511 results about "Melt blending" patented technology

The invention relates to an antistatic MLCC release film base film and a preparation method thereof. The antistatic MLCC release film base film is prepared by melt blending and biaxial stretching of PET master batch, an antistatic composition and a nano filler, wherein the antistatic composition is prepared by compounding modified PET-PEG and thiophene modified aromatic polyamide; the nano filler is prepared by carrying out melt extrusion on KH550 modified talcum powder and MAH-g-PET (maleic anhydride-grafted polyethylene terephthalate). The antistatic composition disclosed by the invention has the beneficial effects that the antistatic composition is formed by interweaving two polymers, and a stable three-dimensional conductive network is constructed in the PET film, so that the antistatic performance is more efficient, lasting and stable. In addition, through chemically bonded modified talcum powder, the smoothness and low roughness are provided, and meanwhile reinforcing and toughening are achieved; and the single-layer extrusion process can realize ultrathin thin film, the production process is simplified, and the production cost is greatly reduced.

The invention relates to the field of high polymer materials, and discloses a high-wear-resistance elastomer sole material and a preparation method thereof.The material comprises an elastomer matrix and surface-modified boron nitride nanosheets; the elastomer matrix comprises a first dynamic network and a second dynamic network which are formed through crosslinking of dynamic covalent bonds, and the first dynamic network and the second dynamic network are based on different types of dynamic covalent bonds and have different dissociation activation energy barriers or external stimulus response conditions. The surface-modified boron nitride nanosheet and the second dynamic network form a selective interface enhancement effect; the preparation method comprises the steps of polymer functionalization, nanosheet surface modification, melt blending reaction net forming, forming and the like. The obtained elastomer sole material not only has excellent wear resistance and mechanical properties, but also can realize self-repair of graded response aiming at damages of different degrees, and the service life of the material is remarkably prolonged.

The invention relates to the technical field of high polymer material processing, in particular to a blow molding method of a composite toughened film, which comprises the following steps: step 1, preheating matrix resin in preheating equipment; 2, feeding the mixed raw materials into a double-screw extruder for melt blending; 3, feeding the dried composite particles into a hopper of a single-screw blow molding extruder; 4, adjusting the air volume and the air pressure of the cooling system according to the monitoring result; and 5, the formed film pipe is folded into a flat shape through a guide component and led out through a traction roller, the traction speed and the extrusion speed are coordinated to control the traction ratio, corona treatment is conducted on the surface of the thin film to improve the surface energy, then rolling tension is controlled for rolling, and the rolling tension is controlled according to the elasticity and thickness of the thin film to prevent excessive stretching or loosening. The uniform distribution and proper compatibility of the composite toughening component improve the toughness of the film, and maintain the strength and barrier property of the film.

The invention relates to the technical field of films, in particular to a high-surface tension aluminized base film and a preparation method thereof. The method comprises the following steps: grafting modified fumed silica with a silane coupling agent KH-570, and grafting a ternary polymerization shell layer composed of 2-acrylamide-2-methylpropanesulfonic acid, lauryl methacrylate and glycidyl methacrylate on the surface of the modified fumed silica to obtain organic anti-sticking silica; secondly, synthesizing an aromatic sulfonated polyester prepolymer, loading nano titanium dioxide, and carrying out melt blending extrusion with polypropylene to form polar cluster polypropylene master batches; and finally, blending polypropylene resin, the master batch and maleic anhydride grafted polypropylene, and carrying out melt extrusion, air cooling and slow cooling and two-way stretching molding. The obtained base film is high in surface tension, high in aluminized layer adhesive force, excellent in oxygen and water vapor barrier property, good in thermal stability and suitable for the field of high-end packaging.

