8945 results about "Phosphoric acid" patented technology

The invention belongs to the technical field of perovskite solar cells, and particularly discloses a carbazolyl conjugate enhanced self-assembled monomolecular layer and a preparation method and application thereof, and the self-assembled monomolecular layer takes carbazole as a substrate and an aromatic ring as a conjugate linking group. The highly conjugated molecular system can induce molecular orbital overlap, increase dipole moment, promote formation of a compact self-assembled monomolecular film, reduce interface non-radiative recombination and enhance hole extraction and transmission performance. Meanwhile, phosphoric acid is used as an anchoring group, so that firm self-assembly of SAM molecules on the surface of the ITO substrate can be realized. The SAM material is simple in preparation method, high in yield, low in preparation cost and good in stability. When the compound is applied to a trans-perovskite solar cell as a hole transport layer, photoelectric conversion efficiency exceeding 24.6% can be obtained, and the compound is an organic semiconductor material with a very good prospect.

The invention belongs to the technical field of perovskite solar cells, and particularly discloses a self-assembly monomolecular film hole transport material based on diphosphoric acid and a preparation method and application thereof.The diphosphoric acid serves as an anchoring group, the chelation between the material and a conductive base can be effectively enhanced, the self-assembly characteristic of the material on the surface of a substrate is improved, and the hole transport efficiency is improved. The compact and smooth self-assembled monomolecular film is formed. Meanwhile, the electron and space effects of alkyl chains or benzene ring connecting units are regulated and controlled, so that the molecular stereo configuration and energy level matching are optimized. The material disclosed by the invention is simple in synthesis steps and low in preparation cost, and industrial synthesis of the material can be realized. When the material is applied to an inverted perovskite solar cell as a hole transport layer, photoelectric conversion efficiency exceeding 24.7% and excellent device stability performance can be obtained, and huge commercial prospects are shown.

The present invention discloses a self-assembled monolayer hole transport material based on an alkyl polyphosphate anchoring group, a synthesis method thereof, and an application in an inverted perovskite solar cell. The present invention uses carbazole or 3,6-diphenylcarbazole with good hole transport properties as a parent core, and achieves complete coverage and stable self-assembly of the material on the substrate surface by improving the anchoring group from traditional alkyl monophosphate to alkyl diphosphate and triphosphate. The synthesis method of the present invention is simple and the synthesis cost is low. The prepared material can achieve the dual functions of hole transport and perovskite interface passivation, while enhancing the self-assembly strength and stability. When the material is used as a hole transport layer in an inverted perovskite solar cell, a photoelectric conversion efficiency of >20% can be obtained without doping, and the material has broad application prospects.

The invention relates to the technical field of lithium iron phosphate production, and discloses a carbon-coated titanium-doped lithium iron phosphate positive electrode material and a preparation method thereof.The preparation method comprises the following steps that 1, a ferrous solution and a phosphorus source solution are mixed in proportion, dopamine hydrochloride is added, a pH regulator is dropwise added in the stirring state, the pH of the solution is adjusted to 4.0-5.5, a reaction is conducted, a titanium source solution is added, and a reaction solution is obtained; after uniformly stirring, continuously dropwise adding a pH regulator to regulate the pH value of the solution to 5.5-6.5; the iron phosphate octahydrate coated with the titanium-embedded polydopamine is obtained; 2) calcining the titanium-embedded polydopamine-coated ferrous phosphate octahydrate in an inert gas atmosphere to obtain carbon-coated titanium-doped anhydrous ferrous phosphate; 3) mixing the carbon-coated titanium-doped anhydrous ferrous phosphate with lithium phosphate and a carbon source, ball-milling, mixing, spray-drying and calcining to obtain a carbon-coated titanium-doped lithium iron phosphate positive electrode material; the synthesis process is simple, and energy consumption is reduced.

