5189 results about "Phosphoric acid" patented technology

The present invention discloses a self-assembled monolayer hole transport material based on an alkyl polyphosphate anchoring group, a synthesis method thereof, and an application in an inverted perovskite solar cell. The present invention uses carbazole or 3,6-diphenylcarbazole with good hole transport properties as a parent core, and achieves complete coverage and stable self-assembly of the material on the substrate surface by improving the anchoring group from traditional alkyl monophosphate to alkyl diphosphate and triphosphate. The synthesis method of the present invention is simple and the synthesis cost is low. The prepared material can achieve the dual functions of hole transport and perovskite interface passivation, while enhancing the self-assembly strength and stability. When the material is used as a hole transport layer in an inverted perovskite solar cell, a photoelectric conversion efficiency of >20% can be obtained without doping, and the material has broad application prospects.

The invention provides a high-temperature-resistant and high-salt-resistant nano imbibition agent as well as a preparation method and application thereof. The high-temperature-resistant and high-salt-resistant nano imbibition agent is prepared from amination modified mesoporous silica nanoparticles, nano cellulose, rhamnolipid, an anionic surfactant, citrate modified sodium zirconium phosphate, polyethylene glycol-b-polycaprolactone and a sulfydryl-carboxyl imidazoline derivative, therefore, the composite carrier formed by the aminated mesoporous silica nanoparticles and the nanocellulose has high mechanical strength and uniform dispersity, the oil-water interfacial tension is reduced through the synergistic effect of the rhamnolipid and the anionic surfactant, and the crude oil stripping efficiency is remarkably improved; the citrate modified sodium zirconium phosphate enables the salt resistance of the system to be greatly improved, and in a high-temperature and high-salt oil reservoir environment, the nano imbibition agent can remarkably improve the crude oil recovery rate and reduce the injection pressure and dosage; meanwhile, good adsorption resistance is achieved, and reservoir blockage is prevented; in addition, low-toxicity corrosion inhibition components protect equipment, and the service life of an oil well is prolonged.

The invention relates to the technical field of cables, and provides a fireproof flame-retardant 10kV power cable and a preparation method thereof. The fire-resistant flame-retardant 10kV power cable comprises a conductor and a fire-resistant flame-retardant layer, the fireproof flame-retardant layer is prepared from the following raw materials in parts by weight: 35 to 45 parts of linear low-density polyethylene, 40 to 50 parts of ethylene-vinyl acetate copolymer, 25 to 30 parts of modified aluminum hydroxide, 5 to 8 parts of polyethylene grafted maleic anhydride, 10 to 12 parts of phosphate modified halloysite nanotube, 5 to 8 parts of ZIF-8 loaded zinc borate core-shell particles, 15 to 20 parts of magnesium hydroxide and 2 to 3 parts of silane coupling agent. 0.5 to 1 part of antioxidant, 0.5 to 1 part of calcium stearate and 1 to 1.5 parts of polyethylene wax. According to the cable prepared in the invention, the situation that a conductor is exposed and the fire resistance is lost due to cracking and falling under long-time high-temperature baking is avoided; the continuous effectiveness of the flame retardant at high temperature is improved.

The invention discloses a chitosan modified lithium iron phosphate and carbon composite positive electrode material and a preparation method thereof.The preparation method comprises the steps that 1, lithium hydroxide, phosphoric acid and ferrous sulfate heptahydrate are mixed to prepare a uniform and stable solution, and a lithium iron phosphate precursor is prepared through a solvothermal method; step 2, dissolving chitosan in an acetic acid aqueous solution, and magnetically stirring under a water bath condition until the chitosan is completely dissolved to prepare a chitosan solution; and 3, adding the lithium iron phosphate precursor into a chitosan solution, uniformly mixing, carrying out ball milling and freeze drying, and carrying out high-temperature carbonization treatment in an inert gas to obtain the chitosan modified lithium iron phosphate and carbon composite positive electrode material. The method is simple to operate, low in cost and uniform in product particle size distribution.