The invention discloses a recycled modified polypropylene composite material preparation system and a resource recovery method, and relates to the technical field of high polymer material science and engineering. The raw material pretreatment module adopts near infrared spectrum classification, multi-stage cleaning, drying and crushing, and the moisture content is controlled to be less than 0.5%; the melt blending module melts the materials at 180-220 DEG C, modifiers and additives are added, and vacuum degassing is performed to remove impurities; adding a reinforcing agent into the modification reinforcing module, and performing ultrasonic dispersion and dynamic vulcanization; the molding processing module is used for manufacturing a product through extrusion, injection molding or calendaring; the quality detection module is used for detecting mechanical and thermal properties; the waste recovery module is used for crushing and melting granulation to realize a closed loop; the intelligent control module uses a PLC to coordinate each module. Integrated treatment of waste polypropylene is achieved, the purity of raw materials and the performance of a composite material are improved, the resource utilization rate is increased through closed-loop recycling, manual intervention is reduced through intelligent control, product stability is guaranteed, economic and environment-friendly benefits are achieved, and high-valued circulation of waste plastic is promoted.

The invention discloses a high-performance polyether-ether-ketone modified sealing material and a preparation method thereof, and relates to the technical field of sealing materials. The high-performance polyether-ether-ketone modified sealing material is prepared from the following raw materials in percentage by mass: 5 to 10 percent of polytetrafluoroethylene micro powder, 5 to 10 percent of graphene nanosheets, 10 to 15 percent of silicon carbide whiskers, 0.5 to 2 percent of silane coupling agent and the balance of polyether-ether-ketone, the preparation method of the high-performance polyether-ether-ketone modified sealing material comprises the following steps: mixing graphene nanosheets with a silane coupling agent, deionized water and absolute ethyl alcohol, carrying out ultrasonic dispersion for 2 hours, carrying out pretreatment to obtain a graphene nanosheet suspension, mixing the graphene nanosheet suspension with silicon carbide whiskers, polytetrafluoroethylene micro powder and polyether-ether-ketone, carrying out melt blending, and carrying out compression molding to obtain the high-performance polyether-ether-ketone modified sealing material. And cooling to obtain the high-performance polyether-ether-ketone modified sealing material.

The invention belongs to the technical field of high polymer materials, and discloses a bio-based spiral macromolecular flame retardant as well as a preparation method and application thereof. The novel bio-based spiral macromolecular flame retardant PDVPA is successfully prepared on the basis of common industrial raw materials in combination with bio-based renewable vanillin, and the novel bio-based spiral macromolecular flame retardant PDVPA is applied to preparation of a flame-retardant TPEE composite material by adopting a melt blending process. The phosphorus element in the PDVPA molecular structure is used as a main flame-retardant functional group, and can promote the charring of the spiral structure of the PDVPA molecular structure; meanwhile, an imine bond can be subjected to a trimerization reaction under a high-temperature condition to form a cross-linked network structure, so that the molten drop phenomenon during TPEE combustion is effectively inhibited. The invention provides a new way for improving the safety performance of the high polymer material and reducing the dependence on fossil resources.

The invention discloses a preparation method of a mute tube core layer and a mute tube. The preparation method comprises the following steps: step 01, adding 15-55 parts by weight of polypropylene resin, 0.5-10 parts by weight of a coupling agent, 0.5-5 parts by weight of a lubricant, 0.05-1 part by weight of an antioxidant and 0.1-3 parts by weight of other additives into a twin-screw extruder from a main feeding port of the twin-screw extruder, and melting and mixing to form an intermediate melt; 02, 45-85 parts by weight of barium sulfate is added into a double-screw extruder through at least two side feeding ports of the double-screw extruder, the barium sulfate and the intermediate melt are subjected to melt blending, and a blended melt is formed; and step 03, extruding the blended melt by a twin-screw extruder, and sequentially passing through a melt pump and a pipeline core mold to form the pipe core of the mute pipe. According to the preparation method, the filling proportion of barium sulfate is increased to 70% or above, the material density is larger than 2.4 g / cm < 3 >, and the noise test of a drainage pipe system of the mute pipe prepared through the preparation method is smaller than 20 dB.

