823 results about "Hydrogen fluoride" patented technology

The invention belongs to the technical field of oil and gas development, and particularly relates to an oil and gas well blocking remover and a preparation method thereof. The blocking remover comprises the following components: 5-8% of low-carbon composite organic acid, 5-7% of fluoboric acid, 6-9% of ammonium bifluoride, 4-6% of an anti-acid sludge mutual solvent, 2-4% of a corrosion inhibitor, 2-4% of polyoxypropylene polyoxyethylene propylene glycol ether, 8-12% of a permeation dispersion surfactant, 2-5% of a sulfur dissolving agent, 2-5% of a stable chlorine dioxide solution and the balance of water. The preparation method comprises the following steps: adding the low-carbon composite organic acid, the fluoboric acid and the ammonium bifluoride into water and stirring; adding an acid sludge resisting mutual solvent and a sulfur dissolving agent, and stirring; adding the corrosion inhibitor, the polyoxypropylene polyoxyethylene propylene glycol ether and the permeation dispersion surfactant, and stirring; and finally, reducing the stirring speed, adding the stable chlorine dioxide solution, and stirring to uniformly mix. The blocking remover provided by the invention is comprehensive in blocking removal function, very good in dissolving and dispersing performance on complex blocking substances, very small in corrosion damage to a shaft pipe wall and wide in applicability.

The invention provides a waste photovoltaic module high-value recovery process based on pyrolysis and wet purification, which comprises the following steps: carrying out pyrolysis decarburization on a waste photovoltaic module to obtain a glass plate, a crystalline silicon battery piece and a copper-tin soldering strip; the method comprises the following steps of: performing alkaline leaching on a crystal silicon cell to obtain a dealuminized crystal silicon wafer, performing acid pickling on the dealuminized crystal silicon wafer to obtain a silver-removed crystal silicon wafer and a silver leaching solution, and extracting a silver elementary substance from the silver leaching solution; removing impurities from the silver-removed crystal silicon wafer through a hydrofluoric acid solution to obtain a high-purity crystal silicon wafer; recovering a copper strip from the copper-tin soldering strip through a high-temperature smelting reduction method; after fluorine-containing pyrolysis gas generated in the pyrolysis process is subjected to combustion and heat exchange, hydrogen fluoride is removed in a two-stage alkali liquor absorption mode, then washing is conducted, and finally obtained flue gas is discharged. According to the wet purification process, the waste crystalline silicon battery piece can be subjected to high-purity recovery, and the crystalline silicon piece, silver and copper with high purity can be obtained. The hydrogen fluoride is removed by adopting a two-stage alkali liquor absorption method, so that the treatment efficiency of the hydrogen fluoride in the pyrolysis gas is improved.

A non-woven battery separator and processes for forming the non-woven battery separator includes a fiber blend including cellulose fibers, microfibrillated fibers, and optionally polyester and / or aramid fibers. Also disclosed are batteries including the non-woven battery separator. During fabrication, the non-woven battery separator can be effectively dried at temperatures between 120°C and 180°C, which results in the fibers absorbing water when in use. Some battery electrolytes such as lithium hexafluorophosphate react with water to form hydrogen fluoride (HF), which can be corrosive and shorten battery lifecycles and affect performance. Absorbing water from the electrolyte increases the battery life cycle by reducing HF generation.

The utility model discloses an electronic-grade hydrofluoric acid production system, industrial hydrofluoric acid is input into the system to obtain high-purity electronic-grade hydrofluoric acid, and the system comprises a graphite evaporator, a rectifying tower and a condenser, the graphite evaporator is provided with a feeding pipeline and a condensed water outlet, and the feeding pipeline is used for inputting industrial hydrofluoric acid into the graphite evaporator; a steam pipeline is further arranged on the graphite evaporator, the other end of the steam pipeline is connected with the rectifying tower, the steam pipeline is used for conveying gas heated by the graphite evaporator into the rectifying tower, and the rectifying tower is used for rectifying and separating hydrofluoric acid gas produced by the graphite evaporator; industrial hydrofluoric acid is added into the graphite evaporator to be heated to obtain hydrofluoric acid, then the hydrofluoric acid is fed into the rectifying tower with a certain height to be distilled, backflow is conducted in proportion, the product quality meets the requirement, and continuous production can be achieved through combination of the graphite evaporator and the rectifying tower; liquid hydrofluoric acid is used as a raw material, high risk of anhydrous hydrogen fluoride gas is avoided, and safety of the system is improved.