Provided is a flame retardant and latent hardener composition including a blend of 30-100% (by weight based on total solids) of diammonium hydrogen phosphate, and dihydrogen phosphate, 0-50% (by weight based on total solids) of monoammonium. The flame-retardant / hardener composition is prepared as a solid blend or a liquid composition, the liquid composition being an aqueous composition including a liquid aqueous solution of the contents ranging from 25% w / w to 80% w / w. Methods for making flame retarded fiber boards using the composition as flame retarder and a hardener for the resin used in the production of the boards are also provided.

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

A forest fire retardant composition contains a retardant compound that includes a phosphate salt. The phosphate salt may include diammonium phosphate, diammonium orthophosphate, monoammonium phosphate, monoammonium orthophosphate, monosodium phosphate, disodium phosphate, disodium phosphate hydrate, sodium ammonium phosphate, sodium ammonium phosphate hydrate, sodium tripolyphosphate, trisodium phosphate, or dipotassium phosphate, and combinations thereof. The forest fire retardant composition may include an ammonium source. The composition may be in the form of a dry concentrate, a liquid concentrate, or a final diluted product. The final diluted product is effective in suppressing, retarding, and controlling forest fires while exhibiting corrosion resistance and low toxicity.

The invention discloses a lithium manganese iron phosphate positive electrode material with a core-shell structure, which is prepared by the following steps: mixing a manganese source, an iron source, a phosphorus source, lithium carbonate and a carbon source, grinding and drying to prepare a pre-sintered material; then carrying out gas crushing on the pre-sintered material to obtain a pre-gas crushed material, and carrying out heat preservation at the temperature of 200-600 DEG C; putting the pre-gas crushed material subjected to heat preservation into an iron salt solution for quenching reaction to obtain iron compound coated lithium manganese iron phosphate; and finally, mixing the lithium iron manganese phosphate coated with the iron compound, a lithium source, a phosphorus source and a carbon source, grinding, drying, and carrying out secondary calcination to obtain the lithium iron manganese phosphate material with the core-shell structure. During preparation of the lithium manganese iron phosphate positive electrode material, a lithium manganese iron phosphate pre-sintered body and an iron salt solution are subjected to a quenching reaction to form an iron compound coated lithium manganese iron phosphate pre-sintered body, and then the iron compound coated lithium manganese iron phosphate pre-sintered body and other raw materials of lithium iron phosphate are subjected to a secondary calcination reaction to generate the composite positive electrode material with a core-shell structure. A coating structure is formed, the reaction between manganese and electrolyte is reduced, the dissolution of manganese is inhibited, the Gingtaler effect of manganese is relieved, and the stability of the material is improved; and the material has the advantages of high energy density, high power density, excellent cycle performance and strong core-shell interface bonding force.

The invention provides a high-temperature-resistant and high-salt-resistant nano imbibition agent as well as a preparation method and application thereof. The high-temperature-resistant and high-salt-resistant nano imbibition agent is prepared from amination modified mesoporous silica nanoparticles, nano cellulose, rhamnolipid, an anionic surfactant, citrate modified sodium zirconium phosphate, polyethylene glycol-b-polycaprolactone and a sulfydryl-carboxyl imidazoline derivative, therefore, the composite carrier formed by the aminated mesoporous silica nanoparticles and the nanocellulose has high mechanical strength and uniform dispersity, the oil-water interfacial tension is reduced through the synergistic effect of the rhamnolipid and the anionic surfactant, and the crude oil stripping efficiency is remarkably improved; the citrate modified sodium zirconium phosphate enables the salt resistance of the system to be greatly improved, and in a high-temperature and high-salt oil reservoir environment, the nano imbibition agent can remarkably improve the crude oil recovery rate and reduce the injection pressure and dosage; meanwhile, good adsorption resistance is achieved, and reservoir blockage is prevented; in addition, low-toxicity corrosion inhibition components protect equipment, and the service life of an oil well is prolonged.

