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490results about How to "High porosity" patented technology

Cellulose composite microsphere and preparation method thereof

The invention discloses a cellulose composite microsphere, a preparation method thereof and application. The particle size of the cellulose composite microsphere is 1mum-1200mum, the specific surface area of the cellulose composite microsphere is 100m<2>/g-500m<2>/g, and the aperture of the cellulose composite microsphere is 200nm-900nm. The preparation method comprises the following steps of: preparing a mixture solution of cellulose and a composite material by using the cellulose as a matrix, a polymer material as composite material and a water solution of alkali/urea or alkali/thiourea as a solvent, and obtaining the cellulose composite microsphere through sol-gel phase transition and cross-linking agent cross linkage. The advantages of cellulose microsphere are reserved by the cellulose composite microsphere, and due to the adding of the composite material, new functional groups are simultaneously added for the surface of the microsphere and further decoration and modification are facilitated. An organic solvent used in the preparation method disclosed by the invention can be reused, the whole preparation technology is simple, low in time consuming, undemanding for equipment and convenient for industrial production, and the prepared cellulose composite microsphere has a good flow property and mechanical property and a wide application.
Owner:CHONGQING CHINA TOBACCO IND CO LTD +1

Nano iron nitride-carbon composite catalyst for positive electrode of lithium-air battery and preparation method of composite catalyst

The invention relates to a nano iron nitride-carbon composite catalyst for a lithium-air battery and a preparation method of the composite catalyst. The method comprises the steps of feeding iron salt, organic ligand and a surface active agent into a solvent, and carrying out heating reflux; mixing the obtained nano-sized mesoporous metal organic framework complex and a nitrogenous organic compound, and carrying out heat treatment on the mixture in the presence of ammonia gas to realize carbonization and nitridation by one step. The catalyst is formed by compounding nanoscale primary iron nitride particles and carbon material; carbon covers and partly covers the surfaces of the nanoscale primary iron nitride particles; rich mesoporous gaps exist among the stacked nanoscale primary iron nitride particles. The rich mesoporous structure of a precursor is maintained by the catalyst, the catalyst has large specific surface area and high porosity, and is beneficial to diffusing oxygen molecules into the catalyst material particles, so that the contact between oxygen and the catalyst is promoted, and the utilization rate of the catalyst is increased; the electrical conductivity is effectively improved by the carbon material on the surfaces of the particles; the nano iron nitride-carbon composite catalyst is good in stability, so that the catalytic performance is well exerted. The charge and discharge polarization of the lithium-air battery is effectively reduced; furthermore, the method is simple and convenient, the operation is easy, the cost is low, and large-scale production can be easily implemented.
Owner:CENT SOUTH UNIV

Kevlar nano fiber porous membrane, and preparation method and application thereof

The invention belongs to the technical field of fiber membranes, and discloses a Kevlar nano fiber porous membrane which has high strength, high temperature resistance and solvent resistance, and a preparation method and application thereof. The preparation method comprises the following specific steps: dissolving Kevlar fibers in organic solvent, adding assistants and strong alkali, heating, and stirring to disperse, thus obtaining a Kevlar nano fiber dispersion; adding a pore forming agent into the dispersion, uniformly stirring to from a membrane casting solution, and performing vacuum degassing for later use; forming the membrane casting solution into a membrane on a glass plate through blade coating, evaporating the solvent, putting into a gel bath to obtain a gel membrane, and soaking in water; and performing heat treatment on the soaked gel membrane to obtain the Kevlar nano fiber porous membrane having high strength, high temperature resistance and solvent resistance. According to the invention, the Kevlar fibers are dispersed into nano fibers and then formed into the membrane through a mild method, so that the excellent properties of high strength, high modulus and solvent resistance are reserved; and a three-dimensional porous structure is endued. Thus, the Kevlar nano fiber porous membrane is applicable to water treatment in a harsh environment.
Owner:GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI

Asymmetrically-structural ceramic ultrafiltration membrane and preparation method thereof

The invention relates to an asymmetrically-structural ceramic ultrafiltration membrane and a preparation method thereof, wherein the preparation method thereof comprises the steps: dispersing one-dimensional fibrous material in sol and sufficiently mixing the material with the gel; by adding deionized water, controlling the weight ratio of gel particle to fiber in membrane preparing solution in a range from 0.01 to 0.4, adjusting pH value of the solution, adding dispersing agent, thickening agent and defoaming agent to formulate the membrane preparing solution, coating membrane on a porous support body and drying the porous support body to form a transition layer; coating the gel-containing membrane preparing solution on the surface of the transition layer, air-drying, oven-drying and roasting the wet membrane, and naturally cooling the membrane to result in the asymmetrically-structural ceramic ultrafiltration membrane. Since the transition layer is composed of fiber and sintering is promoted through the gel, resistance of the transition layer is advantageously lessened and interior combination strength of the transition layer is enhanced; the fiber-constructed transition layer divides large pores into small pores to provide larger total porosity and flowing pore channel, thus high permeation flux is maintained while high selectivity is obtained.
Owner:NANJING UNIV OF TECH

Preparation method of waterproof and moisture permeable fabric membrane, waterproof and moisture permeable fabric and preparation method of membrane

The invention provides a preparation method of a waterproof and moisture permeable membrane. The preparation method comprises the following steps: dissolving a hydrophobic polymer in a first spinning solvent to obtain a hydrophobic spinning liquid; carrying out first electrostatic spinning on the hydrophobic spinning liquid to obtain a monolayer waterproof and moisture permeable membrane; or dissolving a hydrophilic polymer in a second spinning solvent to obtain a hydrophilic spinning liquid; carrying out second electrostatic spinning on the hydrophilic spinning liquid to obtain a hydrophilic nanofiber membrane; and compositing the monolayer waterproof and moisture permeable membrane and the hydrophilic nanofiber membrane to obtain the double-layered waterproof and moisture permeable membrane. The method provided by the invention is simple in process flow, low in energy consumption and high in production efficiency, and is suitable for industrial production. The waterproof and moisture permeable membrane obtained by the method provided by the invention has extremely high porosity and a small gap size, and gaps are zigzag holes rather than through holes, thus facilitating pass of water vapor molecules but blocking pass of water drops. Therefore, the waterproof and moisture permeable fabric has high hydrostatic pressure resistance, ventilation, moisture permeability and mechanical strength.
Owner:ZHEJIANG WEIXING IND DEV

Lithium-sulfur battery anode material comprising porous metal and preparation method thereof

ActiveCN102723470ALarger than surfaceHigh porosityCell electrodesLithium sulfideLithium–sulfur battery
The invention discloses lithium-sulfur battery anode material comprising porous metal. The porous metal is compounded with lithium sulfide so as to be used as the anode material of the lithium-sulfur battery. The invention also discloses a preparation method of the lithium-sulfur battery anode material comprising the porous metal. According to the invention, by utilizing the characteristics of high electric conductivity, high porosity, high specific surface area and the like of the porous metal, elemental sulfur or the lithium sulfide is filled into pores of the porous metal, metal/sulfur composite material can be manufactured, and the utilization rate of the elemental sulfur and the lithium sulfide and the multiplying performance of the composite electrode can be increased; and simultaneously, by utilizing the strong interaction between the porous metal and the elemental sulfur or the lithium sulfide, the elemental sulfur, the lithium sulfide or polysulfide generated in a charge-discharge process can be more firmly attached on the surface of the porous metal, the dissolution of the polysulfide in an electrolyte, the shuttle effect caused by the dissolution of the polysulfide in the electrolyte and the deactivation on an anode and a cathode by redox product of the polysulfide can be restrained, and the circulation stability of a metal/sulfur composite electrode and the lithium-sulfur battery can be increased.
Owner:INST OF PHYSICS - CHINESE ACAD OF SCI