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention belongs to the technical field of flame-retardant macromolecules, and particularly relates to intrinsic heat-conducting flame-retardant recycled epoxy resin and a preparation method thereof. The preparation method comprises the following steps: (1) carrying out a reaction on diethanol amine and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) to obtain an intermediate A; and (2) carrying out condensation polymerization on the intermediate A and phenylphosphonic acid to prepare the phosphate-terminated polyester flame retardant (PEF). And (3) carrying out epoxidation on 4, 4 '-biphenol to prepare the liquid crystal epoxy precursor LEP. And (4) mixing PEF, LEP and 3, 3 '-dithiodipropionic acid, and heating and curing to prepare the epoxy resin. The prepared epoxy resin has intrinsic heat conduction, flame retardance and efficient recoverability, and is a high polymer material with great potential.

The invention belongs to the field of modified self-repairing calcium aluminate cement 3D printing, and particularly relates to a phosphate modified self-repairing calcium aluminate cement 3D printing material and a preparation method thereof. The phosphate modified self-repairing calcium aluminate cement 3D printing material prepared by the invention is prepared from the following raw materials in parts by mass: 60 to 70 parts of calcium aluminate cement, 3 to 7 parts of silica fume, 2 to 4 parts of metakaolin, 0.5 to 3.5 parts of double-template modified calcium bentonite, 0.8 to 1.5 parts of amino modified sodium polyphosphate and 0.15 to 0.8 part of basalt fiber. The invention relates to a concrete anti-microbial agent, which is prepared from the following raw materials in parts by weight: 20-30 parts of water, 20-30 parts of water, 20-30 parts of water, 20-30 parts of nano calcium carbonate, 20-30 parts of nano calcium carbonate, 20-30 parts of magnesium phosphate cement coated bacteria-loaded porous microspheres, 20-30 parts of a polycarboxylate superplasticizer, 20-30 parts of an organic silicon defoaming agent and 25-35 parts of mixing water. The technical-economic cooperation requirement of building 3D printing under complex working conditions is met, and various indexes of phosphate modified calcium aluminate cement applied to the 3D printing technology are met.

The invention relates to a modified chrome corundum ramming material and a preparation and construction process thereof, and belongs to the technical field of chrome corundum ramming materials. The ramming material comprises a material A, a material B and a material C, wherein the material A comprises chrome corundum aggregate, titanium dioxide coated aluminum oxide microspheres, calcium sulfide dehydrate and silicon carbide porous microspheres; the material B comprises chromium oxide-zirconium oxide composite nano powder, sodium thiosulfate pentahydrate, tricalcium phosphate and hexagonal boron nitride flaky crystals; and the material C comprises an aluminum dihydrogen phosphate-magnesium hydroxide compound, a calcium fluoride-aluminum oxide co-melt and a silane coupling agent. The preparation process comprises the steps of pretreatment of all the components, preparation of composite powder and layered preparation. The construction process comprises the steps of pretreatment, wet-process mixing, layered ramming, negative-pressure permeation, medium-temperature reaction, spraying curing, integral firing and the like. Generation of hexavalent chromium can be effectively inhibited, the thermal shock resistance, the mechanical strength and the heat-conducting property of the material are remarkably improved, and the material has the advantages of being good in environment friendliness, long in service life, excellent in construction performance and the like.

This invention discloses a method for leaching lithium iron phosphate mixed powder with iron salts and recovering all components, belonging to the field of battery recycling. The invention uses an iron salt solution to leach the mixed powder, obtaining a lithium-containing leachate and leaching residue. Ferrous ions in the leachate are regenerated into ferric iron through acidification and oxidation, and recycled for leaching the next batch of mixed powder. After reaching a preset number of cycles, the leachate is used for re-leaching multiple batches of leaching residue to improve the lithium leaching rate. Ultimately, a enriched solution containing Li, Fe, Cu, and Al and graphite-containing iron phosphate residue are obtained. Copper is recovered from the enriched solution through iron powder replacement, and a high-purity lithium chloride solution is obtained through extraction and separation, while ferric chloride (recycled) and aluminum chloride crystals are also recovered. The leaching residue is treated with hydrochloric acid to obtain regenerated graphite, and the pH is adjusted with alkali to obtain high-purity iron phosphate. This method achieves full component recovery under mild conditions, reducing separation steps and chemical consumption through a "leaching-regeneration-leaching" cycle mechanism, thus achieving both environmental and economic benefits.

