526 results about "Phosphide" patented technology

The invention relates to the technical field of biodiesel hydrogenation catalysts, and particularly discloses a hydrogenation catalyst of organic bentonite loaded cerium-zirconium solid solution and nickel-molybdenum phosphide as well as a preparation method and application of the hydrogenation catalyst. The hydrogenation catalyst with the organic bentonite loaded with the cerium-zirconium solid solution and the nickel-molybdenum phosphide comprises an organic bentonite carrier, the cerium-zirconium solid solution and the nickel-molybdenum phosphide, the loading capacity of the cerium-zirconium solid solution on the organic bentonite carrier is 2-2.5 wt%; the cerium-zirconium solid solution comprises cerium dioxide and zirconium dioxide; the loading capacity of the nickel molybdenum phosphide on the organic bentonite carrier is 10-15 wt%; and the nickel molybdenum phosphide is Ni2Mo3P. The organobentonite carrier provides an acid site and promotes deoxidation path optimization, the layered structure of the organobentonite carrier can limit the cerium-zirconium solid solution and the nickel-molybdenum phosphide, and organic groups are also embedded into the layered structure, so that the organic compatibility of the organobentonite carrier to biodiesel is improved, and the catalytic efficiency is improved. The cerium-zirconium solid solution provides oxygen vacancies, promotes hydrogenation / deoxidation, and improves the thermal stability and sintering resistance of the catalyst.

The invention relates to a preparation method of a high-activity transition metal phosphide catalyst, which comprises the following steps: taking basic nickel cobalt carbonate (NiCo-OH / NF) grown on foamed nickel in situ as a precursor, placing the precursor at the downstream of a tubular furnace, placing NaH2PO2 at the upstream of the tubular furnace, annealing in a nitrogen atmosphere at 350 DEG C for 2 hours, and naturally cooling to obtain NiCoP / NF; the preparation method comprises the following steps: soaking NiCoP / NF in a potassium salt solution of a boride, washing, and carrying out vacuum drying to obtain a boron-potassium modified catalyst precursor NiCoP-BK / NF; in a three-electrode system, electrodeposition is carried out in an electrolyte containing a Ni source, a Fe source and deionized water, and the high-activity transition metal phosphide-nickel iron hydroxide NiCoP-BK-coated NiFe-LDH / NF heterojunction composite catalyst is obtained. The activity and stability of the transition metal phosphide catalyst can be remarkably improved, and the preparation method is simple and low in cost.

The invention provides a biological magnesium alloy micro-arc oxidation coating supercritical hole sealing method based on a thermodynamic sedimentary phase diagram, which comprises the following steps: establishing deposition-dissolution balance of metal ion phosphide and hydroxide of a phosphate conversion film in a supercritical carbon dioxide environment at different pH values to obtain the thermodynamic sedimentary phase diagram; selecting a NaH2PO4 solution according to a thermodynamic sedimentary phase diagram, and adding NaHCO3 to obtain a hole sealing solution; the hole sealing solution is injected into a reaction kettle to be heated, and then a refrigerator is started to convert generated carbon dioxide gas into supercritical carbon dioxide; and the biological magnesium alloy subjected to micro-arc oxidation is placed in the hole sealing solution in the reaction kettle to be pressurized, and holes of the micro-arc oxidation coating on the surface of the biological magnesium alloy are sealed. The invention provides a supercritical hole sealing method for a biological magnesium alloy micro-arc oxidation coating based on a thermodynamic sedimentary phase diagram. And the hole sealing effect is good.

