520 results about "Superplasticizer" patented technology

The invention relates to a polycarboxylate superplasticizer compounding production line. The production line comprises an intelligent raw material pretreatment unit, a multi-component precise proportioning unit, a gradient temperature control compounding reaction unit, an online quality monitoring feedback unit and a finished product self-adaptive filling unit which are connected in sequence. The multi-component precise proportioning unit is internally provided with a dynamic proportioning adjusting system, and the feeding amount can be corrected according to the solid content deviation of raw materials and the target fluidity; the gradient temperature control compound reaction unit realizes temperature and speed coordinated regulation and control through a sectional temperature control module and a stirring speed linkage device; and the online quality monitoring feedback unit forms closed-loop control with the above two units by means of a near infrared spectrum detection module. The invention aims to solve the problem that the existing production line lacks the dynamic ratio adjustment of the actual solid content deviation of the raw material and the target fluidity, the reaction stage temperature control and stirring rate cooperative regulation and control and the online detection closed-loop control; therefore, the problems of low proportioning precision, poor reaction process controllability and large performance fluctuation of the water reducing agent are solved.

The invention discloses a coal gangue-based reinforced cement composite material and a preparation method thereof, and relates to the technical field of building materials. The coal gangue-based reinforced cement composite material is prepared from a coal gangue-based reinforced admixture, calcium ion doped modified multi-walled carbon nanotubes, polypropylene fibers, P.O42.5 Portland cement, metakaolin, silica fume, a polycarboxylate superplasticizer and water, calcium ion doped modified multi-walled carbon nanotubes and a coal gangue based reinforced admixture are cooperatively added into a cement matrix, seamless filling from nanometer to micrometer is achieved, a tough interface transition area is formed, pressure is jointly borne by a compact matrix and a strong interface, the compressive strength and breaking strength of the material are remarkably enhanced, and meanwhile, the compressive strength and breaking strength of the material are greatly improved. Migration of moisture and ions is effectively blocked, and the anti-permeability performance of the material is improved.

The invention discloses low-carbon red-mud-based alkali-activated foam concrete and a preparation method thereof, and belongs to the field of low-carbon foam concrete. Specifically, the mix proportion and the preparation method of the low-carbon red-mud-based alkali-activated foam concrete are as follows: P.O42.5 ordinary Portland cement provided by building materials in Qingdao Weidong macro, the I-grade fly ash is S95-grade granulated blast-furnace slag produced by Henan Province Platinon Casting Material Co., Ltd., and Jinshu New Material Co., Ltd., the I-grade fly ash is S95-grade granulated blast-furnace slag produced by Henan Province Platinon Casting Material Co., Ltd. The Bayer process red mud powder is produced by Hebei Province Shihozhuangfei Mine Product Co., Ltd. The exciting agent is selected from an industrial liquid sodium silicate solution produced by Henan Jinmoistening New Material Co., Ltd. And solid sodium hydroxide particles with AR analytical purity of 96%; the admixture is selected from a TR-26C type polycarboxylate superplasticizer produced by Henan Fuhua Information Science and Technology Co., Ltd. And the foaming agent is a TR-E type animal protein foaming agent produced by Henan Zhuichun Information Science and Technology Co., Ltd. Compared with existing foam concrete, the low-carbon alkali-activated foam concrete provided by the invention uses a large amount of industrial solid waste, reduces the use cost, reduces the use amount of cement under the condition of ensuring the compressive strength, and is simple and convenient to operate, reasonable in process, low-carbon, environment-friendly, rapid in cement setting and hardening, and suitable for large-scale use.

The invention discloses high-strength durable pervious concrete and a preparation method thereof, and belongs to the technical field of building materials. The concrete is prepared from the following raw materials in parts by weight: 160 to 220 parts of cement, 1200 to 1600 parts of coarse aggregate, 170 to 230 parts of fine sand, 160 to 200 parts of water, 3 to 4.5 parts of polycarboxylate superplasticizer, 5 to 15 parts of silica fume, 1 to 3 parts of polypropylene fiber, 8 to 12 parts of modified nano cellulose and 5 to 7 parts of flexibilizer, wherein the flexibilizer comprises modified graphene oxide, propylene glycol monomethyl ether and polyisoprene rubber. The interface compatibility is enhanced through the modified nanocellulose, microcracks are reduced, the bonding strength of aggregate and cement is improved, and the compressive strength is improved; the toughening agent component endows the concrete with toughness and durability, the toughening agent component and the toughening agent component have a synergistic effect, and the concrete prepared by mixing the various raw materials has excellent mechanical properties and durability on the basis of good water permeability, and has a wide market application prospect.

