760 results about "Ammonium fluoride" patented technology

The invention discloses a silicon-carbon negative electrode material, porous carbon and a preparation method, the porous carbon is prepared by mixing ammonium fluoride and a pre-carbonized material to prepare a premix; and putting the premix in an inert atmosphere, and carrying out pre-activation, drying, carbonization, activation and crushing treatment to obtain the composite material. And uniformly depositing the nano silicon particles into the porous carbon skeleton through a mature CVD (Chemical Vapor Deposition) process to obtain the silicon-carbon composite material. Fluorine and nitrogen co-doping modification can increase the defect degree of a carbon skeleton, efficiently relieve mechanical stress accompanied by lithium storage volume expansion of the silicon negative electrode in a micro scale, provide abundant lithium ion transport and mass transfer channels and enhance the conductivity of porous carbon, and ammonium fluoride is used as a supplementary activator besides water vapor, so that the porosity of the porous carbon is further improved, and the conductivity of the porous carbon is improved. An effective space is provided for uniform deposition of silicon, the fluorine-containing carbon layer can induce formation of a high-stability SEI film rich in LiF on the surface of the nano silicon material, and the interface stability and coulombic efficiency of the silicon negative electrode are further improved.

The present invention provides a lithium iron phosphate positive electrode material, a preparation method therefor, and a use thereof. The preparation method comprises: in a calcination and cooling phase for lithium iron phosphate synthesis, introducing hydrogen to react with lithium iron phosphate, so as to generate highly-conductive Fe2P on the surface of the lithium iron phosphate; then mixing the lithium iron phosphate with ammonium fluoride and carrying out secondary calcination to form a fluorine coating; and forming a stable and robust positive electrode-electrolyte layer on the surface of a positive electrode. By means of composite surface modification, the method of the present invention successfully improves the conductivity of the material and inhibits the decomposition of Fe2P in an electrolytic solution, thereby greatly improving the rate performance and the cycle performance of the material.

The invention discloses a composite coated graphite negative electrode material, a preparation method thereof and a lithium ion solid-state battery, and belongs to the technical field of lithium ion solid-state batteries, the composite coated graphite negative electrode material comprises a graphite matrix and a composite coating layer, and the composite coating layer comprises an inner layer amorphous lithium chloride and an outer layer nanocrystalline LiF / Li3N composite phase. Mixing graphite, lithium chloride containing crystal water and ammonium fluoride to obtain a mixed material; placing the mixed material in a microwave reaction cavity, heating the mixed material to 600-700 DEG C at the microwave power of 800-1200 W in an H2 / Ar mixed atmosphere, and keeping the temperature for 20-60 minutes; and cooling the sintered mixed material, grinding, and sieving with a 100-300 mesh sieve to obtain the composite coated graphite negative electrode material with a coating layer thickness of 10-50 nm. The invention provides an innovative amorphous LiCl / nanocrystalline LiF-Li3N gradient coating layer design, the performance of the lithium ion battery is remarkably improved by optimizing an ion migration path, enhancing the interface stability and reducing the process cost, and a new engineering way is provided for realizing high magnification and long cycle performance of the sulfide all-solid-state battery.

The invention discloses a carbon-doped titanium dioxide nanotube-molybdenum disulfide energy-storage antibacterial material and a preparation method thereof. The preparation method comprises the following steps: carrying out primary anodic oxidation on a clean titanium foil in a mixed electrolyte of ethylene glycol, water and ammonium fluoride; after ultrasonic treatment is carried out in a hydrochloric acid solution for set time, secondary anodic oxidation is carried out, and the mixed electrolyte of the secondary anodic oxidation is the same as that of the primary anodic oxidation; annealing the titanium foil subjected to anodic oxidation twice in an argon atmosphere, putting an annealed sample into a mixed solution of sodium molybdate, a sulfur source and glucose, and carrying out hydrothermal treatment; and the titanium foil subjected to hydro-thermal treatment is cleaned and dried, and the carbon-doped titanium dioxide titanium foil with the surface covered with molybdenum disulfide is obtained. The MoS2-coated carbon-doped titanium dioxide nanotube (TNT-C-atMoS2) with high biocompatibility developed by the invention has a synergistic effect of charge antibiosis and chemical sterilization, so that the problem of intractable biological fouling of a titanium-based metal material in ocean engineering equipment is effectively solved.