The invention discloses a coal tar hydrogenation catalyst as well as a preparation method and application thereof. The catalyst comprises a carrier and an active metal component, wherein the carrier is a gallium modified silicon-aluminum carrier; in the gallium modified silicon-aluminum carrier, based on the mass of the gallium modified silicon-aluminum carrier, the mass content of gallium oxide is 2.0%-5.0%, the mass content of silicon dioxide is 20.0%-60.0%, and the mass content of aluminum oxide is 35.0%-78.0%; the active metal component comprises Mo and a group VIII metal element; the Mo comprises + 5 valence Mo; the group VIII metal element exists in the catalyst in the form of metal phosphide. The catalyst has high hydrogenation activity, appropriate cracking activity and good stability, and effectively improves the quality and yield of coal tar hydrogenation product oil.

The invention relates to composition and preparation of a thick-film copper conductor sintered at different temperatures and different atmospheres, and belongs to the field of chemical preparation. Comprising the following steps: mixing 65-85% of copper powder, 3.0%-15.0% of glass, 15.0%-35.0% of an organic adhesive and 0.1-1.5% of an additive which is one or more of titanium trioxide or stannous oxide, cuprous oxide and copper oxide, rolling into slurry, and sintering at 850-950 DEG C under the protection of nitrogen or ammonia gas to obtain a copper conductor. The medium-temperature copper paste is prepared by the following steps: mixing 60.0-85.0% of copper powder, 3.0-13.0% of glass, 8.0-25.0% of an organic adhesive and 0.2-1.6% of an additive which is one or more of titanium sesquioxide or stannous oxide, cuprous oxide and copper oxide, rolling into paste, and sintering at 450-650 DEG C under the protection of nitrogen or ammonia gas to obtain a copper conductor. The low-temperature copper paste is prepared by mixing 60.0-85.0% of copper powder, 3.0-13.0% of glass, 8.0-25.0% of an organic binder and 0.1-2.0% of an additive which can be one or more of elemental elements of magnesium, zinc, boron and phosphorus or one or more of nickel phosphide, nickel boride, copper phosphide and copper oxide, rolling the mixture into paste, and sintering the paste in air at 250-350 DEG C to obtain a copper conductor.

A composite positive electrode material precursor, a preparation method therefor and a use thereof. The composite positive electrode material precursor comprises a porous iron phosphate core, a carbon-coated inner layer covering the surface of the core and doped with metal phosphide, and an iron phosphate-coated outer layer covering the surface of the carbon-coated inner layer; and at least part of the carbon-coated inner layer is arranged in pores of the porous iron phosphate core. The surface and pores of the porous iron phosphate core are provided with the carbon-coated inner layer doped with the metal phosphide, so that the electrical conductivity of the material can be significantly improved, the use of conductive carbon is reduced, and the tap density can be prevented from being greatly reduced while improving the rate performance and low-temperature performance of the material. In addition, forming the iron phosphate-coated outer layer on the surface of the carbon-coated inner layer effectively avoids direct contact between the metal phosphide and an electrolyte and reduces side reactions, thereby improving the cycle performance of lithium ion batteries.

The invention belongs to the technical field of water electrolysis hydrogen production catalysts, and particularly relates to a preparation method and application of a bimetallic phosphide coupling layered double hydroxide electrocatalyst. The preparation method comprises the following steps: by taking a nickel source, an iron source, ammonium fluoride and urea as reactants, carrying out hydrothermal reaction to form a nickel-iron layered double hydroxide nano-catalyst precursor on a conductive substrate; and carrying out phosphating treatment on the nickel-iron layered double hydroxide nano-catalyst precursor by an electrodeposition method to obtain the bimetallic phosphide coupled layered double hydroxide electrocatalyst. Under the 1M potassium hydroxide solution test condition, the overpotential required by the catalyst is 89 mV when the current density in a linear scanning voltammetry curve is 10 mA cm <-2 >, and the catalyst is high in stability, simple in manufacturing process, energy-saving, suitable for industrial application and capable of being used for large-scale water electrolysis hydrogen production.