The invention relates to the technical field of fluid-state solidified soil, and particularly discloses high-fluid-state solidified soil and a preparation method thereof. The high-flow-state solidified soil is prepared from the following raw materials in parts by weight: 1100 to 1200 parts of recycled aggregate, 700 to 800 parts of river sand, 100 to 130 parts of a curing agent, 18 to 22 parts of a polycarboxylic acid water reducing agent, 75 to 85 parts of solidified soil repairing microcapsules and 55 to 95 parts of water, the solidified soil repairing microcapsule is prepared by taking polylactic acid and nano calcium carbonate grafted polyethylene glycol as composite membrane materials, and wrapping and forming sulphoaluminate cement paste through an emulsification-solidification method. The solidified soil repairing microcapsules are introduced into the solidified soil, pores in an interface transition area can be filled, micro cracks can be repaired, and the durability of the solidified soil is improved.

The invention relates to the technical field of building materials, in particular to all-solid waste alkali-activated recycled concrete and a preparation method thereof. The concrete is prepared from the following raw materials in parts by weight: 360 to 500 parts of blast furnace slag, 180 to 400 parts of recycled concrete, 90 to 270 parts of recycled red bricks, 40 to 90 parts of silica fume, 30 to 90 parts of phosphogypsum, 240 to 370 parts of iron tailing sand, 350 to 420 parts of recycled concrete coarse aggregate, 200 to 400 parts of alkali activator, 10 to 30 parts of polycarboxylate superplasticizer, 20 to 50 parts of sodium tetraborate decahydrate and 300 to 500 parts of water. According to the invention, through fine proportioning and functional synergy of all the components, a solution of all-solid waste concrete with excellent mechanical properties, durability, construction performance and economical efficiency is provided, and the concrete has a wide application prospect in the fields of green buildings and solid waste recycling.

The invention discloses a lithium slag based salt corrosion resistant concrete pole and a preparation method thereof. The pole is made of lithium slag based geopolymer concrete. The concrete comprises the following components in parts by mass: 20-30 parts of dealkalized red mud, 15-25 parts of activated lithium slag, 10-15 parts of slag, 5-8 parts of silica fume, 6-10 parts of magnesium phosphate cement, 12-18 parts of a composite alkali activator, 25-35 parts of machine-made sand, 40-50 parts of gravel, 0.4-0.6 part of a polycarboxylic acid water reducer, 0.8-1.2 parts of composite fibers, 2-3 parts of a salt corrosion-resistant corrosion inhibitor and 25-35 parts of water. The outer surface of the electric pole is coated with an organic silicon-fluorosilicone resin hydrophobic coating; the salt-corrosion-resistant corrosion inhibitor is prepared by compounding nano silicon dioxide, a hydrotalcite precursor and a triphosphonic acid-based corrosion inhibitor, the concrete pole is obtained through the processes of red mud and lithium slag pretreatment, raw material mixing, centrifugal forming, curing and surface treatment, and has excellent salt corrosion resistance and mechanical property.

The invention relates to a polycarboxylic acid water reducer and a preparation method thereof, and the water reducer is prepared from the following raw materials: 45 to 55 percent of isopentenyl polyoxyethylene ether, 28 to 35 percent of acrylic acid, 1.5 to 2.5 percent of modifier, 0.3 to 0.5 percent of ammonium persulfate, 0.03 to 0.06 percent of ascorbic acid, 5 to 8 percent of hydroxyethyl methylacrylate, 0.15 to 0.25 percent of 2, 4-diphenyl-4-methyl-1-pentene and the balance of water. The modifier is prepared from the following raw materials: 1, 5-dichloronaphthalene, p-nitrostyrene, dimethyl sulfate, ceric ammonium nitrate and tetramethylpiperidine oxide. The polycarboxylate superplasticizer has excellent neat paste fluidity and fluidity retention capability, has low 1h time-dependent variable slump which is below 18mm and optimally 10mm when applied to concrete, has a water-reducing rate of more than 40% and a gas content of less than 3.8%, and also has more advantages in compressive strength ratio.