The invention discloses an efficient thermal cycle drying device for producing flaky ammonium bifluoride, and relates to the technical field of ammonium bifluoride production. Comprising a machine body, an exhaust pipe and an air inlet sleeve, a first shell and a second shell are sequentially mounted at the upper end of the machine body from left to right, an air inlet cavity is formed in the bottom of the inner side of the machine body, and a mounting cylinder is connected to the upper end of the air inlet cavity through a spring; through cooperation of a mounting cylinder, a movable cylinder, a scraping plate and a first adjusting assembly, when materials are subjected to traditional one-way vibration blowing heat exchange, the materials are thrown and turned in the other direction to increase the drying uniformity, meanwhile, the air flow pressure of an exhaust hole is correspondingly adjusted, and the heat exchange drying effect is improved; and through cooperation of the movable barrel and the second adjusting assembly, when materials with the large water content and the large feeding amount are dried, the moving speed of the materials is increased, meanwhile, the air flow pressure of the exhaust holes is correspondingly adjusted, and the heat exchange drying effect is improved.

The invention relates to a method for recovering lithium and fluorine from aluminum electrolysis hazardous waste, which comprises the following steps: firstly, mixing organic polyol and alkaline hydroxide according to a molar ratio of 1: (0.5-2) to obtain a eutectic solvent; heating the eutectic solvent to 80-150 DEG C, and adding a proper amount of raw material fine powder and calcium oxide for reaction leaching; carbonating and filtering the leachate to obtain lithium carbonate; washing the leaching residues with an acetic acid solution to obtain a calcium fluoride product; the concentration of fluorine ions in the leachate is smaller than or equal to 200 ppm, and the purity of calcium fluoride is larger than or equal to 90%; the leaching rate of lithium in the method is greater than 85%; the slag feeding rate of fluorine is greater than 95%; and no hydrogen fluoride gas is generated in the method. According to the method, a non-toxic and biodegradable eutectic solvent is adopted as a leaching agent, and efficient leaching of lithium and fluorine in the aluminum electrolysis dangerous waste materials is achieved; calcium oxide is used as a precipitating agent, free fluorine is promoted to be precipitated and recycled as calcium fluoride, the whole process meets the requirement of green metallurgy, and the win-win situation of resources and the environment is achieved.

The invention discloses a simulated screening and process optimization method of an anhydrous hydrogen fluoride desulfurization adsorbent, and relates to the technical field of anhydrous hydrogen fluoride, and the method comprises the following steps: constructing a database, and establishing a basic screening library; constructing an intelligent screening engine, and performing force field parameter correction on the materials in the basic screening library to capture a high-polarity solvent effect; calculating and extracting adsorption selectivity, Henry coefficients and working capacity indexes, and screening out a primary candidate material set; a core candidate material is optimized; determining an optimal adsorbent model; the microscopic adsorption data of the optimal adsorbent model are converted into macroscopic process parameters, the macroscopic process parameters are imported into a macroscopic process simulator for prediction, and process optimization is completed. According to the method, the strong polar solvent effect is simulated by constructing the corrected force field environment, and high-throughput screening of the adsorption materials is achieved in combination with an active learning strategy; an electronic grade refinement and modification strategy is utilized to optimize adsorption sites, and microcosmic adsorption data and a macroscopic mass transfer model are coupled to realize accurate prediction and optimization of an adsorption process.

The invention discloses a method for generating 1234yf through one-step fluorination of 240db. The method comprises the following step: reacting 240db and hydrogen fluoride under the action of a fluorinated catalyst to generate 1234yf, the catalyst comprises a Ce-Zr composite oxide carrier and one or more than two of Ni, La, Cr, Co, Fe, Sb, Mo and Cu loaded on the carrier. The method disclosed by the invention has the characteristics of stable and controllable process and long service life of the catalyst while ensuring high selectivity and high yield, effectively reduces material consumption and equipment maintenance cost in industrial production, and overcomes the problems of economy and stability in large-scale production in the prior art.