The invention discloses a preparation method of a high-entropy phosphide nanotube, which successfully prepares a nanotube phosphide with a high-entropy structure by adopting a hydrogen bond organic framework (HOF)-metal organic framework (MOF) template conversion method. In the preparation process of the material, a core-shell structure (HOF (MOF)) is firstly formed, the core gradually disappears through a diffusion mechanism, and finally, the material is converted into a hollow nanotube structure which is uniform and controllable in size. According to the hollow structure, the specific surface area is remarkably increased, more active sites are provided, the transmission path of reactant molecules is optimized, and the electro-catalytic performance is greatly improved. Besides, the overall tubular morphology of the material is uniform, the size is controllable, and compared with a traditional granular material, the specific surface area is remarkably increased, so that more reaction sites are exposed in the external environment, and the catalytic efficiency and the reaction rate of the material in an electro-catalytic reaction are greatly improved.

The invention discloses a hydrocracking catalyst as well as a preparation method and application thereof. The catalyst comprises a carrier and an active metal component, the carrier comprises a modified Y molecular sieve and aluminum oxide, and the modified Y molecular sieve has the following properties: the crystal particle size is 500 nm or less, the molar ratio of silicon oxide to aluminum oxide is 8-55, the specific surface area is 640-800 m < 2 > / g, the unit cell parameter is 2.433-2.460 nm, and the average pore size is 10-30 nm; the active metal component comprises Mo and a group VIII metal element; the Mo comprises + 5 valence Mo; the group VIII metal element exists in the catalyst in the form of metal phosphide. The catalyst has excellent isomerization performance and aromatic hydrocarbon conversion capability, and is suitable for a hydrocracking process for producing special oil and lubricant base oil.

The invention provides a multifunctional carbon fiber lithium battery based on a sulfide composite electrolyte membrane and a preparation method and application of the multifunctional carbon fiber lithium battery, and belongs to the technical field of lithium batteries and functional composite materials. According to the invention, a nitrogen phosphide interface layer is constructed on the surface of a sulfide electrolyte membrane or a nitrogen phosphide derivative is dispersed in a bulk phase, so that the stability of an electrolyte and a metal lithium interface is effectively improved, and lithium dendrites are inhibited; and by combining the multifunctional characteristics of the carbon fiber and glass fiber woven cloth, high specific energy and light weight can be realized, the overall safety and mechanical strength are enhanced, and the composite material is suitable for various high-performance energy storage occasions.

The invention provides a preparation method of a molybdenum phosphide / titanium nitride composite material and a battery positive electrode material and a lithium-carbon dioxide battery, and belongs to the technical field of new energy materials. And then a titanium nitride conductor layer is deposited on the molybdenum phosphide by using an atomic layer deposition technology to prepare the molybdenum phosphide / titanium nitride, the molybdenum phosphide is combined as a transition metal phosphide to have stable catalytic performance, and the titanium nitride is used as a conductor to have excellent conductivity. The lithium-carbon dioxide battery positive electrode catalyst with high catalytic activity, high conductivity and excellent stability is obtained through the synergistic effect of the two materials, and when the lithium-carbon dioxide battery positive electrode catalyst is applied to a lithium battery, higher energy density, longer cycle life and better rate capability are shown, so that the overall performance of the battery is improved, and the application prospect is wide. The requirements on high-performance batteries in the fields of electric automobiles, energy storage systems and the like are met.

The invention relates to the technical field of batteries, and discloses a secondary battery, a battery device and a power utilization device. The secondary battery comprises a positive electrode plate, the positive electrode plate comprises a positive electrode film layer, the positive electrode film layer comprises a positive electrode active material, the positive electrode active material comprises an inner core and a coating structure coating the surface of the inner core, and the coating structure comprises conductive phosphide and carbon. According to the secondary battery provided by the embodiment of the invention, by introducing the coating structure jointly formed by the conductive phosphide capable of assisting in improving the electronic conductivity and the carbon, the electronic conductivity of the positive electrode active material can be improved while the positive electrode active material has relatively high compaction density without increasing the content of a carbon layer; therefore, the volume energy density and the rate capability of the secondary battery can be improved.