The present invention relates to a free-flowing powder composition comprising biochar as a carrier for admixture, especially a superplasticizer. The present invention also relates to the preparation method of such a free-flowing powder composition and its use for a mineral binder composition.

The invention relates to the technical field of concrete admixtures, in particular to a viscosity reduction type polycarboxylate superplasticizer and a preparation method thereof. The viscosity reduction type polycarboxylate superplasticizer is formed by polymerizing a comonomer under the action of an oxidizing agent, a reducing agent and a chain transfer agent, the comonomer comprises methoxyallyl polyoxyethylene ether, an air-entraining functional monomer, a viscosity-reducing functional monomer, a silicon-containing functional monomer, unsaturated acid and ferrous sulfate. The polycarboxylate superplasticizer provided by the invention can effectively reduce the viscosity of concrete, so that a concrete mixture has good flowability, workability and wrapping property, meanwhile, the strength of the concrete is not influenced as far as possible, the strength of the concrete is kept at a good level, and the concrete keeps good constructability. Moreover, when the viscosity-reducing polycarboxylate superplasticizer is prepared, the reaction can be completed at the normal pressure of 20-25 DEG C, the preparation steps are simple, the reaction condition is mild, no toxic gas is released, energy can be effectively saved, and the viscosity-reducing polycarboxylate superplasticizer meets the green building material standard.

The invention provides a retarding type polycarboxylate superplasticizer as well as a preparation method and application thereof, and belongs to the technical field of building material concrete admixtures. The retarding type polycarboxylic acid water reducing agent is prepared from the following raw materials in parts by weight: 300 to 400 parts of polyether macromonomer, 60 to 150 parts of unsaturated carboxylic acid micromonomer, 30 to 60 parts of unsaturated sulfonic acid monomer, 15 to 30 parts of alkylphenol polyoxyethylene ether phosphate, 1.5 to 12 parts of chain transfer agent, 2 to 15 parts of initiator, 15 to 50 parts of caustic soda liquid and 200 to 600 parts of solvent. The polycarboxylic acid water reducing agent product with the retarding characteristic is synthesized through an RAFT method, the binding force between phosphate radicals and calcium ions in a cement pore liquid of the preparation raw material alkylphenol polyoxyethylene ether phosphate is high, hydration of C3A and formation of ettringite are delayed, the retarding effect of the water reducing agent is enhanced, and the polycarboxylic acid water reducing agent has the anion characteristic and the nonionic characteristic and can be used as a water reducing agent. And the workability of the concrete is improved.

The invention belongs to the technical field of building materials, and particularly relates to a silane modified starch-based polycarboxylate superplasticizer and a preparation method thereof. The water reducing agent is prepared by taking renewable sulfonated starch as a raw material, performing graft modification through vinyltriethoxysilane (A151), introducing active double bonds into starch molecules, and then copolymerizing with monomers such as isopentenol polyoxyethylene ether (TPEG) and acrylic acid. Compared with the prior art, the mixing amount of the vinyltriethoxysilane (A151) is only 1%-5% of the mass fraction of the acrylic acid, the mixing amount is low, and the cost is saved; the water reducing and dispersing performance of the starch-based polycarboxylic acid water reducing agent is improved, and a certain viscosity reducing effect is achieved.

The invention relates to the technical field of pavement materials, in particular to a regenerated cement stabilized macadam mixture and a preparation method thereof. The mixture is prepared from chemical enhanced recycled coarse aggregate, basalt fiber and other raw materials, and the chemical enhanced recycled coarse aggregate is prepared through the steps of hydrochloric acid solution treatment, chemical modification solution soaking and the like. The preparation method comprises the following steps: weighing the raw materials according to the ratio, mechanically stirring part of the raw materials uniformly, adding the polycarboxylate superplasticizer, stirring, adding water, and stirring. The mixture has remarkable advantages, realizes efficient recycling and reusing of waste resources, improves the resource utilization rate, improves the pavement performance, reduces the maintenance cost, reduces ecological damage and environmental pollution, meets the environmental protection requirements, reduces the raw material and road maintenance and repair cost, has good economic benefits, and provides an effective scheme for sustainable development of related fields.

