114 results about "Hydrogen" patented technology

The invention discloses a method for preparing a single-layer tungsten diselenide nanoband based on a space confinement strategy. By changing the flow and the growth time of hydrogen, effective control on the width and the thickness of a nanoband can be realized. The method comprises the following steps: uniformly spraying tungsten trioxide powder to one substrate, then covering the substrate by the other substrate, and forming micro reaction space which is of a 'sandwich'-like structure. Growth of a tungsten diselenide nanoband is carried out by utilizing a constant-pressure chemical vapor deposition method; physicochemical characteristics of a one-dimensional transition metal chalcogenide strongly depend on suspension key types on the edge of the one-dimensional transition metal chalcogenide, metallic properties are displayed by an ultranarrow band, and conversion from the metallic properties to semiconductor properties can be displayed from the edge to the center of a wider band; the tungsten diselenide nanoband is widely applied to micro-nano photoelectric devices due to the special property; industrial production of the tungsten diselenide nanoband can be realized through an experimental method of the invention.

The invention discloses a rare-earth metal arylamine group compound as well as preparation method and application thereof. The invention discloses the rare-earth metal arylamine group compound which is characterized in that a general formula of the rare-earth metal arylamine group compound is (2,6-R12PhNH)5LnLi2(THF)2, wherein Ln is a rear-earth metal selected from one of neodymium, samarium, ytterbium or yttrium; R1 is selected from one of hydrogen, methyl or isopropyl. The rare-earth metal arylamine group compound has the advantages that the rare-earth metal arylamine group compound has a definite structure; raw materials used in the preparation method are simple, easily obtained and cheap; the reaction process is simple and easily operated; the rare-earth metal arylamine group compound product is conveniently purified and the yield of the product is high; the rare-earth metal arylamine group compound has a high activity when acting as a single component catalyst to catalyze a hydrogen phosphine reaction of aldehyde or ketone and phosphite ester; the use amount of the catalyst is less; the yield is high; a substrate has wide universality; a new and simple method is provided for synthesis of a-hydroxyphosphonate.

Disclosed is a liquid crystal composition. The liquid crystal composition includes liquid crystal molecules including at least one of a liquid crystal compound having an alkenyl group and a liquid crystal compound having an alkoxy group, and a first stabilizer including a compound having a structure represented by Formula 1:where n is 0 or 1; m is 0 or 1; k is 0 or 1; Z1, Z2, and Z3 are each independently a single bond, —C═C—, —OCO—, —COO—, —CF2O—, or a C1 to C5 alkylene group; X1, X2, X3, and X4 are each independently hydrogen or halogen; Y is hydrogen, an alkylene group, an alkoxy group, a hydroxyl group, —NHCOCH3, or ═O; and A and B are cyclic compounds.

Systems and methods for measuring the content of an element in a soil comprises: a neutron source for irradiating the soil with neutrons; a detector assembly configured to detect an INS gamma spectrum of the soil; an instrument for measuring a moisture content of the soil; and a processor in communication with the detector assembly, the processor configured to: apply a moisture calibration coefficient to calculate a net peak area of a characteristic peak of the element in the INS gamma spectrum, the moisture calibration coefficient calculated to account for the moderation of fast neutrons by hydrogen atoms of water present in the irradiated soil at the location under analysis; and generate a concentration of the element in the soil. The instrument for measuring a moisture content of the soil may comprise the detector assembly. Systems and methods incorporating a temperature-controlled housing for the gamma detector assembly are also provided.

The mineralogical, chemical, magnetic, and physical properties of a rock can be used to determine the amount of hydrogen that was generated during rock alteration and the remaining amount of hydrogen generation potential. The methodologies evaluate the hydrogen generation potential of geological samples and identify natural hydrogen source rocks. The mineralogy, elemental composition, iron content and oxidation state, and other properties of a geological sample may be determined. From the determined mineralogy and other properties of the geological sample, the amount of hydrogen which the geological sample may have generated may be quantified. This method can determine the maturity of hydrogen source rocks, the potential volume of hydrogen that can be generated in other parts of a given geologic province with higher degrees of hydrogen source rock maturity, and quantify the potential remaining volume of hydrogen that can be still be generated via secondary enhanced hydrogen stimulation processes.

