11611 results about "Silicon dioxide" patented technology

The invention belongs to the technical field of enamel glaze preparation, and particularly relates to a high-temperature-resistant compact enamel glaze preparation method, which comprises: 1, enamel frit preparation: mixing 45-65% by mass of silicon dioxide, 10-15% by mass of anhydrous borax, 5-10% by mass of sodium carbonate, 2-6% by mass of lithium carbonate, 2-6% by mass of calcium carbonate, 2-6% by mass of strontium carbonate, and 3-6% by mass of ice crystal to form a batch, melting at 1300 DEG C for 2-3 hours, carrying out water quenching to prepare an enamel material, drying, and sieving with a 200-mesh sieve to obtain enamel frit powder; step 2, preparing enamel glaze slip, namely mixing and ball-milling 40-55% of enamel frit powder, 15-30% of 316 # stainless steel powder, 5.5-10% of clay suspending agent and 25-50% of water in percentage by mass to obtain the enamel glaze slip; and step 3, enamel coating and firing. The enamel coating has excellent high temperature resistance and corrosion resistance and long service life, and the preparation process is simple in requirement, simple and convenient to operate and suitable for industrial production.

The invention belongs to the technical field of biodegradable materials, and particularly relates to an environment-friendly degradable modified composite material, a preparation method and application. The material comprises PBAT, PBS, PLA, an inorganic mineral filler, natural plant fibers, PBAT-PTMO, nano-silica, an auxiliary agent and a plasticizer. In the preparation process, PLA is prevented from being hydrolyzed in vacuum drying, calcium carbonate and nano silicon dioxide are preheated and activated, natural plant fibers are dispersed through steam explosion and ethanol treatment, and raw material pretreatment comprises high-speed mixing and agglomeration breaking and medium-speed secondary premixing so as to realize uniform distribution. The co-rotating twin-screw extruder accurately controls the temperature, the speed, the rotating speed and the length-diameter ratio, and ensures melting plasticizing, uniform mixing and stable extrusion molding. According to the invention, by adopting accurate proportioning of multiple raw materials and a modification treatment process, the properties of mechanics, degradation, processing and the like of the material are synergistically improved, and the material is widely applied to multiple fields such as packaging bags, disposable tableware and agricultural plastic mulching films.

The invention relates to the field of concrete, and provides high-strength concrete and a preparation method thereof, and the high-strength concrete comprises modified basalt chopped fiber, a self-repairing agent, cement, fly ash, slag powder, coarse aggregate, natural sand, a water reducing agent and an air entraining agent. The modified basalt chopped fiber is oxidized by hydrogen peroxide, etched by hydrochloric acid and modified by a nano silicon dioxide coating, so that the interface bonding force is enhanced. The self-repairing agent is prepared by adopting expanded perlite to load bacillus through thallus culture, purification, dipping adsorption and low-temperature vacuum drying, CaCO3 deposition can be induced at concrete cracks, and self-repairing is achieved. The invention further provides a preparation method of the concrete. The preparation method comprises the steps of aggregate screening, hydrated liquid preparation, wet mixing, fiber and self-repairing agent adding, vibration forming and curing. The crack resistance of the concrete is improved by enhancing the fiber-matrix interface bonding force, meanwhile, the service life of the concrete is prolonged by utilizing a biological self-repairing technology, and the concrete is suitable for high-durability concrete engineering.