The invention relates to the technical field of tailing concrete poles, in particular to a prestressed tailing concrete pole and a manufacturing method thereof, and the prestressed tailing concrete pole comprises the following components in parts by mass: 550-600 parts of modified iron tailings, 180-200 parts of a prestressed modifier, 500-600 parts of slag, 30-45 parts of silica fume, 180-200 parts of fly ash, 6-8 parts of a polycarboxylate superplasticizer, 5-10 parts of a viscosity modifier and 5-10 parts of an auxiliary enhancer. Through the synergistic effect of the prestress modifier, the viscosity modifier and the modified iron tailings, bleeding and segregation of the high-volume tailing concrete in the vibrating process are prevented, the homogeneity of the material is ensured, the formed electric pole has extremely high internal compactness and a smooth surface, and therefore the freeze-thaw resistance and durability of the electric pole are greatly improved. The modified iron tailings are used for replacing part of traditional cementing materials and aggregates, so that the production cost is remarkably reduced, extremely high additional value is given to industrial solid wastes, the problems of environmental risk and land occupation caused by stockpiling of the industrial solid wastes are solved, and the national green development strategy is met.

The invention relates to a graphene oxide modified cement-based grouting material as well as a preparation method and application thereof. The graphene oxide modified cement-based grouting material is prepared from cement, graphene oxide, silica fume, a polycarboxylate superplasticizer, an accelerator and water. The invention also provides a preparation method of the graphene oxide modified cement-based grouting material, which comprises the following steps: adding GO into an aqueous solution containing a polycarboxylic acid water reducer, stirring and then carrying out ultrasonic treatment to form a GO suspension; premixing silica fume and cement to obtain a dry mixture; and adding the GO suspension into the dry mixture, mixing and stirring, and then doping an accelerator to obtain the graphene oxide modified cement-based grouting material. The invention further provides application of the graphene oxide modified cement-based grouting material as a reinforcement treatment material for loose accumulation bodies and broken rock stratums. The GO modified grouting material solves the problem that the performance of a cement-based material is affected due to the fact that GO is not uniformly dispersed and larger aggregates are easily formed in the existing GO modified grouting material.

The invention discloses a polycarboxylate superplasticizer with a linear water-reducing rate as well as a preparation method and application of the polycarboxylate superplasticizer. The water reducing agent is prepared from a polyether macromonomer phosphating derivative, a carboxylic acid monomer, a sulfonic acid monomer, an ester slump retaining monomer, a linear regulation and control monomer and other units through a free radical emulsion polymerization process. Compared with a traditional polycarboxylic acid water reducer, the water reducer has more regular side chain arrangement, higher charge density, higher adsorption capacity and more stable dispersing performance, the water-reducing rate can be linearly increased along with the increase of the mixing amount within the effective mixing amount range, and the water-reducing efficiency is improved. The problem that the concrete fluidity is difficult to control due to nonlinear fluctuation of the water reducing rate of a traditional polycarboxylic acid water reducing agent is solved, and the method has important significance on improving the concrete construction stability and the engineering quality. The product provided by the invention has excellent mud resistance and slump loss resistance besides high linear water-reducing rate, is suitable for various cast-in-place and precast concrete projects, and has remarkable economic value and application prospect.

The invention discloses a preparation process of composite cement based on activation of steel slag micro powder, belongs to the technical field of cement preparation, and aims to solve the technical problem that durability and stability of cement are difficult to further improve in the prior art. A composite cement preparation process based on steel slag micro powder activation comprises the following steps: adding final powder, a polycarboxylate superplasticizer, a retarder and a defoaming agent into a stirring kettle, and uniformly stirring to obtain composite cement; according to the invention, through synergistic combination of the composite activator, the activated steel slag micro powder and the porous silicon-aluminum-calcium sustained-release microspheres, a multi-layer reaction system with early-stage excitation, middle-stage reinforcement and long-term reinforcement effects is constructed; all the components are complementary in time and space to form a compact and continuous skeleton structure, the aperture is refined, the interface is stabilized, and the internal humidity and ion supply are maintained, so that the compressive strength and breaking strength of the concrete are remarkably improved, the shrinkage rate is reduced, and the impermeability and freeze-thaw resistance are improved.