The invention discloses a phosphorus oxyfluoride reaction and separation integrated preparation tower, and belongs to the field of industrial equipment for phosphorus oxyfluoride preparation, the preparation tower comprises a tower body, the tower body is provided with a feeding area, a reaction area and a separation area, the feeding area and the separation area are both filled with filler sections of filler, a first feeding port is formed in the bottom of the filler section in the feeding area, and a second feeding port is formed in the bottom of the reaction area. A tubular heat exchanger is arranged in each reaction zone, a threaded pipe is arranged on each tubular heat exchanger, filler is also filled between the threaded pipes, a second feeding hole is formed in the upper part of the reaction zone on the top layer, and polyphosphoric acid and anhydrous hydrogen fluoride are contacted in the reaction zones to form a concentration stepped reaction and a temperature stepped reaction; and the phosphorus oxyfluoride gas generated after the reaction is fractionated through the filler section on the separation area and enters the next process from the top of the tower body. According to the invention, the reaction and separation of phosphorus oxyfluoride production are integrated, the energy consumption of phosphorus oxyfluoride production is reduced, the production cost is reduced, and the reaction yield is improved.

The invention relates to the technical field of lithium dihydrogen phosphate, and discloses a method for preparing battery-grade lithium dihydrogen phosphate by using lithium precipitation mother liquor. The method comprises the following steps: (1) mixing a hydrochloric acid solution with a lithium precipitation mother solution until the pH value of the obtained reaction solution is 4-5; (2) heating the reaction solution, adding the sodium phosphate solution into the reaction solution to adjust the pH value to 9-10, and reacting to obtain crude lithium phosphate; (3) adding a phosphoric acid solution into the crude lithium phosphate until the pH value of the obtained mixed solution is 3-5.5; (4) carrying out first reduced pressure evaporation on the crude lithium dihydrogen phosphate solution, and carrying out solid-liquid separation on a first concentrate to obtain a first solid phase and a first mother solution; (5) dissolving the first solid phase in hot water, carrying out second reduced pressure evaporation, and carrying out solid-liquid separation on a second concentrate to obtain a second solid phase and a second mother solution; the solid content of the second concentrate is higher than that of the first concentrate. The lithium dihydrogen acid prepared by the method is high in purity, and the comprehensive yield of lithium is high.

The invention discloses a waste battery lithium iron phosphate positive electrode black powder recovery method which comprises the following steps: S1, activating and roasting positive electrode black powder to obtain pretreated black powder, and mixing and ball-milling the pretreated black powder, an oxidizing agent and an activating solvent to obtain pre-oxidized black powder; s3, the pre-oxidized black powder and an inorganic solvent are mixed for a leaching reaction, and mother liquor A and iron phosphate slag are obtained; s4, adding a pH regulator into the mother liquor A to remove impurities so as to obtain mother liquor B; s5, mixing and purifying the iron phosphate slag and phosphoric acid to obtain crude iron phosphate, washing the crude iron phosphate with water, and adding a complexing agent for further purification to obtain high-purity iron phosphate; and S6, concentrating the mother liquor B to obtain concentrated mother liquor C, and introducing carbon dioxide into the concentrated mother liquor C to precipitate lithium to obtain the battery-grade lithium carbonate. According to the process, iron, lithium, phosphorus and other elements in the positive electrode black powder are efficiently separated and recycled, low-acid or acid-free green leaching of lithium is achieved, the lithium leaching rate is larger than or equal to 98.0%, and the purity of obtained iron phosphate is larger than or equal to 99.3%; the purity of lithium carbonate is greater than or equal to 99.0%.

The invention provides an iron-based phosphate positive electrode material as well as a preparation method and application thereof. The preparation method of the positive electrode material comprises the following steps: reacting a mixed material containing metallic iron and a phosphorus source at normal temperature to 100 DEG C to form a solid-liquid mixture containing a phosphate iron salt compound; mixing the solid-liquid mixture with an acidity regulator, a carbon source and a sodium source, and sanding to obtain slurry; performing drying treatment on the slurry to obtain a precursor material; and sintering the precursor material under a protective atmosphere condition to obtain the iron-based phosphate positive electrode material. According to the method provided by the invention, the metal iron and the phosphorus source do not need to be mixed and completely dissolved to form a solution in the reaction process, and anhydrous iron phosphate does not need to be formed firstly, so that the method for preparing the iron-based phosphate positive electrode material is short in process and relatively low in requirements on reaction conditions, and is applicable to industrial production and large-scale production.