Biomass-based grading porous carbon and preparation method thereof

ActiveCN109516458ARealize high-value utilizationHigh porosityCarbon compoundsHybrid capacitor electrodesDouble saltBiomass
The invention discloses a biomass-based grading porous carbon and a preparation method thereof. The method comprises the following steps of shearing and sieving the biomass raw materials to 20 to 80 meshes; adding the materials into a double-salt system water solution; performing stirring; performing low-temperature hydro-thermal method pre-carbonization treatment for 5 to 20h at 180 to 300 DEG C;performing washing and filtering to obtain a pre-carbonization product; then raising the temperature to 600 to 1000 DEG C in inert atmosphere; performing carbonization activation treatment for 0.5 to8h; performing acid washing, alkali washing or ultrasonic treatment on the obtained product; then washing the materials by water to the neutral state; performing drying to obtain the biomass-based grading porous carbon. The hydrothermal carbonization is performed during the pre-carbonization; the double-salt system is used as a salt template and a pre-hole-forming agent; the adverse conditions are provided for the subsequent carbonization activation for preparing the porous carbon; the obtained porous carbon has high specific surface area and the loose three-dimensional connection pore passage structures; high electrical conductivity and good capacitive characters are realized; the biomass-based grading porous carbon can be applied to supercapacitors as carbon electrodes.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Composite aerogel photocatalyst for recovering titanium dioxide/silicon dioxide

The invention relates to a recoverable TiO2-SiO2 composite aero-gel photo-catalyst as well as the preparation method thereof. The invention is characterized in that the sol-gel method is firstly utilized for respectively preparing TiO2 sol and SiO2 sol, then the two are mixed according to a certain proportion to obtain a mixed sol, and then TiO2-SiO2 composite alcogel is obtained through polycondensation reaction; the TiO2-SiO2 composite alcogel is used for preparing TiO2-SiO2 composite aero-gel after drying, and the composite aerogel is used for obtaining composite aero-gel aggregates after baking for 6 to 8 hours. The pore size of the obtained composite aero-gel aggregates is distributed between 2.5 nm to 10 nm, and the particle diameter is distributed between 10 nm to 15 nm, while the particle diameter of the aggregates is distributed between 0.1 mm and 0.3 mm. Compared with the prior art, the TiO2-SiO2 composite aero-gel photo-catalyst has the advantages that the prepared TiO2-SiO2 composite aero-gel has large specific surface area, high porosity, uniform pore distribution, etc., wherein, TiO2 is in the anatase crystal form. Compared with the TiO2 nanometer powder absorbent, the photo catalytic activity of the TiO2-SiO2 composite aero-gel is higher, the photo catalytic efficiency is better, and the regeneration and the reuse of the composite aero-gel are convenient as the particles of the aero-gel aggregates are larger, thereby the recoverable TiO2-SiO2 composite aero-gel photo-catalyst is widely applicable to the treatment of a great amount of wastewater.
Owner:PLA SECOND ARTILLERY ENGINEERING UNIVERSITY

Soil passivating agent suitable for northern sewage irrigation area farmland and application method of soil passivating agent

The invention provides a soil passivating agent suitable for northern sewage irrigation area farmland and further provides an application method of the soil passivating agent, wherein the application method mainly aims at northern sewage irrigation area heavy metal contaminated soil. The soil passivating agent comprises, by mass, 1-6 parts of clay minerals, 1-5 parts of biological carbon and 1-3 parts of humic acid. The clay minerals comprise one or more of sepiolite, zeolite, serpentine, talcum, attapulgite, olivine and bentonite. According to the soil passivating agent containing the sepiolite, the biological carbon and the humic acid, the ecological hazard of heavy metal ions can be reduced through effects such as complexation and electrostatic adsorption of the biological carbon and the heavy metal ions, and the sepiolite can generate ion-exchange action with heavy metal in soil to fix the heavy metal in the soil, so that the purpose of heavy metal pollution removing is achieved. The passivating agent is especially suitable for being applied to the sewage irrigation area farmland soil, soil fertility can be increased, and the hazard of the heavy metal can also be effectively reduced.
Owner:CHINESE RES ACAD OF ENVIRONMENTAL SCI

