349 results about "Acid group" patented technology

The invention relates to the field of water treatment, and discloses a scale and corrosion inhibitor for seawater circulating cooling water, which is prepared from phosphonic acid grafted maleic anhydride-acrylic acid copolymer, hydroxyethylidene diphosphonic acid, amino trimethylene phosphonic acid, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N- The anti-corrosion coating is prepared from the following raw materials: N, N-diethylaminomethyl-benzotriazole, gamma-aminopropyltriethoxysilane, zinc salt and a polyoxyethylene-polyoxypropylene block copolymer. The core of the invention is that all the raw material components form the thermo-sensitive polyelectrolyte compound through a self-assembly process. The compound is stably dispersed at low temperature by utilizing the cloud point effect of the block copolymer, and is subjected to phase change and preferential deposition on a high-temperature heat exchange surface, so that targeted and efficient delivery of various active components is realized. According to the invention, the problems of incompatibility of components and poor stability of a traditional compound agent are solved, the product has excellent storage stability, and efficient and synergistic corrosion and scaling control can be realized under high-temperature and high-salinity working conditions.

Processing aids and lubricants with free acid groups and relatively high molecular weights are used as process aids in the formation of extrudates and other molded materials. The compositions of this invention can be used as defined, or can be used with prior art processing aids, depending on the end use application. The novel materials and process provide a useful alternative to the sole use of fluorine-based polymer processing aids.

A pigment dispersion liquid containing a copolymer (A) having a first segment (a1) derived from a nitrogen-containing polymerizable unsaturated monomer having a tertiary amino group and / or a nitrogen-containing heterocyclic group, and a second segment (a2) derived from a polymerizable unsaturated monomer having a polyoxyalkylene chain, a hydrocarbon group-containing acidic compound (B), a pigment (C), and an aqueous solvent (D), and a hydrocarbon group-containing acidic compound (B) having a C5-23 saturated or unsaturated hydrocarbon group (b1) and at least one acid group (b2) selected from the group consisting of a carboxyl group, a phosphate group, a sulfonic acid group, and a phenol group.

The invention relates to the technical field of all-vanadium redox flow batteries, and discloses a supported electrolyte of all-vanadium redox flow battery positive and negative electrolyte and a preparation method thereof, and the supported electrolyte comprises an aqueous solution containing vanadium ions, sulfonate ions, sulfate ions and phosphonic acid groups. The sulfonic acid group (-SO3H) has strong polarity and high ionization degree, after the sulfonic acid group (-SO3H) is mixed with the phosphonic acid group (-PO3H2) and sulfuric acid, the ionic environment of the electrolyte can be optimized, the activation energy of V (II) / V (III) and V (IV) / V (V) electricity on electron transfer is reduced, and compared with an existing sulfuric acid supported electrolyte, the reversibility of electrochemical reaction is remarkably improved, and the electrochemical activity of the electrolyte is enhanced; meanwhile, phosphonic acid groups have high complexing ability, can form stable chelates with vanadium ions and can form complexing-dispersing synergy with sulfonic acid groups, the solubility of the vanadium ions is improved, and agglomeration and crystallization of the vanadium ions are inhibited.

The invention relates to the technical field of admixtures for cement concrete, in particular to a polycarboxylic acid admixture for enhancing low-activity admixtures and a preparation method thereof, the polycarboxylic acid admixture is formed by polymerizing the following components: polyether macromonomer, unsaturated carboxylic acid I, exciting functional monomer A, slump retaining functional monomer B, rheological functional monomer C, oxidizing agent, reducing agent, chain transfer agent and water; the exciting functional monomer A, the slump retaining functional monomer B and the rheological functional monomer C are sequentially added, and the exciting functional monomer A is formed by polymerizing polyhydric alcohol, unsaturated carboxylic acid II, an initiator, phosphonic acid and an alcohol amine small monomer. Through molecular design, key functional groups such as phosphonic acid groups, amino groups and sulfonic acid groups are innovatively introduced into a polycarboxylic acid main chain, so that the polycarboxylic acid admixture has multiple synergistic functions of reducing the cement consumption, effectively activating a low-activity cementing material, stably improving the working performance of concrete and the like.