The invention discloses concrete with anti-freezing performance and a preparation method thereof, and belongs to the technical field of concrete. The invention aims to solve the problems that the porosity of an interface transition area is high, hydration products are easy to degrade and the anti-freezing and anti-permeation performances are insufficient under the working conditions of high altitude, low air pressure, strong ultraviolet rays and salt-freezing synergy of the existing large-dosage fly ash concrete. The concrete is prepared from the following components in parts by weight: 100 parts of cement, 100 to 150 parts of coal ash, 280 to 320 parts of fine aggregate, 1000 to 1200 parts of modified basalt coarse aggregate, 1.5 to 3.5 parts of polycarboxylic acid water reducing agent, 0.2 to 0.6 part of PEG (Polyethylene Glycol) coated chitosan quaternary ammonium salt microspheres, 0.05 to 0.25 part of chitosan grafted nano cerium oxide composite particles, 1.0 to 3.0 parts of bacillus pseudofirmus microcapsule-polyvinylpyrrolidone mixture and 0.03 to 0.12 part of trisodium citrate. Through the synergistic effect of all the components, the interface structure of the concrete is effectively optimized, the ultraviolet aging resistance, the salt-freezing synergistic damage resistance and the chloride ion infiltration resistance are improved, the high-altitude severe service condition is adapted, and reliable material support is provided for high-altitude infrastructure construction.

The invention relates to the technical field of building material preparation, and particularly discloses a preparation process of a low-temperature fluid curing agent and a stabilized soil building material thereof, and the preparation process comprises the following steps: (1) adding modified starch into water, uniformly stirring, and removing oxygen; then adding maleic anhydride and persulfate, and heating to react; and after the reaction is finished, adding ethanol, separating out the precipitate, and drying to obtain the CMSS-g-MA. (2) adding glycine betaine into water, uniformly stirring, then adding CMSS-g-MA, and heating to react; and carrying out spray drying on the obtained reaction liquid to obtain the modified betaine powder. And (3) taking sulphoaluminate cement, ordinary Portland cement, a polycarboxylate superplasticizer, a silane coupling agent, the modified betaine powder, hydroxyethyl cellulose and the like as raw materials, and uniformly mixing the raw materials to obtain the low-temperature fluid curing agent. The solidified soil slurry can be better prevented from being frozen in a low-temperature environment, the stability of the internal structure of the solidified soil is kept, and a guarantee is provided for low-temperature construction.

The invention relates to the technical field of civil engineering materials, in particular to a cement-based composite coiled material for emergency rescue and a rapid construction method.The cement-based composite coiled material for emergency rescue comprises a stereoscopic three-dimensional structure fabric and hydraulic cement-based filler, the stereoscopic three-dimensional structure fabric is filled with the hydraulic cement-based filler, and the hydraulic cement-based filler is arranged in the stereoscopic three-dimensional structure fabric. One side of the bottom of the three-dimensional structure fabric further comprises a waterproof wear-resistant coating; the hydraulic cement-based filler is prepared from the following components in parts by weight: 30 to 45 parts of high belite sulphoaluminate cement, 10 to 20 parts of ordinary Portland cement, 10 to 15 parts of fly ash, 5 to 8 parts of alpha-semi-hydrated gypsum, 3 to 5 parts of an expanding agent, 0.5 to 1.5 parts of a polycarboxylic acid type water reducing agent, 25 to 35 parts of silica sand and 0.1 to 0.8 part of a thickening time control agent. The prepared cement-based composite coiled material for emergency rescue has good tensile property, and the prepared cement-based composite coiled material meets the one-day compressive strength gt; the 28-day compressive strength is gt; the pressure is 65 MPa; the one-day tensile strength is gt; 3.5 MPa, 28-day tensile strength gt; and the performance index requirement of 5.5 MPa is met.

The invention relates to the technical field of conductive materials, and discloses ECC concrete based on carbon black doping and a preparation method and application thereof.The preparation method includes the following steps that cement, slag, quartz sand, silica fume and limestone powder are subjected to dry mixing to obtain a dry material; dispersing carbon black and a dispersing agent in water to obtain carbon black dispersion liquid; and mixing the dry material, the carbon black dispersion liquid, a polycarboxylate superplasticizer and polyethylene fibers to obtain the carbon black doped concrete. The conductivity of the ECC concrete is improved through the carbon black, the ECC concrete is applied to the field of friction nano-generators, potential difference can be formed through extrusion of an automobile in the using process, and therefore current is output to supply power to traffic lights, monitoring equipment and the like.