The present invention relates to a system and a treatment method for treating high-phosphorus wastewater and resourcefully utilizing phosphorus elements. The system includes a bipolar membrane electrodialysis device, a phosphorus precipitator, and a membrane treatment device. Inside the bipolar membrane electrodialysis device, there are successively arranged a cathode, a first bipolar membrane, a main cation exchange membrane, a main anion exchange membrane, a second bipolar membrane, and an anode. Between the first bipolar membrane and the main cation exchange membrane is an alkali chamber, between the main cation exchange membrane and the main anion exchange membrane is a wastewater chamber, between the main anion exchange membrane and the second bipolar membrane is an acid chamber, the outside of the first bipolar membrane is a cathode chamber, and the outside of the second bipolar membrane is an anode chamber; the high-phosphorus wastewater is input into the wastewater chamber, the acid chamber is provided with a phosphoric acid recovery pipe, and the alkali chamber and the wastewater chamber are respectively connected to the phosphorus precipitator through an alkali liquid pipe and a first water production pipe; the phosphorus precipitator is provided with a precipitant inlet for inputting a calcium precipitant or a magnesium precipitant, the concentrated water outlet of the membrane treatment device is connected to the wastewater chamber, and the produced water of the membrane treatment device is reused as reclaimed water.

The invention relates to a bionic exosome for anti-inflammation and repair as well as a preparation method and application thereof, and belongs to the field of cosmetics. The bionic exosome provided by the invention comprises a membrane structure and an internal load phase, the membrane structure comprises a phospholipid bilayer, a stabilizer and a targeting ligand; the internal load phase comprises a solvent and an active component; the phospholipid bilayer is composed of phospholipid compounds; preferably, at least one of the distearoyl phosphatidyl ethanolamine-polyethylene glycol 2000 and the 1, 2-dioleoyl-sn-glycerol-3-phosphoethanolamine is adopted as the phospholipid compound, and at least one of the distearoyl phosphatidyl ethanolamine-polyethylene glycol 2000 and the 1, 2-dioleoyl-sn-glycerol-3-phosphoethanolamine is adopted as the phospholipid compound; at least one of cholesterol, phytosphingosine and sodium stearoyl glutamate is preferably adopted as a stabilizer, so that the stabilizer of the obtained bionic exosome is improved, and the bionic exosome has the advantages of high encapsulation efficiency, good encapsulation efficiency stability, simplicity in operation, excellent anti-inflammatory and repairing effects and the like.

The invention relates to the field of battery materials, in particular to a preparation method and application of a high-rate silicon-carbon negative electrode material. The preparation method of the high-rate silicon-carbon negative electrode material comprises the steps of silicon powder pretreatment, silicon-carbon powder composite ball milling, phosphoric acid treatment, high-temperature carbonization and the like. The preparation method of the high-magnification silicon-carbon negative electrode material is simple in process and high in success rate, the cycle stability of a negative electrode is effectively improved, the silicon-carbon negative electrode material has the characteristics of low expansion volume and long cycle life, the phenomenon that a surface oxide layer hinders lithium ion diffusion is avoided, and the service life of the silicon-carbon negative electrode material is prolonged. The comprehensive performance requirement of the existing lithium ion battery on the negative electrode material is met, and the application potential is very wide.

The invention provides a self-repairing hydrated salt phase change microcapsule as well as a preparation method and application thereof, and belongs to the field of phase change materials. The preparation method comprises the following steps: preparing a hydrated salt phase change material and sorbitol into eutectic melt by adopting a melting method; strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica are added into the eutectic melt, and blending is performed to obtain a core material; The preparation method comprises the following steps: adding strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica into the eutectic melt; bio-based polyurethane-polyurea is used as a shell material, the core material is coated in the shell to prepare the microcapsule, and the temperature of the coating operation is not higher than the phase change temperature of the hydrated salt phase change material; the surface is coated with a super-hydrophobic coating. According to the invention, a solid filler system is constructed, and a low-temperature preparation process is combined, so that the phase-change microcapsule with high performance, high reliability and high safety is developed.

