5329 results about "Maleic acid" patented technology

The invention relates to the field of matt films, in particular to a BOPP matt film suitable for a direct coating process and a preparation method of the BOPP matt film. The BOPP matt film suitable for the direct coating process comprises an upper surface layer, a middle core layer and a lower surface layer which are sequentially arranged, the upper surface layer is an extinction layer and comprises polypropylene random copolymer, 40-51 wt% of high-density polyethylene, 2-3 wt% of n-alkyl chain modified hyperbranched polyester and 5-8 wt% of maleic anhydride-styrene melt grafted polypropylene random copolymer; the middle core layer comprises homo-polypropylene; and the lower surface layer comprises homo-polypropylene. According to the matt film, the roughness of the matt layer can be improved by optimizing the components of the matt layer, the problem of whitening'hard spots' on the surface of the matt film in a direct coating process is solved, and then the quality of a coated matt film product is improved, so that the appearance quality of products such as laminated paper, paper boxes and labels which are subsequently laminated is ensured.

The invention discloses an environment-friendly calcium-zinc composite heat stabilizer and a preparation method thereof, and relates to the technical field of heat stabilizers. The environment-friendly calcium-zinc composite heat stabilizer is prepared from the following raw materials in parts by mass: 10-20 parts of zinc stearate, 20-30 parts of calcium stearate, 10-15 parts of an auxiliary stabilizer, 5-8 parts of a plasticizer, 1-5 parts of an antioxidant and 2-5 parts of filler, wherein the auxiliary stabilizer is a mixture of beta-diketone, modified organic acid intercalated hydrotalcite and modified silicon dioxide; the modified organic acid intercalated hydrotalcite is obtained by splitting expanded vermiculite, adding zinc and lanthanum compounds, coprecipitating with organic acid, and adding a modifier; the modified silicon dioxide is obtained by adding a coupling agent into a solid substance obtained by splitting expanded vermiculite for modification and carrying out a series of chemical reactions with maleic anhydride and pentaerythritol. PVC plastic prepared by adding the calcium-zinc composite stabilizer into PVC paste resin and resin powder has good thermal stability.

The invention discloses a polypropylene composite material based on rare earth element modification and a preparation method and application thereof, and belongs to the technical field of medical instruments, and the polypropylene composite material comprises the following raw materials in parts by weight: 100 parts of medical grade PP, 3-8 parts of a rare earth organic complex, 5-10 parts of nano-hydroxyapatite, 2-5 parts of a maleic anhydride grafted PP compatilizer and 0.3-0.5 part of an antioxidant, the invention also provides specific preparation steps and application thereof. According to the invention, oxide + salt bimorphological rare earth and an organic ligand are complexed to form a rare earth organic complex, so that the problem of poor dispersity of inorganic rare earth is solved, and meanwhile, the material is endowed with antibacterial and antistatic functions; through a melt blending-in-situ fiber forming process, the rare earth complex forms gradient distribution in a polypropylene matrix, the surface layer is enriched with antibacterial components, and the inner layer is enhanced in mechanical property, so that a low-cost solution with high strength, antibacterial property and biocompatibility is provided for high-end medical instruments, and the market blank is filled.

The invention relates to an anti-static PP composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The antistatic PP composite material is prepared from the following components in parts by weight: 60 to 80 parts of PP resin, 10 to 20 parts of glass fiber, 0.1 to 0.5 part of a lubricant, 0.3 to 2 parts of a modified antistatic agent, 0.5 to 1.5 parts of a modified flame retardant and 0.2 to 0.8 part of an antioxidant, in the modified antistatic agent, an alkanolamide bond intermediate forms a conductive film, so that the resistivity is reduced, static dissipation is promoted, the material is endowed with lubricity, and the generation of static electricity is reduced; in addition, maleic anhydride forms a conductive layer and cooperates with quaternary ammonium salt to enhance hydrophilicity and accelerate charge transfer; a piperazine pyrophosphate derivative in the modified flame retardant and a phosphorus-nitrogen flame retardant cooperate to construct an expanded carbon layer to isolate a fire source and oxygen, so that the service life is prolonged; the anti-static PP composite material prepared by the invention not only has a good anti-static effect, but also has excellent flame-retardant and tensile properties.