The embodiment of the invention discloses a nano composite material and a preparation method, a use method and a device thereof, and the nano composite material is characterized by comprising a first nano particle and a second nano particle which are combined; the first nano-particles are transition metal nano-particles, and the second nano-particles are one or a combination of the following materials: lithium nitride nano-particles, lithium oxide nano-particles, lithium phosphide nano-particles, lithium selenide nano-particles and lithium sulfide nano-particles. The nano composite material can be subjected to magnetic regulation and control under low voltage, and high-speed and high-density electronic spin information storage is realized.

The invention relates to the technical field of catalyst processing, and discloses a high-activity transition metal phosphide electrolyzed water catalyst and a preparation method thereof, and the high-activity transition metal phosphide electrolyzed water catalyst comprises the following components by weight: 1-3 parts of cobalt chloride hexahydrate; 0.5 to 1.5 parts of ruthenium trichloride; 0.5 to 1.5 parts of iridium chloride (III) hydrate; 1-2 parts of copper sulfate pentahydrate; 2 to 4 parts of sodium hypophosphite; 1 to 2 parts of urea; 1 to 2 parts of glucose; 1-2 parts of sodium sulfide nonahydrate; 0.5 to 1 part of crystalline aluminum chloride; 50 to 100 parts of deionized water; and 0.1 to 0.5 part of hexadecyl trimethyl ammonium bromide. By introducing the plasma auxiliary treatment technology, the electronic structure of the catalyst is optimized, the conductivity and stability of the catalyst are improved, and the efficiency and durability of hydrogen production through water electrolysis are enhanced.

The invention discloses a fireproof coated pipe as well as a preparation method and application thereof, and relates to the field of organic composite materials. The fireproof coated pipe comprises a mother blank material and a liquid waterproof agent, wherein the mother blank material comprises a flame-retardant polymer matrix, coated graphite and a heat-conducting filler; the coated graphite is formed by expanded graphite and a coating layer on the surface, and the coating layer comprises a silicon source and a phosphorus source. The surface of the expanded graphite is coated with the silicon dioxide-phosphide composite material, so that the compatibility of the filler and a specific type of flame-retardant polymer matrix can be improved, the addition amount of the heat-conducting filler is reduced to ensure uniform dispersion, and synergistic multiplication of a flame-retardant function and optimization of a heat-conducting network are realized; meanwhile, a specific type of liquid waterproof agent is introduced and is extruded and blended with the master batch, so that the material is endowed with excellent waterproofness, meanwhile, the compatibility with other core properties is ensured, the waterproof coated pipe material with efficient heat conduction, flame retardance, waterproofness and mechanical strength is provided, and the application field is expanded.

A nickel iron phosphide / nickel molybdate core-shell structure composite electrode material, the nickel iron phosphide / nickel molybdate core-shell structure composite electrode has a nickel foam substrate, and the nickel foam substrate has an array of nickel iron phosphide / nickel molybdate core-shell structure. The present invention also relates to a preparation method of the electrode, comprising the following steps: first pre-treating the nickel foam substrate to remove oxides and impurities on the surface of the nickel foam substrate; placing the nickel foam in a reactor for hydrothermal treatment by an in-situ growth method to obtain a nickel molybdate precursor with a cubic array structure; then placing the nickel molybdate precursor in a potassium ferrocyanide solution for ion exchange to obtain a nickel iron Prussian blue / nickel molybdate composite electrode; finally, placing the nickel iron Prussian blue / nickel molybdate composite electrode in a tubular furnace, phosphating under an argon atmosphere, and obtaining a nickel iron phosphide / nickel molybdate core-shell structure composite electrode. The preparation method of the present invention is simple, and the prepared nickel iron phosphide / nickel molybdate core-shell structure composite electrode has significantly improved electrochemical performance and stability compared with a single phosphide electrode.