The invention discloses a high-voltage-resistant brominated flame-retardant polyamide composition and a preparation method thereof, and belongs to the technical field of flame-retardant materials. The composition comprises the following components in percentage by mass: 30-80 wt% of aliphatic polyamide, 10-30 wt% of a brominated flame retardant, 0.5-10 wt% of an antimony-based synergist, 0.5-10 wt% of aromatic zinc carboxylate, 0.5-5 wt% of hydroxyapatite, 0.1-50 wt% of a reinforcing agent and 0-5 wt% of other auxiliaries, the sum of the contents of all the components is 100 wt%, and the raw material components are subjected to melt blending processing through a single-screw or double-screw extruder. The invention provides the high-voltage-resistant brominated flame-retardant polyamide composition, the relative tracking index (CTI) of the high-voltage-resistant brominated flame-retardant polyamide composition is greater than 400V, and the high-voltage-resistant brominated flame-retardant polyamide composition has high-level flame retardance and cost effect.

The invention discloses a protective base film for a polaroid and a preparation method of the protective base film, and belongs to the technical field of optical display equipment protective films. The protective base film comprises an antistatic PET base material layer and a self-adhesive layer, the antistatic PET base material layer is prepared by blending optical-grade PET slices and antistatic master batches, the master batches are prepared by taking ionic liquid dihydric alcohol as a comonomer, and the base film is endowed with lasting and stable intrinsic antistatic performance; the self-adhesive layer is formed by melting and blending a polyurethane acrylate prepolymer, a modified montmorillonite filler, other matrix materials and auxiliaries according to a specific ratio and carrying out an online UV curing process. Through innovative material design and an integrated forming process, the prepared protective base film has excellent optical transparency, lasting antistatic property, appropriate bonding strength, clean stripping property and outstanding damp-heat aging resistance, the comprehensive performance is remarkably superior to that of a traditional gluing protective film, and the production process is more environment-friendly and efficient.

The invention discloses a multi-layer composite polypropylene color master batch and a preparation method thereof.The multi-layer composite polypropylene color master batch comprises an inner layer, a middle layer and an outer layer, the inner layer is coated with the middle layer, the middle layer is coated with the outer layer, matrix resin, a composite toughening agent and an interface modifier are subjected to melt blending in a double-screw extruder, nano reinforcing filler is added, extrusion granulation is performed, and the multi-layer composite polypropylene color master batch is obtained. Carrier resin, hyperbranched polyesteramide and a toner pre-dispersion body are mixed at a high speed and then uniformly coated on the outer surface of the inner layer through fluidized bed equipment, and a mixture of a weather-proof additive and a lubricant is attached to the outer surface of the middle layer by adopting an electrostatic spraying process to form the outer layer. According to the multi-layer composite color master batch, the matrix resin and the composite toughening agent have a synergistic effect, so that the impact strength of the color master batch is improved, the cavity structure of hyperbranched polyesteramide is coated with the toner, the silane is used for treating the nano filler to reduce agglomeration and chromatic aberration, the outer layer delays aging, the lubricant reduces the extrusion torque, and the multi-layer composite color master batch is adaptive to a high-speed pipe production line.

The invention belongs to the technical field of polymer composite materials, and discloses a large-scale preparation method of a PPS-based composite material with low expansion and high dimensional stability. According to the method, a multi-scale synergistic enhancement system of graphene and nano silicon dioxide is constructed, a maleic anhydride grafted PPS compatilizer is introduced into melt blending, and interface chemical anchoring is achieved through amino-maleic anhydride-epoxy ternary reaction. The filler is premixed according to the mass ratio of 1: 1 after being subjected to surface functionalization, the total content is 15-30 wt%, and the composite material is obtained through twin-screw reactive extrusion and injection molding. The invention provides the large-scale preparation method of the low-expansion high-dimensional-stability PPS-based composite material which is reasonable in structural design, high in process controllability, excellent in performance index and suitable for industrial production, and the problem that thermal expansion suppression and interface strengthening are difficult to consider at the same time in the prior art is solved.