The invention belongs to the technical field of flame retardants, and particularly relates to a high-thermal-stability polyphosphate flame retardant and a preparation method thereof. The DOPO is modified through the polyethylene glycol acrylate, methyl methacrylate and dicumyl peroxide composite solution, double bonds of the polyethylene glycol acrylate and P-H bonds of the DOPO can be subjected to nucleophilic addition to form stable C-P bonds, and thermal migration of the DOPO is hindered; dOPO has polymerization double bonds of methyl methacrylate and long carbon chains of polyethylene glycol acrylate, so that the compatibility of the polyphosphate flame retardant and a polymer substrate is improved, and phase separation is avoided; maleic anhydride grafted silicone oil is connected to the surface of an amino modified gamma-cyclodextrin-modified DOPO inclusion compound, so that the polyphosphate flame retardant has high thermal stability and high compatibility after long-chain alkyl modification; amino groups in the modified gamma-cyclodextrin react with maleic anhydride grafted silicone oil to generate an amido bond cross-linked network, so that the thermal migration of DOPO is reduced together, and the high thermal stability of the polyphosphate flame retardant is improved.

The invention relates to the technical field of polymeric membrane materials, and particularly discloses an antistatic polyethylene composite membrane and a preparation method thereof. Comprising the following raw materials in parts by weight: 100 parts of low-density polyethylene, 5-9 parts of high-density polyethylene, 10-20 parts of maleic anhydride grafted polyethylene, 8-15 parts of a polyvinyl alcohol modified material, 3-5 parts of antistatic modified carbon black, 0.5-1 part of an antioxidant and 1-2 parts of a dispersing agent, the polyethylene composite film has excellent dispersibility, can effectively enhance the mechanical properties of the polyethylene composite film through the synergistic effect of physical filling and chemical grafting, forms a layer of conductive network structure, namely a conductive film, on the surface of the material through the combined effect of the polyethylene composite film and the antistatic agent, prevents the generation and accumulation of static electricity, and has good compatibility among the raw materials. And the material has excellent mechanical property and antistatic property.

The invention relates to an oil-resistant flame-retardant composite sealing material as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. Fluororubber, nitrile rubber, ethylene propylene diene monomer, chlorinated polyethylene and maleic anhydride grafted polypropylene are adopted to prepare composite rubber according to a certain proportion; then adding hydrogenated polyisobutene, a vinyl polydimethylsiloxane-polymethylsiloxane silsesquioxane cross-linked polymer, an E-GMA-VA terpolymer, magnesium hydroxide, basalt fiber powder, ammonium polyphosphate, triphenyl phosphate, expansible graphite, zinc borate, a vulcanizing agent, an accelerant, an anti-aging agent, a plasticizer and other components according to a proportion, and performing banburying in special steps; the prepared sealing material has good mechanical properties, especially has oil resistance and flame retardance, and the service life is greatly prolonged.

The invention relates to the technical field of flame-retardant polypropylene composite materials, in particular to a flame-retardant reinforced polypropylene composite material containing flame-retardant modified glass fibers and a preparation method of the flame-retardant reinforced polypropylene composite material. The flame-retardant modified glass fiber-containing flame-retardant reinforced polypropylene composite material is prepared from the following raw materials: 30 to 60 parts of polypropylene, 5 to 60 parts of flame-retardant modified glass fiber, 5 to 20 parts of piperazine pyrophosphate, 5 to 20 parts of melamine polyphosphate, 0.5 to 5 parts of flame-retardant synergist, 1 to 6 parts of maleic anhydride ester-grafted polypropylene, 0.5 to 3 parts of coupling agent, 0.3 to 3 parts of lubricant and 0.2 to 0.5 part of antioxidant. The flame-retardant modified glass fibers are glass fibers subjected to surface modification by using a focused piperazine phosphate-melamine polyphosphate random copolymer. According to the technical scheme, the problem that the mechanical property and flame retardant property of glass fiber reinforced polypropylene in the prior art are difficult to optimize at the same time can be solved, and the glass fiber reinforced polypropylene has ideal popularization and application prospects.