The invention discloses a gas-sensitive material for monitoring an environment-friendly gas characteristic substance CO as well as a preparation method and application thereof, and relates to the technical field of gas-sensitive materials. The preparation method comprises the following steps: dissolving tin tetrachloride pentahydrate, sodium hydroxide and polyvinylpyrrolidone, adding ammonium fluoride, reacting at 155-165 DEG C, drying the product, and calcining at 295-305 DEG C to obtain SnO2 nanoparticles; the preparation method comprises the following steps: performing ultrasonic mixing on SnO2 deionized water dispersion liquid and MoS2 nanosheet ethylene glycol dispersion liquid, and then drying to obtain the MoS2 / SnO2 composite material with a mesoporous hollow nanotube structure, and the volume ratio of ethylene glycol to deionized water is (0.9-1.1): 1. The MoS2 / SnO2 gas sensitive material has the advantages of low density, high pore volume, large specific surface area, high structural stability and the like. And when applied to a CO resistive sensor, the catalyst has good CO selectivity, high sensitivity and good long-term stability.

The invention discloses an environment-friendly titanium alloy etching solution as well as a preparation method and an etching method thereof, and relates to the technical field of printed circuit board production. The environment-friendly titanium alloy etching solution comprises the following components in percentage by mass: 10-30% of ammonium fluoride, 5-15% of an oxidant, 0.1-1% of a wetting agent, 0.3-1.5% of a stabilizer, 2-10% of an accelerator and 0.5-3% of a lateral erosion inhibitor. The stabilizer is selected from at least one of Tween 20, Tween 40 and Tween 85; and the accelerator is selected from at least one of sodium methylene dinaphthalene sulfonate, sodium dibutyl naphthalene sulfonate and dodecyl benzoate. The environment-friendly titanium alloy etching solution disclosed by the invention can selectively and quickly etch titanium alloy without corroding a copper surface and other metals, so that etching factors are effectively increased, and the problem of lateral erosion of a fine circuit is solved. Meanwhile, ammonium fluoride is used as a main agent of the etching liquid instead of hydrofluoric acid, so that the environmental pollution can be effectively reduced.

The invention discloses a preparation method of a light high-strength hollow SiO2 aerogel composite board, which comprises the following steps: uniformly mixing tetramethyl orthosilicate and methanol, adjusting the pH value to be acidic, adding a mixed solution of ammonium fluoride and water, uniformly stirring, and hydrolyzing to obtain silica sol; the preparation method comprises the following steps: putting a water-soluble powder modifier into silica sol, and dispersing under ultrasonic waves to form a stable suspension; putting the suspension into a mold, adding a catalyst, uniformly stirring, and standing for reaction to obtain wet gel; putting the wet gel into a mixed solution of water and methanol, dissolving the powder modifier in the wet gel by using ultrasonic waves, and repeatedly replacing a soaking solution until the powder modifier in the wet gel is completely dissolved; and after the wet gel becomes transparent, aging and drying the wet gel in sequence to prepare the lightweight high-strength hollow SiO2 aerogel composite board. According to the invention, the one-time forming qualification rate of large-size aerogel products is improved; a large-size hollow structure in the prepared hollow SiO2 aerogel composite board has a relatively strong energy absorption effect, and the hollow SiO2 aerogel composite board is high in strength, light in weight and simple to manufacture.