Techniques are described for producing actinium-225 by arranging a converter material at least partially around a target material, where the target material includes radium-226. The converter material comprises a compound of lithium and hydrogen at least partially enriched with lithium-6 and deuterium, and is configured to convert thermal neutrons to fast neutrons, which are then incident on the radium-226. If the fast neutrons have a kinetic energy of at least 6.4 MeV, they will initiate a (n,2n) reaction that converts radium-226 into radium-225, which then decays into actinium-225. The process can desirably be performed within an environment rich in thermal neutrons, such as within a fission reactor.

A method of producing hydrogen from ammonia includes exposing ammonia to a rare-earth / NiO / Al2O3 nanocomposite material. The rare-earth / NiO / Al2O3 nanocomposite material catalyzes the decomposition of ammonia into hydrogen. The rare-earth / NiO / Al2O3nanocomposite material is in the form of rare-earth doped NiO nanoparticles distributed on a Al2O3 matrix. The rare-earth doped NiO nanoparticles include a rare-earth dopant selected from the group consisting of La, Ce, Nd, Sm and combinations thereof, at a concentration of 1 to 20 wt. % based on the total weight of the rare-earth / NiO / Al2O3 nanocomposite material. The rare-earth doped NiO nanoparticles are spherical with an average diameter in a range from 1 to 200 nm. The rare-earth / NiO / Al2O3 nanocomposite material achieves a 90% or greater conversion of ammonia to hydrogen, based on the total amount of ammonia, at a temperature less than or equal to 550° C., when used to catalyze the decomposition of ammonia.

The invention discloses a rare bismuth II type superlattice material and a preparation method thereof. The superlattice material has an InAs (Bi) / GaSb or InAs (Bi) / InAsSb superlattice structure formed by alternately laminating InAs (Bi) layers and GaSb layers or InAsSb layers, and the InAs (Bi) layers are formed by introducing Bi elements into the InAs layers. The preparation method of the superlattice material comprises the following steps: (1) selecting an InSb, InAs or GaSb substrate, performing thermal cleaning on the substrate at 500 DEG C, and cleaning the substrate by using atomic hydrogen in an ultrahigh vacuum environment; (2) alternately laminating InAs (Bi) layers and GaSb layers or InAsSb layers by utilizing a molecular beam epitaxial growth technology, and finally growing a GaSb layer or InAsSb layer as a stop layer, (3) carrying out rapid thermal annealing treatment at the temperature of 380-420 DEG C; the time is 0.5 to 1 min; and (4) characterizing the photoluminescence property of the superlattice. According to the invention, the strain distribution and the energy band structure of the material are obviously improved, the more flexible wavelength regulation and control capability is realized, the hole effective quality is reduced, and the carrier mobility and the quantum efficiency are improved.

The present invention discloses a quantitative calculation method for the hydrogen and oxygen isotopes in surface water during the evaporation fractionation process in the field of isotope tracing technology, aiming to solve the problems of low calculation accuracy and large uncertainty in the existing calculation methods. It includes: analyzing the kinetic effect of the evaporation fractionation process; constructing the probability mass function of the isotope body and decomposing the ratio of the heavy / light isotope body; quantitatively describing the dissipation rate of the heavy / light isotope body in the evaporation fractionation; combining the water evaporation rate to obtain the change efficiency of the heavy / light isotope body during the evaporation fractionation process; and calculating the isotope body content in the remaining surface water. The present invention enhances the application adaptability of the calculation method to various conventional and extreme situations, reveals the isotope fractionation change law in surface water during the evaporation process, and improves the reliability of the results.

The application discloses a method and device for obtaining local gas temperature and equivalence ratio of a combustion field. Laser-induced breakdown spectroscopy technology is used to form a target plasma by laser-induced breakdown of a flame to be measured. Firstly, reference signals of the target plasma are collected to obtain a reference signal set, and current hydrogen atomic spectral line broadening and current plasma temperature of the target plasma are calculated. Then, the reference signals are input into a gas temperature characterization model to obtain a local gas temperature. The reference signals and spectral line intensities are input into a spectral line intensity correction model to obtain a corrected spectral line intensity set. Finally, the corrected spectral line intensity set, the current plasma temperature and the current hydrogen atomic spectral line broadening are input into an equivalence ratio measurement model to obtain the equivalence ratio of the flame to be measured. Through step-by-step correction of spectral intensity, the application can avoid the influence of temperature on equivalence ratio measurement, improve the accuracy of equivalence ratio measurement, and realize local gas temperature measurement.

