689 results about "Hafnium" patented technology

The invention belongs to the technical field of adsorbent preparation, and relates to a preparation method of a series of M-TCBB metal organic framework materials and application of the M-TCBB metal organic framework materials to adsorption of sulfur dioxide and ammonia gas. The preparation method comprises the following steps: dispersing [9, 9 '-dicarbazole]-3, 3', 6, 6 '-tetracarboxylic acid (H4TCBB) serving as an organic ligand and any one or more of yttrium salt, zirconium salt, hafnium salt, cerium salt and thorium salt in a solution according to a certain mass ratio, and carrying out solvothermal reaction at 100-120 DEG C; and after the reaction is finished, centrifuging to take a precipitate, washing and drying to obtain a series of M-TCBB metal organic framework materials. The series of M-TCBB metal organic framework materials prepared by the invention have relatively good adsorption acting force on sulfur dioxide and ammonia gas, and are high in adsorption cycle stability; under a humid condition, capture of sulfur dioxide and ammonia gas shows a humidity enhancement characteristic, namely, water vapor promotes enhancement of the adsorption capacity of sulfur dioxide and ammonia gas.

The invention provides a surface-modified sulfide electrolyte and a preparation method thereof, and an all-solid-state battery, the surface-modified sulfide electrolyte comprises a sulfide electrolyte and a modification layer coated on the surface of the sulfide electrolyte, the chemical general formula of the modification layer is LiaMbNcXd, 0 < = a < = 3, 0 < = b < = 1, 0 < = c < = 1, 0 < = d < = 6, and 0 < = c < = 1. M is at least one element of magnesium, aluminum, calcium, iron, zirconium, niobium, tantalum, tungsten, gadolinium, yttrium, indium, hafnium, lanthanum and ytterbium, and X is at least one element of oxygen, sulfur, fluorine, chlorine, bromine and iodine. According to the surface-modified sulfide electrolyte, the modification layer with high ionic conductivity and high oxidation potential is coated outside the sulfide electrolyte, so that when the surface-modified sulfide electrolyte is applied to a positive electrode of an all-solid-state battery, the modification layer can improve the oxidation potential of the electrolyte on the premise of not reducing the ionic conductivity of the electrolyte; the effects of improving the interface stability between the positive electrode active material and the sulfide electrolyte and further improving the cycle performance of the battery are achieved.

The present application provides an entropy-regulated composite dielectric film, which comprises a polymer matrix; and fillers dispersed in the polymer matrix, wherein the fillers comprise Bi 4‑a M 1a Ti (3‑3b) M 2b O 12 , wherein M1 comprises at least one of lanthanum, neodymium, samarium and praseodymium, M2 comprises at least one of zirconium, hafnium and tin, 0 The entropy-regulated composite dielectric film has high temperature resistance, high breakdown strength, high polarization strength, high energy storage density and good stability.

The invention discloses a nickel-based alloy composite plate and a preparation method thereof, and belongs to the technical field of nickel-based alloys, the nickel-based alloy composite plate comprises a stainless steel bottom plate and a nickel-based alloy plate, and the nickel-based alloy plate comprises, by weight, 52-58 parts of nickel powder, 17-21 parts of molybdenum powder, 8-12 parts of copper powder, 7-9 parts of boron powder, 2-3 parts of modified hafnium carbide powder, 4-7 parts of an alloy reinforcing agent and 2-3 parts of a fluxing agent. The modified hafnium carbide prepared from hafnium oxide and nano carbon powder successfully replaces metal hafnium with high cost in the traditional process; and meanwhile, the actual adding proportion of the modified hafnium carbide in the nickel-based alloy plate is greatly reduced, the cost of industrial mass production is doubly reduced from the two aspects of raw material selection and dosage control, and the economic requirement of large-scale production is better met.