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

The invention provides a method for recycling a waste lithium iron phosphate battery positive electrode material based on organic solvent soaking. The method comprises the following steps: mixing waste lithium iron phosphate positive electrode material powder and a crown ether chelating type co-dissolving agent to obtain a leaching solution; hydrogen peroxide is added into the leachate, the pH is adjusted, a diammonium hydrogen phosphate solution is added, and iron phosphate and filtrate containing lithium ions are obtained; adding sodium carbonate into the filtrate containing lithium ions, and adjusting the pH value to obtain lithium carbonate; mixing the iron phosphate with a phosphoric acid solution to obtain purified iron phosphate; and mixing the purified iron phosphate, lithium carbonate and acetylene black to obtain the regenerated lithium iron phosphate positive electrode material. According to the method for recycling the positive electrode material of the waste lithium iron phosphate battery based on soaking of the organic solvent, the leaching rate of the lithium element is effectively increased, the selectivity to other metal ions is low, and the regenerated positive electrode material of the lithium iron phosphate battery has relatively high discharge capacity and good cycling stability.

The invention provides a biochar composite porous material for heavy metal contaminated soil remediation and a preparation method and application of the biochar composite porous material. The preparation method comprises the steps that biomass raw materials are subjected to high-temperature pyrolysis carbonization and then smashed, ground and sieved, and biochar powder is obtained; dispersing in a phosphoric acid solution to obtain a biochar solution, and filtering, washing and drying after a hydrothermal activation reaction to obtain activated biochar; dispersing in a chitosan solution, carrying out ultrasonic oscillation, filtering, washing and drying to obtain modified charcoal; mixing sodium bentonite, attapulgite and deionized water, uniformly mixing the modified charcoal, the functional slurry and a sodium carboxymethyl cellulose solution to obtain composite slurry, performing compression molding to obtain a green body, and then drying and calcining the green body. The biochar composite porous material prepared by the invention can simultaneously play multiple roles of physical adsorption, chemical chelation, ion exchange and the like in a heavy metal contaminated soil treatment process, so that efficient fixation of various heavy metal ions is realized.

The invention discloses a manganese hydrogen phosphate precursor, lithium iron manganese phosphate, a preparation method of the manganese hydrogen phosphate precursor, a positive pole piece containing the lithium iron manganese phosphate, a battery containing the lithium iron manganese phosphate, and an electric device containing the lithium iron manganese phosphate. The preparation method comprises the following steps: firstly, carrying out primary precipitation reaction on soluble manganese salt and a precipitator to prepare manganese hydroxide, and then carrying out secondary precipitation reaction on the manganese hydroxide and phosphoric acid to prepare the manganese hydrogen phosphate precursor. The manganese hydrogen phosphate precursor with low impurity ion content and high yield is prepared through secondary precipitation reaction.

The invention relates to a waste photovoltaic panel recycling method which comprises the following steps: crushing a waste photovoltaic panel until the size of the waste photovoltaic panel is 80-160 meshes, and preparing powder; carrying out acid leaching treatment on the powder, and respectively collecting a leaching solution and a solid material; an acid leaching solution adopted in the acid leaching treatment is a mixed acid aqueous solution of hydrochloric acid and sulfuric acid; the pH of the leachate is adjusted to be neutral with an alkaline agent, then the leachate is mixed with metal iron to be subjected to a replacement reaction, and metal copper is prepared; the solid material is mixed with water, hydrofluoric acid and a flotation agent are added into the obtained mixture for flotation treatment, floats and precipitates are collected respectively, the floats comprise silicon powder, the precipitates comprise glass powder, and the flotation agent comprises one or two of hexadecyl potassium hydrogen phosphate and sodium dodecyl sulfate. According to the recycling method, the silicon powder, the glass powder and the metal copper can be comprehensively recycled from the waste photovoltaic panel.