The invention discloses a mercury method detection device for deposited metal diffusible hydrogen, relates to the technical field of diffusible hydrogen detection, and aims to solve the problem that the detection efficiency, the operation convenience and the safety are difficult to guarantee by adopting a mercury method in the prior art. The device comprises a detection mechanism, a sample collecting and placing mechanism, a vacuum mechanism, a mercury storage mechanism, a control end and a sealed ventilation cabinet, the detection mechanism is used for collecting and detecting diffusible hydrogen; the sample receiving and placing mechanism is used for realizing automatic operation of sample taking and placing, lifting and positioning; the vacuum mechanism is used for providing a vacuum environment for diffusible hydrogen collection; and the mercury storage mechanism is used for storing, conveying and recycling mercury. The method has the advantages that the detection efficiency, the operation convenience and the safety are improved.

A system including a material is described. The material includes at least one rare earth (R), hydrogen (H), and at least one dopant (D). The material includes R, H, and D with R:H:D in a ratio of 1:x:y, where x is greater than 2 and less than 3, and y is at least 0.4 and less than 1.

A method of deploying a pulsed neutron logging tool. The method may comprise detecting natural gamma rays from the subterranean formation via one or more detectors of the pulsed neutron logging tool, broadcasting neutrons into the subterranean formation, and detecting neutron-induced gamma rays and natural gamma rays from the subterranean formation. The method may further comprise creating an inelastic spectrum, a capture spectrum, or a capture time decay from the natural gamma rays or the neutron-induced gamma rays, forming an inelastic yields, a capture elemental yields, or a formation sigma form the inelastic spectrum, the capture spectrum, or the capture time decay, creating a closure model from the inelastic yields and / or capture elemental yields and / or a formation sigma, and identifying a porosity, a mineral weight fraction, or a quality figure of merit from the closure model that quantifies geologic hydrogen reservoir quality.

The invention relates to a device (2) for detecting hydrogen, in particular small amounts of hydrogen, in a liquid circuit (3) and for removing the hydrogen, in particular the small amounts of hydrogen, from the liquid circuit (3). According to the invention, the device (2) is characterized by - a platinum plate (4) which is arranged or can be arranged in the liquid circuit (3), and - a temperature sensor (6) designed and configured to measure the temperature of the platinum plate (4).

The utility model discloses a storage tank for deuterium isotope abundance detection, which comprises a tank body and a cover body, and two horizontal sides of the cover body are fixedly connected with support frames. The method comprises the following steps: putting a magnesium rod into a tank body from a magnesium rod putting opening, sealing, vacuumizing, injecting a water sample into a reaction container, heating the tank body, enabling the magnesium rod to react with the water sample to generate deuterium-labeled hydrogen, and sucking the deuterium-labeled hydrogen in the tank body after the reaction container is cooled to room temperature. The cover body and the tank body are both fixed with the support frame while normal detection of the deuterium isotope abundance is ensured, and the base at the bottom of the support frame is matched with the upper suction cup, so that stable connection between the storage tank and a working table can be ensured, deviation of the storage tank is avoided, and the storage tank is convenient to use. Therefore, the use stability of the storage tank for deuterium gas isotope abundance detection is improved.

The application discloses a rapid detection method of paraffin in beeswax. The detection method comprises the following steps: dissolving the to-be-detected beeswax sample by using a deuterium solvent to perform nuclear magnetic resonance hydrogen spectrum test, and qualitatively and quantitatively analyzing the paraffin in the beeswax according to the nuclear magnetic resonance hydrogen spectrum result. Two conditions need to be met simultaneously when using the nuclear magnetic hydrogen spectrum to judge whether the paraffin is doped in the beeswax: (1) an ester characteristic proton peak appears near the chemical shift of 4.07 ppm; and (2) the relative integral intensity of the alkyl proton peak in the chemical shift range of 0.9-1.58 ppm is obviously enhanced compared with a standard spectrum. The detection method is simple and rapid, has good linear relationship, high accuracy and good repeatability.