The invention belongs to the technical field of controllable preparation of high-entropy nano materials and electrolyzed water catalysts, and particularly discloses a preparation method for controllable preparation of a two-dimensional high-entropy sulfide efficient electrolyzed water catalyst based on a two-dimensional high-entropy hydroxide template. The preparation method comprises the following steps: respectively adding at least five metal precursors into deionized water, then adding ammonium fluoride and urea, carrying out uniform ultrasonic mixing, and carrying out a stirring reaction to obtain a template two-dimensional high-entropy hydroxide; and placing the obtained two-dimensional high-entropy hydroxide template in the middle position of a single-temperature-zone tubular furnace, continuously introducing argon into a quartz tube, and carrying out vulcanization reaction in an argon atmosphere to obtain the target product, namely the two-dimensional high-entropy sulfide. By utilizing the synthesis method of the two-dimensional high-entropy sulfide, the problems of high synthesis temperature, non-uniform element distribution, unstable two-dimensional structure and the like of the two-dimensional high-entropy sulfide can be solved, the phenomena of phase separation, segregation and the like in high-temperature synthesis are avoided, the production cost and the process difficulty are reduced, and the yield of the two-dimensional high-entropy sulfide is improved. A series of high-performance two-dimensional high-entropy sulfide electrolyzed water catalysts are synthesized.

The invention relates to an elementary substance / alloy-metal oxyhydroxide anchored noble metal single atom / cluster heterojunction catalyst. A preparation method comprises the following steps: 1) dissolving a metal salt A, urea and ammonium fluoride in deionized water to obtain a mixed solution B; 2) performing hydrothermal reaction on the mixed solution B and a carrier to obtain a primary sample 1; 3) performing high-temperature calcination on the primary sample 1 in a mixed atmosphere of hydrogen and argon to obtain a primary sample 2; and 4) putting the preliminary sample 2 into a noble metal compound C solution for vacuum impregnation, taking out the sample after impregnation, and drying to obtain the catalyst. According to the scheme, the metal salt A is used as a metal source of a simple substance / alloy, the metal salt A is subjected to hydro-thermal synthesis to form a metal hydroxide and then subjected to high-temperature calcination reduction, the metal salt A is calcined to form the simple substance / alloy, then the simple substance / alloy is soaked in the precious metal compound solution C to form a metal oxyhydroxide, and meanwhile precious metal single atoms / clusters are anchored; the prepared catalyst is high in activity, and the preparation method is simple.

In order to solve the problem that an existing BOE etching solution cannot consider the etching rate, the etching uniformity and the service life of the etching solution at the same time, the invention provides a BOE etching solution which comprises the following components: hydrogen fluoride, ammonium fluoride and a corrosion inhibitor, the corrosion inhibitor comprises a compound shown as a structural formula 1: # imgabs0 # structural formula 1, R1 is selected from substituted or unsubstituted C2-C6 alkyl, and R2 is selected from substituted or unsubstituted C2-C6 ether-containing alkyl. The BOE etching solution provided by the invention has a relatively high silicon oxide / silicon nitride and Si etching selection ratio, can effectively improve the etching uniformity, is beneficial to reducing surface defects, and ensures the flatness and smoothness of an etched surface. In addition, the BOE etching liquid is stable in chemical composition and long in service life.

The invention provides a method for preparing a spinel type catalyst rich in oxygen vacancies under the assistance of magnetization treatment and application of the spinel type catalyst. The synthesis method of the catalyst comprises the following steps: (1) preparing a precursor of the catalyst by adopting a hydrothermal method: putting a metal foam carrier into a mixed solution of metal salt ions such as ferric nitrate, manganous nitrate and cobalt nitrate, adding ammonium fluoride and urea, carrying out hydrothermal reaction, repeating the hydrothermal reaction for several times, and washing and drying to obtain the precursor; and (2) putting the catalyst precursor into a magnetization reactor, putting the magnetization reactor in the center of an alternating magnetic field coil, and carrying out magnetization treatment on the catalyst precursor in an air or oxygen atmosphere to obtain the spinel type catalyst rich in oxygen vacancies. The method is simple in process and low in cost, and the obtained product is uniform in morphology and good in repeatability and has high photo-thermal catalytic oxidation toluene performance. Through a clean, pollution-free and in-situ directional heating electromagnetic induction auxiliary technology, removal of oxygen atoms on the surface of the spinel catalyst is promoted, so that rich oxygen vacancies are introduced into cobalt-manganese spinel, the exchange effect between the catalyst and oxygen molecules is accelerated, and the reaction rate of catalytic oxidation of VOCs is promoted. When the intensity of simulated sunlight is 500 cm <-2 >, the concentration of toluene is 1000 ppm, the air speed is 45000 mL.gcat <-1 >. H <-1 >, the conversion rate of toluene reaches 86% or above, and high-efficiency oxidation of toluene can be realized under the driving of the simulated sunlight.

