An ultrahigh-strength active powder concrete is a mixture prepared by mixing the following materials according to weight portion: 1000 portions of Portland cement, 600-1400 portions of quartz sand, 90-400 portions of siliceous dust, 200-400 portions of silicon powder, 100-300 portions of quartz powder, 80-350 portions of high-strength steel fiber, 15-30 portions of high-efficiency water reducing agent, 250-320 portions of water, 60-120 portions of AEA expanding agents, 0-15 portions of latex powder, 0-10 portions of polyester fiber and 0-2 portions of antifoam agents. The preparation method comprises the following steps: preparing the materials according to the weight proportion, firstly mixing water, cement, quartz sand, siliceous dust, silicon powder, quartz powder, AEA expanding agents, high-efficiency water reducing agent, latex powder, polyester fiber, and antifoam agents into pasty state; then adding high-strength steel fiber, and mixing for 4-6 minutes. The prepared active powder concrete has super-high compressive and bending strengths, high mechanical property and high durability.