The invention relates to an atomic gas chamber and a preparation method thereof. The preparation method of the atomic gas chamber comprises the following steps: providing an atomic gas chamber glass bulb; rubidium steam is filled in the atomic gas chamber glass bulb; the atomic gas chamber glass bulb is filled with mixed gas; wherein the mixed gas comprises xenon 129, xenon 131, hydrogen and a buffer gas; the voltage division ratio of the xenon 129 to the xenon 131 is (1: 4)-(1: 9); carrying out heat preservation treatment on the atomic gas chamber glass bulb, and reacting rubidium steam with hydrogen to generate a rubidium hydride film layer; and the rubidium hydride film layer covers the inner wall of the atomic gas chamber glass bulb. According to the preparation method of the atomic gas chamber, provided by the invention, the atomic spin relaxation time of xenon 129 and xenon 131 can be prolonged, the relaxation performance of two isotopes can be balanced, the performance of the atomic gas chamber is further improved, and the requirements of application scenes such as a quantum inertia instrument on the atomic spin stability of the atomic gas chamber are met.

The application discloses a kind of based on pulse neutron technology's borehole in-situ lithium ore content measurement method and device, device includes pulse neutron generator, neutron detector, gamma detector and electronic processing equipment, measurement method includes: obtaining the time spectrum information of borehole in-situ place detection neutron, according to time spectrum information, neutron lifetime is calculated;According to the formation of different lithium ore grade under the macroscopic cross section of neutron lifetime calculation;According to the relationship equation of formation macroscopic cross section and lithium content, based on the calculation of formation macroscopic cross section, obtains scale lithium content;The calibration curve of lithium content is scaled based on the distribution of formation macroscopic cross section and scaled calculation, and the actual lithium ore grade distribution of formation is obtained.According to the change of time spectrum attenuation under different borehole size, wellbore correction equation is established, and the influence of wellbore is corrected.According to gamma energy spectrum, the content of hydrogen in water-containing wellbore is monitored, and the influence of water-containing wellbore is corrected according to hydrogen characteristic peak count.

This invention discloses a system and method for monitoring the hydrogen damage state of metals, comprising: a hydrogen charging device for electrochemically charging a plate-shaped sample of the same metal as the target metal that has not undergone hydrogen damage; a hydrogen permeation measuring device for converting hydrogen atoms permeating into the sample into hydrogen ions during the hydrogen charging process and measuring the current generated by the free electrons produced during the conversion process in real time to obtain a hydrogen permeation curve; and an ultrasonic measuring device for emitting ultrasonic guided waves to the sample during the hydrogen charging process and receiving the nonlinear response signal generated by the guided waves exciting ultrasonic waves inside the sample, and then performing cepstral analysis on the received signal to obtain the nonlinear coefficients at different time periods. Based on this, combined with the hydrogen permeation curve, the correlation between the nonlinear response signal and the degree of hydrogen damage is determined, and then the nonlinear response signal of the target metal is substituted into the correlation to obtain the hydrogen damage state inside the metal. This invention can monitor and evaluate the degree of hydrogen damage inside metals in real time.

This application discloses a control method, device, and storage medium for an online material moisture monitoring system, relating to the field of material moisture monitoring technology. The method includes: starting a neutron generator assembly; when the start-up time of the neutron generator assembly is greater than or equal to a preset preheating time, activating a neutron detector assembly and a gamma detector; determining the cumulative scattered neutron share of the measured material based on the detection results of the neutron detector assembly, and obtaining the cumulative scattered neutron share to match the corresponding target hydrogen density from a preset correlation library; generating a gamma spectrum based on the gamma rays monitored by the gamma detector according to pulse amplitude classification and counting, and extracting the water hydrogen characteristic peak area from the gamma spectrum; determining the solidified hydrogen ratio based on the target hydrogen density, the water hydrogen characteristic peak area, and the energy spectrum calibration coefficient of the gamma spectrum; and determining the free water content of the measured material based on the solidified hydrogen ratio. This application solves the problem of low accuracy in moisture monitoring through dual-modal collaborative detection.