The invention belongs to the technical field of electrical epoxy resin materials, and particularly relates to anti-aging electrical epoxy resin and a preparation method thereof. The epoxy resin is prepared from the following raw materials in parts by weight: 70 to 80 parts of epoxy resin, 3 to 5 parts of modified nano silicon dioxide, 1 to 3 parts of aminated graphene, 5 to 8 parts of polyurethane, 0.5 to 1 part of methyltriethoxysilane, 0.1 to 0.5 part of lauryl sodium sulfate, 0.5 to 1 part of antioxidant and 0.5 to 1 part of ultraviolet absorbent. Through silane modified nano silicon dioxide and aminated graphene, the anti-aging and corrosion-resistant performance of epoxy resin is improved, nano silicon dioxide enhances hardness and rigidity, aminated graphene improves toughness and heat conductivity, nano silicon dioxide and aminated graphene have a synergistic effect, multiple physical barriers are formed, permeation of aging factors and corrosive media is reduced, and the anti-aging and corrosion-resistant performance of epoxy resin is improved. And the surface is subjected to hydrophobic treatment by adopting methyl triethoxysilane, so that the weather resistance and the moisture resistance are further improved.

The invention relates to a self-cleaning nano coating material and a preparation process thereof, and belongs to the technical field of functional coatings. The coating material is prepared from nano silicon dioxide, nano aluminum oxide, graphene nanosheets, nitrogen-doped titanium dioxide, fluorinated silane, polyurethane, polydimethylsiloxane, a microcapsule repairing system, ethanol and deionized water according to a specific proportion through a multi-layer composite structure. The preparation process comprises the steps of base material surface pretreatment, reinforced particle surface modification, base material dissolution, functional additive introduction and multi-layer coating preparation. Through bottom layer enhancement, middle layer flexible buffering and surface layer functional design, excellent mechanical strength, wide-spectrum photocatalytic performance, self-repairing capacity and environmental adaptability are achieved. The problems that in the prior art, a self-cleaning coating is insufficient in mechanical performance, low in photocatalytic efficiency, lack of a self-repairing function and poor in weather resistance are solved, the service life of the coating is remarkably prolonged, and the functional stability of the coating is remarkably improved.

The invention discloses high-toughness ultra-high performance concrete and a preparation method thereof, and relates to the technical field of polymer modified materials thereof. The concrete is composed of a cementitious material composite system, a fiber-reinforced system and a polymer modifier, the cementitious material comprises Portland cement, nano-silica, a rice hull ash-based auxiliary cementitious material and gradient grading quartz powder, and the fiber system adopts steel fiber / basalt fiber / polypropylene fiber multi-scale composite reinforcement. And a polyurethane emulsion interface modifier is matched. During preparation, a dry mixing-fiber dispersion-wet mixing three-stage process is combined with a microfluidization emulsification and segmented polymerization technology, so that uniform dispersion of fibers and matrix-fiber interface reinforcement are realized. The scheme has high strength, high toughness and industrial feasibility, and is suitable for harsh engineering scenes such as bridge joints and explosion-proof structures.

The invention belongs to the field of photovoltaic glass coatings, and particularly relates to a super-hydrophilic anti-reflection wear-resistant self-cleaning coating for room-temperature curing of photovoltaic glass, which takes nano silicon dioxide sol as a main film-forming agent to cure and form a film and comprises the following raw materials in parts by weight: 55-90 parts of deionized water, 9-20 parts of nano silicon dioxide sol, 1-10 parts of a silane coupling agent and 0.001-1 part of nano titanium dioxide. The coating is prepared from the following components in parts by weight: 0.01-1 part of a surfactant, 0.01-1 part of modified polyvinyl alcohol, 0.01-1 part of water-based acrylic resin, 0.001-1 part of an antistatic agent, 1-5 parts of a curing agent, 1-5 parts of a flatting agent and 0.1-1 part of a wear-resistant agent. The super-hydrophilic anti-reflection wear-resistant self-cleaning coating has super hydrophilicity, the water contact angle is below 10 degrees, the hydrophilicity, the antistatic property, the anti-reflection property, the wear resistance and other properties of glass can be remarkably improved, and when the super-hydrophilic anti-reflection wear-resistant self-cleaning coating is applied to photovoltaic module glass, the photoelectric conversion efficiency in photovoltaic power generation can be improved.

The invention provides hydrophobic silica wet gel, hydrophobic silica aerogel, and methods that can be used to form an enhanced hydrophobic silica aerogel sheet having an advantageous combination of properties. Some embodiments of the invention provide a hydrophobic silica aerogel having advantageous properties, such as desirable performance on visible transmission, haze, or both.