The invention relates to the technical field of blood purification materials, in particular to a zirconium-titanium bimetal MOF hollow microsphere adsorbent and a preparation method and application thereof. The adsorbent is based on a Zr / Ti bimetallic node and a phosphonic acid-carboxylic acid mixed ligand, a composite MOF hollow microsphere structure with high stability and high specific surface area is constructed through a solvothermal and polymerization synergistic reaction in a water-in-oil suspension system, a phosphonic acid group and Zr are strongly coordinated to improve the stability of a framework, and the composite MOF hollow microsphere structure has a high specific surface area. The carboxylic acid group keeps the hydrophilicity of the pore channel; meanwhile, a cross-linked network of acrylamide and N, N '-methylene bisacrylamide penetrates through crystal gaps in the balling process, so that the material has excellent mechanical strength and fluid stability; and a sulphobetaine amphoteric polymer brush layer is constructed on the surface of the MOF through endogenous initiation point modification and surface in-situ controllable free radical polymerization technologies, so that protein adsorption and platelet adhesion are effectively inhibited, the blood compatibility is remarkably improved, and meanwhile, the channel accessibility is maintained to promote rapid diffusion and adsorption of bilirubin.

The problem to be solved by the present invention is to provide an aqueous pigment dispersion that can maintain superior dispersibility and long-term storage stability, and that can be used for producing printed matter superior in color development in printing on plain paper. The present invention relates to an aqueous pigment dispersion that contains a pigment including C.I. pigment red 150, a water soluble organic solvent, and a radical polymer having an aromatic ring structure or a heterocyclic structure and having an acid value of 50 to 120 mgKOH / g, acid groups in the radical polymer being partially or entirely neutralized with a basic compound, the radical polymer being contained at a mass ratio to the pigment in the range of 0.001 to 0.1.

The invention relates to the technical field of polyamide nanofiltration membranes, in particular to an acid and alkali resistant high-strength nanofiltration membrane and a preparation method thereof. The problem that the strength and the acid and alkali resistance of a polyamide nanofiltration membrane in the prior art cannot be considered at the same time is solved. The base membrane material of the polyamide nanofiltration membrane is modified polyethersulfone and is obtained by chemically bonding a carbon nanotube subjected to double surface modification by titanium dioxide sol-gel and a KH550 coupling agent in a polyester non-woven fabric, and the modulus of the material is improved by utilizing an inorganic-organic hybrid network; the functional layer of the polyamide nanofiltration membrane is made of modified polyamide, and the modified polyamide functional layer is formed by forming a polyamide matrix through polymerization reaction of 2, 2 '-disulfonic acid-4, 4'-diaminobiphenyl, piperazine and trimesoyl chloride and introducing 4-amino-2, 2, 6, 7-tetramethyl-1, 3-pentanediol at the same time. And the chemical resistance is improved by a free radical capturing group generated by 2, 2, 6, 6-tetramethylpiperidine and octa-isobutyl cage type silsesquioxane.

The invention relates to the technical field of adsorbents, and provides an efficient molecular sieve adsorbent for adsorbing carbon dioxide and a preparation method of the efficient molecular sieve adsorbent aiming at the problem that a traditional Na-type 13X molecular sieve is poor in CO2 adsorption performance under low partial pressure. The adsorbent is prepared by using a template agent, aluminum hydroxide, nano aluminum oxide and silica sol as raw materials through the steps of crystallization, calcination and the like. The template agent is a functional molecule integrating a phosphonic acid group, long-chain alkyl and polyethylene glycol dicarboxylic acid, the phosphonic acid group stabilizes a skeleton, the long-chain alkyl provides a graphene-like layer to inhibit water molecule adsorption, and the polyethylene glycol dicarboxylic acid guides micropores to grow orderly and cooperate with each other to form the efficient molecular sieve adsorbent for carbon dioxide adsorption. The CO2 adsorption capacity, the dynamic adsorption rate and the moisture resistance of the adsorbent under low partial pressure are improved.

The embodiment of the invention provides a perovskite cell and a preparation method thereof, a laminated cell and a photovoltaic module. The perovskite cell comprises a substrate, a first hole transport layer, a second hole transport layer, a tunneling layer, a perovskite functional layer, an electron transport layer and an electrode layer which are sequentially arranged in a preset direction, and the first hole transport layer comprises a carbazole derivative with a carboxyl anchoring group. The second hole transport layer comprises a compound of foldable molecules containing phosphonic acid groups, and the tunneling layer is of a network structure. The technical scheme provided by the embodiment of the invention at least has the following advantages: 1, foldable molecules containing phosphonic acid groups cover the gaps of the first hole transport layer after being folded to serve as the second hole transport layer, so that the wettability (contact angle lt: 10 degrees) of the perovskite precursor is improved;

The present invention relates to a highly dispersible organic-inorganic hybrid nanoparticle radical scavenger having excellent low elution characteristics and reversible regenerability and to an electrode composition comprising same, the highly dispersible organic-inorganic hybrid nanoparticle radical scavenger comprising nanoparticles in which an oxide of cerium (Ce) and silicon (Si) and an oxide of at least one metal (M) selected from transition metals and lanthanides are combined, wherein the nanoparticles have at least one functional group selected from an alkylsulfonic acid group and a fluoroalkylsulfonic acid group.