The invention discloses an electrolyte for a lithium manganate lithium ion battery and a preparation method thereof, and the electrolyte comprises the following components in percentage by mass: 70-90% of an organic solvent, 5-20% of a lithium salt and 0.5-10% of an additive, the organic solvent is formed by mixing cyclic carbonate and chain carbonate according to the mass ratio of (10-30): (70-90); the lithium salt adopts one or more of lithium hexafluorophosphate (LiPF), lithium tetrafluoroborate (LiBF) and lithium bis (trifluoromethane sulfonimide) (LiTFSI), and the concentration of the lithium salt is 0.8 to 1.5 mol / L; the additives comprise a manganese ion complexing agent, a film forming accelerant and an antioxidant. In the invention, the manganese ion inhibition effect is as follows: the complexing agent and Mn (II) ions form a stable complex, so that the concentration of free Mn (II) in the electrolyte is reduced by more than 80%, migration and deposition of the free Mn (II) to the negative electrode are inhibited, and the dissolution amount of the Mn element of the positive electrode is reduced by 65% after 500 times of circulation at 45 DEG C.

The invention relates to the technical field of biochemical engineering, in particular to a method for preparing chiral alpha-trifluoromethyl alcohol by using imine reductase AtRedAm, trifluoromethyl ketone is reduced into corresponding chiral trifluoromethyl alcohol at an excellent conversion rate by using the imine reductase AtRedAm, and enantioselectivity is high. The reaction depends on an NADPH (Nicotinamide Adenine Dinucleotide Phosphate) coenzyme circulation system, 10% dimethyl sulfoxide is used as a reaction cosolvent, the reaction is carried out in a 100mM (pH = 7.5) phosphate buffer solution for 16 hours, the highest molar conversion rate reaches 99%, and the highest optical purity reaches 95%.

The invention provides a self-assembled monomolecular layer hole transport material based on a polycarbazole derivative and a preparation method and application thereof, and the self-assembled monomolecular layer hole transport material has a structure as shown in a formula I. The self-assembled monomolecular layer hole transport material is simple in structure, high in hole transport property, strong in interface passivation ability, high in thermal stability, and suitable for large-scale application; a polycarbazole derivative is taken as a mother nucleus, an alkyl / aryl chain is taken as a linking group, phosphoric acid is taken as an anchoring group, and rigid conjugated large-plane polycarbazole with a specific structure is taken as the mother nucleus, so that molecular accumulation can be improved, and the hole transport performance of the material can be improved. By taking a phosphate group as a tail end, single-molecule self-assembly can be realized, a perovskite interface can be passivated, the energy loss at the interface is reduced, and the battery performance is improved.

The invention belongs to the technical field of PCTFE film preparation, and particularly relates to a preparation process of a PCTFE film with low water vapor permeability, high strength and yellowing resistance. The preparation process comprises the following steps: (1) preparing modified polytrifluorochloroethylene resin; (2) preparing a mixture of fluorosilane modified alpha-zirconium phosphate and vermiculite nanosheets; (3) preparing a KH-550 silane coupling agent modified aluminum borate crystal whisker; and (4) preparing the PCTFE film with low water vapor permeability, high strength and yellowing resistance. According to the preparation technology of the PCTFE film, segmented temperature control is matched with the shearing speed in the twin-screw extrusion process, agglomeration of a mixture of fluorosilane modified alpha-zirconium phosphate and vermiculite nanosheets is avoided, performance complementation of all the components is ensured, the strength of the prepared PCTFE film is enhanced through aluminum borate whiskers, and the tensile strength of the PCTFE film is improved. The antioxidant and the ultraviolet light absorber solve the oxidation problem in high-temperature processing, and synchronous improvement of barrier, strength and weather resistance is achieved.

