1336results about How to "High porosity" patented technology

The invention relates to the technical field of ceramics, and particularly discloses a preparation method of a bamboo charcoal pot ceramic material, which comprises the following steps: weighing the following raw materials in parts by weight: 25-30 parts of bamboo charcoal powder, 20-25 parts of quartz powder, 10-15 parts of silicon carbide, 10-14 parts of a whisker readjustment-based bonding agent, 8-12 parts of albite, 7-11 parts of a magnesium oxide-doped modified filling agent and 5-10 parts of clay. According to the bamboo charcoal pot ceramic material disclosed by the invention, the bamboo charcoal powder is matched with the quartz powder, silicon carbide, albite and clay raw materials, and the impact resistance, the heat-conducting property and the wear-resisting property of the product are harmoniously improved by adding the continuous balance agent based on whisker readjustment and the filling agent modified by doped magnesium oxide and blending and matching the raw materials; and the product has remarkable cold and heat resistance and scrubbing stability.

The invention discloses a bio-based foam adsorption material as well as a preparation method and adsorption application thereof. The bio-based polymer is used as a foam skeleton, the adsorbent with a large specific surface area is added to further improve the foam adsorption capacity, the cross-linking agent and the reinforcing filler improve the overall strength of the foam, and the bio-based foam adsorption material with the high adsorption capacity is obtained. The bio-based foam disclosed by the invention is light in weight, controllable in hydrophilicity and hydrophobicity, and capable of separating and removing pollutants such as oil and organic dye. The foam has high adsorption capacity and good cyclic adsorption capacity, can be repeatedly used, is biodegradable, does not pollute the environment, can effectively adsorb dangerous chemicals existing in a water body, does not cause secondary pollution, and can be used for decontamination treatment of organic pollutants in industrial wastewater.

The invention discloses a negative carbon coplanar filling system arrangement and mining method, which comprises the following steps of: stoping by adopting a rear gangue high-porosity filling coal mining technology, retaining a stoping roadway on one side of a filling section by utilizing a gob-side entry retaining technology, and reinforcing by adopting a roadway-side support body; the mining roadway serves as a CO2 filling roadway of the working face and a mining roadway on one side of an adjacent filling working face; when the working face advances by 300-500 m, the working face is separated from a rear goaf through a sealing wall, and a sealed storage space is formed; then, drill holes are formed in the goaf through the CO2 injection and filling roadway, and CO2 injection and filling pipelines are arranged in the mining roadway and the drill holes; and CO2 is injected into the goaf by the CO2 injection pump through the CO2 injection pipeline, and after injection is completed, CO2 injection in the next closed space is started until injection of the working face is completed. The system is simple in arrangement, CO2 filling and coal mining filling do not interfere with each other, operation is flexible, the sealing performance of the sealing space is good, the dual purposes of solid waste disposal and CO2 sealing are achieved, and green mining of coal resources is achieved.

The invention provides an instant-penetration expanded polytetrafluoroethylene artificial blood vessel and a preparation method thereof. The preparation method comprises the following steps: mixing PTFE dispersion resin and lubricating oil with a first compression ratio, and curing to obtain a first PTFE mixture; mixing the PTFE dispersion resin with a second compression ratio and lubricating oil, and curing to obtain a second PTFE mixture, wherein the first compression ratio is higher than the second compression ratio; the first PTFE mixture is pre-pressed into a middle layer cylinder; pre-pressing the second PTFE mixture into an inner-layer cylinder and an outer-layer cylinder; the middle-layer cylinder is put into the outer-layer cylinder, the inner-layer cylinder is put into the middle-layer cylinder to obtain a composite cylinder, and the composite cylinder is subjected to blank pressing treatment to obtain a secondary blank pressing cylinder; and carrying out one-way stretching on the secondary compaction cylinder to obtain the instant-penetration expanded polytetrafluoroethylene artificial blood vessel which is not layered after being punctured.