The invention belongs to the technical field of water electrolysis hydrogen production catalysts, and particularly relates to a preparation method and application of a bimetallic phosphide coupling layered double hydroxide electrocatalyst. The preparation method comprises the following steps: by taking a nickel source, an iron source, ammonium fluoride and urea as reactants, carrying out hydrothermal reaction to form a nickel-iron layered double hydroxide nano-catalyst precursor on a conductive substrate; and carrying out phosphating treatment on the nickel-iron layered double hydroxide nano-catalyst precursor by an electrodeposition method to obtain the bimetallic phosphide coupled layered double hydroxide electrocatalyst. Under the 1M potassium hydroxide solution test condition, the overpotential required by the catalyst is 89 mV when the current density in a linear scanning voltammetry curve is 10 mA cm <-2 >, and the catalyst is high in stability, simple in manufacturing process, energy-saving, suitable for industrial application and capable of being used for large-scale water electrolysis hydrogen production.

The invention discloses a selective etching solution for a titanium and / or copper metal layer of a circuit board and a preparation method of the selective etching solution, and the selective etching solution comprises the following components: 10-20% of persulfate, 4-8% of o-nitrobenzenesulfonate, 0.5-1% of phosphoric acid, 0.2-0.8% of 3-(aminomethyl) pyrazole, 0.3-1.5% of ammonium fluoride, 2-5% of cyclohexanediamine tetraacetic acid, 0.1-0.5% of cyclodextrine and the balance of water. The etching solution can selectively etch a titanium and / or copper metal layer, through selection and cooperation of etching solution components, etching is uniform and stable, taper angle and lateral etching control is good, metal wires are smooth, no metal residues exist, and a good etching solution is provided for the circuit board etching process.

The invention discloses a ruthenium-doped nanoneedle sheet carbon-loaded cobaltosic oxide self-supporting electrode as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing a ruthenium-cobalt precursor from a mixed solution of cobalt nitrate hexahydrate, ammonium fluoride, ruthenium trichloride and urea through a hydrothermal method, drying, and calcining in air to obtain the RCO catalyst grown on the carbon cloth. The catalyst has a nanoneedle sheet type structure, can provide a high-quality reactant transmission channel, shows excellent oxygen evolution reaction electrocatalytic activity and stability in alkali / acidic electrolyte, can be used as an efficient anode catalyst for acid and alkaline solution water electrolysis devices, and has a good market prospect.

The invention discloses a preparation method and application of octahedral cuprous oxide containing defects, and belongs to the technical field of material preparation. In order to solve the problems that in existing cuprous oxide preparation, a defect structure is difficult to accurately regulate and control, and the crystal form uniformity is insufficient, the method comprises the steps that a copper source solution, a glucose solution, a sodium citrate solution and an ammonium fluoride solution with specific concentrations are mixed according to the volume ratio, the pH is adjusted to 10.5-11, then a hydrothermal reaction is conducted, and a target product is obtained through centrifugation, filtration, washing and drying. The method comprises the following specific steps: mixing solutions, reacting in a high-pressure reaction kettle at 140-165 DEG C for 4-6 hours, and realizing octahedral crystal form construction and defect regulation and control by controlling the raw material ratio and reaction conditions. The preparation method is simple in process and high in controllability, and the prepared octahedral cuprous oxide containing defects can serve as a catalyst to be applied to the fields of catalytic decomposition of ammonium perchlorate and the like and has good industrial application prospects.