The invention belongs to the field of soil remediation materials, and particularly relates to a humic acid composite remediation material for a coal chemical industry polluted site and a preparation method of the humic acid composite remediation material. The method comprises the following steps: 1) uniformly mixing raw materials, alkali liquor and phosphide, standing, taking supernate, adding acid liquor to adjust the pH value of a system, and performing suction filtration to obtain a humic acid solution; 2) drying the solid obtained by the standing operation in the step 1), adding an acid solution, uniformly mixing, filtering, cleaning, adding a strong acid for corrosion, filtering again, cleaning, and drying to obtain a base material; and (3) heating the organic raw material, the emulsifier and the solvent, adding the mixed solution of the acyclic carboxylic acid and the humic acid solution while keeping stirring, adding the initiator, performing thermal reaction, adding the base material while being hot, uniformly mixing, drying and grinding to obtain the humic acid composite repair material. The humic acid composite remediation material can effectively improve the structure and quality of soil and effectively improve the soil remediation efficiency.

The invention provides a high-activity catalyst for producing hydrogen by electrolyzing water as well as a preparation method and application of the high-activity catalyst. Specifically, the catalyst for producing hydrogen by electrolyzing water comprises: a carbon sintered body carrier; the active components are loaded on the surface and inside the carbon sintered body carrier, the active components comprise nickel molybdenum nitride (NiMoN), cobalt phosphide (CoP) and cerium oxide, and the catalyst has a porous structure. The catalyst is low in cost, high in activity and good in stability, the cost of hydrogen production through water electrolysis can be effectively reduced, and the hydrogen production efficiency is improved.

The invention belongs to the technical field of battery negative electrode materials, and particularly relates to a phosphorus-based negative electrode material with a coating structure as well as a preparation method and application of the phosphorus-based negative electrode material. On the basis of the prior art, nano nickel phosphide, red phosphorus and carbon nanospheres are subjected to ball milling to prepare a main body phosphorus-based material, and then the main body phosphorus-based material is coated with a coating layer prepared from a nanofiber material, pyrrole and 5-azaindole, so that the coating layer of the phosphorus-based negative electrode material has elasticity, the volume expansion rate of the phosphorus negative electrode material is reduced, and the service life of the phosphorus negative electrode material is prolonged. According to the nickel phosphide-based negative electrode material and the preparation method thereof, the interface interaction between the phosphorus-based negative electrode material and the binder is enhanced, the prepared nickel phosphide grows on the black phosphorus nanosheet, so that the nickel phosphide has good dispersity, the nickel phosphide nanocrystals can be effectively prevented from being agglomerated, and the energy storage capacity of the nickel phosphide is improved; and after the 5-hydroxy vanillin is grafted, the adhesive has excellent wet adhesion resistance, and can prevent the dissolution of phosphorus element, so that the cycle efficiency of the electrode is improved.

The present invention relates to a precursor for the production of an alloy used as a catalyst. The precursor comprises a metallic substrate, a layered structure comprising binders, metallic particles, and at least one metal oxide, metal phosphide, and / or metal sulfide, wherein the layered structure is arranged on the metallic substrate.

The invention relates to a layered composite electrode and a preparation method and application thereof. The electrode takes foamed nickel as a substrate layer, a layer of manganese phosphide is grown on the surface of the foamed nickel by adopting a hydrothermal method, then Co oxide is deposited on the surface of the manganese phosphide layer by adopting a cyclic voltammetry (CV) electrodeposition technology, and the CozO / MnyPx / NF electrode is obtained after cleaning and drying, and the catalyst on the surface of the CozO / MnyPx / NF electrode is of a nanosheet structure. Lattice distortion of the MnxP nano material is induced through a Co and O double-doping strategy, the electronic structure of the MnxP nano material is optimized, and the oxygen vacancy content is increased, so that the oxygen evolution performance of the catalyst is improved.