The mineralogical, chemical, magnetic, and physical properties of a rock can be used to determine the amount of hydrogen that was generated during rock alteration and the remaining amount of hydrogen generation potential. The methodologies evaluate the hydrogen generation potential of geological samples and identify natural hydrogen source rocks. The mineralogy, elemental composition, iron content and oxidation state, and other properties of a geological sample may be determined. From the determined mineralogy and other properties of the geological sample, the amount of hydrogen which the geological sample may have generated may be quantified. This method can determine the maturity of hydrogen source rocks, the potential volume of hydrogen that can be generated in other parts of a given geologic province with higher degrees of hydrogen source rock maturity, and quantify the potential remaining volume of hydrogen that can be still be generated via secondary enhanced hydrogen stimulation processes.

The invention discloses a tungsten oxide hydrogen-sensitive reaction in-situ characterization method and system, and the method specifically comprises the steps: placing an intrinsic sample or an isotope sample into a quartz test cavity, heating the intrinsic sample or the isotope sample, introducing mixed gas, testing a reflection spectrum through a spectrometer, and testing resistance through a resistance meter; putting the intrinsic sample into a quartz test cavity, heating, introducing mixed gas or reaction gas under vacuum, vacuumizing after reaction, heating, and introducing tail gas into a mass spectrum for component analysis; putting the isotope sample into a quartz test cavity, heating, introducing reaction gas under vacuum, and introducing tail gas into a mass spectrum for component analysis; and completing tungsten oxide hydrogen-sensitive reaction in-situ characterization according to test results of the spectrograph, the mass spectrometer and the resistance tester. Based on a vacuum partial pressure gas distribution technology, a quadrupole mass spectrometer is taken as a core, an in-situ detection system capable of simultaneously monitoring various parameters during response of the gasochromic material and hydrogen is designed and built, and the in-situ detection system can be used for research on a response mechanism of the gasochromic material, such as WO3, to hydrogen.

To provide a metal evaporation method in which rare metal can be easily recovered.SOLUTION: A metal evaporation method evaporates at least a part of metal composition by heating, in a non-contact manner in the same container, a metal composition containing rare metal elements and a perovskite-type complex oxide expressed by Formula (1): ABHaO3-b (1) (where A denotes one or more kinds of elements selected from a group consisting of lanthanoid element and elements of group 2 in the periodic table, B denotes one or more kinds of elements selected from a group consisting of elements of group 3 in the periodic table, elements of group 4 in the periodic table and transition metal element of a fourth period of the element periodic table, symbols a and b are amounts of hydrogen and oxygen vacancy, respectively, and represent numerical values in the following range: 0≤a≤1.0, 0≤b≤0.5).SELECTED DRAWING: None

A logging tool is used to measure formation porosity. The tool has a pulsed neutron generator and multiple dual-function detectors that can detect neutrons and gamma rays. The ratios of thermal neutrons, epithermal neutrons, and captured gamma rays from multiple detectors are used to obtain multiple neutron porosities and multiple gamma-ray porosities at different exploration depths. The neutron porosity and gamma-ray porosity can be further corrected by excluding peak regions attributed to hydrogen and / or chlorine to reduce shale effects and / or chlorine effects. The neutron porosity and gamma-ray porosity can be combined to provide a better porosity assessment at different exploration depths in the formation over the entire porosity measurement range (0-100 p.u.).

The invention relates to an under-expansion jet fire radiation fraction evaluation processing method and application. The radiation fraction evaluation processing method comprises the steps that the proportion of all gas components, the absolute pressure of mixed gas and the temperature of the mixed gas are obtained; determining the molar mass, the gas adiabatic index and the air-fuel ratio of the mixed gas; determining the constant-pressure adiabatic combustion temperature of the mixed gas; the gas speed at the leakage opening is determined; determining the gas density at the leakage port; determining the flame Froude number of the under-expansion jet flame; the radiation fraction of the under-expansion jet flame is determined according to the flame Froude number of the under-expansion jet flame, and the radiation fraction of the under-expansion jet flame is determined according to the following calculation formula: xR = 0.28 Frf-0.66, in the formula, xR is the radiation fraction, and Frf is the flame Froude number. The radiation fractions of the mixed gas under-expansion jet fire determined by the method are good in consistency, and the method can be suitable for evaluating under-expansion jet fire flames of gas pipelines and storage equipment doped with hydrogen and methane in different doping proportions.