The invention discloses a catalyst for an n-butene isomerization reaction and a preparation method thereof, and belongs to the technical field of catalysts. The preparation method comprises the following steps: mixing a silicon source, an aluminum source, tetrapropylammonium hydroxide and water, adding boric acid, and crystallizing to obtain a seed crystal; the method comprises the following steps: mixing a silicon source, an aluminum source, pyridine and water, adding a seed crystal and ammonium fluoride, and crystallizing to obtain a core-shell type molecular sieve; adding the core-shell type molecular sieve into the bimetallic complex solution for dipping to obtain a metal-loaded type molecular sieve; adding the metal-loaded molecular sieve into a triethyl phosphine ethanol solution for treatment to obtain a phosphorus-modified molecular sieve; uniformly mixing the phosphorus-modified molecular sieve, pseudo-boehmite, sesbania powder and water, kneading, performing extrusion molding, drying and calcining to obtain the catalyst. The catalyst prepared by the invention is used for n-butene isomerization reaction, and has excellent catalytic activity and isobutene selectivity.

The invention relates to the field of fiber materials, and provides a low-dielectric constant glass fiber and a preparation method thereof, and the low-dielectric constant glass fiber comprises basalt glass fiber and a silicon oxyfluoride layer coating the surface of the basalt glass fiber. The basalt glass fiber is prepared by adopting a melting wire drawing method, the average diameter is 5.0-15.0 microns, and the volume ratio of a crystalline state to an amorphous state is controlled to be (5.0-15.0): (85.0-95.0). The thickness of the silicon oxyfluoride layer is 140-400 nm, and the silicon oxyfluoride layer is obtained through a sol-gel method and is formed by conducting dipping, ultrasonic treatment and purging on tetraethoxysilane and ammonium fluoride sol and then conducting heat treatment in an inert atmosphere. The preparation method comprises the steps of basalt raw material crushing, acid pickling, melting, wire drawing and gradient cooling, and the uniformity and stability of the fibers are ensured. The preparation conditions, impregnation parameters, purging pressure and heat treatment temperature of the modified sol are all optimized, so that uniform coating and stability enhancement are realized. The glass fiber provided by the invention has low dielectric constant and excellent heat resistance and hydrophobicity, and is suitable for the fields of high-frequency electronic substrates, aerospace and 5G communication.

The invention relates to a method for detecting high-content zinc element in ore. The detection method comprises the following steps: adding a zinc-containing ore sample into a mixture of ammonium fluoride, hydrobromic acid, hydrochloric acid, nitric acid and perchloric acid, dissolving, taking melt with hydrochloric acid to obtain a solution to be detected, drawing a zinc standard working curve, detecting the strength of the solution to be detected, and calculating the content value of the zinc element on the zinc standard working curve according to the strength value. According to the scheme provided by the invention, the operation is simple and convenient and the detection result is accurate when the high-content zinc element in the ore is detected.

The invention provides an ultra-pure thorium fluoride production process which comprises the following steps: preparing a nanoscale ThF4.xNH4F precursor through a gas-liquid-solid three-phase reaction, atomizing an ammonium fluoride solution into microdroplets by adopting ultrasonic atomization, and carrying out synergistic reaction with gaseous ammonium fluoride and a liquid-phase thorium nitrate solution; a microwave-plasma synergistic fluorination reaction is adopted, and the precursor is heated in a high-purity inert atmosphere to generate crude thorium fluoride; according to the ultra-pure thorium fluoride production process provided by the invention, the purity of thorium fluoride is remarkably improved through the technical means of preparation of a nanoscale precursor through a gas-liquid-solid three-phase reaction, microwave-plasma synergistic fluorination, multi-stage sublimation combined with graphene-based nano trapping membrane purification, intelligent process control, by-product closed-loop recovery and the like; the impurity content is low, and the requirements of nuclear reactor fuel substrates and high-end optical coatings on ultra-high purity are met. The method has the advantages of high yield, high process stability and small purity fluctuation among batches, and the production efficiency and the product consistency are obviously improved.