The invention relates to a high-temperature acidolysis reaction defluorination method, and belongs to the technical field of phosphorus chemical resource recycling. The technical problem to be solved by the invention is to provide a high-temperature acidolysis reaction defluorination method which is simple to operate and high in defluorination rate. According to the method, phosphorite powder / white fertilizer is subjected to high-temperature acidolysis, fluoride in the phosphorite powder / white fertilizer reacts with strong acid, fluorine is separated from a reaction system in a gas form, and hydrofluoric acid is obtained through condensation. The method is simple, is simple and convenient to operate, and is easy to realize technologized large-scale production. Meanwhile, due to the destructive effect of the strong acid on the lattice structure of the phosphorus-calcium compound, citrate-soluble phosphorus can be converted into soluble phosphate, subsequent phosphorus recovery is facilitated, comprehensive utilization of phosphorite and elimination of white fertilizer output are achieved, meanwhile, the problems of material accumulation and resource waste of enterprises are solved, and the method conforms to the circular economy concept of green development.

The invention relates to the technical field of hydrogen fluoride adsorption, and particularly discloses a hydrogen fluoride adsorption tower which comprises a tower body, a gas inlet pipeline arranged on the lower section of the tower body, a gas outlet pipeline arranged on the upper section of the tower body, a plurality of layers of adsorption beds arranged in the tower body in the vertical direction, and adsorbents arranged on the adsorption beds. The material changing mechanism comprises a waste material pipe rotationally arranged in the tower body, a driving part I for driving the waste material pipe to rotate, a plurality of inverted conical funnels respectively arranged below the plurality of layers of adsorption beds and a plurality of trapping boxes arranged on the waste material pipe, and the waste material pipe penetrates through all the adsorption beds; a plurality of spiral scrapers for driving the adsorbent to radially flow are arranged on the waste pipe, the upper end of the inverted-cone-shaped funnel exceeds the outer edge of the adsorption bed, an annular air jet hole is formed in an outlet in the bottom of the inverted-cone-shaped funnel, and the trapping boxes surround the waste pipe in an annular array; the device has the beneficial effects that saturated aluminum oxide is separated in time, so that the adsorption effect of the aluminum oxide is improved.

A wastewater recycling device for a hydrogen fluoride production line is characterized in that a water outlet of a recycling water tank is connected to a spiral humidifying distributor through a connecting pipeline, the recycling water tank is sequentially provided with a primary reaction tank, a primary sedimentation tank, a secondary reaction tank, a secondary sedimentation tank and a fluorine removal agent adding tank from top to bottom, the primary reaction tank is located at a water inlet of the recycling water tank, and the secondary reaction tank is located at a water outlet of the recycling water tank. The first-stage reaction tank is communicated with the first-stage sedimentation tank, the first-stage sedimentation tank is communicated with the second-stage reaction tank, the second-stage reaction tank is communicated with the second-stage sedimentation tank, and the second-stage sedimentation tank is connected with the spiral humidification distributor through the fluorine removal agent adding tank. The wastewater recycling device for the hydrogen fluoride production line has the beneficial effects that the wastewater recycling device for the hydrogen fluoride production line can realize all recycling of production wastewater of hydrogen fluoride production enterprises, not only solves the problems that gypsum slag is easy to raise dust in the loading process due to high temperature and small granularity and dangerous wastes are avoided, but also realizes zero discharge of the production wastewater of the hydrogen fluoride production enterprises; and the unorganized emission of dust is reduced.

The invention discloses a gas mixing and uniformizing device for hydrogen fluoride gas phase etching, which comprises a device body, the device body internally comprises a first-stage mixing cavity, a second-stage mixing cavity, a third-stage mixing cavity and a reaction cavity which are sequentially communicated, the first-stage mixing cavity is arranged at the top of the device, and three groups of gas inlet pipelines are respectively arranged outside the device and are communicated with the first-stage mixing cavity; a plurality of groups of spiral blades which are arranged in an annular array are arranged in the second-stage mixing cavity, an annular hole partition plate is arranged at the communication part of the third-stage mixing cavity and the second-stage mixing cavity, a porous partition plate is arranged between the third-stage mixing cavity and the reaction cavity, and flow guide holes which are communicated up and down are formed in the annular hole partition plate and the porous partition plate; a manual sample inlet and a manipulator sample inlet are respectively arranged in front of and behind the reaction cavity, and an exhaust port is arranged at the bottom of the reaction cavity. The method has the advantages that the efficient mixing and uniform distribution of the ethanol steam, the hydrogen fluoride gas and the carrier gas can be realized, and the stability and the etching quality of the etching process are improved.