The invention discloses a hollow aramid aerogel fiber with a hierarchical pore structure as well as a preparation method and application of the hollow aramid aerogel fiber. The preparation method comprises the following steps: by using a coaxial wet spinning method, using a spinning solution A as a shell spinning solution and a spinning solution B as a core spinning solution, simultaneously extruding the spinning solution A and the spinning solution B into a coagulating bath, carrying out in-situ dynamic sol-gel conversion, and then carrying out specific drying to obtain the hollow aramid aerogel fiber with the hierarchical pore structure, the middle of the hollow aramid fiber aerogel fiber with the hierarchical pore structure is of a hollow structure, and the fiber wall is of the hierarchical pore structure. The prepared hollow aramid fiber aerogel fiber with the hierarchical pore structure has the advantages of being large in specific surface area and high in porosity, the inner diameter, the outer diameter and the wall thickness of the fiber and the size, the morphology and the pore size distribution of pores in the fiber wall can be adjusted and controlled, the preparation method has universality, the preparation process is simple, and large-scale production is easy to achieve.

The invention discloses a water-retaining controlled-release fertilizer and a preparation method thereof, and relates to the technical field of controlled-release fertilizers. According to the invention, the attapulgite is modified by a phosphoric acid solution, so that the surface of the attapulgite has acidic groups, and the groups can be adsorbed with positive ions in the fertilizer, so that nutrients are adsorbed and fixed on the surface of the attapulgite, and the speed of releasing the fertilizer nutrients into a soil solution is delayed; meanwhile, the modified attapulgite and some nutritional ingredients in the fertilizer can form indissolvable compounds, so that the nutrients are slowly released along with gradual dissolution of the compounds, and the fertilizer efficiency of the fertilizer is prolonged; when the modified attapulgite encounters water, the entering speed of water can be effectively slowed down, dissolution of nutrients in fertilizer particles is controlled, and then the slow and controlled release effect is achieved; and the modified attapulgite can regulate the pH value of the soil, so that the soil environment is more suitable for plant growth and slow release of fertilizer nutrients.

The invention provides a preparation method of a polyester loose nanofiltration membrane, and belongs to the technical field of nanofiltration membrane preparation. The preparation method provided by the invention comprises the following steps: dissolving a water-phase monomer in a sodium hydroxide solution to obtain a NaOH solution containing the water-phase monomer; soaking an ultrafiltration membrane in the NaOH solution containing the aqueous phase monomer to obtain an ultrafiltration membrane supporting layer; contacting the ultrafiltration membrane supporting layer with a trimesoyl chloride solution, and carrying out interfacial polymerization reaction to obtain a primary nanofiltration membrane; and carrying out heat treatment on the primary nanofiltration membrane to obtain the polyester loose nanofiltration membrane. The water-phase monomer is a compound which has a non-planar distorted structure and simultaneously contains phenolic hydroxyl groups and alcoholic hydroxyl groups. The method provided by the invention is simple and easy to implement, relatively low in required cost and beneficial to realizing large-scale industrial production of the high-efficiency nanofiltration membrane. The polyester loose nanofiltration membrane prepared by the preparation method disclosed by the invention has relatively high permeation flux, and meanwhile, a relatively high Na2SO4 retention rate can be kept.

The invention relates to the technical field of sodium ion batteries, in particular to a sodium ferric sulfate positive electrode material and a preparation method and application thereof. The preparation method of the sodium ferric sulfate positive electrode material comprises the following steps: obtaining a carbon foam substrate; weighing raw materials according to the stoichiometric ratio of the sodium ferric sulfate positive electrode material, and adding the raw materials into a solvent to obtain a mixed solution; depositing the mixed solution on a carbon foam substrate by adopting an electrostatic spray deposition method to obtain a precursor film; and sintering the precursor film to obtain the sodium ferric sulfate positive electrode material. According to the preparation method, the carbon foam is adopted as a substrate material, the sodium ferric sulfate precursor is prepared through electrostatic spray deposition, and then the sodium ferric sulfate material is obtained through sintering treatment, so that the specific discharge capacity, the rate capability and the cycle performance of the sodium ferric sulfate material are all remarkably improved.