The invention belongs to the technical field of fly ash solid waste resource utilization, and particularly relates to a method for preparing flaky alumina by using fly ash, which is characterized by comprising the steps of fly ash pretreatment, intermediate preparation and alumina preparation, ammonium fluoride used in the alumina preparation step is a recycling product of fluorine-containing tail gas in the step, and ammonium fluoride used in the alumina preparation step is a recycling product of fluorine-containing tail gas in the step. The preparation method comprises the following specific operation steps: 1) pretreating fly ash, namely treating fly ash with a NaOH solution and an HCl solution to obtain a mixture of quartz and mullite; (2) preparing an intermediate, namely reacting a mixture of quartz and mullite with CeO2 to obtain a K3Al (SO4) 3 intermediate; and 3) preparing aluminum oxide, purifying the K3Al (SO4) 3 intermediate, grinding and mixing the purified K3Al (SO4) 3 intermediate and ammonium fluoride crystals according to the F / Al molar ratio, and roasting at high temperature to obtain a flaky aluminum oxide product. The method has the beneficial effects that the problem of low purity of flaky aluminum oxide in the existing method for preparing the aluminum oxide from the fly ash is solved, and the purity of the flaky aluminum oxide is 99.2-99.8%.

The invention relates to a preparation method and application of a CoFe2O4 / FeOOH (at) IF self-supporting electrode for efficient electrocatalytic synthesis of ammonia. The invention relates to a preparation method and application of a CoFe2O4 / FeOOH (at) IF self-supporting electrode with high ammonia yield and Faraday efficiency in the field of nano materials. The invention aims to solve the problems of low electrochemical nitrate reduction synthesis ammonia yield and low Faraday efficiency. The preparation method comprises the following steps: taking foam iron (IF), cobalt nitrate hexahydrate, ferric trichloride hexahydrate, urea and ammonium fluoride as raw materials, preparing a CoFeOOH (at) IF precursor material through a one-step hydrothermal reaction, and then successfully preparing the CoFe2O4 / FeOOH (at) IF self-supporting electrode with high ammonia yield and Faraday efficiency through tubular furnace calcination. The CoFe2O4 / FeOOH (at) IF self-supporting electrode can be directly used as a working electrode to electrocatalyze nitrate radicals to reduce and synthesize ammonia.

Provided are a wide-temperature-range solid-state electrolyte, a preparation method thereof and use thereof in solid-state lithium metal batteries. The preparation method includes: dissolving a lithium salt and a magnesium salt in a solvent to obtain a mixed salt solution; and mixing the mixed salt solution with an ammonia fluoride solution, subjecting a resulting mixture to reaction, and subjecting a resulting reaction product to centrifugation, washing, and drying in sequence to obtain magnesium-doped lithium fluoride nanoparticles; and mixing the magnesium-doped lithium fluoride nanoparticles, a liquid plasticizer, a polymer monomer and a thermal initiator to obtain a liquid precursor, and subjecting the liquid precursor to curing to obtain the wide-temperature-range solid-state electrolyte, where the polymer monomer is a mixture of ethoxylated trimethylolpropane triacrylate and hexafluorobutyl methacrylate.

The invention belongs to the technical field of chemical detection, and particularly relates to a method for detecting the content of boron in soil and sediment, which comprises the following detection methods: S1, weighing a sample and putting the sample into a digestion tank; s2, adding a digestion solution into the digestion tank; s3, after uniform stirring, putting the digestion tank into a microwave digestion instrument for microwave digestion; s4, after digestion is completed, closing the microwave digestion instrument, and after the digestion tank is cooled to the room temperature, filtering to remove precipitates; s5, transferring the digestion solution into a volumetric flask, and fixing the volume for subsequent analysis; and S6, analyzing the digestion solution by using ICP-OES / MS (Inductively Coupled Plasma-Optical Emission According to the method for detecting the boron content in the soil and the sediment, ammonium fluoride is used for replacing hydrofluoric acid in boron detection of the soil and the sediment, use of toxic reagents is reduced, mannitol is added, a stable complex is formed by mannitol and boron, and the recovery rate of boron is increased.