The invention discloses a residual oil hydrogenation carbon residue removal catalyst as well as a preparation method and application thereof. The catalyst comprises a carrier and an active metal component, the carrier is aluminum oxide containing silicon and gallium; on the basis of the weight of the catalyst, the mass content of the carrier is 74%-83%, the content of the group VIII metal in terms of oxide is 2%-6%, and the content of molybdenum in terms of oxide is 15%-24%; the active metal component comprises Mo and a group VIII metal element; the Mo comprises + 5 valence Mo; the group VIII metal element exists in the catalyst in the form of metal phosphide. The catalyst has good hydrogenation carbon residue removal performance, can deeply remove polycyclic aromatic hydrocarbon and heterocyclic aromatic hydrocarbon in residual oil and reduce precursors of carbon residues, and has good stability.

The invention belongs to the technical field of electro-catalysis water decomposition, and relates to a self-supporting W-NiCoP / NF composite material and a preparation method and application thereof. Cobalt salt, terephthalic acid, acetic acid and foamed nickel are subjected to a first solvothermal reaction, and defect type Co-MOF / NF is obtained; immersing the defect type Co-MOF / NF into a tungstate solution, and then carrying out a second solvothermal reaction to obtain a defect type W-Co-MOF / NF precursor; and carrying out phosphating heat treatment on the defect type W-Co-MOF / NF precursor and a phosphorus source in an inert atmosphere to obtain the W-Co-MOF / NF composite material. According to the preparation method disclosed by the invention, the tungsten-doped nickel-cobalt bimetallic phosphide with rich defect structures is successfully constructed on the foamed nickel substrate through a step-by-step solvothermal and gas-phase phosphating strategy, so that organic combination of a bimetallic synergistic effect and defect engineering is realized; the prepared self-supporting composite material has more active sites, a better electronic structure regulation effect and better stability.

The invention relates to the field of electro-catalysis new materials, and provides a biomass-based carbon-supported iron phosphide nano-catalyst and a preparation method and application thereof.According to the technical scheme, waste pomelo peel biomass is fully utilized, the stability and conductivity of a metal phosphide catalyst are improved, phytic acid is used as a phosphorus source for green synthesis of metal phosphide, and the metal phosphide is recycled. The problems of high energy consumption and high pollution in a traditional ammonia synthesis process are solved through an electro-catalysis technology, the technical and use requirements in actual production are met, and a brand-new ammonia synthesis way is provided.

The invention discloses a NiMoO4 / Ni (OH) 2 (at) NiPx layered structure catalyst as well as a preparation method and application of the NiMoO4 / Ni (OH) 2 (at) NiPx layered structure catalyst. The preparation method of the catalyst comprises the following steps: step 1, cleaning the nickel substrate; step 2, synthesizing a nickel molybdate (NiMoO4) precursor on the nickel substrate through a hydrothermal method; and step 3, growing a nickel hydroxide and nickel phosphide compound (Ni (OH) 2 and NiPx) on the surface of NiMoO4 through an electro-deposition method. The catalyst has a three-dimensional layered structure, a one-dimensional NiMoO4 micron / nanorod is used as a support, a two-dimensional Ni (OH) 2 nanosheet grows on the surface of NiMoO4, and zero-dimensional NiPx nanoparticles are embedded on the Ni (OH) 2 nanosheet. The catalyst shows excellent performance in hydrogen evolution reaction, has high activity and good stability, and is suitable for clean hydrogen production.

The invention relates to a negative active material and a preparation method thereof, a negative pole piece and a sodium ion battery. The negative electrode active material comprises a core-shell structure metal phosphide, and the core-shell structure metal phosphide comprises: an inner core, which comprises a bimetal phosphide derived from a Prussian blue compound; the shell layer covers at least part of the surface of the inner core, and the shell layer comprises metal phosphide. According to the negative electrode active material provided by the invention, through the synergistic effect of the bimetal phosphide derived from the Prussian blue compound in the inner core and the metal phosphide of the shell layer, the cycle performance and the rate capability of the battery are improved.