The invention provides a composite packaging film and a preparation method thereof, and belongs to the technical field of packaging films. The composite packaging film comprises the following raw materials: poly (butylene adipate-terephthalate), polylactic acid, a maleic anhydride grafted PS copolymer and a chain extender, wherein the addition amount of the maleic anhydride grafted PS copolymer accounts for 1-5% of the total mass of the poly (butylene adipate-terephthalate) and polylactic acid. According to the invention, inorganic filler does not need to be added, and the chain extender ADR4370S and the compatilizer PS-MA are added to form a synergistic regulation mechanism in a melt blending process: the chain extender acts on a molecular chain layer to improve the length of the molecular chain and the rheological behavior of a melt; the compatilizer PS-MA acts on a phase interface layer surface to enhance interface bonding between PLA and PBAT phases, so that the molecular structure and the interface structure of a blending system are optimized at the same time, and the mechanical property, the processing stability and the structural uniformity of the film are improved.

The invention discloses mint cool cloud velvet and a preparation method thereof, and relates to the technical field of cloud velvet. Silicon dioxide loaded with a composite cool feeling agent is used as cool feeling particles, and the cool feeling particles and PET slices are subjected to melt blending to prepare cool feeling master batches; the silane coupling agent modified jade powder and the cool master batch are added into the PET fiber to form a two-stage cool enhancing effect. PET hollow spinning is adopted to form a hollow structure, and a phase-change material is poured into the hollow structure for hot-pressing fusion sealing. The solid-liquid phase change mechanism of the selected phase change material enables the prepared cloud velvet to trigger heat absorption at a slightly high temperature in a comfortable area of a human body, so that the effect of modifying a tone to cool and the effect of staggering are achieved, and the cool feeling persistence is realized. In the fiber forming process, an all-dimensional annular high-speed strong cold air blowing technology is adopted, a spinning melt is instantly and rapidly cooled with extremely small errors, a unique crystalline state, different from that of other polyester fibers, of cloud wool is caused, and the effect of combining light weight and fluffiness is achieved. The cloud velvet prepared by the invention has the effects of long-acting cool feeling and fluffiness.

The invention discloses a preparation method of a high-performance electric-breakdown-resistant capacitor base film, which comprises the following steps: S1, preparing modified polypropylene master batch: mixing polypropylene, a cycloolefin copolymer, a barium titanate-carbon nanotube modified composite filler and an antioxidant, and carrying out melt blending, extrusion and granulation to obtain the modified polypropylene master batch; s2, carrying out melt extrusion on the modified polypropylene master batch, cooling and casting; s3, carrying out two-way stretching and heat setting on the obtained casting piece to obtain a polypropylene film; and S4, performing plasma treatment on the surface of the polypropylene film to obtain the high-performance electric-breakdown-resistant capacitor base film. The high-performance electric-breakdown-resistant capacitor base film prepared by the method has excellent electric breakdown resistance, mechanical strength, flame retardance and heat resistance, has a long-acting flame retardant effect, is excellent in comprehensive performance and has a wide market application prospect.

The invention relates to the technical field of radiation refrigeration films, and discloses a porous polyvinylidene fluoride based composite radiation refrigeration film and a preparation method thereof. The method comprises the following steps: firstly, carrying out melt blending on PVDF, NaCl and ZnO nanoparticles and forming a film, then dissolving out NaCl through water washing, and constructing a continuous three-dimensional porous structure in a PVDF matrix; and immersing the obtained porous PVDF / ZnO membrane material into a methanol aqueous solution containing 2-methylimidazole, so that ZnO is subjected to a coordination reaction at the pore wall and is converted into the ZIF-8 nanocrystal in situ. In the thin film prepared by the steps, the micron-sized salt-induced pore structure, the nano-sized ZIF-8 particles and the interface of the ZIF-8 particles jointly form a multi-stage scattering network, so that the scattering ability of the thin film in the solar spectrum range of 0.25-2.5 microns can be remarkably enhanced, the high infrared emission performance of the PVDF matrix in an atmospheric window of 8-13 microns is maintained, and the thin film has high solar reflectivity and high infrared emissivity, and can be used for preparing the solar film. An excellent radiation refrigeration effect can be achieved, and the heat-dissipating material is suitable for being applied to building outer surfaces, equipment heat dissipation, individual heat management and the like.