The invention discloses a low-carbon magnesia-carbon refractory material for clean steel smelting and a preparation method thereof, and relates to the technical field of magnesia-carbon refractory materials. The low-carbon magnesia-carbon refractory material comprises the following components: 40-50 wt% of fused magnesite with the particle size of 3-5 mm, 20-30 wt% of fused magnesite with the particle size of 1-3 mm, 10-20 wt% of fused magnesite with the particle size of less than or equal to 74 [mu] m, 8-12 wt% of silicon powder, 1-3 wt% of alumina powder and 3-5 wt% of crystalline flake graphite. 2-4 wt% of a composite additive and 4-6 wt% of phenolic resin are added; the composite additive comprises andalusite and mullite. The material has excellent mechanical properties, thermal shock resistance, oxidation resistance and erosion resistance; the preparation method has the characteristics of low cost and simple process, and the prepared low-carbon magnesia carbon refractory material has excellent oxidation resistance, thermal shock resistance and slag resistance by exerting the phase volume expansion effect and intergranular phase enhancement effect of the multiphase ceramic; the used graphite is low in content, graphite consumption and molten steel recarburization risk can be reduced, and the method is suitable for smelting clean steel.

The invention provides a layer-by-layer self-assembled nanofiltration membrane and a preparation method and application thereof.The layer-by-layer self-assembled nanofiltration membrane comprises a base membrane and a self-assembled coating formed on the base membrane, and the self-assembled coating at least comprises an initial alternating coating and a separation alternating coating; the molecular weight cutoff of the base membrane is not less than 500kDa; the initial alternate coating is formed by alternately assembling a large-molecular-weight cationic polyelectrolyte layer and an anionic polyelectrolyte layer, and the separation alternate coating is formed by alternately assembling a small-molecular-weight cationic polyelectrolyte layer and an anionic polyelectrolyte layer; the initial alternating coating is formed on the base membrane, and a high-molecular-weight cationic polyelectrolyte layer in the initial alternating coating adopts cationic polyelectrolyte with the number-average molecular weight not less than 500kDa; and the small-molecular-weight cationic polyelectrolyte layer in the separation alternate coating is cationic polyelectrolyte with the number-average molecular weight not exceeding 100kDa. The layer-by-layer self-assembled nanofiltration membrane provided by the invention has more excellent permeability and micropollutant rejection rate.

According to the seawall ecological slope protection structure and the construction method thereof, the seawall ecological slope protection structure comprises a seawall body, the seawall body is filled with mud filling pipe bags, a wave wall is arranged at the top of the seawall body, a bagged gravel layer is laid on the slope surface of the seawall body, a polyurethane gravel protection slope is laid on the bagged gravel layer, and a wave dissipation platform is arranged on the slope surface; according to the seawall, the structural porosity of the seawall can be effectively improved, energy transportation and material exchange between the ocean and the land can be continued, meanwhile, the wave dissipation effect is good, and the structure is resistant to corrosion; the method is simple in form and high in universality, the construction step of cast-in-place concrete of a traditional seawall concrete slope protection structure is basically avoided, the site construction period and maintenance period are greatly shortened, the porosity of the polyurethane gravel slope protection is high, plant growth is facilitated, and the ecological property of the seawall structure is improved; and a good ecological effect can be created.