The invention belongs to the technical field of composite coatings, and particularly relates to a corrosion-resistant and ultraviolet-resistant protective coating for wind power generation equipment and a preparation method thereof.The corrosion-resistant and ultraviolet-resistant protective coating for the wind power generation equipment is prepared from, by mass, 40-60 parts of gradient fluorosilicone modified polyurethane resin, 5-12 parts of core-shell type ZnO-coated MOFs composite particles, 1-3 parts of a curing agent, 1-3 parts of a curing agent and 1-3 parts of a curing agent. According to the invention, the problems of poor ultraviolet resistance, poor weather resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance and the like in the existing coating and the preparation process thereof are well solved; the shielding layer is single and incapable and has a poor self-repairing effect; and the coating toughness of an epoxy resin system is insufficient and cannot adapt to fatigue deformation of equipment under a vibration working condition.

The invention provides anti-cracking and anti-seepage high-performance concrete, which relates to the technical field of concrete and comprises Portland cement, aggregate, a high-activity mineral admixture, a calcium-magnesium composite expanding agent, nano silicon dioxide particles, a microcapsule-packaged sodium silicate and calcium lactate solution, paraffin / expanded graphite composite phase change microspheres, steel fibers, PVA fibers and nano cellulose. The self-repairing concrete has the characteristics that the anti-cracking performance is comprehensively improved, the anti-seepage grade is broken through, the self-repairing capability is long-acting, the construction adaptability is enhanced, and the like.

The invention discloses a cement-based aerogel heat preservation and heat insulation coating material for concrete and a spraying construction process of the cement-based aerogel heat preservation and heat insulation coating material, and belongs to the technical field of concrete materials. The coating material is prepared from powder, composite emulsion and water, and the powder is prepared by mixing superfine sand, cement, modified silicon dioxide-carbon nanotube composite aerogel powder, hollow glass beads, nanofibers, graphene nanosheets, an ultraviolet light absorber, a water reducing agent and a defoaming agent. The composite emulsion is composed of an acrylate copolymer emulsion, a polyvinyl acetate-ethylene emulsion, a temperature-sensitive polymer emulsion and a coalescing agent. Based on the multi-stage pore network and multi-component emulsion optimization design and multi-component synergistic effect, the material has good fluidity after being mixed, and has low heat conductivity coefficient, high strength and high toughness after being hardened; the construction technology of high-pressure water flushing and layered spraying is provided, and the method has the advantages of being efficient in construction, stable in quality and the like and can be applied to heat preservation and heat insulation of a concrete structure in a severe environment.

The invention relates to the technical field of oilfield exploitation, and discloses a nanometer oil-displacing agent for oilfield oil extraction and a preparation method thereof.The nanometer oil-displacing agent takes modified nanometer silicon dioxide and a surfactant as main components, polymer macromolecules are modified on the surface of the nanometer silicon dioxide to serve as a main body of the nanometer oil-displacing agent, and the nanometer oil-displacing agent is prepared. Under the action of the surfactant, the nano silicon dioxide can flow into the fine throat and the micro throat, and the polymer macromolecules of the branched structure can generate a relatively strong interaction force with the rock, so that the polymer macromolecules are firmly adhered to the surface of the rock, the adhesion of crude oil on the surface of the rock is reduced, a smooth crude oil channel is constructed, and the flowing pressure of liquid is reduced; and crude oil fluidity is improved. The structure of the cross-linking agent contains quaternary ammonium cations, so that the electrostatic repulsion effect between nano silicon dioxide can be greatly enhanced, aggregation between nano silicon dioxide and nano silicon dioxide can be avoided, the interfacial tension can be efficiently maintained, the oil-water interfacial tension is greatly reduced, and the recovery rate of crude oil is effectively increased.