The invention discloses a lightweight heat-insulation cement-based composite material, and relates to the technical field of cement-based composite materials, the lightweight heat-insulation cement-based composite material comprises the following material components by weight: 40-60 parts of a cement matrix, 20-35 parts of a lightweight aggregate, 5-12 parts of a polymer modifier, and 0.5-0.3 part of a functional additive, the cement matrix is sulphoaluminate cement or Portland cement, and the functional additive is a water-based composite material. The lightweight aggregate comprises hollow glass beads with the particle size of 0.1-0.5 mm, expanded perlite with the particle size of 0.5-2 mm and surface modified aerogel particles, the aerogel particles are silicon dioxide aerogel or silicon carbide aerogel, the surface area of the aerogel particles is 700-600 m / g, the pore diameter of the aerogel particles is 40-50 nm, the polymer modifier is acrylate-styrene copolymer emulsion, and the particle size of the polymer modifier is 1-10 m / g. The solid content of the acrylate-styrene copolymer emulsion is 50-45%, the glass transition temperature of the acrylate-styrene copolymer emulsion is-10 DEG C to 15 DEG C, and the functional additive comprises a cellulose ether thickener, a polycarboxylate superplasticizer and a nano aluminum oxide dispersion liquid.

The invention relates to anti-crack expansive concrete and a preparation method thereof, and relates to the technical field of building materials. The concrete is prepared from the following components in parts by mass: Portland cement, fly ash, slag powder, silica fume, an expansion composition, nano calcium carbonate, sand, gravel, water, a hydration temperature rise inhibitor, a polycarboxylic acid water reducer and carboxyl modified polypropylene fibers. The preparation method comprises the steps of primary mixing and final mixing. According to the anti-crack expansive concrete disclosed by the invention, the hydration temperature rise inhibitor is added to reduce hydration heat, meanwhile, the early-stage and short-term strength is improved, and the early-stage and short-term strength loss caused by temperature cracks generated by reduction of the hydration heat is avoided.

The invention belongs to the technical field of concrete, and particularly relates to porous concrete as well as a preparation method and application thereof. The porous concrete is prepared from the following raw materials in parts by mass: 100 parts of Portland cement, 5 to 15 parts of silica fume, 140 to 160 parts of gravel, 10 to 20 parts of steel slag, 30 to 50 parts of sand, 0.8 to 1.5 parts of polycarboxylic acid water reducing agent, 8 to 15 parts of mixed resin, 0.3 to 0.8 part of water repellent, 0.9 to 1.2 parts of modified polypropylene fiber and 45 to 60 parts of water. The porous concrete disclosed by the invention is high in compressive strength, good in water permeability and strong in durability, and is particularly suitable for road engineering in high and cold, high-humidity and heavy traffic areas in China.

The invention discloses a tensile and anti-crack concrete pole, which belongs to the technical field of concrete materials and comprises the following components in proportion: 380-450 kg / m < 3 > of cement, 20-40 kg / m < 3 > of silica fume, 50-80 kg / m < 3 > of fly ash, 1000-1150 kg / m < 3 > of broken stone, 650-750 kg / m < 3 > of sand, 0.5-1.5 kg / m < 3 > of synthetic fiber, 30-80 kg / m < 3 > of steel fiber, 130-160 kg / m < 3 > of water, 25-40 kg / m < 3 > of expanding agent and 4.5-7.5 kg / m < 3 > of multi-branched temperature-sensitive polycarboxylic acid superplasticizer. The multi-branched temperature-sensitive polycarboxylic acid high-efficiency water reducing agent is prepared by co-polymerizing a multi-branched chain transfer agent, a temperature-sensitive polymerizable monomer, acrylic acid and polyethylene glycol monomethyl ether acrylate, and has the advantages of excellent dispersion effect, high-temperature slump retaining property, few pores of an electric pole, high compactness and better tensile and anti-cracking properties.