The invention discloses a shallow lake submerged plant planting matrix and an efficient planting method. The method comprises the steps of submerged plant planting matrix preparation, seedling preparation, culture and maintenance and seed throwing. The planting substrate comprises the following components in percentage by weight: 54-74% of common soil; 12 to 33% of sediment; 11-12% of river sand; 1% of kaolin; after the raw materials are uniformly mixed, a small amount of water is added for multiple times, so that the sticky planting substrate is formed. Propagules such as submerged plant seedlings, buds and seeds are wrapped with the planting substrate. The submerged plants and the planting substrate form a stable whole body which is not easy to separate; after the plant seedlings are maintained and cultivated for 5 days, the submerged plant seedlings are thrown and planted in the lake water area. A small amount of degradable environment-friendly substrate raw materials are added, so that the strength and toughness of the planting substrate can be improved, the substrate can be kept in water until the submerged plants are stable in rooting and germination, necessary nutrient elements can be provided for growth of the submerged plants, and rapid and stable growth of the submerged plants is promoted.

The invention discloses a cellulose-based in-situ growth MOF composite aerogel preparation method, which comprises: mixing cellulose powder and dimethylimidazole, adding into deionized water, gradually adding cobalt nitrate and zinc chloride, uniformly stirring, carrying out a heating reaction, adding polyethyleneimine, uniformly stirring, adding a cross-linking agent, carrying out cross-linking, washing, and drying to obtain the cellulose-based in-situ growth MOF composite aerogel. The composite hydrogel is obtained; and finally, sealing, heating and baking the composite hydrogel, washing and drying to obtain the composite aerogel. According to the method, the MOF is synthesized on the cellulose in situ under the low-temperature water phase condition, the composite aerogel containing the MOF material is obtained, the MOF material synthesized on the cellulose in situ has good porosity and particle size and uniformly covers the cellulose, loss of active components is avoided, the problem that the MOF material is prone to agglomeration is solved, and the preparation method is suitable for industrial production. Meanwhile, the adsorption performance is also effectively improved, the adsorbent has good affinity with water, and the surface can be promoted to adsorb three metal ions of vanadium, molybdenum and nickel at the same time.

The remediation method for the moderately and severely cadmium-polluted rice field aims at strictly controlled cadmium-polluted rice fields, and is divided into two stages of strict control and safe utilization for remediation. In the strict management and control stage, an activating agent is applied to the soil in spring, then microalgae are inoculated, cadmium-enriched plants are planted, the plants are collected after being full of the microalgae, the plants are harvested when the plants grow to the enrichment extreme value, stubbles are reserved for growth, and the steps are repeated till winter; applying an activating agent in winter, planting green manure, and harvesting in spring in the next year; the process is cyclically carried out until the cadmium content of the soil is reduced to a safe utilization level. Entering a safe utilization stage, applying an activating agent in spring, inoculating nitrogen-fixing cyanobacteria, collecting the cyanobacteria after the cyanobacteria overgrow, and repeating the steps until the rice seedlings are transplanted; applying nitrogen-fixing blue-green algae, and planting rice; applying an activating agent after rice harvesting, planting winter green manure, and harvesting in next spring; the process is cyclically carried out until the cadmium content of the soil is reduced to a preferential protection level. The method is low in cost, high in remediation efficiency and good in effect, and a new way is provided for cadmium-polluted rice field remediation.

The invention provides a positive pole piece, a preparation method thereof and a battery, and aims to solve the technical problem of poor cycle performance of the battery caused by gas production of a lithium supplement agent. The positive pole piece comprises a current collector and a first active material layer arranged on the current collector, the first active material layer comprises a first positive active material, a lithium supplement agent and a first conductive agent, and the first conductive agent comprises porous carbon. The lithium supplement agent and the porous carbon are added into the first active material layer of the positive pole piece, and the porous carbon can promote the lithium supplement agent to be dispersed in the first active material layer and improve the porosity of the positive pole piece, so that a large number of lithium ions released by the lithium supplement agent can be conducted through pore channels in the porous carbon; moreover, gas generated by the lithium supplement agent can be led out and released through the pore channels in the porous carbon, so that the damage of the gas generated by the lithium supplement agent to the interface of the positive pole piece is relieved, the transmission efficiency of lithium ions in the positive pole piece is improved, and the cycle performance of the battery is improved.