The invention discloses a preparation method of a B1-grade flame-retardant fire-resistant control cable, belongs to the technical field of flame-retardant fire-resistant cables, and aims to solve the technical problem that the mechanical strength and the fire-resistant and flame-retardant performance of an inorganic flame-retardant modified fire-resistant fire-resistant control cable in the prior art need to be further improved. The method comprises the following steps that a plurality of cable cores are arranged in parallel, gaps among the cable cores are filled with filling ropes to form filling layers, the cable cores filled with the filling layers are wrapped together through a wrapping tape, and a wrapping layer is formed outside the cable cores. According to the invention, maleic anhydride modified polyethylene is used as a phase solvent, and polyethylene is cross-linked and enhanced by modified graphite and modified polysiloxane, so that not only is the mechanical strength of the cable material effectively improved, but also the fire resistance and flame retardance of the cable material are improved.

The invention belongs to the technical field of oil and gas field development, and particularly relates to a CO2 thickening agent for supercritical CO2 oil displacement and a preparation method of the CO2 thickening agent. The preparation method of the CO2 thickening agent for supercritical CO2 oil displacement comprises the following steps: (1) mixing a maleic anhydride compound and a styrene compound, dissolving in water, introducing inert gas, and heating; (2) slowly dropwise adding a mixed solution of a vinyl acetate compound and an initiator, and cooling after the reaction is finished; and (3) filtering, washing a solid phase by using an anhydrous alcohol substance, drying, and grinding to obtain a thickening agent product. The supercritical CO2 thickened by the thickening agent prepared by the invention can effectively slow down the viscous fingering phenomenon in the displacement process and improve the CO2 sweep efficiency, thereby improving the crude oil recovery rate.

The invention relates to the technical field of high polymer materials, and particularly discloses a high-strength polypropylene composite material for a filter plate and a preparation method of the high-strength polypropylene composite material. The preparation method of the polypropylene composite material comprises the following steps: uniformly mixing polypropylene, polyimide, maleic anhydride grafted polypropylene, nylon 6, a maleic anhydride grafted styrene-butadiene-styrene copolymer, aminated calcium carbonate, modified glass fiber, an antioxidant and a lubricant according to a mass ratio of 100: (12-18): (2-5): (1-2): (3-5): (3-7): (6-10): (0.2-0.5): (0.1-0.3), carrying out melt blending, extruding, cooling, granulating, and carrying out extrusion molding to obtain the polypropylene composite material. Through the synergistic effect of the nano calcium carbonate and the glass fibers, the mechanical property of polypropylene is improved, all the raw materials are crosslinked to form a uniform network structure, more energy is absorbed when a matrix is impacted by external force, and it is guaranteed that the filter pressing plate is not damaged when deforming under the high-temperature and high-pressure conditions; the obtained polypropylene composite material is high in strength, good in heat resistance and excellent in comprehensive performance.

The invention discloses a green phosphorus-free and nitrogen-free corrosion and scale inhibitor, and relates to the technical field of energy-saving and environment-friendly water treatment agents. The corrosion and scale inhibitor is prepared from polyaspartic acid, hydrolytic polymaleic acid, acrylic acid / hydroxypropyl acrylate copolymer, polyepoxysuccinic acid, delta-valerolactam, sodium borate, zinc sulfate heptahydrate and benzotriazole according to a specific proportion. The preparation method comprises the following steps: preparing the modified polyaspartic acid, adding other components, mixing the modified polyaspartic acid and other components, adjusting the pH value, homogenizing, filtering, filling and the like. The corrosion and scale inhibitor has excellent corrosion and scale inhibition performance, the corrosion inhibition efficiency of the corrosion and scale inhibitor reaches up to 88.6%, and the scale inhibition rate ranges from 90.5% to 92.4%. Compared with a contrast agent, the efficient corrosion and scale inhibition performance is provided, meanwhile, the water treatment agent has the advantages of being environmentally friendly, economical and the like, and is a green water treatment agent with great application prospects.

The invention relates to the technical field of high polymer materials, in particular to ethylene-vinyl acetate copolymer modified polypropylene high-toughness plastic particles and a preparation process thereof. The composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of polypropylene, 15 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride-2-ethylhexyl acrylate copolymer grafted ethylene-vinyl acetate copolymer, 3 to 8 parts of nano silicon dioxide / graphene quantum dot composite filler, 5 to 12 parts of polyolefin elastomer, 0.5 to 2 parts of antioxidant and 0.5 to 2 parts of lubricant. The content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20-33 wt%, the composite filler is modified through a silane coupling agent KH-560, the grafting rate of the grafted ethylene-vinyl acetate copolymer is 1.5-3.5 wt%, and the composite filler is prepared through a melt grafting method. Through multi-component collaborative design and process optimization, the low-temperature toughness, rigidity, heat resistance and aging resistance of the material are improved, the problems of rigidity and toughness imbalance, low-temperature brittleness, poor stability and the like of a traditional modification system are solved, and the material is excellent in comprehensive performance and wide in application range.