Provided is a water-based inkjet ink that is excellent in continuous ejection stability and straight ejection, and that provides excellent print density and print quality for prints on various printing substrates, particularly paper substrates, and further has good resolubility. [Solution] The aqueous inkjet ink comprises pigment particles including a pigment and a pigment dispersing resin that covers at least a portion of the surface of the pigment, an acetylene diol surfactant (B-1) having a measured HLB value of 6 to 9, a siloxane surfactant (B-2), an alkanediol having 3 to 4 carbon atoms, an alkanediol having 5 to 8 carbon atoms, and a glycol ether having 4 to 10 carbon atoms, wherein the pigment dispersing resin comprises a crosslinked reaction product of a polymer (A-1) that has an aromatic ring and an acid group and an acid value of 50 to 160 mg KOH / g, and a compound (A-2) that has multiple glycidyl ether groups in one molecule, and the compound (A-2) is blended in an amount that results in a glycidyl group content of 50 to 200 mol %.

Provided is a fluoroelastomer composition comprising a fluoroelastomer (a), a cross-linking agent (b), and an organic acid (c), wherein the organic acid (c) is at least one selected from the group consisting of an organic acid having 3 to 10 carbon atoms and having one acid group in a molecule, and an organic acid having 2 to 10 carbon atoms and having two or more acid groups in a molecule.

A release agent contains a polymer of a polymerizable component containing a (meth)acrylate having a long-chain alkyl group with carbon atoms of 12 to 22 and an acid group-containing ethylenic unsaturated bond-containing monomer, wherein an acid group is neutralized by ammonia and / or amines.

An ambipolar molecule, a preparation method thereof, and an application thereof are described. The chemical structure general formula of the ambipolar molecule provided by this application is represented by formula I.where R includes a Lewis base group, X1, X2, X3, X4, and X5 each include at least one of a hydrogen atom and a halogen atom, X1, X2, X3, X4, and X5 are not simultaneously hydrogen, and n is an integer greater than or equal to 1. The ambipolar molecule of this application simultaneously possesses a Lewis acid group and a Lewis base group, enabling it to passivate two types of defects at perovskite grain boundaries, namely undercoordinated anions and undercoordinated cations. Thus, when used in perovskite materials, such an ambipolar molecule can significantly improve the conversion efficiency and stability of perovskite.

The invention relates to the technical field of concrete admixtures, and particularly discloses a concrete super-plasticity-retaining retarder and a preparation method thereof. The concrete super-plasticity-retaining retarder is prepared from 100 to 200 parts of carboxyl / phosphonic acid group-containing unsaturated polyether monomer, 50 to 150 parts of phosphonic acid group-containing unsaturated monomer, 20 to 80 parts of acrylic acid, 1 to 5 parts of ammonium persulfate, 1 to 5 parts of ascorbic acid, 5 to 15 parts of chain transfer agent, 5 to 15 parts of nonionic polyurethane thickener, 1 to 2 parts of preservative and 600 to 800 parts of deionized water. According to the invention, the retarding effect and the stability when the retarder is used together with different types of water reducing agents can be improved.

To provide a laminate having a polyolefin layer, a vapor-deposited film, and an adhesive layer, the laminate exhibiting excellent gas barrier performance and excellent adhesion between the adhesive layer and an adjacent layer thereto.SOLUTION: A laminate comprises, in this order in the lamination direction, a first polyolefin layer, an adhesive layer containing a polyolefin plastomer and an acid group-containing ethylene-based polymer, and a second polyolefin layer, wherein a vapor-deposited film is further provided between the first polyolefin layer and the adhesive layer and / or between the adhesive layer and the second polyolefin layer.SELECTED DRAWING: Figure 1

A coloring composition includes at least one compound S selected from a compound S-1 represented by Formula (1) or a compound S-2 in which the compound S-1 is coordinated to a metal atom, a pigment, a resin P, and a solvent, in which the resin P includes at least one selected from a graft resin P-1 having a specific graft chain, a block copolymer P-2 including a specific structure, or a resin P-3 in which at least one terminal of a polymer chain including a specific structure is capped with an acid group.