The invention discloses a compound represented by a formula (1), or a tautomer, a mesomer, a raceme, an enantiomer, a diastereoisomer, or a mixture form thereof, or a pharmaceutically acceptable salt, a prodrug or a solvate thereof, the structure of the formula (1) is represented as follows: # imgabs0. Strong hydrophilic sulfonic acid inner salt and / or phosphoric acid inner salt side chains are introduced at the position of (AAA and the like)-PAB (self-destruction group), so that the druggability (including hydrophilicity and stability) of the antibody drug conjugate corresponding to the compound is greatly enhanced, the in-vivo drug removal effect is reduced, and the tumor treatment effect is improved.

The invention relates to a comprehensive recovery method of lithium iron phosphate black powder, and belongs to the technical field of lithium iron phosphate battery recovery. The technical problem to be solved by the invention is to provide the lithium iron phosphate black powder comprehensive recovery method. The method comprises the following steps: mixing lithium iron phosphate black powder with acid, and adding an oxidizing agent for reaction to obtain iron phosphorus slag; the iron phosphorus slag is subjected to acid pickling and then acid leaching to obtain secondary acid leaching liquid; and dropwise adding the secondary acid leaching solution into bottom water to generate a precipitate, and adjusting the molar ratio of phosphorus to iron or the molar ratio of phosphorus to (iron and manganese) to obtain battery-grade iron phosphate or ferromanganese phosphate. According to the method, alkali is not adopted as a precipitator, iron powder is not introduced, iron phosphate or the ferromanganese phosphate precursor is obtained through a normal-pressure one-step method, the problems that mixing is not uniform when the ferromanganese phosphate precursor is prepared through a solid-phase method, and alkali is needed as the precipitator or organic matter is introduced in a liquid-phase method are solved, use of alkaline chemical reagents and generation treatment of by-products are reduced, and the method is suitable for industrial production. The method has the advantages of simple process, low equipment use requirements, battery grade and high purity of the prepared product, improves the utilization rate of the phosphorus source, and has high yield.

The invention discloses an electrolyte with a temperature switch function and a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The electrolyte provided by the invention comprises the following components: lithium salt, a first organic solvent and a polymer, the lithium salt is at least one of lithium bis (trifluoromethylsulfonyl) imide, lithium bis (fluorosulfonyl) imide, lithium hexafluorophosphate, lithium tetrafluoroborate, lithium difluoro (oxalato) borate and lithium bis (oxalato) borate; the polymer is polymethacrylate, and the first organic solvent is [Cnmim] [TFSI]. According to the electrolyte, the reversible phase transformation process is realized, the electrode reaction can be closed at high temperature, and the lithium battery is prevented from being out of control due to overheating; and when the temperature is reduced to normal temperature, the battery can work normally. The phase transition temperature of the electrolyte is flexible and controllable, and the phase transition temperature can be regulated and controlled to a reasonable interval by optimizing the composition of the electrolyte and the dosage (concentration) of each component, that is, the phase transition temperature is higher than the normal working temperature of the battery and lower than the initial temperature of the heat release side reaction.

The invention relates to a saccharomyces cerevisiae strain for efficiently synthesizing cordycepin as well as a construction method and application of the saccharomyces cerevisiae strain, and belongs to the technical field of microbial genetic engineering. The construction method provided by the invention comprises the following steps: carrying out multi-copy genome integrated expression on heterologous codon optimized 2 '-carbonyl-3'-deoxyadenosine reductase genes and 3 '-adenosine monophosphate phosphohydrolase genes, so as to increase the dosage of key enzymes; and supplementing the defective gene of the engineering strain to obtain the saccharomyces cerevisiae strain B5U3 with high yield of cordycepin. According to the obtained saccharomyces cerevisiae strain for efficiently synthesizing the cordycepin, the cordycepin yield reaches 2.92 g / L after shake flask fermentation, the cordycepin yield reaches 7.5 g / L after fermentation in a fermentation tank, and a foundation is laid for safer and more reliable industrial production of the cordycepin.