The invention provides a preparation method of fluororesin foam with high foaming ratio, and relates to the technical field of foaming materials, and the preparation method comprises the following steps: S1, carrying out melt blending on raw materials containing 90-100 parts of polyvinylidene fluoride (PVDF) and 0-5 parts of an inorganic nucleating agent to prepare a precursor; s2, performing supercritical fluid foaming treatment on the precursor to obtain a micro-foaming nucleation sample; s3, carrying out irradiation crosslinking treatment on the micro-foaming nucleation sample; s4, the irradiated sample is subjected to secondary supercritical fluid foaming treatment, and fluororesin foam is prepared; the nucleating agent is added to cooperate with a low-temperature and high-pressure infiltration process, so that the nucleating efficiency of a PVDF matrix is improved, the nucleation density is improved, PVDF molecular chains can be subjected to a cross-linking reaction through irradiation cross-linking to form a net structure, meanwhile, the melt strength of a micro-foaming precursor is improved, cell collapse and combination are inhibited in the foaming process in the second step, and the foaming performance of the PVDF matrix is improved. And a uniform and compact foam structure is prepared.

The invention discloses a high-wear-resistance supercritical foaming TPU material and a preparation method thereof, and relates to the technical field of high polymer materials, the material is prepared from the following components by weight: 100 parts of TPU particles, 5-20 parts of a wear-resistant filler, 3-10 parts of a compatilizer, 3-5 parts of a supercritical fluid foaming agent, 1-5 parts of a foaming promoter, 0.5-2 parts of an antioxidant and 0.5-2 parts of a lubricant; the wear-resistant filler is a compound of surface amination modified nano silicon dioxide and surface carboxylation modified polytetrafluoroethylene micro powder, the wear-resistant filler, TPU and other auxiliaries are subjected to melt blending granulation to obtain composite master batches, after the master batches are formed into sample strips, the sample strips are subjected to supercritical fluid impregnation and rapid pressure relief foaming, and the final product is obtained. Through a unique compound wear-resistant system and interface design, excellent wear resistance can still be maintained after supercritical foaming, the industrial problem that the wear resistance of a foaming material is poor is solved, the process is environment-friendly, and industrial production is easy.

The invention discloses a low-cost polyester degradable plastic garbage bag and an extrusion blow molding process thereof. The garbage bag is prepared from a composite material with a specific formula comprising poly (butylene succinate) (PBS), polylactic acid (PLA), surface-modified nano calcium carbonate, a degradation aid, a compatilizer and an anti-blocking agent. The key of the preparation process is as follows: deep drying pretreatment of raw materials; uniform dispersion and compatibility of all the components are realized through high-speed mixing and twin-screw melt blending granulation; a single-screw extrusion film blowing machine provided with an internal cooling (IBC) system is adopted, and stable forming of film bubbles and preparation of an ultrathin film are achieved under the condition that the temperature, the blow-up ratio and the traction speed are accurately controlled. Through collaborative innovation of a material formula and a process, the technical problems that an existing degradable garbage bag is high in cost, insufficient in mechanical property, poor in processing stability, uncontrollable in degradation behavior and the like are successfully solved.

The invention provides a block copolymer toughening-based polyether-ether-ketone material and a preparation method thereof, and relates to the technical field of high polymer materials, the method is characterized in that a block copolymer PAEK-B with a specific sequence structure is synthesized by accurately controlling a ternary block copolymerization reaction of hydroquinone, 4, 4 '-difluorobenzophenone and biphenol, and the block copolymer PAEK-B with a specific sequence structure is obtained. And then the mixture is subjected to melt blending with PEEK, so that the toughness of the PEEK is effectively improved, the mechanical property is improved, and meanwhile, the original processing temperature is kept unchanged.

The invention provides a hot melt adhesive and a preparation method thereof, and relates to the technical field of adhesives. According to the hot melt adhesive, amorphous polyolefin (APAO) is used as a main body, ethylene-vinyl acetate copolymer (EVA) is added as a compatilizer, and Fischer-Tropsch wax is used as a viscosity modifier. The preparation method comprises the following steps: firstly synthesizing a dopamine functional polymer, and then carrying out melt blending on the dopamine functional polymer, APAO, EVA, tackifying resin and other components so as to stably introduce a catechol group into a hot melt adhesive system. When the hot melt adhesive is bonded with a metal surface, the catechol group can form a firm coordinate bond with metal ions, so that the adhesive force is greatly improved. The product provided by the invention has high adhesive force, excellent flexibility, good compatibility and construction performance, and is suitable for bonding and sealing metal materials.

