A method of forming a 
metal layer having excellent thermal and 
oxidation resistant characteristics using 
atomic layer deposition is provided. The 
metal layer includes a reactive 
metal (A), an element (B) for the amorphous combination between the reactive metal (A) and 
nitrogen (N), and 
nitrogen (N). The reactive metal (A) may be 
titanium (Ti), 
tantalum (Ta), 
tungsten (W), 
zirconium (Zr), 
hafnium (Hf), 
molybdenum (Mo) or 
niobium (Nb). The amorphous combination element (B) may be aluminum (Al), 
silicon (Si) or 
boron (B). The metal layer is formed by alternately injecting pulsed source gases for the elements (A, B and N) into a chamber according to 
atomic layer deposition to thereby alternately stack atomic 
layers. Accordingly, the composition ratio of a 
nitrogen compound (A-B-N) of the metal layer can be desirably adjusted just by appropriately determining the number of injection pulses of each source gas. According to the composition ratio, a desirable electrical 
conductivity and resistance of the metal layer can be accurately obtained. The atomic 
layers are individually deposited, thereby realizing excellent step coverage even in a complex and compact region. A metal layer formed by 
atomic layer deposition can be employed as a barrier metal layer, a lower 
electrode or an upper 
electrode in a 
semiconductor device.