The invention provides a device and a method for removing MIBK (methyl isobutyl ketone) in raffinate for extracting and separating zirconium and hafnium, the device comprises a tank body, a liquid distribution ring is fixedly connected in the tank body, one side of the liquid distribution ring penetrates through the tank body and is outwards communicated with a feeding pipe, a plurality of spray heads are arranged below the liquid distribution ring in a penetrating manner, the outer end of the tank body is fixedly connected with a bracket, and the bracket is fixedly connected with a rotating shaft. According to the device, raffinate can be quickly conveyed into the tank body by arranging a liquid distribution ring and a spray head, rotation of a rotating shaft and a rotating plate can be completed in cooperation with a gear assembly, the fallen raffinate is scattered, it is ensured that the raffinate can uniformly fall on a steam heating pipe, and the raffinate is uniformly heated; meanwhile, the contact area of the gas phase and the liquid phase can be increased in cooperation with the condensation assembly, the phase splitting barrel and the grid plate, the MIBK separation efficiency is improved, and the purpose of rapidly removing oil is achieved through the principle that the volatility is affected by factors such as liquid diffusion and temperature.

A component for use in a semiconductor processing chamber is provided. A metal or metal alloy component body has a process-facing surface. An intermediate aluminum oxide coating is disposed on the process-facing surface, the intermediate aluminum oxide coating being at least 99% pure by weight and having a porosity of less than 0.1% by volume, the intermediate aluminum oxide coating having a first thickness. A process-exposed layer is disposed on the intermediate aluminum oxide coating, the process-exposed layer comprising at least one of yttrium, hafnium, zirconium, lanthanum, magnesium, and a lanthanide, the process-exposed layer being at least 99% pure by weight, having a porosity of less than 0.1%, and having a second thickness, the second thickness being less than or equal to the first thickness.

The invention relates to the field of coatings, and discloses a wear-resistant and corrosion-resistant high-entropy alloy composite coating and a preparation method thereof.The wear-resistant and corrosion-resistant high-entropy alloy composite coating is prepared by depositing functional high-entropy alloy composite powder on the surface of a base body in a laser cladding mode, the functional high-entropy alloy composite powder comprises high-entropy alloy powder, a modified additive and composite ceramic powder, the modified additive is prepared by using urea and titanium tetrachloride as raw materials, growing nano titanium nitride particles on the surface of a silicon carbide nanowire in situ to prepare a nano titanium nitride / silicon carbide nanowire composite material, and then coating a layer of nano titanium dioxide particles on the surface of the nano titanium nitride / silicon carbide nanowire composite material by using tetrabutyl titanate; and the composite ceramic powder is prepared by compounding zirconium carbide, niobium carbide, hafnium carbide and tantalum disilicide. The hardness, wear resistance and corrosion resistance of the high-entropy alloy coating are enhanced by adding the modified additive and the composite ceramic powder.

The invention belongs to the technical field of processing of nuclear reactor control rod neutron absorber materials, and particularly relates to a preparation method of a nuclear-grade hafnium cast ingot. The method comprises the following steps: preparing sponge hafnium into an electrode block; performing vacuum electron beam melting on the electrode block for at least two times to obtain a finished cast ingot; and processing the finished cast ingot to prepare the nuclear-grade hafnium cast ingot which can be used for processing the control rod profile for the nuclear reactor assembly. According to the preparation method of the nuclear-grade hafnium cast ingot, the tensile strength, the welding performance and the creep performance of a nuclear-grade hafnium profile can be effectively improved; meanwhile, the technological process is simplified, and the technological economy and the production efficiency are remarkably improved; in addition, sponge hafnium is directly adopted for vacuum electron beam melting, so that the cost of raw materials is greatly reduced. According to the method, the application performance of the nuclear-grade hafnium profile is improved, meanwhile, the process is simplified, the production efficiency is improved, the production cost is reduced, and the economical efficiency of nuclear-grade hafnium profile manufacturing is greatly improved.