The invention relates to an insulating weather-resistant powder coating and a preparation method thereof, and belongs to the technical field of coatings, and the powder coating comprises composite modified resin, a dual curing agent, a functional filler, a polyacrylate leveling agent, fumed silica, a benzotriazole ultraviolet light absorber, polytetrafluoroethylene wax powder and the like. A core-shell structure of the composite modified resin is designed, high insulativity is kept through a silane modified epoxy core layer, a weather-proof barrier is provided through an acrylic acid shell layer, and the phase separation problem is solved through interface chemical bonding; a dual-curing mechanism is designed, and isocyanate and acrylic hydroxyl react to form an interpenetrating network while an epoxy core layer is cured by anhydride; a filler synergistic effect is designed, silane coupling agent modified nano boron nitride forms a three-dimensional heat-conducting insulating network, and rutile type titanium dioxide is coated with silicon dioxide, so that ultraviolet aging is resisted. All the components cooperate with one another, so that the coating has excellent insulativity, weather resistance, adhesiveness and the like at the same time.

The invention provides hydrophobic silica wet gel, hydrophobic silica aerogel, and methods that can be used to form an enhanced hydrophobic silica aerogel sheet having an advantageous combination of properties. Some embodiments of the invention provide a hydrophobic silica aerogel having advantageous properties, such as desirable performance on visible transmission, haze, or both.

The invention relates to the technical field of building materials, in particular to a Yellow River superfine sand aggregate interface reinforcing agent and a preparation and use method thereof.The interface reinforcing agent is prepared from 0.05-0.1 part of graphene oxide powder, 50-100 parts of a silane coupling agent, 50-100 parts of nano-silicon dioxide, 10-30 parts of oxalic acid and 5000-7000 parts of water; graphene oxide powder, a silane coupling agent and nano silicon dioxide are jointly used for preparing an interface modifier for performing interface modification treatment on the Yellow River superfine sand, so that the interface bonding force between the Yellow River superfine sand and a cement hydration product is enhanced.

The invention relates to the technical field of concrete preparation, in particular to high-performance self-compacting concrete and a preparation method thereof, solves the defects in the prior art, and comprises the following components: cement, fly ash, slag powder, graphene oxide, nano-silica aerogel, a water reducer and an air entraining agent. Through silanization modification and magnetic field induction, the problem of interface incompatibility of GO and SA is solved. Graded mass transfer paths are formed between nano layers of GO and mesopores and macropores of SA. And the CaCO3 seed crystal in the SA hole directionally guides the oriented growth of the C-S-H gel, so that the early strength development rate is increased.

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention discloses a nano blocking agent for drilling fluid and a preparation method thereof, and belongs to the technical field of blocking agents, the nano blocking agent for drilling fluid is prepared by reaction of a core layer blocking agent and a shell layer blocking agent, the core layer blocking agent is prepared by reacting nano silicon dioxide, gamma-methacryloxypropyltrimethoxysilane and a first part of vinylphosphonic acid, and has secondary blocking capability; and the shell blocking agent is prepared by reacting a second part of vinyl phosphonic acid, styrene and 2-dodecene-1-yl succinic anhydride, and has the characteristic of flexibility. The nano plugging agent has rigid supporting and flexible deformation capabilities, and the high-temperature stability and compressive strength of a plugging layer are remarkably improved. The chemical binding force of the plugging agent and the rock is enhanced; the hydrolysable methoxyl reserved in the core layer provides a secondary plugging function, and the plugging validity period is prolonged. The invention relates to a preparation method of a nano blocking agent for drilling fluid, which is used for preparing the nano blocking agent for drilling fluid.