The present invention discloses a 3D three-dimensional glaze, which comprises the following components in percentage by weight: 45% - 60% of silicon dioxide, 17% - 25% of aluminum oxide, 1% - 2% of calcium oxide, 0.06% - 1.2% of magnesium oxide, 0.4% - 0.6% of sodium oxide, 1% - 3% of potassium oxide, 10% - 20% of zirconium oxide, 0.2% - 0.6% of zinc oxide, and 1% - 3% of boron oxide; the loss on ignition of the 3D three-dimensional glaze is 1.8% - 3.6%. The preparation method of the 3D three-dimensional glaze is to quantitatively weigh powders such as zirconium silicate, quartz powder, calcined alumina, potassium feldspar, ceramic frit powder, sodium carboxymethyl cellulose, and industrial tripolyphosphate, and then sequentially add the powders and emulsifying wax into water and stir to obtain a glaze slurry. After adjusting the viscosity of the glaze slurry, the 3D three-dimensional glaze is obtained by passing through an 80-mesh sieve. The present invention improves the adhesion of the 3D three-dimensional glaze on the surface of the green body, and when fired directly or in combination with other glazes, the three-dimensional glaze lines will not collapse, crack, have bubbles or breakpoints.

The invention relates to the technical field of refractory materials, in particular to a waste magnesia-calcium brick-containing refractory material and a preparation method thereof, and the waste magnesia-calcium brick-containing refractory material comprises the following components: composite aggregate, calcium aluminate cement, urea resin-aluminum dihydrogen phosphate, active alpha-Al2O3 micro powder, silica micro powder and sodium tripolyphosphate. In the room-temperature spraying maintenance and low-temperature working stage, hydration of free CaO in the waste magnesia-calcium bricks and erosion of OH <-> are prevented through the hydrophobic effect of fluorinated polyphosphazene and modified zirconium oxide sol, and the compatibility and wettability of the composite aggregate and cement paste are improved through carboxylic acid groups of carboxyethyl silanetriol and polyethylene glycol monomethyl ether. According to the present invention, with the temperature rising, the aluminum dihydrogen phosphate forms the viscous liquid phase to wrap the aggregate so as to provide the temporary protection, the temperature continues to rise, the zirconium oxide and the nanometer Al2O3 react with the CaO and the MgO to generate the CaZrO3 and the MgAl2O3, the aluminum dihydrogen phosphate reacts with the nanometer Al2O3 in the system to generate the AlPO4, and the CaZrO3, the MgAl2O3 and the AlPO4 form the multi-phase fire-resistant structure so as to further improve the fire resistance of the fire-resistant material;

The invention relates to the technical field of multi-layer fabrics, and discloses a moisture-absorbing sweat-permeable functional fabric and a preparation method thereof. The surface of a polyester fabric is coated with a modified waterborne polyurethane emulsion, the surface of a chinlon fabric is coated with a modified carbon nanotube dispersion liquid, an inner layer and a surface layer are obtained, the inner layer and the surface layer are sewn, and the moisture-absorbing and sweat-permeable functional fabric is obtained. A hydrophilic chain segment in a molecular chain of the waterborne polyurethane improves the moisture absorption and sweat permeation effects through an adsorption-diffusion-desorption mechanism; the phosphorus element is decomposed into phosphoric acid, polyphosphoric acid and other substances during combustion to catalyze the fabric to be dehydrated into carbon, and the boron element enhances the thermal stability and oxidation resistance of a carbon layer, forms a physical barrier effect and improves the flame retardant property; the chitosan and the quaternary phosphonium salt have an antibacterial effect; the carbon nano tube can form a directional moisture guiding channel on the fabric fiber surface or fiber gaps, so that the dynamic moisture permeability of the fabric is improved; in addition, the carbon nanotubes can form a compact and continuous carbon layer at a high temperature, so that the flame retardant property of the fabric is improved.

The invention discloses an endoglucanase truncated mutant and an application of the endoglucanase truncated mutant. According to the invention, based on endoglucanase BsEGL from bacillus subtilis DLG, a truncated mutant is constructed by deleting a carbohydrate binding domain (CBM) of the endoglucanase BsEGL, and the truncated mutant is named as BsEGL [delta] CBM. Compared with BsEGL, the truncated mutant BsEGL delta CBM has the advantages that the thermal stability, the pH stability, the organic solvent tolerance and the like are remarkably improved, and the activity of degrading phosphoric acid expanded cellulose and corncob xylan is obtained. In addition, the enzymatic activity of the truncated mutant BsEGL delta CBM is remarkably improved by 6.41%, and the catalytic efficiency is remarkably improved. Due to the characteristics, the mutant can be suitable for industrial processes such as feed processing, papermaking, biological energy sources, spinning and food brewing, and is particularly suitable for enzyme catalytic reaction under extreme environments such as high temperature and low pH. The invention provides an enzyme preparation tool with excellent performance for efficient degradation of cellulose biomass, and has important application value.