The invention provides a method for regenerating battery-grade iron phosphate from ferrophosphorus slag after lithium extraction. The method comprises the following steps: carrying out wet reduction leaching on the ferrophosphorus slag, removing impurities from a leaching solution, and roasting to prepare the battery-grade iron phosphate. According to the method, under the condition that impurity elements are not introduced, the leaching reaction of the ferrophosphorus slag is strengthened, and the leaching rate of phosphorus and iron elements can reach 99%; the purification liquid is prepared through impurity removal, the impurity removal rate is as high as 99.93%, and the ferrophosphorus loss rate is as low as 2.44%; and synthesizing the battery-grade iron phosphate from the purified liquid through a regulator. According to the method disclosed by the invention, deep removal of metal ions is realized, and the obtained product is high in purity and can completely meet the use requirements of commercially available battery-grade iron phosphate; and the slag obtained after lithium extraction of the waste lithium iron phosphate battery black powder is used as the battery-grade iron phosphate regeneration raw material, so that the iron phosphate regeneration cost can be reduced, the problems of solid waste stockpiling and landfill are effectively avoided, the resource utilization rate is increased, and deep recycling and green and environment-friendly circulation of the waste lithium battery resource are realized.

The invention relates to the field of gene engineering, and discloses a D-3-phosphoglycerate dehydrogenase mutant, a coding gene thereof and application of the D-3-phosphoglycerate dehydrogenase mutant and the coding gene. Compared with a protein with an amino acid sequence as shown in SEQ ID NO: 1, the mutant comprises mutation at the 131 site and / or the 285 site. The mutant can specifically catalyze a substrate 3-phosphoglycerate to synthesize 3-phosphate-hydroxypyruvic acid, can effectively promote synthesis of L-serine in a metabolic pathway of microorganisms, improves the yield and conversion rate of the L-serine, and reduces the yield of byproducts at the same time.

The invention provides an anion-cation co-doped modified lithium manganese phosphate positive electrode material and a preparation method thereof, the lithium manganese phosphate positive electrode material comprises anion-cation doped lithium manganese phosphate and a carbon layer, the carbon layer is coated on the surface of the anion-cation doped lithium manganese phosphate, the chemical general formula is LiMn < 0.6 > Fe < 0.4-x > M < x > PO < 4-y > Fy, 0.001 < = x < = 0.03, 0.01 < = y < = 0.5, and 0 < = y < = 0.5. M is a cation, and Y is a fluorine ion. According to the preparation method, carbon layer coating and anion and cation co-doping modification of the lithium manganese iron phosphate positive electrode material are simultaneously realized through a one-step hydrothermal method, and the prepared lithium manganese iron phosphate positive electrode material is in an irregular spherical shape, relatively smooth in particle surface, and relatively high in large and small particle grading and compaction; after a performance test, compared with an electrode material which is not doped with anions and cations, the material disclosed by the invention has the advantages that the stability and the discharge capacity of the material are remarkably improved, and the electrochemical performance of the lithium manganese iron phosphate positive electrode material is effectively improved.

The invention relates to a preparation method and application of high-compaction-density composite sodium ferric phosphate. The preparation method comprises the following steps: weighing a sodium source, an iron source and a phosphorus source according to a stoichiometric ratio of [xNa + (a-x) A]: [yFe + (b-y) B]: P = a: b: (c + 2), mixing and dispersing the iron source, the sodium source, the phosphorus source and a chelating agent into pure water, reacting for a period of time at a certain temperature, transferring into a sand mill for grinding, adding a dispersing agent, cane sugar, the dopants A and B, and obtaining slurry F after grinding; and carrying out spray drying on the slurry F to obtain powder K. The powder K is transferred to a tubular furnace, and the oxygen content is 1t under the N2 protective atmosphere; and calcining at the temperature of 450-600 DEG C under the pressure of 50 ppm, and then carrying out air jet pulverization to obtain sodium ferric pyrophosphate positive electrode material powder with high compaction density and a molecular formula of (NaxAa-x) (FeyBb-y) (PO4) cP2O7. When the product is used, the compaction density is high, the dynamic performance of the material is enhanced, the thermal stability and chemical stability of the material are improved, and the electrochemical performance is good.