Provided is a method that allows for the etching of a silicon nitride film with respect to a silicon oxide film with high selectivity and high precision while preventing a degradation in the shape of the silicon oxide film portion during etching. The etching method of dry etching a film structure which is formed in advance on a wafer disposed in a processing chamber and in which an end portion of a film stack including a silicon nitride film and silicon oxide films vertically sandwiching the silicon nitride film forms a sidewall of a trench or hole, by supplying a gas for processing into the processing chamber, without using plasma includes: forming, as a first process, a reaction layer on the silicon nitride film by reaction of hydrogen fluoride gas at 30° C. or higher and 55° C. or lower; removing, thereafter, as a second process, the reaction layer having been formed in the first process, through volatilization by performing heating at 70° C. or higher and 110° C. or lower without causing the hydrogen fluoride gas to flow; and etching the silicon nitride film from the end portion in a lateral direction by performing the first and second processes a plurality of times.

The invention belongs to the field of inorganic chemical industry, and particularly relates to a method and a system for efficiently utilizing a phosphate fertilizer byproduct, the method comprises the following steps: carrying out acidolysis on fluosilicic acid with the concentration of more than or equal to 45% wt and concentrated sulfuric acid to generate a mixed solution of silicon tetrafluoride gas and fluorosulfonic acid; the mass ratio of the fluosilicic acid to the concentrated sulfuric acid is controlled to be 1: (4-15); pyrolyzing the obtained fluorosulfonic acid to generate dilute sulphuric acid, hydrogen fluoride and water vapor, forming 98% concentrated sulphuric acid from part of dilute sulphuric acid and fuming sulphuric acid, drying hydrogen fluoride to obtain crude hydrogen fluoride gas, and condensing and rectifying to obtain anhydrous hydrogen fluoride; the rest dilute sulphuric acid is partially compounded and then returned for acidolysis, and the rest dilute sulphuric acid is used for producing white carbon black and flows back to a wet-process phosphoric acid system; and circularly absorbing the obtained silicon tetrafluoride gas by using secondary concentrated fluosilicic acid to obtain fluosilicic acid with the mass concentration of more than or equal to 45%, recycling the fluosilicic acid for acidolysis reaction, and modifying the concentrated by-product silicon dioxide to obtain the high-activity white carbon black. The problems of energy consumption and cost are solved, and efficient circulation and poly-generation of fluorine and silicon resources are achieved in the whole process.

The invention relates to the technical field of surface strengthening treatment and coating preparation, in particular to a micro-arc oxidation electrolyte, a preparation method of the micro-arc oxidation electrolyte and a preparation method of an oxide ceramic coating on the surface of a magnesium-copper dissimilar metal material component. The invention provides a micro-arc oxidation electrolyte. The micro-arc oxidation electrolyte comprises a main film-forming agent, an arcing aid, a pH regulator, a corrosion inhibitor and water, the main film-forming agent comprises ammonium fluozirconate and / or potassium fluozirconate; the arcing aid comprises one or more of disodium hydrogen phosphate, sodium dihydrogen phosphate, ammonium dihydrogen phosphate and diammonium hydrogen phosphate; the corrosion inhibitor comprises one or more of hexamethylenetetramine, ammonium bifluoride and triethanolamine. The micro-arc oxidation electrolyte breaks through the problem that valve metal and non-valve metal cannot be subjected to arc discharge at the same time for micro-arc oxidation treatment in the micro-arc oxidation process.

The invention provides a method for preparing high-purity flaky alumina based on a hydrolysis method, and belongs to the field of high-purity flaky alumina powder. The method comprises the steps that metal aluminum scraps are pretreated; the method comprises the following steps: putting metal aluminum scraps, an alkaline organic matter catalyst and a morphology control agent into water, and carrying out a hydrolysis reaction at a set temperature for a set time to obtain a reaction mixed solution; carrying out solid-liquid separation, washing and drying on the reaction mixed solution to obtain flaky aluminum hydroxide; and roasting the flaky aluminum hydroxide to remove crystal water so as to obtain high-purity flaky aluminum oxide, wherein the alkaline organic matter catalyst comprises at least one of the following components: tetraethylammonium hydroxide, tetramethylammonium hydroxide, tetrapropylammonium hydroxide and tetrabutylammonium hydroxide; the morphology control agent comprises at least one of ammonium bifluoride and ammonium fluoride. The preparation method disclosed by the invention is simple in process flow, free of an impurity removal process, mild in reaction condition, short in reaction time and free of environmental pollution, and the product is regular in shape and high in purity.