A preparation method of porous hafnium carbide superhigh-temperature ceramic is characterized by comprising the following steps: dispersing graphene oxide in a solvent to form a graphene oxide dispersion liquid, mixing a monomer hafnium source solution with the graphene oxide dispersion liquid, and carrying out hydrothermal treatment on a hafnium oxide carbon precursor network structure to obtain the porous hafnium carbide superhigh-temperature ceramic. The organic-inorganic hybrid precursor is subjected to two-stage heat treatment, the first stage is inorganic treatment, the second stage is carbon thermal reduction reaction, and the porous hafnium carbide ultrahigh-temperature ceramic material is obtained. Graphene oxide is used as a structure-directing agent and an in-situ carbon source, a monomer hafnium source is uniformly anchored on the surface of a GO sheet layer on the molecular scale, an organic-inorganic hybrid precursor is formed, after the precursor is subjected to hydrothermal crosslinking, Hf species and a carbon skeleton are highly mixed on the nanoscale, and the Hf / GO composite material is obtained. And the subsequent carbon thermal reduction reaction can be efficiently completed in a low-temperature interval of 1300-1450 DEG C.

This invention discloses a method for preparing high-purity zirconium oxide, belonging to the field of compound preparation technology. The method provides a breakthrough adjustment of the final concentration state and the cooling process after concentration and evaporation of an acidic zirconium oxychloride solution under the action of an oxidant. Simultaneously, crystallization is achieved through a two-stage concentration and evaporation process, followed by calcination to obtain hafnium-free zirconium oxide. The resulting zirconium oxide not only has a high yield but also high purity. Furthermore, the technical solution of this invention avoids the generation of ammonia nitrogen wastewater as in existing technologies, thus not only avoiding environmental impact but also significantly reducing production costs through the recycling of hydrochloric acid condensation, achieving a green and environmentally friendly effect.

The invention relates to the technical field of hydrometallurgy production systems, in particular to a solvent regeneration control system for separating zirconium and hafnium through MIBK method centrifugal extraction, which comprises a control module used on a solvent regeneration neutralization reactor, and the control module comprises a heat exchange module; the heat exchange module comprises a heat exchange unit; the heat exchange unit comprises a cooling liquid flow adjusting unit, a cooling liquid temperature detecting unit and a cooling liquid pressure detecting unit. And the heat exchange module is used for controlling the flow of the cooling liquid, the pressure of the cooling liquid and the temperature of the cooling liquid of the heat exchange unit so as to adjust the temperature of the mixed phase in the neutralization reactor. The control system can monitor the flow, temperature and pressure of cooling liquid in real time, accurately control opening, closing and temperature adjustment of the heat exchange unit, quickly respond to temperature change of a mixed phase in the neutralization reactor, remove reaction heat in time, effectively avoid the problem of extraction system emulsification caused by high-temperature decomposition and polymerization of thiocyanic acid in the solvent regeneration process, and improve the extraction efficiency. The solvent regeneration efficiency and quality are ensured.

The invention discloses a process for removing uranium and thorium from hydrochloric acid system zirconium and hafnium waste acid. The process comprises the following steps: S1, adding a substance containing nitrate radicals into the zirconium-hafnium waste acid of a hydrochloric acid system to obtain zirconium-hafnium waste acid of a nitrate acid mixed acid system; s2, extracting the zirconium and hafnium waste acid of the mixed acid system obtained in the step S1 by adopting a TBP extracting agent to obtain an organic phase 1 containing uranium, thorium, zirconium and RE and a water phase 1 mainly containing RE; s3, the organic phase 1 obtained in the step S2 is subjected to reverse extraction through a nitric acid solution, and an organic phase 2 containing uranium and thorium and a water phase 2 mainly containing zirconium and RE are obtained; and S4, the organic phase 2 obtained in the step S3 is subjected to reverse extraction through sulfuric acid, and a blank organic phase 3 and a water phase 3 containing uranium and thorium are obtained. The process provided by the invention can realize removal of radioactive uranium and thorium in the hydrochloric acid system zirconium-hafnium waste acid. The process is high in uranium and thorium removal rate, low in zirconium and rare earth loss rate and beneficial to further comprehensive utilization of valuable elements in the waste acid.

