The application provides a conductive and heat-conductive composite ink as well as a preparation method and application thereof. The conductive and heat-conductive composite ink comprises cluster-state material liquid drops in a pomegranate-like structure; the cluster-state material in the pomegranate-like structure comprises
graphene,
liquid metal and one-dimensional conductive and heat-conductive material; the
graphene is assembled on the surface of the
liquid metal to form
hybrid microspheres, and the one-dimensional conductive and heat-conductive material is bridged between the
hybrid microspheres to form the cluster-state material in the pomegranate-like structure. The composite ink provided by the application can obtain a dense, high-conductive and bidirectional heat-conductive film, which is used for a thermal interface material and simultaneously has
electromagnetic shielding performance in a GHz
frequency band and high interface
thermal conductivity, so that key parts in an electronic device are protected from
electromagnetic wave interference and high temperature, and high-speed operation of the electronic device is ensured.