The invention discloses a controllable preparation method of a methanol-mediated ammonium fluoride-assisted acetic acid etching zeolite adsorption thermal control coating, and belongs to the field of special functional coatings. The invention aims to solve the problems that a zeolite adsorption coating is low in adsorption capacity in an extreme environment and a microporous structure limits diffusion. Zeolite defects are introduced through ammonium fluoride / methanol etching, and then the hierarchical pore zeolite attached thermal control coating is prepared through acetic acid etching. Methanol is adopted as an etching medium, so that ammonium fluoride can be freely transported in a zeolite channel, in-situ hydrolysis and etching of zeolite are carried out until the ammonium fluoride is in contact with water molecules adsorbed in the zeolite channel, and uniform and controllable etching of the outer surface and the interiors of pores of the zeolite is achieved; and meanwhile, the graded zeolite molecular adsorption coating can realize self-balance of body temperature thermal control by virtue of the strong control capability of the layered and three-dimensional space graded pore channel structure on spectral absorption or emission, so that the heat dissipation capability is greatly enhanced, and the thermal control application of the graded zeolite molecular adsorption coating in spacecrafts is facilitated by virtue of the low-absorption-high-emission performance of the graded zeolite molecular adsorption coating.

The invention discloses a plant-based deodorant and a preparation method thereof, and relates to the technical field of high polymer materials. When the plant-based deodorant is prepared, beta-cyclodextrin reacts with paratoluensulfonyl chloride and then reacts with ethylenediamine, and amino modified cyclodextrin is prepared; the plant-based extract is subjected to inclusion with amino modified cyclodextrin, and a cyclodextrin inclusion compound is prepared; the preparation method comprises the following steps: reacting hydroxyethyl cellulose with methacrylic anhydride to prepare double-bond modified cellulose; carrying out hydrothermal reaction on titanium sulfate, the carboxylated multi-walled carbon nanotube, ammonium fluoride and cerous nitrate to prepare a co-doped titanium dioxide / carbon nanotube; coating the co-doped titanium dioxide / carbon nano-tubes with oleic acid to prepare modified nano-particles; and reacting the double-bond modified cellulose with the cyclodextrin inclusion compound, and then copolymerizing with the modified nanoparticles and the comonomer to obtain the plant-based deodorant. The prepared plant-based deodorant has the advantages of good deodorization effect, slow release and photocatalytic degradation.

The invention discloses a method for treating high-concentration ammonium fluoride wastewater in the electronic industry, which specifically comprises the following steps: firstly, carrying out induced crystallization fluorine resourceful treatment to remove fluoride in the wastewater; performing enzyme catalytic decomposition of hydrogen peroxide to remove hydrogen peroxide in the wastewater; and finally, carrying out integrated anaerobic ammonia oxidation treatment to remove ammonia nitrogen in the wastewater. According to the method disclosed by the invention, a combined process of induced crystallization fluorine recycling, enzyme catalysis hydrogen peroxide decomposition and integrated anaerobic ammonia oxidation is adopted, fluoride removal and fluorine recycling are synchronously realized through an induced crystallization process, and hydrogen peroxide is efficiently removed through an enzymatic reaction; high-efficiency treatment of high-ammonia-nitrogen wastewater is realized through a short-cut nitrification-anaerobic ammonia oxidation process under a low-energy-consumption condition, and the problems of high agent consumption, high sludge yield, high operation cost and low ammonia-nitrogen removal rate of a traditional ammonium fluoride wastewater treatment process (air stripping and chemical coagulation) are solved.