The disclosed and claimed subject matter relates to (1) a process for performing thermal atomic layer etching (ALE) of films that include ZrO2, HfO2, (Hf—Zr)O2 alloy or similar materials which does not require the use of plasmas or corrosive halogenating chemistries and (2) a metal-insulator-metal capacitor (MIMcap) with unique properties enabled by a unique dielectric processing method.

The invention relates to the technical field of hafnium oxide preparation, in particular to a method for preparing hafnium oxide with ultralow iron content, which comprises the following steps: based on N235 extraction separation in a hydrochloric acid system, crushing hafnium oxide raw stone, performing coarse grinding to obtain hafnium oxide powder, then sequentially performing alkali fusion decomposition treatment and acid leaching impurity removal treatment to obtain a zirconium-hafnium mixed solution, and then performing vacuum drying on the zirconium-hafnium mixed solution to obtain the hafnium oxide with ultralow iron content. The preparation method comprises the following steps: taking hafnium as a raw material, carrying out extraction and back extraction to obtain a hafnium-enriched solution, treating the hafnium-enriched solution with ion exchange resin to obtain a high-purity hafnium solution, finally adding saturated ammonia water, filtering and washing the obtained precipitate, drying, and firing to obtain the hafnium oxide with ultralow iron content. According to the invention, while zirconium and hafnium separation is realized, a small amount of contained metal cations, especially iron ions, are fully removed, and the iron content is reduced, so that hafnium oxide with ultralow iron content is obtained.

The invention discloses a method for preparing hafnium oxide from hafnium oxalate feed liquid through an oxidation precipitation method, and belongs to the technical field of hydrometallurgy. The specific method comprises the following steps: adding an oxidizing agent into hafnium oxalate feed liquid to destroy oxalate ions in hafnium oxalate so as to enable hafnium to form hydroxide precipitates; and separating the generated white precipitate, and roasting at high temperature to obtain hafnium oxide. The strong oxidant used in the method is low in cost, high in precipitation efficiency, green, environmentally friendly, free of large pollution to equipment and the environment and wide in application range. The method is simple in process, does not involve a complex process flow, does not need precise equipment, avoids a large amount of alkali liquor required by metal ion precipitation, is simpler in process flow, higher in efficiency and lower in cost, avoids the generation of a large amount of wastewater, and is very environment-friendly. And meanwhile, the process is wide in application range and suitable for various oxalic acid metal feed liquid.

A nickel-based alloy composition consisting, in weight percent, of: 1.5 to 4.5% aluminium, 1.1 to 3.4% titanium, 0.0 to 4.0% niobium, 0.0 to 5.2% tantalum, 0.9 to 6.6% tungsten, 0.0 to 3.0% molybdenum, 0.0 to 24.0% cobalt, 12.5 to 20.6% chromium, 0.02 to 0.15% carbon, 0.001 to 0.015% boron, 0.0 to 0.1% zirconium, 0.0 to 3.0% rhenium, 0.0 to 2.0% ruthenium, 0.0 to 3.0% iridium, 0.0 to 0.5% vanadium, 0.0 to 1.0% palladium, 0.0 to 1.0% platinum, 0.0 to 0.5% silicon, 0.0 to 0.1% yttrium, 0.0 to 0.1% lanthanum, 0.0 to 0.1% cerium, 0.0 to 0.003% sulphur, 0.0 to 0.25% manganese, 0.0 to 0.1 magnesium, 0.0 to 5.0% iron, 0.0 to 0.5% copper, 0.0 to 1.0% hafnium, the balance being nickel and incidental impurities, wherein the following equations are satisfied in which WAl, WTi, WNb, WTa and WW are the weight percent of aluminium, titanium, niobium, tantalum and tungsten in the alloy respectively 0.65≤0.3 WNb+0.15 W 3.6≤WAl+0.5 WTi+0.3 WNb+0.15 WTa≤5.7 WTa+0.92WW≤6.1.