The invention relates to the technical field of coatings, and discloses a heat-insulating powder coating as well as a preparation method and application thereof. The heat insulation powder coating is prepared from the following preparation raw materials in parts by mass: 160 to 220 parts of organic silicon modified polyester resin, 10 to 30 parts of modified hollow glass beads, 30 to 70 parts of modified sericite powder, 40 to 60 parts of titanium dioxide, 3 to 5 parts of hydrophobic SiO2 aerogel and 10 to 20 parts of curing agent, wherein the organic silicon modified polyester resin is prepared by melting and blending weather-proof polyester resin and organic silicon resin according to the mass ratio of (4-9): 1; the temperature of melt blending is 90 to 130 DEG C. According to the coating, the excellent heat insulation performance that the solar reflectance is larger than or equal to 0.87 and the heat conductivity coefficient is smaller than or equal to 0.075 W / m.K is achieved, the excellent mechanical strength, adhesive force, impact resistance and long-acting weather resistance are achieved, and heat loads on the surfaces of building outer walls, industrial furnace shells, household appliances and the like can be remarkably reduced.

The invention relates to the technical field of metallocene polyolefin materials, and particularly discloses a modified polyolefin film material as well as a preparation method and application thereof. The film material is prepared from the following components in parts by weight: 50 to 70 parts of metallocene linear low-density polyethylene, 20 to 35 parts of ethylene-butyl acrylate copolymer, 15 to 25 parts of polyolefin elastomer, 5 to 15 parts of bio-based degradable polyester elastomer, 3 to 8 parts of reactive compatilizer, 5 to 15 parts of organic modified layered double hydroxide, 8 to 20 parts of composite flame retardant, 0.3 to 1.5 parts of antioxidant and 0.5 to 1.5 parts of lubricant. The preparation method comprises the steps of melt blending, casting extrusion, two-way stretching and the like. The thin film has low hardness, high elongation, low melting point and moderate mechanical strength, the performance of the thin film can accurately meet specific application requirements, and the thin film is particularly suitable for the field of composite fabric of clothes, bags, shoes, hats and the like with high requirements for touch feeling and elasticity.

The invention discloses a low-temperature crosslinking process of a crosslinked polyethylene insulating material, and relates to the technical field of cable insulating material preparation. The process comprises the following steps: preparing a crosslinking premix containing a modified basic resin composition and a synergistic crosslinking system, carrying out melt blending and molding to obtain an insulating base material, optimizing the reaction activity of the base material through sectional microwave pretreatment, and carrying out low-temperature crosslinking reaction in a sealed environment through nitrogen replacement and in a saturated nitrogen atmosphere to obtain the high-temperature-resistant insulating material. And finally, carrying out gradient humidifying and cooling treatment to obtain the product. According to the process, the problems of low crosslinking degree, poor uniformity and the like of the existing process are solved through combination of resin modification, collaborative crosslinking system construction, sectional pretreatment and crosslinking environment regulation and control, and the process is suitable for efficient preparation of the high-voltage cable insulating material.

The application belongs to the technical field of antibacterial technology, and discloses a kind of photodynamic antibacterial modified polyester fiber and its preparation method, its preparation method is: (1) with SIPM as surfactant, water-soluble silver salt as precursor, ascorbic acid as reducing agent, prepare water-soluble nano silver powder;(2) after esterification reaction of PTA and EG, add EG, SIPM and water-soluble nano silver powder to carry out polymerization reaction in it, obtain photoresponsive active material;(3) with the base material of nano silver antibacterial masterbatch as ECDP, photoresponsive active material is prepared into nano silver antibacterial masterbatch as additive;(4) after melt blending of modified polyester, water-soluble porogen and nano silver antibacterial masterbatch, the spinning melt is obtained, and the spinning melt is spun, then washed, and the photodynamic antibacterial modified polyester fiber is obtained.The photodynamic antibacterial modified polyester fiber has excellent antibacterial and antiviral properties.

