The invention relates to an
asphalt-based porous hard carbon material prepared under assistance of
chloride addition and a preparation method of the
asphalt-based porous hard carbon material, and belongs to the field of
alkali metal ion battery negative
electrode materials. The method aims at solving the problems that an
existing treatment method for preparing a hard carbon material by taking
asphalt as a
raw material is tedious and high in cost. The preparation method of the asphalt porous hard carbon material comprises the following steps: mixing hard carbon precursors (pure asphalt, pre-oxidized asphalt, pre-carbonized asphalt and the like) and
chloride according to a ratio, and synthesizing a sample through a
solid sintering method. According to the hard carbon material, a large number of micropores and mesopores of 2 nm and below are introduced into a
carbon matrix of the hard carbon material to serve as storage point locations of
sodium ions, so that the hard carbon negative
electrode material with a highly disordered structure is obtained, higher capacity and rate capability (219-350 mAh g <-1 >) are obtained, the first-circle coulombic efficiency is 70-80% under the
current density of 2Ag <-1 >, and the capacity
retention rate is 70-78% after 400 cycles. According to the preparation method, the charge-
discharge capacity and the
cycling stability of the hard carbon material can be improved, and asphalt is adopted as a hard carbon precursor and is rich in source and low in cost.