The invention discloses thermophilic fungus cleavable polysaccharide monooxygenase and application thereof, and belongs to the technical field of enzyme engineering and microbial engineering. The thermophilic fungus lysing polysaccharide monooxygenase provided by the invention has excellent thermal stability; when the lysable polysaccharide monooxygenase is used for synergistically hydrolyzing phosphoric acid swelling cellulose, microcrystalline cellulose and bagasse, the enzymolysis rate is increased, and the problems of poor thermal stability of the lysable polysaccharide monooxygenase, low enzymolysis rate of synergic cellulase and high LPMOs enzyme dosage are solved. The method has high practicability and can be widely applied to the enzymolysis process of various cellulosic substrates, so that the enzymolysis efficiency of the cellulosic substrates is remarkably improved.

The invention discloses low-alkali solid waste cementing material-based plant-growing concrete and a preparation method thereof. The vegetation concrete comprises a base layer framework and a surface layer material laid on the framework. Wherein the base layer framework is prepared from the following raw material components in parts by weight: 160 to 200 parts of low-alkali solid waste cement, 15 to 25 parts of phosphogypsum, 1380 to 2100 parts of mineralized concrete recycled aggregate, 62 to 102 parts of mineral admixture and 60 to 90 parts of mixing water. The surface layer material comprises the following raw material components: 1-5% of sodium alginate, 1-10% of calcium superphosphate, 1-10% of urea and the balance of soil. The mineralized concrete recycled aggregate is prepared by the following steps: soaking the concrete recycled aggregate in a diammonium hydrogen phosphate solution, and separating out the aggregate after soaking is completed, thereby obtaining the mineralized concrete recycled aggregate. According to the plant-growing concrete, alkalinity in concrete pores can be remarkably reduced, and the plant-growing concrete has stable later strength and good plant germination rate.

The invention discloses a preparation method and application of low-magnetic foreign matter and high-compaction lithium iron phosphate. The preparation method comprises the following steps: S1, mixing a lithium source, an iron source, a phosphorus source, a carbon source and water, grinding, drying, sintering in an inert atmosphere at 770-830 DEG C, and cooling to obtain a lithium iron phosphate material; and S2, placing the lithium iron phosphate material obtained in the step S1 in an inert atmosphere for secondary sintering, controlling the oxygen content to be less than 5ppm, and controlling the secondary sintering temperature to be 700-830 DEG C, so as to obtain the low-magnetic foreign matter and high-compaction lithium iron phosphate. The content of magnetic foreign matter iron phosphide in the prepared low-magnetic foreign matter and high-compaction lithium iron phosphate is lower than 50 ppb, the compaction density reaches 2.75 cm < 3 > / g or above, the 0.1 C discharge specific capacity is 163 mAh / g or above, and the 1C discharge specific capacity is 150 mAh / g or above.

The invention relates to the technical field of electrode materials, in particular to a silicon-carbon negative electrode material and a preparation method and application thereof. The silicon-carbon negative electrode material comprises a plurality of silicon-carbon composite particles, each silicon-carbon composite particle comprises porous carbon, nano silicon particles and phosphorus element which are attached in pores of the porous carbon, and coating carbon for coating the porous carbon, and n-type doping of the phosphorus element is formed at the joint of the nano silicon particles and the porous carbon. The preparation method comprises the following steps: (1) adsorbing phosphoric acid in porous carbon, and carrying out a heating reaction in a protective gas atmosphere to generate phosphorus-infiltrated porous carbon; (2) introducing a gaseous silicon source in a protective gas atmosphere, and carrying out silicon deposition on the phosphorus-infiltrated porous carbon by adopting a chemical vapor deposition method to obtain a phosphorus-doped silicon carbon material; and (3) carrying out carbon coating on the phosphorus-doped silicon carbon material to obtain the phosphorus-doped silicon carbon material. According to the method, the rate capability of the silicon-carbon negative electrode material can be remarkably improved while high first efficiency and high gram capacity are ensured.