The embodiment of the invention discloses a biological composite liquid material capable of releasing negative oxygen ions as well as a preparation method and application of the biological composite liquid material. The invention discloses a preparation method of a traditional Chinese medicine. The biological composite liquid material is prepared from 12 to 18 parts of plant extract, 1 to 4 parts of silver ion solution, 2 to 5 parts of titanium dioxide, 10 to 15 parts of nano silicon dioxide, 2 to 8 parts of sodium oxide, 1 to 6 parts of magnesium oxide dispersion liquid, 0.5 to 1.5 parts of calcium hydroxide solution, 1 to 3 parts of ferric oxide colloidal solution, 2 to 6 parts of zinc oxide dispersion liquid, 12 to 18 parts of mixed silica sol and 15 to 20 parts of nano borosilicate liquid material. 0.5-1.5 parts of a surfactant, 4-8 parts of glycerol and 10-15 parts of deionized water. The biological composite liquid material has the characteristic of efficiently releasing negative oxygen ions, can effectively improve the air quality, is good in stability, convenient to use, safe and reliable, can be widely applied to the fields of air purification, medical care, building materials and the like, and has a wide market prospect.

The invention relates to the technical field of ceramic materials, in particular to a ceramic composite material and a preparation method thereof.The ceramic composite material is prepared from, by weight, 30-35 parts of silicon carbide, 15-20 parts of boron nitride, 10-15 parts of silicon dioxide, 8-11 parts of additive based on modified filler and 7-10 parts of ball milling agent based on sodium alginate reconditioning modification. According to the ceramic composite material, silicon carbide and boron nitride are matched with silicon dioxide, the additive based on the modified filler and the ball-milling agent based on sodium alginate reconditioning modification are blended and coordinated, and through coordination and synergism of the raw materials, the obtained product can achieve coordinated improvement of strength, wear resistance and thermal conductivity; and the product has remarkable heat-resistant and corrosion-resistant stability effects.

The invention relates to a preparation method and application of an inner-rigid outer-soft core-shell structure silicon dioxide blocking agent for marine drilling fluid, and belongs to the field of deepwater oil and gas drilling. N-vinyl-2-pyrrolidone, dimethyl diallyl ammonium chloride, acrylamide and 2-acrylamide-2-methylpropanesulfonic acid are polymerized and grafted on the surface of nano silicon dioxide to form the silicon dioxide blocking agent with a core-shell structure and a rigid inside and a soft outside; by means of rigid plugging of a nano material and deformation filling flexible plugging of a high-molecular polymer, shale micro-nano pores are efficiently plugged with rigid inside and flexible outside, so that the stability of a well wall is maintained, meanwhile, secondary generation of hydrates is effectively inhibited, and the safety and efficiency of deepwater drilling are improved; the plugging agent provided by the invention reduces the demand on a large number of thermodynamic inhibitors, not only saves the cost, but also has the characteristic of environmental protection.

The invention discloses a high-strength polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-strength polyethylene film. The high-density polyethylene composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of high-density polyethylene, 25 to 35 parts of linear low-density polyethylene, 12 to 18 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of nano silicon dioxide, 3 to 7 parts of organic montmorillonite, 1.5 to 3.5 parts of hindered amine light stabilizer, 1.5 to 2.5 parts of antioxidant 1010, 0.8 to 1.2 parts of calcium stearate, 0.8 to 1.2 parts of zinc stearate, 0.8 to 1.2 parts of silane coupling agent and 4 to 6 parts of maleic anhydride grafted polyethylene. The composite material is prepared from the following components in parts by weight: 1.5-3.5 parts of a quaternized chitosan-nano silver compound, 6-9 parts of a modified toughening agent, 4-7 parts of a modified heat-resistant agent, 1.5-3.5 parts of a processing aid, 0.15-0.35 part of dibenzoyl peroxide and 0.5-1.5 parts of a nucleating agent DBS. The composite material is excellent in comprehensive performance, high in strength, good in flexibility and puncture resistance, excellent in aging resistance, heat resistance, chemical resistance and antibacterial property, good in processability, capable of meeting the requirements of multiple fields such as packaging and agriculture, scientific in preparation method and high in practical value.