The invention belongs to the technical field of agricultural fertilizers, and provides a soil remediation fertilizer and a preparation method thereof. The preparation method comprises the following steps: S1, sequentially drying and crushing a natural organic matter material to obtain a pretreated natural organic matter material; s2, mixing the pretreated natural organic matter material, microbial flora, a plant growth regulator, a stabilizer and a slow release agent, and performing fermentation treatment to obtain a compound fertilizer; s3, sequentially drying, granulating and packaging the compound fertilizer to obtain the soil remediation fertilizer. The soil remediation fertilizer provided by the invention can effectively solve the remediation problem of organic matter and heavy metal contaminated soil, improve the soil quality and promote plant growth, and has remarkable environmental protection and agricultural sustainable development benefits.

The invention relates to the field of sponge materials, and provides an antibacterial degradable sponge material and a preparation method thereof. The material is prepared from protocatechuic acid modified quaternized chitosan, quaternary ammonium salt grafted gelatin, sodium alginate, polyhydroxybutyrate, polycaprolactone, a polylactic acid-glycolic acid copolymer, hexamethylene diisocyanate, a foaming agent, nano cellulose, vitamin E, polyethylene glycol, triethylamine and dimethylformamide. Protocatechuic acid and quaternized chitosan are subjected to amidation modification, and chitosan and gelatin are subjected to quaternization treatment by adopting 2, 3-epoxypropyl trimethyl ammonium chloride, so that the antibacterial property and biodegradability of the material are improved. In the material preparation process, through vacuum degassing, foaming vacuum degree and humidity control and a multi-step drying process, it is ensured that the average pore size of the material is uniform (50-200 microns) and the porosity is high (50%-90%), and the obtained material has excellent antibacterial property and degradability and has wide application value.

The invention provides a method for preparing porous iron phosphate through an emulsion reaction. The method comprises the following steps: (1) reacting an iron source and a phosphorus source according to a certain proportion to prepare an iron phosphate precursor; (2) reacting the iron phosphate precursor with a foaming agent to obtain emulsified iron phosphate dihydrate; (3) adding a cross-linking agent for further emulsification and dispersion, and adding a curing agent to obtain cured iron phosphate dihydrate; and (4) drying, calcining and crushing the iron phosphate dihydrate to obtain the porous iron phosphate. The method is specifically characterized in that the porous iron phosphate with the three-dimensional foam structure is finally obtained through the processes of emulsification foaming, curing reaction, calcination pore-forming and the like in sequence in the iron phosphate preparation process. The iron phosphate material prepared by the method has rich three-dimensional reticular porous structures, high specific surface area and high porosity. The lithium iron phosphate material prepared from the precursor material is high in electronic conductivity and can adapt to a high-rate lithium iron phosphate process. In addition, the raw materials used in the preparation process are cheap and easy to obtain, the preparation process is stable and controllable, and the iron phosphate prepared by the process has better application value and economic value.

The invention discloses a cold-rolled silicon steel thin strip and a processing method thereof, and relates to the technical field of silicon steel strips. According to the method, the silicon steel plate is cold-rolled into the ultrathin silicon steel strip, then the ultrathin silicon steel strip is subjected to activating treatment through the activating solution and then coated with the anti-corrosion coating, and the prepared ultrathin silicon steel strip has good corrosion resistance. According to the invention, phytic acid and modified polyaspartic acid are added into an activating solution. According to the iron-based organic framework material, polysuccinimide is used as a raw material, dopamine is added for grafting modification, a polymer which takes polyaspartic acid as a framework and is grafted with dopamine is obtained, the dopamine has a catechol group, and the chelating property of the polyaspartic acid to metal ions on the iron-based organic framework material is further enhanced. And meanwhile, phytic acid is added into the activating solution, the phytic acid and the modified polyaspartic acid can form a nano-porous structure, loading of subsequent modified silica sol is facilitated, and therefore the corrosion resistance of the ultra-thin silicon steel strip is further enhanced.

