3results about How to "Fast polymerization rate" patented technology

The utility model relates to extrusion granulation technical field especially relates to a kind of nanometer material compression granulation equipment, including base, the upper surface of base is fixedly installed with stand, the top of stand is fixedly installed with compression box, and the top of compression box is fixedly installed with material hopper, rotation is installed in the compression box with shaft, and the outer wall of shaft is fixedly installed with the stirring rod of equidistance annular distribution, first auger rod is also rotationally installed in the compression box, and first auger rod is located below the shaft, the outer wall of one side of compression box is fixedly installed with auger cylinder, and the end of first auger rod is located in auger cylinder. The utility model has obvious advantages, spraying and stirring synergistic accelerate material polymerization;First auger rod realizes preliminary extrusion plastic forming, densification;Second auger rod completes secondary extrusion with extrusion cylinder, accurately controls granule quality;Granulation mechanism can flexibly adjust granule size shape, high efficiency and stability, satisfy multi-field demand.

The application discloses a kind of solventization electron initiation controlled radical polymerization method of cosolvent regulation, this polymerization method uses higher polymerization temperature and adds cosolvent tetrahydrofuran simultaneously to regulate, solventization electron initiation polymerization still can keep the nature of controlled radical polymerization, can prepare molecular weight precision controllable, narrow molecular weight distribution polymer, and accurate structure block, star and various topological structure polymers such as polymer.The solventization electron initiation controlled radical polymerization method of cosolvent regulation of the application, it includes the following steps: in the solventization electron initiation polymerization system of alkali metal lithium / hexamethylphosphoramide to olefin monomer, adding cosolvent, carrying out controlled radical polymerization, improve polymerization rate and obtain narrow molecular weight distribution polymer;Wherein, the cosolvent is tetrahydrofuran, the dosage of hexamethylphosphoramide is 20mL, the dosage of tetrahydrofuran is 3-6mL, and the polymerization temperature is 50-60 DEG C.

The present application relates to a kind of preparation method of metallocene polyethylene of wide molecular weight distribution, belong to olefin polymerization catalysis technical field.The preparation method of metallocene polyethylene of wide molecular weight distribution provided by the present application includes the following steps: (1) mixed metallocene catalyst, organic aluminum compound and mixed solvent, heating, and into ethylene is carried out polymerization reaction;The mixed solvent includes organic solvent A and organic solvent B, the organic solvent A is inert alkane or aromatic hydrocarbon, and the organic solvent B is the organic solvent containing polar functional group;(2) after reaction, quenching agent is added to terminate the reaction, washing, filtration, drying, it is finished.The present application uses mixed solvent system, and the use amount and the ratio of two components of mixed solvent are adjusted to realize the adjustment of metallocene polyethylene molecular weight distribution, greatly reduce the requirement of complex bifunctional catalyst, catalyst cost is low, polymerization process is simple, product performance is flexible, and application prospect is wide.