Disclosed herein is a method, system and apparatus for forming, by a cyclic process, a dopant concentration gradient in a doped hafnium zirconium oxide (HZO) layer on a substrate, the cyclic process includes, providing the substrate in a reaction chamber, a) pulsing a hafnium precursor(s) into the reaction chamber, where at least a part of the substrate is contacted with the hafnium precursor(s), b) pulsing a zirconium precursor(s) into the reaction chamber, where at least a part of the substrate is contacted with the zirconium precursor(s), c) pulsing an oxygen reactant(s) into the reaction chamber, where at least a part of the substrate is contacted with the oxygen reactant(s), d) pulsing a dopant precursor(s) into the reaction chamber, where at least a part of the substrate is contacted with the dopant precursor(s), and e) purging the reaction chamber.

The invention belongs to the technical field of semiconductor materials, and particularly relates to a hafnium precursor material and a preparation method and application thereof. The hafnium precursor material has a structure as shown in a formula (1). The hafnium precursor material with a specific structure is designed and synthesized, and the molecular structure of the hafnium precursor material contains an alkylene dicyclopentadienyl organic group structure, so that compared with an existing cyclopentadienyl hafnium precursor material (such as cyclopentadienyl) tris (dimethylamino) hafnium), the hafnium precursor material has higher thermal stability, and meanwhile, the hafnium precursor material can be used for preparing a hafnium precursor material. The viscosity is low, the film yield is improved, and the performance of the film prepared from the raw material is better. # imgabs0 #

The invention belongs to the technical field of geological sample analysis and detection, and particularly discloses a method for measuring the amount of each element of lithium ore in a closed acid-soluble system, and the method comprises the following steps: pretreating the lithium ore; the pretreated lithium ore is weighed and put into a closed sample dissolving device, hydrofluoric acid and purified nitric acid are sequentially added, and the closed sample dissolving device is closed; carrying out heat preservation on the closed sample dissolving device twice to obtain a test solution; and measuring the test solution by using an inductively coupled plasma mass spectrometer to obtain a working curve, and calculating the content of the analysis element in the sample solution by using the working curve. The method for determining the amount of each element in the lithium ore by adopting the closed acid-soluble system has the characteristics of simplicity in operation, high efficiency and good stability, realizes simultaneous determination of the amount of lithium, rubidium, cesium, beryllium, strontium, niobium, tantalum, zirconium, hafnium and rare earth elements in the large-batch lithium ore, and further provides a reference for determination of main trace elements in the lithium ore.

The application discloses a method for constructing oxygen defect regulation of hafnium dioxide 5d track electron, comprising the following steps: S1, using a hydrothermal method, by regulating the oxygen partial pressure in the preparation process, preparing hafnium oxide nanocrystals with different oxygen defects and calculating the oxygen defect concentration; S2, according to the first principle, calculating and constructing a hafnium dioxide crystal model under a microstructure, and modifying the corresponding model according to the experimental results of step S1; S3, according to the hafnium dioxide with oxygen defects obtained in step S2, calculating the total state density and the partial state density of the near-oxygen vacancy end hafnium atom and the far-oxygen vacancy end hafnium atom, respectively, calculating the proportion of the d atom track, and establishing a method for regulating the hafnium dioxide 5d track electron.

The present invention discloses a spinodal decomposition hardening compound carbide ceramic and a preparation method thereof, and belongs to the technical field of ceramic materials. The compound carbide ceramic provided by the present invention uses a transition metal source, a titanium source and a zirconium source or a titanium source, a zirconium source and a hafnium source as raw materials, firstly prepares a compound carbide powder by a sol-gel method and heat treatment, and then rapidly hot presses and sinters the compound carbide powder to obtain a compound carbide ceramic block material; the compound carbide ceramic block material is subjected to an aging treatment at 1350 to 1450°C for 2 to 4 hours to obtain the compound carbide ceramic block material. The sample of the present invention after a specific aging treatment shows the phenomenon of spinodal decomposition, and with the occurrence of this phenomenon, the hardness is significantly improved; at the same time, the process is simple and easy to control, the formation mechanism is clear and definite, and it has high industrial application potential.