The invention relates to the technical field of preparation of polymer oil-water separation membranes, in particular to a preparation method, a product and application of a hydrophilic PLA oil-water separation membrane. The preparation method of the hydrophilic PLA oil-water separation membrane comprises the following steps: dissolving polylactic acid in an organic solvent to obtain a spinning solution; carrying out electrostatic spinning on the spinning solution to prepare a PLA nanofiber membrane; the PLA nanofiber membrane is soaked in a dopamine hydrochloride solution, then membrane cloth is taken out, washed and dried, and the hydrophilic PLA oil-water separation membrane is obtained. The preparation method is low in cost and simple in preparation process. The PLA (at) PDA nanofiber membrane prepared by the preparation method disclosed by the invention is relatively high in oil-in-water emulsion separation efficiency and relatively high in separation rate, and has a good separation effect on n-hexane, gasoline, petroleum ether, peanut oil and the like, and the separation efficiency can reach 98% or above. The PLA (at) PDA nanofiber membrane disclosed by the invention is simple and convenient to apply and does not cause secondary pollution.

The invention provides a superfine light-weight high-strength filler and a preparation method thereof, and belongs to the technical field of fillers. The filler is prepared from the following components in parts by weight: 30 to 100 parts of quartz sand, 1 to 10 parts of cullet, 1 to 15 parts of Al2O3, 7 to 15 parts of Li2O, 2 to 8 parts of P2O5, 1 to 12 parts of ZrO2, 3 to 6 parts of composite nucleating agent, 5 to 10 parts of carbonate, 10 to 20 parts of feldspar and 2 to 5 parts of sulfate. The preparation method comprises the following steps: mixing the quartz sand, the cullet, the Al2O3, the Li2O, the P2O5, the ZrO2 and the composite nucleating agent, melting at a high temperature to obtain a base material, nucleating and crystallizing at different temperatures, grinding, adding the carbonate, the feldspar and the sulfate, adding the binder, granulating, and sintering to obtain the product. The lightweight high-strength filler has the characteristics of sound absorption, noise reduction, fire prevention, flame retardance, light mass density, high compressive strength, low water absorption, ecological environmental protection and the like, and is suitable for lime, gypsum and cement-based products; particularly, the high-temperature-resistant and high-strength dry-mixed mortar has a good application prospect in dry-mixed mortar products, such as ceramic tile adhesives, light plastering and self-leveling, as well as acoustic boards, sound insulation barriers, heat insulation boards and fireproof board products.

The invention relates to the technical field of reverse osmosis membranes, in particular to a polyamide reverse osmosis membrane for high-salinity wastewater treatment and a preparation method of the polyamide reverse osmosis membrane. The invention solves the problem that the polyamide reverse osmosis membrane cannot give consideration to both desalination rate and water flux. The polyamide reverse osmosis membrane comprises a polyester non-woven fabric layer, a polysulfone porous layer, a transition layer and a polyamide layer. The polysulfone porous layer is prepared, and the modified pore-forming agent is added to improve the water flux of the reverse osmosis membrane; the hydrophilicity of the reverse osmosis membrane is improved by preparing the transition layer and adding a hydrophilic auxiliary agent when the polyamide layer is prepared; the flux attenuation rate of the polyamide reverse osmosis membrane is reduced by preparing the polyamide layer; the desalination rate of the reverse osmosis membrane is improved by introducing a composite ion complexing agent and graphene quantum dots into the polyamide layer.