An oxide film etching method includes: forming a protective film of a metal or a metal nitride that does not contain silicon so as to cover a protection target film, among the protection target film containing silicon and a silicon-containing oxide film exposed on a surface of a substrate; supplying, to the substrate, a mixed gas including a hydrogen fluoride gas and an ammonia gas to react with the silicon-containing oxide film, and modifying the oxide film to generate a reaction product; and sublimating and removing the reaction product.

The present application relates to a kind of methods for preparing ultra-high purity quartz sand by deep purification, belong to high-purity quartz high-efficiency preparation and non-metallic mineral fine and deep processing technical field.The method is placed in supercritical reaction device with quartz sand raw material, and mixed fluid of composite entraining agent and supercritical carbon dioxide is introduced into the device to carry out reaction, after separation, washing and drying, high-purity quartz sand product is obtained;The composite entraining agent is the combination of acid medium and metal complexing agent;The volume fraction of the acid medium in the mixed fluid is 0.5%~5%, and the acid medium is hydrogen fluoride and / or hydrogen chloride.The method has the advantages of simple process flow, high purification efficiency, controllable purification degree and stable product performance.

The invention provides a NiCoCrHfB (Fe, Ti, Zr and Nb) brazing filler metal and application of the NiCoCrHfB (Fe, Ti, Zr and Nb) brazing filler metal. The brazing filler metal comprises the following components in percentage by mass: 12.0-24.0% of Co; 2.0 to 8.0% of Cr; 16.0 to 32.0 percent of Hf (hydrogen fluoride); 0 to 4.0% of Fe; 0 to 4.5% of Ti; 0 to 4.0% of Zr; 0 to 5.0 percent of Nb; 1.0 to 3.0 percent of B; and the balance Ni. Through research, when the brazing filler metal is applied to brazing of a TiAl-based alloy and other non-TiAl-based alloys, an obtained brazed joint has high high-temperature strength, for example, a TiAl / GH3536 brazed joint obtained under the condition of (1140-1180) DEG C / (10-30) min has the high-temperature shear strength of 355-422 MPa and the high-temperature shear strength of 308-348 MPa at the temperature of 750 DEG C and the high-temperature shear strength of 308-348 MPa at the temperature of 850 DEG C.

The invention belongs to the technical field of chemical engineering and fine fluorine chemical synthesis, and particularly relates to a preparation method of sulfuryl fluoride chloride. According to the preparation method, through the synergistic effect of a gas-liquid reaction system and a closed-loop circulation system, a tertiary amine hydrofluoric acid adduct (such as Et3N.nHF, n = 2-6) is used as a fluorinating reagent, sulfuryl fluoride chloride is generated through a rapid cross-flow reaction in excessive sulfuryl chloride (SO2Cl2) under the conditions that the temperature is 65-100 DEG C and the pressure is 0.5-2.0 MPa, and a liquid-phase byproduct tertiary amine hydrochloride hydrogen fluoride adduct (such as Et3N.HCl. (n-1) HF) is used for preparing the sulfuryl fluoride chloride. Supplementing hydrogen fluoride to regenerate the catalyst and recycling; and after a gas-phase product is pressurized, rectified and purified by a light component removal tower and a heavy component removal tower, totally returning a light component (Cl2 / SO2) and a heavy component (SO2Cl2) to a synthesis system for recycling. According to the method, the reaction temperature, the reaction pressure, the liquid phase dispersion degree and the contact time are accurately controlled, so that the reaction product generates SO2FCl with high selectivity, and the byproduct (R3N.HCl. (n-1) HF) is kept in a liquid phase, so that the reaction can be continuously carried out, and conditions are created for subsequent treatment.