The invention belongs to the technical field of water electrolysis hydrogen production, and discloses a square meter grade stainless steel surface in-situ growth bimetallic phosphide integrated electrode and a preparation method and application thereof.The preparation method comprises the following steps that 1, a stainless steel substrate is subjected to ultrasonic cleaning with deionized water, acetone and ethyl alcohol in sequence and then heated and cleaned with a diluted hydrochloric acid solution, and the stainless steel substrate is dried; and finally, washing with deionized water to obtain a stainless steel substrate with a clean surface. (2) dissolving a phosphorus source and transition metal cation salt in an aqueous solution, and stirring at normal temperature to uniformly mix; and (3) putting the stainless steel mesh with the clean surface obtained in the step (1) into the metal salt solution obtained in the step (2) for heating reaction, washing an obtained sample with water after the reaction is finished, and drying. The preparation method has the advantages that the preparation process is simple, the cost is low, the reaction problem is low, the prepared integrated electrode has excellent electrocatalytic activity and stability, large-scale preparation can be achieved, and the integrated electrode is suitable for large-scale industrial hydrogen production through alkaline electrolysis of water.

The invention provides a method for detecting the content of ferrous phosphide in lithium iron phosphate, and belongs to the technical field of chemical analysis. The detection method comprises the following steps: soaking a lithium iron phosphate sample in hydrochloric acid to dissolve lithium iron phosphate to obtain a mixed solution; then carrying out solid-liquid separation, and cleaning solid substances; the cleaned solid matter is digested with nitric acid, and a digestion solution is obtained; and detecting the contents of Li < + > and Fe < 3 + > in the digestion solution, and calculating to obtain the content of ferrous phosphide in the lithium iron phosphate. The detection method provided by the invention has the advantages of stable and accurate detection result, low consumption of samples and short detection period.

The invention discloses an efficient and stable multifunctional catalyst and a preparation method thereof. The multifunctional catalyst is a carbon-based loaded bimetallic nanoparticle catalyst. The carbon base is a carbon fiber composite carbon nanotube; the bimetallic nano particles are one of Fe-Co nano particles, Fe-Ni nano particles and Co-Ni nano particles; and the carbon base is also loaded with metal nitride and metal phosphide. The carbon fiber composite carbon nanotube as a carrier has high porosity and large specific surface area, mass transfer in the electro-catalysis process can be promoted, MOOH / MOH bonds capable of improving the OER activity can be more easily formed on the surfaces of bimetallic nanoparticles, metal heteroatom bonds in metal nitride and metal phosphide can reduce the binding energy of intermediates in ORR, and the service life of the metal nitride and metal phosphide is prolonged. The catalyst can improve the reaction activity of ORR, is an effective ORR / OER active substance, and can be combined to obtain a stable multifunctional catalyst with efficient catalytic activity.

The invention belongs to the technical field of catalyst preparation, and provides an iron-nickel-phosphorus catalyst, a preparation method and application thereof, and a method for producing an aqueous hydrogen peroxide solution through electro-catalysis. The preparation method comprises the following steps: mixing nickel chloride, ferric chloride, elemental phosphorus and alcohol amine, and carrying out solvothermal reaction to obtain the iron-nickel-phosphorus catalyst. The iron-nickel-phosphorus catalyst containing iron phosphide, nickel phosphide and iron-doped nickel phosphide is obtained by taking a nickel salt, an iron salt, a phosphorus simple substance and a reducing solvent as raw materials and carrying out solvothermal reaction. The iron-nickel-phosphorus catalyst obtained by the invention can efficiently generate hydrogen peroxide through electro-catalysis in an electrolyte with the pH value of 5-9, so that the pH value range of the prepared hydrogen peroxide aqueous solution is wide, and the application range and field are wider; compared with selenium-doped cobalt phosphide in the prior art, the prepared hydrogen peroxide aqueous solution is wider in application.