The invention relates to the technical field of a 
composite material with a 
core shell structure and provides a 
surface chemical plating treatment process for hollow glass microspheres. The 
surface chemical plating treatment process comprises the following steps: carrying out alkaline wash and 
hydrogen peroxide wash before plating to coarsen and hydroxylate the surface of the hollow 
glass microsphere; and carrying out 
chemical plating on the processed hollow 
glass microsphere to obtain a 
metal-plated hollow 
glass microsphere. In the method, complex preprocessing technology, such as 
sensitization, activation and the like in the existing method, can be simplified, and the use of expensive stannous 
chloride and 
palladium chloride which are not environmentally-friendly is avoided. Compared with the existing hot alkaline liquor 
processing method, the process provided by the invention has the advantages that possible 
microsphere fracture caused by the long-time soaking in the alkaline liquor can be avoided, and the surface 
hydroxylation efficiency of the hollow glass 
microsphere can be greatly increased by using 
hydrogen peroxide. The hollow glass 
microsphere processed with the method is easy to plate. The obtained 
metal-plated hollow glass microsphere has the advantages of a complete 
metal layer, light weight, good electrical 
conductivity and the like. When the obtained metal-plated hollow glass is used as a filler, 
material density can be lowered, cost is lowered, 
mechanical property is enhanced, and the plated metal hollow glass microsphere is applied to the aspects of staticelectricity 
coating, 
electromagnetic wave interference coating, wave adsorption 
coating and the like.