The present application belongs to the technical field of battery materials. Disclosed are a doped iron (III) phosphate, a method for preparing same, and use thereof. The chemical formula of the doped iron (III) phosphate is (MnxFe1−x)@FePO4·2H2O, wherein 0<x<1. According to the present application, ferromanganese phosphate is used as a template agent for preparing the doped iron (III) phosphate. The doped iron (III) phosphate is regular in morphology and good in fluidity, facilitates washing and conveying, and can improve the electrochemical performance of the subsequently prepared LiFePO4 / C. When the doping amount of Mn is 11000 ppm, the specific discharge capacity of LiFePO4 / C at room temperature at 0.1 C rate can reach 165 mAh / g; the retention rate of the discharge capacity of 1000 cycles at 45° C. at 1 C rate can reach 97.4%; and at a low temperature of −15° C. the specific discharge capacity at 0.1 C rate is still 134 mAh / g.

The invention relates to the technical field of cables, and provides a fireproof flame-retardant 10kV power cable and a preparation method thereof. The fire-resistant flame-retardant 10kV power cable comprises a conductor and a fire-resistant flame-retardant layer, the fireproof flame-retardant layer is prepared from the following raw materials in parts by weight: 35 to 45 parts of linear low-density polyethylene, 40 to 50 parts of ethylene-vinyl acetate copolymer, 25 to 30 parts of modified aluminum hydroxide, 5 to 8 parts of polyethylene grafted maleic anhydride, 10 to 12 parts of phosphate modified halloysite nanotube, 5 to 8 parts of ZIF-8 loaded zinc borate core-shell particles, 15 to 20 parts of magnesium hydroxide and 2 to 3 parts of silane coupling agent. 0.5 to 1 part of antioxidant, 0.5 to 1 part of calcium stearate and 1 to 1.5 parts of polyethylene wax. According to the cable prepared in the invention, the situation that a conductor is exposed and the fire resistance is lost due to cracking and falling under long-time high-temperature baking is avoided; the continuous effectiveness of the flame retardant at high temperature is improved.

The invention discloses a chitosan modified lithium iron phosphate and carbon composite positive electrode material and a preparation method thereof.The preparation method comprises the steps that 1, lithium hydroxide, phosphoric acid and ferrous sulfate heptahydrate are mixed to prepare a uniform and stable solution, and a lithium iron phosphate precursor is prepared through a solvothermal method; step 2, dissolving chitosan in an acetic acid aqueous solution, and magnetically stirring under a water bath condition until the chitosan is completely dissolved to prepare a chitosan solution; and 3, adding the lithium iron phosphate precursor into a chitosan solution, uniformly mixing, carrying out ball milling and freeze drying, and carrying out high-temperature carbonization treatment in an inert gas to obtain the chitosan modified lithium iron phosphate and carbon composite positive electrode material. The method is simple to operate, low in cost and uniform in product particle size distribution.

The invention relates to the technical field of low-carbon olefin hydration, and discloses a modified hydrated filler as well as a preparation method and application thereof. The modified hydrated filler comprises a filler matrix, and a silane layer, a modified layer A and a modified layer B which are sequentially coated on the outer surface of the filler matrix from inside to outside, the modified layer A contains a pyrrolyl group, an amido group and a furyl group; the modified layer B contains phenoxy, pyrrolyl, furyl, sulfonic acid group, phosphate group and acylamino. The modified hydrated filler provided by the invention can obviously improve the mixing effect of water and alkene and promote the improvement of the yield of low-carbon alcohol.

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.