The invention discloses a high-weather-resistance TPO waterproof coiled material and a preparation method thereof, and belongs to the technical field of high polymer materials. The waterproof coiled material is prepared from the following raw materials: high-density polyethylene, low-density polyethylene, an ethylene-octylene copolymer, ethylene propylene diene monomer, polypropylene, maleic anhydride grafted polyethylene, polyethylene wax, calcium carbonate powder, an antioxidant 1010, modified lignin, modified fumed silica and a modified nano inorganic composite light stabilizer. The tensile strength of the obtained waterproof coiled material is 20.3-21.3 MPa, the elongation at break is 602-621%, the tear strength is 69-77 N / mm, the low-temperature bending property is no crack at-40 DEG C, and the waterproof coiled material is very excellent in heat aging resistance, light aging resistance and artificial climate accelerated aging resistance.

The invention relates to a preparation method of spherical silicon dioxide micropowder with ultralow dielectric loss. The preparation method comprises the following steps: preparing an organic silicon polymer; preparing slurry; performing solid-liquid separation on the synthetic slurry to obtain concentrated slurry, and drying the concentrated slurry to obtain spherical silica powder; carrying out low-temperature heat treatment on the obtained spherical silica powder at 1500-7000 DEG C for h to remove residual organic matters and free water in the powder; then, high-temperature densification is carried out at the temperature of 3000-28000 DEG C for h, and moisture is further removed; adding a modifier into the stirring equipment for surface modification; and after surface modification, drying at 55-300 DEG C for h, and removing modified micromolecular byproducts to obtain the spherical silicon dioxide micro powder with ultralow dielectric loss. The method is simple in production process, short in production period, low in production cost, high in yield and capable of effectively reducing the dielectric loss of the spherical silicon dioxide micro powder.

The invention relates to a comprehensive utilization method of fluosilicic acid containing hydrogen fluoride, which comprises the following steps: 1) reacting a stock solution containing fluosilicic acid with a potassium fluoride raw material, and carrying out solid-liquid separation to obtain potassium fluosilicate and a hydrofluoric acid solution; 2) reacting potassium fluosilicate with a sodium hydroxide raw material, and carrying out solid-liquid separation to obtain a mixture of a potassium fluoride solution, sodium fluoride and silicon dioxide; and returning the potassium fluoride solution to the step 1) to be recycled as a potassium fluoride raw material. According to the scheme, hydrofluoric acid is prepared from fluosilicic acid containing hydrogen fluoride, sodium fluoride and water glass products are produced at the same time, no other byproduct waste is produced, and the raw material utilization rate is high. And meanwhile, the method has the advantages of low raw material cost, low equipment cost and low energy consumption cost, can generate remarkable economic benefits, and is suitable for popularization and application.

The invention relates to the field of building materials, and discloses a multifunctional foamed ceramic sound insulation and heat preservation material for buildings. Comprising the following raw materials in parts by weight: 42 to 48 parts of pottery clay tailings, 14 to 16 parts of fly ash, 10.5 to 12 parts of crushed stone materials, 2.8 to 3.2 parts of a silicon carbide foaming agent, 0.7 to 0.8 part of a borax fluxing agent, 7 to 8 parts of paraffin / silicon dioxide phase change microcapsules, 0.5 to 1.0 part of graphene, 2.0 to 2.5 parts of nano iron powder, 0.05 to 0.5 part of nano silver, 1.0 to 1.5 parts of photocatalytic titanium dioxide and 0.3 to 0.4 part of a fluorosilane coupling agent. A stable matrix structure is constructed through the argil tailings, the fly ash and the crushed stone materials, the silicon carbide foaming agent and the borax fluxing agent reduce the heat conductivity coefficient, the sound insulation performance is improved, the material is endowed with the antibacterial ability through nano-silver and photocatalytic titanium dioxide, indoor sanitation is guaranteed, and a super-hydrophobic layer is constructed through the fluorosilane coupling agent.