The invention relates to the technical field of admixtures, in particular to a manganese slag concrete admixture and a preparation method thereof.The manganese slag concrete admixture is prepared from, by weight, 65-75 parts of ground manganese slag, 10-15 parts of modified metakaolin, 5-8 parts of slag powder, 4-6 parts of gypsum, 3-5 parts of limestone powder, 2-4 parts of alkali activator, 0.3-0.6 part of water retention thickener and 0.5-1 part of polycarboxylate superplasticizer. A layer of itaconic anhydride-myrcene copolymer is grafted on the surface of the modified metakaolin through a covalent ester bond, so that performance guarantee is provided for large-dosage utilization of the manganese slag, and resource utilization of the manganese slag is realized on the premise of meeting the requirement of high-performance concrete.

The invention belongs to the technical field of building materials, and discloses a concrete composite additive and a preparation method thereof. The additive comprises a polycarboxylate superplasticizer, nano silicon dioxide, modified starch ether, bentonite, a calcium sulphoaluminate activator, a bio-based antirust agent and a graphene oxide dispersion liquid. Through a step-by-step mixing process, liquid phase dispersion is performed firstly, then solid phase gradient mixing is performed, and ultrasonic treatment and low-temperature drying are combined, so that the problem of multi-component interface compatibility and activity retention is solved. The obtained additive can synergistically improve the anti-cracking and anti-rust performance of concrete, significantly reduce chloride ion penetration and prolong the durability period. And the preparation method is environment-friendly, efficient and suitable for high-durability concrete engineering.

The invention discloses twisted steel fiber ultra-high performance concrete and a preparation method thereof, and the twisted steel fiber ultra-high performance concrete comprises the following raw materials by weight: 80-90 parts of cement, 20-26 parts of silica fume, 10-15 parts of coarse aggregate, 100-120 parts of quartz sand, 2.5-4 parts of a superplasticizer, 15-25 parts of water, 9-16 parts of twisted steel fiber, 3-5 parts of nano calcium carbonate, 2-3 parts of an expanding agent, and 4-5 parts of straight steel fiber. The cement is selected from PO52.5 ordinary Portland cement, and the quartz sand with the particle size of 30% being 0.1-0.3 mm and the quartz sand with the particle size of 70% being 0.3-0.6 mm are mixed, and the invention relates to the technical field of concrete preparation. According to the twisted steel fiber ultra-high performance concrete and the preparation method thereof, the twisted steel fiber ultra-high performance concrete is outstanding in corrosion resistance, compression resistance, tension resistance, shear resistance and the like.

The invention relates to the technical field of concrete, in particular to a high-bending-resistance road concrete material and a preparation method thereof.The high-bending-resistance road concrete material is prepared from, by weight, 100 parts of aluminate cement, 6-8 parts of filler, 1-1.4 parts of additive, 350-400 parts of basalt coarse aggregate, 200-250 parts of medium sand, 33-37 parts of mixing water and 0.7-0.9 part of polycarboxylate superplasticizer. In the invention, the additive powder modified by the composite solution is mixed with the mineral powder activated by the premixed solution to form a filler with a microporous structure and rich surface functional groups, the microporous structure can internally maintain moisture, so that cement is fully hydrated and pores are refined, and the functional groups can generate a synergistic effect with cement ions and fibers in the additive, so that the cement can be fully hydrated. Cracks are not easy to expand when the interior of a concrete matrix bears bending stress, and fibers in the additives inhibit crack expansion through a bridging effect, so that the fracture resistance of the road concrete material is also improved.

The application discloses a kind of anti-freezing concrete and preparation method of multi-generation recycling, the concrete is by following raw material is formed according to weight parts: cement 405~418 parts, nano silicon dioxide 8~20 parts, river sand 680~735 parts, recycled coarse aggregate 865~890 parts, water 168~194 parts, polycarboxylate superplasticizer 2.2 parts and alkyl benzene sulfonate air entraining agent 0.05~0.1 parts.The application uses nano silicon dioxide as raw material, which has high specific surface area and pozzolanic activity, and the alkyl benzene sulfonate air entraining agent reduces the aggregation of nano silicon dioxide, not only promotes its uniform dispersion in concrete, but also makes the pore distribution in concrete uniform, thereby improving the mechanical properties and frost resistance of concrete, and the second generation and third generation recycled coarse aggregate obtained by crushing after 400 freeze-thaw cycles can be used in structural concrete in cold regions, greatly reducing material waste and environmental pollution.