The invention discloses a process for preparing a polyester fiber fabric by regenerating polyester waste bottle flakes, belongs to the technical field of polyester fiber fabric processing, and aims to solve the technical problem that the moisture absorption and quick drying performance, friction resistance and pilling resistance of the polyester fiber fabric in the prior art need to be further improved. The method comprises the following steps: adding polyester waste bottle flakes into a pulverizer, pulverizing, sieving with a 60-mesh sieve to obtain polyester regenerated powder, and pretreating the polyester regenerated powder to obtain pretreated polyester powder; composite polyester is prepared from modified polysiloxane enhanced copolyester containing nylon 6 and polyvinyl alcohol blocks, and then the porous composite polyester fiber is prepared by taking polyvinyl alcohol as a pore forming agent, so that the moisture absorption and quick drying performance of the polyester fiber fabric is effectively improved, the wearing experience of the polyester fiber fabric is enhanced, and the service life of the polyester fiber fabric is prolonged. The wear-resistant and anti-pilling performance of the polyester fiber fabric is also improved.

The invention provides a preparation method of an integrated and dual-channel PCNFs / ZIF8-SA composite aerogel and a product and application thereof, and the preparation method comprises the following steps: step 1, adding sodium alginate SA and ZIF-8 into a PCNFs suspension, and stirring until the SA is fully dissolved until a uniform mixed solution is formed; the PCNFs is PAN / ZIF-8 / lignin / NaCl carbon nanofibers after hydrophilic modification, and the pH value of the PAN / ZIF-8 / lignin / NaCl carbon nanofibers is 7-8; step 2, pouring the mixed solution into a mold, and performing directional freezing in a freeze dryer to obtain a composite aerogel columnar structure with a directional channel structure; 3, hydrophobic modification is conducted on the upper layer of the composite aerogel columnar structure, a hydrophobic layer with a certain thickness is formed, the lower layer of the composite aerogel columnar structure is a hydrophilic layer, and the hydrophobic layer and the hydrophilic layer are integrated. The aerogel disclosed by the invention has a dual-channel integrated special structure including a fresh water channel and a salt extraction channel, accumulated salt can be extracted from a side channel while efficient solar seawater desalination is realized, an evaporation channel is prevented from being blocked, and the evaporation efficiency and the stability of the composite aerogel are well improved.

The invention relates to a low-temperature graphite negative electrode material and a preparation method thereof, and belongs to the technical field of high polymer materials. According to the prepared low-temperature graphite negative electrode material, firstly, the surface of graphite is pre-oxidized through potassium persulfate, phosphorus pentoxide and concentrated sulfuric acid, and then under the action of sodium nitrate, potassium permanganate and hydrogen peroxide, graphite oxide is prepared; then, ammonium molybdate hydrate and thioacetamide are used as a molybdenum source and a sulfur source, graphite oxide is used as a supporting material, a molybdenum disulfide-graphite compound is synthesized, and the conductivity and the cycling stability are improved; secondly, the surface of the negative electrode is coated with amorphous resin carbon / nickel oxide, so that the ion diffusion efficiency of the low-temperature graphite negative electrode material is enhanced, and the electrochemical lithium storage performance is improved in a low-temperature environment; and finally, the surface of the amorphous resin carbon / nickel oxide is coated with a layer of polythiophene film, so that the rate capability of the negative electrode material is improved due to large surface area and high pores.

The invention discloses application of a magnetic nano composite material as an adsorbent in removal of organic dye in water, and belongs to the technical field of application of composite materials, the magnetic nano composite material (one of Fe3O4-coated TAPT-OMePDA or Fe3O4-coated TAPT-TFPDA) as the adsorbent adsorbs the organic dye in water, the adsorption capacity of Congo red (CR) reaches up to 1603.54 mg / g and 1968.83 mg / g, and the adsorption capacity of the magnetic nano composite material (one of Fe3O4-coated TAPT-OMePDA or Fe3O4-coated TAPT-TFPDA) as the adsorbent adsorbs the organic dye in water. The adsorption of the two adsorbents to the CR accords with a quasi-secondary kinetic model and a Langmuir isotherm model, and belongs to single-layer chemical adsorption. Compared with an adsorbent in the prior art, the Fe3O4 (at) TAPT-OMePDA and the Fe3O4 (at) TAPT-TFPDA have the advantages that the porosity is high, the adsorption efficiency is high, the selectivity is good, and the repeated utilization rate is good.