Labyrinth type current-crossing and bubbling photocatalytic reaction device and method for treating organic waste water thereby

The invention relates to a labyrinth cross flow bubbling light-catalyzed reaction device and the method for treating organic wastewater. It is characterized in that the reactor is equipped with a labyrinth liquid passage formed by parallel baffle plate, gas containing oxygen entering from bottom of reactor into distributing plate and bubble into reacting area, organic wastewater flows from liquid inlet pipe on upper of distributing plate and reactor side face, flows in labyrinth reacting area along baffle plate and contacts with rising bubble, and the particular light catalyst floats in gas and liquid mixing phase. The light catalystic reaction proceeds among gas, liquid and solid reacts phase under irradiation of ultraviolet light from upper side of reactor, the organic matter is degraded, the yielding water is separated through outer solid-liquid separator and the light catalytic reaction is continous proceeded under pump action. The invention is characterized by simple construction, convenient operation, long liquid retention time for thorough contact time of liquid and solid, high mass transfer efficiency and light catalytic reaction efficiency, no limit from light source for reactor design enlargement and easy for industrial application.
Owner:TAIYUAN UNIV OF TECH

Preparation method of graphene/chitosan porous sponge oil absorption material

The invention provides a preparation method of a graphene/chitosan porous sponge oil absorption material. The preparation method is characterized by comprising the following steps: (1), preparing a chitosan solution under a room temperature condition, carrying out ultrasonic dispersion on an oxidized graphene solution, slowly adding the graphene solution into the prepared chitosan solution while stirring, and fully blending so as to obtain an uniformly mixed graphene/chitosan solution, wherein the content of the oxidized graphene is 6%-30%; (2) preparing a glutaric dialdehyde solution, slowly adding the glutaric dialdehyde solution into the prepared graphene/chitosan mixed solution, stirring and uniformly mixing, and then carrying out crosslinking for 1-4 hours at 60-100 DEG C; and placing the solution with different graphene and chitosan mixture ratios into a mould and refrigerating, placing a refrigerated sample into a vacuum freezing drier, and freezing and drying for at least 24 hours, thus obtaining the graphene/chitosan porous sponge material with a three-dimensional structure. The graphene/chitosan porous sponge material has the advantages that the porosity is large, the adsorption rate is high, the adsorption stability is good and the repeating utilization ratio is high.
Owner:QINGDAO UNIV

Preparation method and application of nanometer zero-valence bimetal-supported functional charcoal

The invention relates to a preparation method and an application of nanometer zero-valence bimetal-supported functional charcoal, and belongs to a preparation method and an application of charcoal for water pollution treatment. The preparation method comprises the following steps: immersing charcoal in a sodium hydroxide solution to modify the charcoal, immersing the modified charcoal in a ferrous sulfate and polyethylene glycol mixed solution, carrying out ultrasonic treatment to make an active component Fe be supported on the modified charcoal carrier, and titrating with sodium borohydride to prepare a zero-valence nanometer iron charcoal-based material; and filtering the nanometer zero-valence iron charcoal-based material, washing the filtered nanometer zero-valence iron charcoal-based material, gradually adding a silver nitrate solution to the above obtained zero-valence iron-supported charcoal solution, and strong stirring to obtain a nanometer zero-valence Ag/Fe bimetal charcoal-based adsorbent. The functional charcoal is prepared from abundant agricultural wastes, the specific surface area and the porosity of the charcoal are greatly improved through regulating the structure of the charcoal by using an in situ supporting and liquid phase reduction technologies, and the charcoal can be widely applied to the sewage treatment field.
Owner:CHINA UNIV OF MINING & TECH
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