The invention discloses a high-strength polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-strength polyethylene film. The high-density polyethylene composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of high-density polyethylene, 25 to 35 parts of linear low-density polyethylene, 12 to 18 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of nano silicon dioxide, 3 to 7 parts of organic montmorillonite, 1.5 to 3.5 parts of hindered amine light stabilizer, 1.5 to 2.5 parts of antioxidant 1010, 0.8 to 1.2 parts of calcium stearate, 0.8 to 1.2 parts of zinc stearate, 0.8 to 1.2 parts of silane coupling agent and 4 to 6 parts of maleic anhydride grafted polyethylene. The composite material is prepared from the following components in parts by weight: 1.5-3.5 parts of a quaternized chitosan-nano silver compound, 6-9 parts of a modified toughening agent, 4-7 parts of a modified heat-resistant agent, 1.5-3.5 parts of a processing aid, 0.15-0.35 part of dibenzoyl peroxide and 0.5-1.5 parts of a nucleating agent DBS. The composite material is excellent in comprehensive performance, high in strength, good in flexibility and puncture resistance, excellent in aging resistance, heat resistance, chemical resistance and antibacterial property, good in processability, capable of meeting the requirements of multiple fields such as packaging and agriculture, scientific in preparation method and high in practical value.

The present invention relates to the technical field of regenerated plastics, and in particular relates to a flame-retardant regenerated plastic and a preparation method therefor. The regenerated plastic comprises the following specific components: 90-100 parts of regenerated high-density polyethylene, 5-10 parts of high-density polyethylene, 1-2 parts of calcium stearate, 1-2 parts of carbon black, 8-12 parts of maleic-anhydride-grafted polyethylene, 2-3 parts of an antioxidant, and 6-8 parts of a polyurethane elastomer. The regenerated high-density polyethylene is used as a main material, the high-density polyethylene is added thereto, the maleic-anhydride-grafted polyethylene is used as a compatibilizer, and then polyhydroxy polybutadiene, epoxidized hydroxyl-terminated polybutadiene and polypropylene oxide glycol are compounded and react with diphenylmethane diisocyanate to generate a polyurethane elastomer, thereby toughening the regenerated polyethylene; moreover, a flame-retardant effect is achieved by means of the synergy of phosphorus and nitrogen; therefore, a regenerated polyethylene plastic with high tensile strength and good flame-retardant performance is prepared. The regenerated plastic can be widely used in a plurality of fields, and has a relatively high level of practicability.

The invention discloses a heat-resistant flame-retardant reinforced polyamide composition as well as a preparation method and application thereof, and the heat-resistant flame-retardant reinforced polyamide composition comprises the following raw materials in parts by weight: 30-41 parts of polyamide, 15-20 parts of a flame retardant, 2-5 parts of a synergistic flame retardant, 10-20 parts of syndiotactic polystyrene, 2-8 parts of a compatilizer and 10-30 parts of glass sheets. The polyamide comprises one or more of PA66 (polyamide 66) and PA6 (polyamide 6); the compatilizer comprises maleic anhydride grafted syndiotactic polystyrene; according to the invention, syndiotactic polystyrene with excellent dimensional stability and polyamide are selected for composite modification, so that the obtained composition has the advantages of high dimensional stability, low warpage, excellent mechanical property, flame retardance and heat resistance, simple process, good processability and low cost. And the composite material can meet the fields of automobiles, electronic appliances, traffic equipment, aerospace automobiles, electric tools and sports equipment with high requirements on dimensional stability, warping property, strength, flame retardance and heat resistance.