The invention belongs to the technical field of aluminum electrolysis waste recovery treatment, and particularly relates to a method for efficiently recovering aluminum electrolysis waste through an ion recombination technology. The method comprises the following steps: crushing the aluminum electrolysis waste, mixing with the aluminum-containing waste and sulfuric acid, roasting and modifying; mixing and stirring the modified waste and water, and filtering; carrying out impurity removal and concentration on the filtrate, and adding carbonate or phosphate to initiate a lithium precipitation reaction; mixing the filter residue and the filtrate precipitate with an alkaline solution, carrying out an alkaline leaching reaction to prepare a sodium metaaluminate mixed solution, and washing the filter residue with water to obtain a sodium fluoride solution; introducing carbon dioxide into the mixed solution or adjusting the pH value to 10-12 to obtain an aluminum hydroxide precipitate and a sodium carbonate solution; the sodium fluoride solution reacts with ammonia water to prepare an ammonium fluoride solution and sodium hydroxide, ammonium fluoride is used for preparing high-purity aluminum fluoride, and the sodium hydroxide solution is recycled. According to the method, valuable elements such as aluminum, lithium and fluorine in the aluminum electrolysis waste can be efficiently recycled, cyclic utilization of resources is promoted, and environmental pollution is effectively reduced.

The invention relates to the technical field of digestion, in particular to a pretreatment method for digesting a glass substrate. The pretreatment method comprises the following four key steps: firstly, crushing and grinding a glass substrate sample into powder so as to increase the contact area and accelerate the subsequent reaction speed; next, adding a mixture of ammonium bifluoride and ammonium fluoride and the powder sample into a polytetrafluoroethylene beaker, adding a small amount of water for wetting, and then adding concentrated hydrochloric acid and concentrated nitric acid to effectively promote the dissolution of the sample; then, the beaker is placed on a heating plate to be heated and digested, and after it is confirmed that the sample is completely digested by monitoring the state of the solution, the sample is cooled to the room temperature. And finally, transferring the digestion solution to a volumetric flask, rinsing the original beaker for multiple times with pure water, and diluting to a constant volume. According to the method, the digestion time is remarkably shortened, the background interference is reduced, the detection precision is improved, and the method is particularly suitable for the requirements of high-end analysis equipment such as AAS and ICP.

The invention discloses a preparation method of high-purity bis (fluorosulfonyl) imide alkali metal salt. The method comprises the following steps: (1) synthesizing bis (chlorosulfonic acid) imide by taking sulfamic acid, chlorosulfonic acid, thionyl chloride and chlorosulfonic acid isocyanate as raw materials; (2) fluorinating the bis (chlorosulfonic acid) imide by ammonium fluoride to obtain bis (fluorosulfonyl) imide ammonium salt; (3) treating the imidodisulfuryl fluoride ammonium salt solution with a strong acid ion exchange column and concentrating under reduced pressure to obtain imidodisulfuryl fluoride; (4) reacting the alkali metal salt with bis (fluorosulfonyl) imide to obtain bis (fluorosulfonyl) imide alkali metal salt; and (5) carrying out a series of purification processes on the bis (fluorosulfonyl) imide alkali metal salt to obtain the high-purity bis (fluorosulfonyl) imide alkali metal salt. The preparation method has the advantages of mild reaction conditions, low danger coefficient in the technological process, easiness in control, no use and generation of corrosive acid, greenness and environmental protection, and high yield and high purity of the bis (fluorosulfonyl) imide alkali metal salt, and is suitable for large-scale industrial application.

The invention belongs to the technical field of new energy batteries, and particularly relates to a method for preparing sodium tetrafluoroborate. The method uses relatively cheap and readily available ammonium fluoride, sodium bicarbonate, and boron trichloride gas as raw materials, wherein ammonium fluoride and sodium bicarbonate are added to an organic solvent and stirred uniformly to obtain a dispersion, boron trichloride gas is introduced, the dispersion is fully reacted, nitrogen is purged from the reaction liquid, and the filtrate is filtered to obtain a filtrate, which is concentrated, crystallized, filtered, washed, and dried to obtain sodium tetrafluoroborate. The method has the advantages of simple process, rapid and thorough reaction, no water by-product, and reduced preparation cost of sodium tetrafluoroborate while achieving a yield and purity equivalent to or even superior to that of existing sodium tetrafluoroborate.