A coating according to an exemplary embodiment of this disclosure, among other possible things includes a bond coat including gettering particles and diffusive particles dispersed in a matrix; a top coat disposed over the bond coat, the top coat includes metal silicate particles; and an intermediate layer between the bond coat and the top coat. The intermediate layer includes hafnium silicate particles and matrix. A concentration of metal silicate in the intermediate layer is less than a concentration of metal silicate in the top coat. An article is also disclosed.

The invention relates to the technical field of electrolyte materials, in particular to a halide solid electrolyte material containing doped metal and preparation and application of the halide solid electrolyte material. The invention provides the halide solid electrolyte material containing the doped metal, the structural formula of the halide solid electrolyte material containing the doped metal is shown as Li < 2 + x > Al < x > Hf < 1-x > Cl < 6 >, and x is greater than or equal to 0.1 and less than or equal to 0.4. By optimizing the content of an aluminum element and the content of a hafnium element in the solid electrolyte material and partially replacing Hf < 4 + > with a heterovalent metal Al < 3 + >, although a lattice gap is reduced, more Li < + > is introduced into a lattice, so that the transmission efficiency of Li < + > is higher, and the purposes of improving the ionic conductivity, the capacity and the cycling stability are achieved; and the content of Al metal in the earth crust is rich, so that the cost is low, the production cost can be further reduced, and the wide application rate of the product can be improved.

The utility model relates to the technical field of extraction devices, and discloses a zirconium and hafnium fractional extraction device which comprises a separation box, a fractionation cavity is formed in the upper portion of the interior of the separation box, a first rotating shaft is arranged in the fractionation cavity, a plurality of sets of first stirring blades are fixedly arranged on the first rotating shaft, and a cleaning plate is fixedly installed at the bottom of the first rotating shaft. The cleaning plate is attached to the sealing plate, the sealing plate is arranged in the middle of the interior of the separation box, the cleaning plate is arranged, the cleaning plate is attached to the sealing plate, liquid materials remaining on the sealing plate can be pushed into the circulating groove in the sealing plate when the cleaning plate rotates, the circulating groove is in a long strip shape, and therefore the liquid materials can be separated from the circulating groove. According to the cleaning plate, liquid materials can flow into the mixing cavity at the bottom of the circulating groove more quickly and intensively, meanwhile, in the rotating process of the cleaning plate, the strip shape is well matched with the rotating path, the liquid materials can be continuously and effectively collected, and omission is reduced.

The invention relates to the field of hydrometallurgy, and discloses a method for converting hafnium oxalate feed liquid into hafnium oxychloride feed liquid, which is characterized by comprising the following steps: adding an HCl solution and an oxidizing agent into the hafnium oxalate feed liquid, and reacting at a certain temperature to obtain a hafnium oxychloride solution. The method has the advantages of simple operation, no introduction of any metal impurity ions, small reagent consumption, low energy consumption, low cost, high efficiency, no physical state change, and realization of continuous production. The method for adding the HCl solution and the oxidizing agent into the oxalate feed liquid is also suitable for converting oxalate solutions of other metal ions into chloride solutions, including but not limited to zirconium oxalate, titanium oxalate, thorium oxalate, scandium oxalate, niobium oxalate, tantalum oxalate, vanadium oxalate, cobalt oxalate, cesium oxalate and rubidium oxalate.