The invention discloses a sodium-ion battery electrolyte and a preparation method thereof, and relates to the technical field of sodium-ion batteries, the electrolyte comprises a sodium salt, a composite solvent, an additive and an auxiliary agent, the sodium salt is formed by compounding sodium bis (fluorosulfonyl) imide, sodium bis (trifluoromethanesulfonyl) imide and modified sodium bis (oxalato) borate, and the composite solvent is formed by compounding sulfolane, 1, 3-butanediol, 1, 3-butanediol, 1, 3-butanediol, 1, 3-butanediol, 1, 3-butanediol, 1, 3-butanediol, 1, 3-butanediol, 1, 3-butanediol and 1, 3-butanediol. The auxiliary agent is nano-scale ZIF-8, the additive is 1, 3-propylene glycol dimethyl ether, dimethyl carbonate, fluoroethylene carbonate and ethyl acetate, the additive is modified 1, 3-propane sultone, trimethyl phosphate and hydroquinone dimethyl ether, and the auxiliary agent is nano-scale ZIF-8. According to the electrolyte, sodium bis (oxalato) borate is modified after being treated by hydrogen peroxide and has efficient hydrofluoric acid resistance, meanwhile, hydrofluoric acid generated by the reaction of fluorine-containing sodium salt and water in the electrolyte can be specifically removed by utilizing an auxiliary agent of the nano ZIF-8 and a synergistic effect formed by the sodium salt and the auxiliary agent, and damage of the hydrofluoric acid to a negative electrode SEI film is avoided; and the cycle life of the sodium ion battery is prolonged.

The etching method disclosed herein includes a process (a) of preparing a substrate within a chamber of a plasma processing apparatus. The substrate includes a silicon-containing film. The etching method also includes a process (b) of etching the silicon-containing film by chemical species from a plasma formed from a process gas within the chamber. The process gas includes a phosphorous-containing gas, a fluorine-containing gas, and a hydrogen-containing gas. The hydrogen-containing gas contains at least one selected from the group consisting of hydrogen fluoride, H2, ammonia, and a hydrocarbon.

The invention provides a nitrogen-fluorine double-element doped porous carbon material, a silicon-carbon negative electrode material and a preparation method thereof, and the preparation method of the porous carbon material comprises the following steps: mixing porous carbon with ammonium fluoride and / or ammonium bifluoride, and carrying out vapor deposition coating or liquid phase coating; and calcining the coated porous carbon material in a closed environment in an inert atmosphere to obtain the nitrogen-fluorine double-element doped porous carbon material. According to the invention, by utilizing the characteristics of nano-scale micropores and super-large specific surface of porous carbon and the properties of low melting point and low boiling point of ammonium fluoride and ammonium bifluoride, a uniformly coated ammonium fluoride and ammonium bifluoride coating layer is obtained by adopting a vapor deposition or liquid phase coating method, and then the porous carbon material is obtained by utilizing high-temperature calcination treatment. According to the present invention, the characteristics of high specific surface and nano-scale micropores can be simultaneously retained, and after the silicon-carbon negative electrode material is prepared, the expansion of the silicon-carbon negative electrode material is substantially reduced, the cycle performance of the material is ensured, and the rate capability of the obtained silicon-carbon negative electrode material is improved.

The present application relates to a solid electrolyte with a lithium salt modification layer. A lithium metal battery, comprising: a positive electrode; a garnet solid electrolyte disposed on the positive electrode; and a lithium negative electrode disposed on the garnet solid electrolyte, wherein a modification layer is disposed at the interface of the lithium negative electrode and the garnet solid electrolyte, the modification layer comprising an inorganic lithium salt. A method of forming a lithium metal battery, comprising: treating a garnet solid electrolyte with an acid solution; and exposing the acid-treated garnet solid electrolyte to hydrogen fluoride to form a modification layer at the surface layer of the garnet solid electrolyte.

The utility model relates to the technical field of anhydrous ammonium hydrogen fluoride preparation, and discloses a micro-channel reaction device for preparing anhydrous ammonium hydrogen fluoride, which comprises a raw material tank, a vaporizer, a micro-channel reactor and a shell-and-tube heat exchanger, two driving motors are mounted at the upper end of the micro-channel reactor, stirring rods are mounted at the lower ends of the driving motors through motor shafts, a plurality of stirring blades are arranged on the stirring rods, a micro-channel groove is formed in the middle in the micro-channel reactor, a plurality of channels are uniformly distributed in the micro-channel groove, and two catalysts are mounted at the bottom end in the micro-channel reactor. Two driving motors are started, the driving motors drive stirring rods to rotate through motor shafts, the flow speed of ammonium bifluoride gas is increased, multiple channels are formed in the micro-channel groove, the contact area and the retention time of reaction gas can be increased through the channels, the reaction efficiency is improved, the reaction gas reacts with other reactants under the action of a catalyst, and the reaction efficiency is improved. Anhydrous ammonium bifluoride and other byproducts are generated, so that the reaction is sufficient.

