone, tiles, stone accouterment for a garden, countertop, bathtub, sink, a geopolymer slab, a structural geopolymer composition, a reinforced geopolymer composition, a steel reinforced geopolymer composition, or as a substitute for structural concrete in foundations, beams, columns, or slab with the addition as necessary of steel reinforcement.