The invention discloses preparation and application of an imido covalent organic framework material containing imidazolyl ionic liquid. The imido covalent organic framework material (ILs-TPN-COFs) containing the imidazolyl ionic liquid is obtained by connecting the imidazolyl ionic liquid [CnCmILs (at) Br] to an imido covalent organic framework TPN-COFs through a covalent bond. The material has an ionic liquid tertiary amine N active site and a halogen anion active site, and can promote CO2 activation and ring opening of epoxide. The ILs-TPN-COFs catalytic material has the advantages of uniform distribution of active sites, better stability, easiness in separation of the catalyst from a reaction system, better repeatability and the like. According to the invention, the prepared novel ILs-TPN-COFs material is applied to catalysis of synthesis of propylene carbonate from carbon dioxide and epoxypropane, and shows excellent catalytic performance under mild reaction conditions.

The invention discloses a nickel and cadmium-containing nonferrous metal wastewater treatment method, and relates to the technical field of wastewater treatment. The preparation method comprises the following steps: by taking polyvinyl alcohol and gelatin as raw materials, carrying out amination modification through 3-amino-trimethoxysilane to prepare an aminated gelatin solution, and then adding a modified metal organic framework adsorption material and modified nitrogen-containing biochar to react to prepare an adsorbent with a good adsorption effect on metal nickel and cadmium. The modified metal organic framework adsorption material and the modified nitrogen-containing biochar have amino groups, so that the modified metal organic framework adsorption material and the modified nitrogen-containing biochar have good dispersibility in the aminated gelatin, and the adsorption effect of the adsorbent is improved.

The invention belongs to the technical field of water-absorbing material preparation, and provides a crop straw-based degradable water-absorbing resin as well as a preparation method and application thereof. The method comprises the following steps: pretreating crop straws by using an alkaline solution to obtain straw cellulose; the preparation method comprises the following steps: mixing straw cellulose, a first ethanol solution and a first alkali liquor for a first reaction, then adding a second ethanol solution and chloroacetic acid for a second reaction, and then adding a second alkali liquor for a third reaction to obtain straw cellulose sodium carboxymethyl; and mixing the straw cellulose sodium carboxymethyl, acrylic acid, an initiator, a cross-linking agent and water, and reacting to obtain the crop straw-based degradable water-absorbent resin. According to the method disclosed by the invention, a reaction inert structure in the straw cellulose can be removed, a crystalline region of the cellulose is destroyed, a homogeneous reaction preparation system is constructed, the grafting efficiency of the water-absorbent resin is improved, complete degradation of the water-absorbent resin is realized, and the production cost of the water-absorbent resin is also reduced.

The invention relates to the technical field of saline-alkali soil improvement, and discloses a saline-alkali soil improvement system and method for combined control of agriculture, forestry, animal husbandry, planting, breeding and breeding, and the saline-alkali soil improvement system for combined control of agriculture, forestry, animal husbandry, planting and breeding comprises a first planting area; a drip irrigation assembly; a water seepage assembly; the drainage channel is arranged below the surface of the saline-alkali soil corresponding to the first planting area; and a first flow guide member. According to the method, salt-tolerant plants are planted in the saline-alkali soil, so that the infiltration capacity of water in the soil can be improved, and absorption and leaching of salt in the soil are promoted; the drip irrigation assembly is adopted to irrigate the salt-tolerant plants, and water molecule movement can bring salt in soil to the deep position of the soil, so that the salt return phenomenon caused by the capillary action of water molecules is avoided; by arranging the water seepage assembly, the movement speed and the conveying effect of saline-alkali water in soil conveyed to the drainage channel can be increased, and infiltration and collection of the saline-alkali water are accelerated; by arranging the drainage channel, saline-alkaline water in the soil can be absorbed and discharged.