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

A biodegradable polymer composite, a method of making the same and use for same are provided. The biodegradable polymer composite has about 30 to 99.5% by weight of a polymer selected from a group consisting of polybutylene adipate terephthalate (PBAT), polybutylene succinate (PBS), polyhydroxyalkanoates (PHA), and polycaprolactone (PCL) grafted with a compatibilizer selected from a group consisting of maleic anhydride, glycidyl methacrylate, pyromellitic anhydride, acrylic acid, polyacrylic acid, methylene diphenyl diisocyanate, poly(glycidyl methacrylate, copolymer(s) of glycidyl methacrylate; and about 0.5 to 50 % by weight a nano-filler or a micro-filler. The biodegradable polymer composite does not contain polylactic acid. Surfaces of the nano-filler or the micro-filler may be modified using a grafting agent so that the biodegradable polymer composite has enhanced mechanical properties, increased heat resistance, compostablity and / or improved processability. The biodegradable polymer composite may be used to make flexible articles, such as a freezer wrap and a farming sheet.

The invention relates to the technical field of cables, and provides a fireproof flame-retardant 10kV power cable and a preparation method thereof. The fire-resistant flame-retardant 10kV power cable comprises a conductor and a fire-resistant flame-retardant layer, the fireproof flame-retardant layer is prepared from the following raw materials in parts by weight: 35 to 45 parts of linear low-density polyethylene, 40 to 50 parts of ethylene-vinyl acetate copolymer, 25 to 30 parts of modified aluminum hydroxide, 5 to 8 parts of polyethylene grafted maleic anhydride, 10 to 12 parts of phosphate modified halloysite nanotube, 5 to 8 parts of ZIF-8 loaded zinc borate core-shell particles, 15 to 20 parts of magnesium hydroxide and 2 to 3 parts of silane coupling agent. 0.5 to 1 part of antioxidant, 0.5 to 1 part of calcium stearate and 1 to 1.5 parts of polyethylene wax. According to the cable prepared in the invention, the situation that a conductor is exposed and the fire resistance is lost due to cracking and falling under long-time high-temperature baking is avoided; the continuous effectiveness of the flame retardant at high temperature is improved.

Provided is a dispersant for hydraulic compositions that has high dispersibility and can reduce the viscosity of the hydraulic composition. [Solution] A dispersant for hydraulic compositions comprising: a polymer (P) having a structural unit (1) formed from a compound represented by general formula (1), and a structural unit (2) formed from a compound containing at least one selected from acrylic acid, methacrylic acid, fumaric acid, maleic acid, maleic anhydride, itaconic acid, itaconic anhydride, and salts thereof; and an ether compound (A) which is a compound in which 1 to 500 moles of an alkylene oxide having 2 to 4 carbon atoms are added to 1 mole of a mono- to tetrahydric aliphatic alcohol having 2 to 24 carbon atoms, wherein the mass average molecular weight of the polymer (P) is 5,000 to 5,000,000, and the mass ratio (A / P) of the ether compound (A) to the polymer (P) is greater than 0 and less than or equal to 0.25.

The invention relates to the technical field of food packaging materials, and discloses a high-barrier recyclable eleven-layer co-extrusion film for food packaging and a preparation process thereof, and the preparation process comprises the following steps: preparing a compound which contains a hindered phenol group and a cinnamate group and has a compatible function; the preparation method comprises the following steps: compounding a compound which contains a hindered phenol group and a cinnamate group and has a compatible function with maleic anhydride grafted polyethylene resin PE-g-MAH to prepare a compatible component; the high-barrier recyclable eleven-layer co-extrusion film for food packaging is prepared by taking PA6, BVOH and PE as raw materials, improving the compatibility of BVOH and PE by utilizing compatible components, carrying out hydrolysis reaction on water-soluble BVOH to realize interlayer separation of PE and PA and adopting an eleven-layer co-extrusion blow molding film forming process. And the sanitary performance meets the national standard requirement, and the product is easy to recycle and conforms to the environment-friendly trend.

The invention relates to the technical field of nylon 6, and discloses a carbon nanotube grafted ABS modified nylon 6 composite material, acylating chlorinated carbon nanotubes and lysine are subjected to an amidation reaction, double bonds on ABS and double bonds on maleic anhydride are combined, anhydride modified ABS and amino modified carbon nanotubes are subjected to a ring-opening reaction, and the carbon nanotube grafted ABS modified nylon 6 composite material is obtained. The carbon nanotubes are grafted to the ABS, agglomeration of the carbon nanotubes is avoided, the carbon nanotubes can form a uniform network structure under the action of external force, a large amount of external force is absorbed, the toughness of a matrix is improved, a large amount of carboxyl introduced to the surface of the ABS plastic and amide groups in the nylon 6 matrix are subjected to hydrogen-bond interaction, a three-dimensional hydrogen-bond network is formed, and the toughness of the matrix is improved. According to the present invention, the compatibility and the interfacial force between the nylon 6 and the carbon nano-tube grafted ABS are improved, such that the nylon 6 and the carbon nano-tube grafted ABS can be uniformly distributed so as to form the sea island structure, and can buffer more stress effects under the action of the external force, such that the obtained composite material has excellent toughness.