The application discloses a refinery gas composition determination method and related device, and relates to the field of gas analysis. The absolute correction factor of nitrogen and the relative correction factor corresponding to each stable gas are determined, and the absolute correction factor of the stable gas with relatively stable content in air is determined. Similarly, the absolute correction factor of each alkane is determined according to the absolute correction factor of methane and the relative correction factor of each alkane relative to methane, and the absolute correction factor of hydrogen is determined according to the content of hydrogen in the production sample containing hydrogen and the chromatographic peak area of hydrogen, wherein the chromatographic peak area of hydrogen is obtained by processing the production sample by a thermal conductivity detector. The determination of the absolute correction factor of each gas component is realized, and on the basis, the concentration of each component in the sample can be determined by combining the detection of the chromatographic peak area of each component of the refinery gas sample, thereby providing a reliable reference for subsequent resource utilization.

The invention discloses a natural hydrogen formation cause identification method based on cluster isotope, which comprises the following steps: obtaining a purified hydrogen sample to be detected through separation and purification treatment; performing cluster isotope measurement on the purified hydrogen sample to obtain a cluster isotope value representing the abundance deviation random distribution degree of the dideuterium molecules; when it is judged that the cluster isotope value is in the original thermodynamic equilibrium state, the formation temperature of the purified hydrogen sample is inverted according to the theoretical function relation between the cluster isotope value and the thermodynamic equilibrium temperature; and comparing the formation temperature with a pre-established formation temperature range of different cause types of natural hydrogen, and determining the cause type of the purified hydrogen sample. According to the method, the cluster isotope delta DD is introduced as an anti-interference core index, and multi-source information verification and temperature quantitative inversion are combined, so that a fundamental breakthrough of the natural hydrogen cause from qualitative speculation to accurate quantitative judgment is realized.

The invention discloses a method for identifying the producing area of saffron crocus by extracting saffron crocus aldehyde and measuring the stable isotope ratio of the saffron crocus aldehyde. The invention discloses a method for extracting crocetin from saffron crocus and measuring the stable isotope ratio of carbon to hydrogen to oxygen. The method comprises the following steps: S1, determining the stable isotope ratio of carbon to hydrogen to oxygen of a crocetin standard substance by using an elemental analysis-stable isotope mass spectrometer; s2, extracting crocus sativus aldehyde from the crocus sativus sample to obtain a crocus sativus aldehyde extracting solution; s3, determining the carbon, hydrogen and oxygen stable isotope ratio of crocetin in the crocetin extracting solution by using a gas chromatography-stable isotope mass spectrometer; and S4, calibrating the carbon, hydrogen and oxygen stable isotope ratio of crocetin in the crocetin extracting solution by adopting the carbon, hydrogen and oxygen stable isotope ratio of the crocetin standard substance. The standard substance is used for calibrating the stable isotope ratio of carbon, hydrogen and oxygen of the single compound crocetin, and the method can be used for identifying the producing area of crocetin.

The mineralogical, chemical, magnetic, and physical properties of a rock can be used to determine the amount of hydrogen that was generated during rock alteration and the remaining amount of hydrogen generation potential. The methodologies evaluate the hydrogen generation potential of geological samples and identify natural hydrogen source rocks. The mineralogy, elemental composition, iron content and oxidation state, and other properties of a geological sample may be determined. From the determined mineralogy and other properties of the geological sample, the amount of hydrogen which the geological sample may have generated may be quantified. This method can determine the maturity of hydrogen source rocks, the potential volume of hydrogen that can be generated in other parts of a given geologic province with higher degrees of hydrogen source rock maturity, and quantify the potential remaining volume of hydrogen that can be still be generated via secondary enhanced hydrogen stimulation processes.