The invention belongs to the technical field of wet electronic chemicals, and particularly relates to a buffer oxide etching solution (BOE) with high selection ratio of silicon dioxide (SiO2) to silicon oxynitride (SiOxNy) in semiconductor manufacturing, and the etching solution comprises the following components in percentage by mass: 0-20% of HF, 20-40% of NH4F, 0.01-0.05% of an impregnating compound, 0.005-0.01% of an additive and the balance of ultrapure water. The wetting agent is introduced, so that the wettability of the silicon dioxide film layer can be improved, and the etching roughness is improved; meanwhile, after 2-(2-(2-hydroxyethoxy)-ethoxy)-ethyl phosphonic acid is added, a phosphonic acid group can form coordination with a Si-N bond in silicon oxynitride, and the silicon oxynitride film etching selection ratio of silicon dioxide can be remarkably increased under the condition that the silicon dioxide etching rate is not reduced. The etching liquid is stable, the solution is clear and transparent, and the addition of the additive can reduce the surface tension and improve the infiltration and undercutting capabilities of the etching liquid.

An electrostatic image developing toner and a method for producing the toner, the electrostatic image developing toner containing a colorant, a resin composition (P) and an ester composition (C), the resin composition (P) being a resin composition obtained by condensing an amorphous polyester-based resin (A) having an acid group with an amine compound, the ester composition (C) being one or more selected from the following ester compositions (CI) and (CII). The ester composition (CI): an ester composition containing a condensate of a carboxylic acid component (CI-ac) containing 20 mol% or more of an aliphatic monobasic carboxylic acid compound having 10 to 30 carbon atoms and an alcohol component (CI-al) containing 90 mol% or more of an aliphatic alcohol having 2 or more valences having 2 to 14 carbon atoms; the ester composition (CII): an ester composition containing a condensate of an alcohol component (CII-al) containing 20 mol% or more of an aliphatic monohydric alcohol having 10 to 30 carbon atoms and a carboxylic acid component (CII-ac) containing 90 mol% or more of an aliphatic carboxylic acid compound having 2 or more valences having 2 to 14 carbon atoms.

The present application relates to the technical field of anti-icing, and provides a water gel material for promoting ice nucleation, a preparation method of the water gel material and an anti-icing coating, which can solve at least part of the problems existing in the ice nucleation materials in the prior art. The water gel material has a polymer network structure, which is obtained by mixing and reacting a first monomer, a second monomer, a photoinitiator and a crosslinking agent in water and then solidifying. The first monomer is a compound having an enamide group, and the second monomer has an enoic acid group. Experiments prove that the water gel material provided by the present application can induce the rapid formation and growth of ice nuclei at an ambient temperature of-2 DEG C. Compared with the existing ice nucleation materials, the water gel material has a higher nucleation temperature and good optical effect, and does not affect the transparency of the material.

This invention relates to the field of solar cell technology, and in particular to a self-assembled monolayer based on a fluorinated alcohol solvent, its preparation method, and a solar cell. The method involves adding a fluorinated alcohol as a co-solvent to a solution of the self-assembled monolayer material, which is then deposited onto the surface of a metal oxide electrode to construct a hole transport layer. The hydroxyl groups of the fluorinated alcohol can form hydrogen bonds with the phosphorus-oxygen double bonds in the phosphonic acid groups, reducing the electron density of the phosphorus atoms and thus weakening the chemisorption barrier of the self-assembled monolayer on the electrode surface, promoting the formation of a uniform and dense monolayer film. The resulting interface layer effectively suppresses interface defects and promotes hole extraction. Organic solar cells prepared using this method exhibit excellent performance in terms of energy conversion efficiency, stability, and large-area processing adaptability. This invention features a simple process, low cost, and good reproducibility, and has promising prospects for industrial application.

The present invention provides a composition capable of obtaining a transfer film having improved bendability when having a layer containing metal oxide particles. The composition contains an amine compound, metal oxide particles, and an adhesive polymer having an acid group, as a substituent of a nitrogen atom of the amine compound, has a substituent containing a linking group having a linking chain length of 3 or more, and the weight average molecular weight of the amine compound is 100 or more.

The present invention relates to a water-absorbing resin and a method for manufacturing the same. The method for manufacturing the same is to perform a polymerization reaction on an acid group-containing monomer using a specific amount of a foaming agent under pressure sealing to obtain a core layer having a specific surface porosity, and then perform a surface cross-linking reaction on the core layer using an acyclic monoterpene alcohol having a carbon number of 10 to 12 and a surface cross-linking agent, so that the water-absorbing resin obtained has both good water-absorbing properties and superior deodorizing efficacy.