The invention relates to the technical field of biological induction of calcium carbonate deposition, in particular to self-repairing concrete for biological induction of calcium carbonate deposition and a preparation method thereof. The cement comprises the following components in parts by weight: 320-380 parts of Portland cement and the like. The biomineralization composite inducer contains a genetically engineered bacterium solution, a urea-calcium chloride solution and a nano strontium carbonate seed crystal; the nano silicon dioxide-graphene composite powder is prepared by chemical vapor deposition; the wall material of the double-response microcapsule contains a temperature-sensitive polymer, and the core material contains a plurality of components; nanocellulose whiskers are also added; self-repairing is achieved through cooperation of multiple components, and all the components are specially treated or prepared. The self-repairing concrete is high in self-repairing efficiency, and wide cracks can be repaired; the mechanical property is excellent, and the compression strength and the breaking strength are remarkably improved; working performance is good, and construction is convenient; durability is good, and erosion and permeability are resisted; environmental protection and economy are considered, and the application prospect is wide.

The invention relates to the field of oil well opening and killing fluid production, in particular to a solid-free well killing fluid for shale oil reservoir and a preparation method of the solid-free well killing fluid. The solid-free well killing fluid for the shale oil reservoir comprises the following raw materials in parts by mass: 50-70 parts of water, 10-30 parts of a density regulator, 3-6 parts of a copolymer tackifier, 1-3 parts of a dispersant, 3-7 parts of a filtrate reducer and 2-4 parts of a corrosion inhibitor. The copolymer tackifier is obtained by initiating copolymerization by taking acrylamide, a quaternary ammonium salt-containing monomer, an unsaturated silane coupling agent and polyethylene glycol diacrylamide as monomer free radicals, and the dispersing agent comprises gas-phase nano silicon dioxide and a fluorine-containing surfactant. Through reasonable compatibility of all the components in the formula, especially the copolymer tackifier, the effect that one agent has multiple functions is achieved, and meanwhile the high temperature resistance, the corrosion inhibition performance and the clay stability of the well killing fluid are improved.

The invention belongs to the technical field of cement manufacturing, and particularly relates to high-strength weather-resistant environment-friendly cement and a preparation method thereof. The environment-friendly cement is prepared from the following raw materials in parts by mass: 40 to 55 parts of Portland cement, 15 to 25 parts of fly ash, 10 to 15 parts of slag powder, 6 to 12 parts of biomass reinforced composite mineral material, 2 to 4 parts of nano silicon dioxide, 1 to 4 parts of modified polymer emulsion and 1 to 3 parts of additive. The biomass reinforced composite mineral material is prepared from zeolite, bentonite, sepiolite and chitosan; the modified polymer emulsion comprises a modified polyacrylate emulsion and a modified polystyrene-butadiene emulsion in a mass ratio of (1-3): 1; the additive is prepared from basalt fiber, sodium lignin sulfonate, a rosin thermopolymer and sodium gluconate. The environment-friendly cement prepared by the invention not only has high strength and good weather resistance, but also remarkably reduces carbon footprint and saves natural resources.

The invention relates to the technical field of plastic packaging preparation, in particular to an anti-aging plastic packaging material and a preparation method thereof.The anti-aging plastic packaging material is prepared from, by mass, 100-140 parts of polylactic acid, 60-80 parts of PBAT, 2-5 parts of a composite anti-aging agent, 1-2 parts of a lubricant, 2-4 parts of a flame retardant and 3-6 parts of a compatilizer; the composite anti-aging agent comprises a modified anti-aging agent obtained by compounding functionalized montmorillonite and modified silicon dioxide, the functionalized montmorillonite is carnosic acid grafted rare earth ion modified montmorillonite, and the modified silicon dioxide is epoxy methyl oleate grafted silicon dioxide. According to the anti-aging plastic packaging material provided by the invention, a plastic material system with multiple protection mechanisms is constructed through the synergistic effect of all the components, and the prepared plastic packaging material not only keeps good biodegradability, but also has excellent ultraviolet light resistance and oxidation resistance.