The invention relates to the technical field of metal material hot working, and discloses a hot-rolled coiled plate production process which comprises the following steps: preparing a reaction type protective agent, the high-temperature-resistant coating is prepared from the following raw materials in parts by weight: 20 to 40 parts of tetraethoxysilane, 5 to 15 parts of triethyl phosphate, 1 to 5 parts of triethyl borate, 0.5 to 2.0 parts of cerous nitrate (III) hexahydrate, 0.1 to 1.0 part of lithium acetate and 0.01 to 0.05 part of vanadyl acetylacetonate (IV). Coating the surface of a hot-rolled plate blank with the protective agent; the coated plate blank is heated in a heating furnace, so that the protective agent forms a molten-state protective layer in situ; carrying out hot rolling on the plate blank with the molten protective layer; and cooling and coiling the hot-rolled steel strip. In the whole heating and hot rolling process, the molten protective layer isolates the contact between the steel and the oxidizing atmosphere, so that the generation of oxide scales is fundamentally inhibited, the production process is simplified, and the metal yield is increased.

The invention belongs to the technical field of traditional Chinese medicine detection, and discloses a detection method for a characteristic spectrum of Uighur medicine Kspecific heat extracting tablets and application of the detection method. The detection method provided by the invention comprises the following steps: preparing a test sample solution by taking a 75% methanol solution as a solvent, and determining the test sample solutions prepared from different batches of test samples by adopting ultra-high performance liquid chromatography to obtain a characteristic spectrum; the chromatographic conditions of the ultra-high performance liquid chromatography are as follows: a chromatographic column is a C18 chromatographic column, a mobile phase A is acetonitrile, a mobile phase B is a 0.1 vol% phosphoric acid solution, and the flow velocity is 0.25-0.35 mL / min; the detection wavelength is 0 to 18 minutes, and the wavelength is 327 nm; the time is 18 to 28.5 min, and the wavelength is 254 nm; when the time is 28.5 to 37.6 minutes, the wavelength is 242 nm; after 37.6 to 70 minutes, the wavelength is 210 nm; the sample size is 1 microliter, the column temperature is 20-40 DEG C, and gradient elution is carried out. The invention provides a more scientific identification and quality control method for the Kespecific heat tablets.

The invention relates to a base membrane for a composite current collector based on SiO2 nano composite modification and a preparation method of the base membrane. Synergistic modified nano SiO2 is compounded with aluminum hypophosphite, montmorillonite and the like to form modified auxiliary particles, the modified auxiliary particles and PET master batches are subjected to blending extrusion, and meanwhile, the surface of the base membrane is coated with a modified coating containing nano SiO2, so that the composite current collector is obtained. The mechanical property, the thermal stability and the flame retardance of the base film are obviously improved.

The invention discloses a perfluorohexanone fire extinguishing agent and a preparation method and application thereof.The perfluorohexanone fire extinguishing agent is prepared from, by mass, 60-70 parts of perfluorohexanone microcapsules, 10-20 parts of aluminum hydroxide, 6-10 parts of graphite, 5-10 parts of titanium dioxide, 4-8 parts of ultraviolet absorbent, 2-6 parts of ammonium polyphosphate, 3-6 parts of calcium oxide, 1-3 parts of fumed silica, 1-3 parts of nano-silica and 1-3 parts of trimethyl phosphate. According to the formula and process of the fire extinguishing agent, through triple technical innovation of shell layer modification, nano compounding and supercritical deposition, the breakthrough of efficient explosion suppression, long-acting anti-after-combustion, low toxicity and environment friendliness of the fire extinguishing agent is achieved, and the industrial popularization potential is achieved.