The invention discloses a surface etching method for revealing dislocation defects of tellurium indium lead single crystals, and relates to a method for revealing crystal defects. The invention aims to provide a surface etching method capable of accurately exposing crystal defects. The method comprises the following steps: firstly, carrying out directional cutting, multi-stage mechanical polishing and chemical mechanical polishing on a PIT single crystal to obtain a smooth and damage-free surface; and reacting iodine with concentrated nitric acid to generate iodic acid as a main oxidant, adding hydrofluoric acid for activation, diluting with an acetic acid-water mixed solution, and etching the crystal at a low temperature of 10 + / -1 DEG C under ultrasonic assistance. According to the method, the regular triangular conical etching pit can be formed on the PIT single crystal (001) surface, the depth is 100-300 nm, the pit bottom points to the [001] direction, and the dislocation defect is clearly revealed. The method has the advantages of clear etching morphology, high sensitivity, high reliability and simplicity and convenience in operation, and can be applied to the fields of PIT single crystal quality evaluation, defect analysis and growth process optimization.

The invention relates to an improved process for the manufacture of a fluorinated organic compound, wherein the process comprises a fluorination reaction of an organic precursor compound having at least one chlorine substituent and / or at least one double bond, and said organic precursor compound is reacted in liquid phase in HF (hydrogen fluoride) serving as solvent and fluorinating agent in the presence of a fluorinating catalyst, and wherein the fluorination reaction is performed in liquid phase in a SiC block chemical reactor, and wherein the reaction mixture is withdrawn from SiC block chemical reactor, and wherein the process comprises optionally isolating and / or purifying the targeted fluorinated organic compound.

The production of HFO-1132, and in particular HFO-1132 E, may be produced from 1, 1, 2-trichloro-1, 2, 2-trifluoroethane (CFC-113), and the production of HFO-1132, and in particular HFO-1132 E, may be produced from 1, 1, 2-trichloro-1, 2, 2- In a first step, 1, 1, 2-trifluoroethane (HFC-143) is produced by hydrogenating 1, 1, 2-trichloro-1, 2, 2-trifluoroethane (CFC-113) by reacting with hydrogen in the presence of a catalyst to produce 1, 1, 2-trifluoroethane (HFC-143). The 1, 1, 2-trifluoroethane (HFC-143) may then be dehydrofluorinated in the presence of a catalyst to produce trans-1, 2-difluoroethylene (HFO-1132E) and / or cis-1, 2-difluoroethylene (HFO-1132Z). The cis-1, 2-difluoroethylene (HFO-1132Z) may then be isomerized to produce the trans-1, 2-difluoroethylene (HFO-1132E), and then the cis-1, 2-difluoroethylene (HFO-1132Z) may be isomerized to produce the cis-1, 2

The invention discloses a method for producing anhydrous hydrofluoric acid from photovoltaic fluorine-containing waste materials. The waste materials are fluorine-containing solid press filter residues or filter cake biscuits obtained through solid-liquid separation after photovoltaic fluorine-containing waste liquid treatment. The method comprises the following steps: drying, crushing and screening the waste until the waste is matched with the fluorite powder in particle size, returning the oversize product to the crushing, closed-loop granulating and homogenizing; continuously metering and uniformly mixing the homogenized waste and fluorite powder according to a mass ratio of 20: 1 to obtain a mixed fluorine-containing raw material, and continuously feeding the mixed fluorine-containing raw material into a rotary reaction furnace; fuming sulfuric acid and concentrated sulfuric acid are mixed into mixed acid, the mixed acid is continuously added into a reaction furnace, the mixed acid reacts at the temperature of 300-350 DEG C to generate a fluorine-containing gas phase, and reaction heat is indirectly provided by circulation of high-temperature gas in a jacket of the reaction furnace; the crude product gas enters a degassing tower to remove SO2 and SiF4 after being subjected to dust removal, washing, cooling, condensation, rectification, deacidification and dehydration, and an anhydrous hydrofluoric acid product is obtained. According to the method, waste recycling is achieved, and fluorite consumption and waste disposal amount are reduced.