The present invention provides the application of Lewis acid in preparing ethylene-maleic anhydride alternating copolymer. The present invention introduces a co-catalyst Lewis acid into a copolymerization catalytic system, greatly improves the copolymerization activity of ethylene and maleic anhydride, reduces the polymerization temperature, shortens the polymerization reaction time, significantly reduces ethylene pressure, reduces energy consumption, avoids high-pressure production equipment, improves the safety factor during production operation, and then improves monomer conversion, significantly improves production efficiency. Moreover, the present invention provides a preparation method, which is simple and easy, has mild process conditions, and is more suitable for industrial production and promotion and application.

The invention relates to the technical field of optical cable material preparation, and discloses a nano-modified polyethylene optical cable sheath material and a preparation method thereof.The nano-modified polyethylene optical cable sheath material is prepared from, by weight, 80-100 parts of high-density polyethylene, 25-40 parts of EVA resin, 10-15 parts of modified nylon fibers, 5-8 parts of a composite flame retardant, 0.1-1 part of an antioxidant, 0.1-2 parts of a coupling agent and 0.5-5 parts of a lubricant; the modified nylon fiber is a modified molybdenum disulfide reinforced polyamide 6 fiber, and the modified molybdenum disulfide is formed by grafting nano silicon dioxide after modifying dopamine on the surface of molybdenum disulfide; the composite flame retardant is a core-shell flame retardant which takes magnesium-aluminum double hydroxide as a core and a maleic anhydride grafted styrene-ethylene-butadiene-styrene block copolymer as a shell, and a P-N flame retardant is distributed in the core shell. The polyethylene optical cable sheath material is endowed with good mechanical property and flame retardant property.

The invention discloses an anti-shrinkage light, soft and elastic sole foaming material and a preparation method thereof, and belongs to the technical field of footwear products. The light, soft and elastic sole foaming material is formed by chemically foaming an EVA (Ethylene Vinyl Acetate) composite raw material, the EVA composite raw material is prepared from 50 to 70 parts of EVA, 20 to 40 parts of olefin thermoplastic elastomer, 10 to 20 parts of styrene elastomer, 1.5 to 3 parts of maleic anhydride grafted ethylene-octylene copolymer compatilizer, 0.4 to 0.8 part of peroxide cross-linking agent, 3 to 4 parts of foaming agent, 1 to 1.5 parts of zinc oxide, 1 to 1.5 parts of polyethylene wax substance and 0.5 to 1.5 parts of poly (butylene succinate). 0.3 to 1 part of polyamide 12 microspheres and 2 to 3 parts of nano montmorillonite. The foaming material can resist shrinkage when being used as a shoe sole part, and has good rebound performance and the like, so that the high-quality requirement of sneakers, the mass production stability and the like are met.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PVB (Polyvinyl Butyral) film and a preparation method thereof. The PVB film provided by the invention is prepared from the following components in parts by mass: 100 parts of PVB resin, 33 to 36 parts of triethylene glycol di-2-ethylhexoate, 7 to 9 parts of integrated anti-radiation toughening filler, 1 to 2 parts of organic montmorillonite, 0.8 to 1.2 parts of composite coupling agent, 0.5 to 1 part of ultraviolet light absorber, 0.6 to 0.8 part of antioxidant and 0.8 to 1 part of heat stabilizer. The integrated anti-radiation toughening filler adopts a core-shell structure, the anti-radiation core is composed of bismuth oxide and tungsten oxide according to the mass ratio of 3: 1, and the elastic coating layer is maleic anhydride grafted modified POE. The preparation method comprises the steps of pre-dispersion treatment, component mixing, melt extrusion, film casting, graded cooling, two-way stretching and the like. Through the core-shell structure design of the integrated anti-radiation toughening filler and the optimized processing technology, the anti-radiation performance and the toughening performance are synergistically improved, and the prepared film has the advantages of excellent anti-radiation effect, high toughness and good transparency.