Provided are: an ink that contains a pigment, water, a water-soluble organic solvent having a boiling point of 200°C or lower, a water-soluble polymer A which contains an acid group, and a water-soluble polymer B which contains an ethylene oxide group and does not contain an acid group, the amount of the water-soluble organic solvent having a boiling point of 200°C or lower being 5-20 mass% relative to the total amount of the ink, the total amount of the water-soluble polymer A and the water-soluble polymer B being 3-8 mass% relative to the total amount of the ink, and the water-soluble polymer A and the water-soluble polymer B both being free within the ink without being adsorbed to the pigment; and the use of the aforementioned ink.

The invention discloses a battery monomer, an isolating membrane, a preparation method of the isolating membrane, a battery device and a power utilization device, the battery monomer comprises the isolating membrane and electrolyte, and the isolating membrane comprises a porous base membrane; the coating is arranged on at least one side of the porous base membrane and comprises a polymer additive, and the polymer additive comprises a first functional group and a second functional group; the first functional group comprises one or more of bis (fluorosulfonyl) imino group, bis (trifluoromethyl) sulfonyl imino group, trifluoroboric acid group, hexafluorophosphoric acid group, sulfonic acid group, hexafluoroarsenate group, trifluoromethanesulfonic acid group, difluorophosphoric acid group, bis (oxalato) boric acid group, difluoro (oxalato) boric acid group, difluoro (oxalato) phosphoric acid group, tetrafluoro (oxalato) phosphoric acid group and imidazolyl; the second functional group comprises one or more of quaternary ammonium ions, pyrrolidinyl, pyrrolyl, piperidinyl, pyridyl and imidazolyl. The battery monomer has good dynamic performance; the invention provides the isolating membrane for realizing the beneficial effects of the battery monomer, the preparation method of the isolating membrane, the battery device and the power utilization device.

The invention belongs to the technical field of photocatalysis, and particularly relates to a composite catalyst as well as a preparation method and application thereof. The preparation method of the composite catalyst comprises the following steps: by taking melem as a photocatalytic active center, mixing melem with an H < + > solution at room temperature, and providing additional active sites by utilizing interaction between H < + > in a Bronsted acid solution and melem molecules, so as to prepare the composite catalyst with a synergistic catalytic effect. The acid group is introduced to the surface of the photocatalyst for modification, so that the modified photocatalyst has the properties of a solid acid catalyst at the same time, glucose is induced to be isomerized into fructose under the photocatalysis action of the composite catalyst, and meanwhile, under the synergistic effect of acid catalysis and photocatalysis in the composite catalyst, the fructose content is increased. Fructose is converted into hydroxymethylfurfural with high selectivity, and efficient and targeted preparation of hydroxymethylfurfural under a pollution-free condition is realized.

Organic molecules with free acid groups and a molecular weight of greater than 140 g / mol used in combination with surfactants, are used as processing aids in the formation of extrudates and other molded materials. The compositions of this invention can be used as defined herein, or can be used with prior art processing aids, depending on the end use application. The novel materials and processes provide a useful alternative to the sole use of fluorine-based polymer processing aids.

The application discloses an ionic liquid-based magnetic liquid and a preparation method thereof. The ionic liquid-based magnetic liquid comprises a magnetic mesoporous material, a functionalized ionic liquid and a base carrier liquid. The cation of the functionalized ionic liquid is R1R2R3R4N + , wherein R1 is C8-C 20 alkylcarboxylic acid group, R2 is C1-C8 alkyl, R3 is C1-C8 alkyl, and R4 is C1-C8 alkyl. The anion of the functionalized ionic liquid is any one of F ‑ , Cl ‑ , Br ‑ , and I ‑ . The application further provides the preparation method of the ionic liquid-based magnetic liquid. The ionic liquid-based magnetic liquid has good stability, is not easy to volatilize, is not flammable, can be applied to a wide temperature range, and the preparation method is simple and has low requirements on equipment.

This invention belongs to the field of pharmaceutical preparation technology, specifically relating to an HDAC inhibitor based on a tyrosine backbone, its synthesis method, and its application. The invention uses L-tyrosine as the backbone, with its aromatic ring as the Cap region, linked by a flexible alkyl chain via an ether bond, and terminated by an isohydroxamic acid group (ZBG). The tyrosine backbone provides a rigid structure, reducing entropy loss and enhancing hydrophobic interactions with the HDAC surface. By introducing substituents (such as halogens, methyl groups, etc.) onto the tyrosine benzene ring, the affinity with the HDAC active pocket is further optimized. The prepared compound b19 exhibits an HDAC inhibition capacity of 100%. 50 The concentration reached 26.8 nM, exhibiting superior antitumor activity compared to SAHA, especially against solid tumors such as HeLa cells with IC50. 50 It is 0.55 μM.