The invention discloses antioxidant heat-resistant cast steel and a preparation method thereof. The cast steel comprises the following components in percentage by mass: 0.08-0.15% of C; 0.1% to 0.8% of Zr; 0.05% to 0.8% of Hf; 0.1% to 0.8% of Re; 8.0% to 11.0% of Cr; 0.5% to 2.5% of Ni; 1.0% to 2.0% of Mo; 0 < Si < = 0.5%; 0 < Mn < = 1.0%; 0 < P < = 0.025%; 0 < S < = 0.015%. According to the antioxidant heat-resistant cast steel added with zirconium, hafnium and rhenium and the electroslag remelting preparation method of the antioxidant heat-resistant cast steel, the grain size of heat-resistant steel is larger than or equal to the ASTM7 grade; the service life is not less than 500 hours under the conditions of 650 DEG C and 170 MPa, the service life is not less than 150 hours under the conditions of 700 DEG C and 100 MPa, and the weight gain rate is not more than 0.1 mg / cm < 2 > after oxidation for 100 hours at 700 DEG C.

Provided are a multilayer ceramic capacitor and a method of manufacturing the same, the multilayer ceramic capacitor including a capacitor body including a dielectric layer and an internal electrode layer, and an external electrode disposed on an outer surface the capacitor body, wherein the dielectric layer includes a plurality of dielectric grains, at least one of the plurality of dielectric grains includes a dielectric composite in which a barium titanate-based compound is doped with hafnium (Hf) or a first transition metal; and a subcomponent including a rare earth element, a second transition metal, or a combination thereof.

A grease composition that includes at least an oil-based medium, a thickener, and a fullerene-like nano-structure. The fullerene-like nano-structure includes a plurality of layers each comprised of a metal chalcogenide composition has a molecular formula of MX2, where M is a metallic element selected from the group consisting of titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), zirconium (Zr), niobium (Nb), molybdenum (Mo), technetium (Tc), ruthenium (Ru), rhodium (Rh), palladium (Pd), silver (Ag), cadmium (Cd), hafnium (Hf), tantalum (Ta), tungsten (W), rhenium (Re), osmium (Os), iridium (Ir), platinum (Pt), gold (Au), mercury (Hg) and combinations thereof, and X is a chalcogen element selected from the group consisting of sulfur (S), selenium (Se), tellurium (Te), oxygen (O) and combinations thereof.

The invention provides a ferroelectric capacitor and a preparation method thereof, the ferroelectric capacitor comprises a bottom electrode, a ferroelectric layer and a top electrode which are sequentially arranged from bottom to top, the ferroelectric layer is a lanthanum-doped hafnium zirconium oxide film prepared by an atomic layer deposition method, and the doping concentration of lanthanum in the lanthanum-doped hafnium zirconium oxide film is less than 1 at%. The ferroelectric capacitor can solve the problems that in the prior art, a ferroelectric capacitor based on an HZO cannot give consideration to a high k value and strong ferroelectricity, and is difficult to meet a low-power-consumption application scene.

The invention provides a niobium-hafnium alloy material and a preparation method and application thereof, and belongs to the field of nonferrous metal materials. The preparation method of the niobium-hafnium alloy material comprises the following steps that a scandium-zirconium alloy wire or a rare earth-zirconium alloy wire is wound on a metal niobium rod, the metal niobium rod is electrified and heated to generate a high-temperature area, and metal hafnium is placed in a low-temperature area; the iodine reacts with metal hafnium in the low-temperature area to generate hafnium iodide, the generated hafnium iodide is diffused to the high-temperature area and decomposed into metal hafnium on the surface of the niobium rod wound with the alloy wire, and a scandium-zirconium-niobium-niobium metal rod with a scandium-zirconium-niobium rod or a rare earth zirconium-niobium rod as the center and with the metal hafnium wrapped on the surface or a rare earth zirconium-niobium-hafnium metal rod with the metal hafnium wrapped on the surface is formed; raising the temperature of the metal niobium rod and keeping constant temperature for a certain time; and then smelting is conducted, and the niobium-hafnium alloy material is obtained. According to the prepared niobium-hafnium alloy material, the processing performance of metal hafnium is effectively improved, the internal and surface defects of the alloy are reduced, the high-voltage electrostatic oxidation corrosion resistance is improved, and the service life of equipment is prolonged.