The invention discloses a high-strength polypropylene urine cup and a preparation process thereof, and relates to the technical field of polypropylene. The high-strength polypropylene urine cup is prepared from a high-strength polypropylene material through plasticizing, injection molding and compression molding. The high-strength polypropylene material is prepared from the following raw material components in parts by weight: 100 parts of homo-polypropylene, 10 to 20 parts of modified polypropylene, 10 to 15 parts of maleic anhydride grafted polypropylene, 5 to 12 parts of modified talcum powder, 5 to 10 parts of high-density polyethylene, 0.1 to 0.2 part of beta-nucleating agent, 2 to 4 parts of flexibilizer, 1.5 to 3 parts of lubricant, 0.5 to 1 part of antioxidant and 1 to 2 parts of antistatic agent. Through the synergistic effect of the modified polypropylene, maleic anhydride grafted polypropylene, high-density polyethylene, modified talcum powder and other raw materials, the high-strength polypropylene material with high strength and high transparency is comprehensively obtained.

The invention relates to the technical field of materials, and discloses an antibacterial composite pp material and a preparation process thereof.The antibacterial composite pp material is prepared from polypropylene as a main raw material and a compatilizer, a functional fiber modified additive, a rubber additive and the like as auxiliary materials through mixing and extrusion granulation processes. Wherein the functional fiber modified additive is medical stone fiber of which the surface is modified with a reactive macromolecular antibacterial agent, and the reactive macromolecular antibacterial agent can interact with a maleic anhydride group in a compatilizer structure in a subsequent melt extrusion process, so that the interface bonding performance between the medical stone fiber and polypropylene is greatly improved; further, the reinforcing effect of the medical stone fiber is fully exerted, so that the mechanical strength of the polypropylene material is effectively improved. In addition, triclosan in the structure of the macromolecular antibacterial agent has a broad-spectrum antibacterial effect, so that the polypropylene material can be endowed with excellent broad-spectrum antibacterial performance.

The invention relates to the technical field of composite pipes, and discloses a wear-resistant acid-corrosion-resistant environment-friendly anti-explosion PE pipe. The pipe adopts a multi-layer co-extrusion structural design, and comprises a wear-resistant inner layer, a reinforced middle layer and a protective outer layer. High-density polyethylene is used as a base material, silicon carbide particles and aluminum oxide particles with the surfaces subjected to multifunctional modification are combined to serve as reinforcing filler, and functional polyethylene is used as a base interface modification material, so that the problems that in a traditional pipe, particles and a base interface are low in bonding force, uneven in dispersion, prone to falling off and the like are solved. Carboxyl and unsaturated double bonds are introduced into the functionalized polyethylene through a maleic anhydride grafting technology, so that efficient chemical combination of particles and a matrix is realized, and the mechanical property and the chemical stability of the composite material are improved. The inner layer enhances wear resistance through high particle content, the middle layer provides support and corrosion resistance, and the outer layer improves weather resistance and protection performance of the pipe.

The invention discloses a preparation method of antibacterial fibers and a fabric, and relates to the technical field of textile fabrics. When the antibacterial fiber is prepared, 1, 6-hexanediol, 2-(bromomethyl) diethyl succinate and diethyl 2, 2 ': 6', 2 '-terpyridine-4'-yl phosphonate are polymerized to prepare polyester; the preparation method comprises the following steps: reacting polyester with 7-(dimethylamino) coumarin to prepare modified polyester; the preparation method comprises the following steps: polymerizing maleic anhydride and methyl-vinyl polysiloxane and coating the surface of a phase change microcapsule with the maleic anhydride and the methyl-vinyl polysiloxane to prepare a pre-modified phase change microcapsule; the pre-modified phase change microcapsule and 1-hydroxymethyl-5, 5-dimethyl hydantoin are subjected to a reaction, and a modified phase change microcapsule is prepared; preparing a spinning solution from the modified polyester, the modified phase change microcapsules and copper chloride, performing electrostatic spinning, and performing chlorination finishing to obtain the antibacterial fiber. The antibacterial fiber prepared by the invention has excellent antibacterial, anti-aging, flame-retardant and mechanical properties.