The application discloses an anti-ultraviolet aging polycarbonate modified material and application thereof, and belongs to the technical field of polymer material modification. The material comprises synergistically modified polycarbonate, an organic small-molecule functional regulator, an antioxidant, a light stabilizer, a lubricating dispersant and an inorganic filler, wherein the synergistically modified polycarbonate is constructed into a multiple synergistic network by introducing a borate dynamic covalent structure, a Schiff base structure and a rare earth coordination structure, and the organic small-molecule functional regulator is p-hydroxybenzophenone. The preparation method comprises preparation of the synergistically modified polycarbonate and a subsequent melt blending and extrusion process. Through the technical scheme, the synergistic effect of ultraviolet absorption, energy transfer and free radical inhibition is realized, the yellowing degree of the material is significantly reduced, the mechanical property retention rate and the optical stability are improved, and the material is suitable for the fields of automobile transparent parts, outdoor optical materials and electronic and electrical shell.

The invention belongs to the technical field of composite materials, and particularly relates to a high-strength frozen fruit frame synthesized by coal gangue modified recycled plastic and a preparation method thereof. 40-70 parts of regenerated PP resin, 30-50 parts of HDPE, 0-60 parts of coal gangue and 0.5-2 parts of a composite dispersant are used as core components, the coal gangue is subjected to surface modification through the composite dispersant, the problem of interfacial compatibility between the coal gangue and a resin matrix is solved, then a sectional temperature control process of a twin-screw extruder is performed, gradient heating at 170-195 DEG C is performed, and melt blending is performed, so that the regenerated PP composite material is obtained. And finally, the high-strength frozen fruit frame which is excellent in mechanical property, has the cost reduced by 20-30% and is environmentally friendly is prepared, and synergistic high-value utilization of plastic waste and coal-based solid waste is achieved.

The invention discloses a polyhydroxyalkanoate composition and a preparation method thereof. The polyhydroxyalkanoate composition comprises the following components in parts by mass: 100 parts of polyhydroxyalkanoate; 0.5 to 5 parts of unsaturated D-polylactic acid; 0.5 to 5 parts of poly (L-lactic acid); the preparation method comprises the following steps: S1, carrying out melt blending on the polyhydroxyalkanoate and the unsaturated D-polylactic acid, and enabling the polyhydroxyalkanoate and the unsaturated D-polylactic acid to fully react, so as to obtain an intermediate product; and S2, carrying out melt blending on the intermediate product obtained in the step S1, poly-L-lactic acid and an ester exchange inhibitor to finally obtain the polyhydroxyalkanoate composition with excellent thermal stability, high melt strength and high crystallization speed.

The invention relates to a high-breathability and high-fitness in-vitro fixing device with a shape memory function and a preparation method of the high-breathability and high-fitness in-vitro fixing device, and relates to the field of biomedical materials, the high-breathability and high-fitness in-vitro fixing device comprises the following components in parts by mass: 40-45 parts of polycaprolactone, 40-45 parts of polylactic acid, 4-6 parts of a compatilizer, 0.5-1.5 parts of a cross-linking agent, 8-12 parts of nano-hydroxyapatite, 10-20 parts of biocompatible polyurethane and 0.1-0.3 part of a coloring agent. The preparation method comprises the following steps: mixing the raw materials, carrying out melt blending, and carrying out extrusion granulation to obtain composite particles; the composite particles are subjected to melt-blowing spinning, and non-woven cloth is obtained; and carrying out hot press molding on the non-woven fabric, shaping and cooling to obtain the high-breathability and high-fitness in-vitro fixing device with the shape memory function. The in-vitro fixing device prepared by the invention has a silk net structure, has good air permeability, a shape memory function and fitness, and has good mechanical properties and antibacterial properties.

This application provides a self-healing polyurethane material, its preparation method, and its applications, relating to the field of polymer materials technology. The material uses a polyurethane matrix constructed from polyols and polyisocyanates, and introduces aromatic polyaldehyde compounds to form reversible dynamic bond structures with hydrazine compounds, thereby endowing the material with excellent self-healing properties. By controlling the type of chain extender and the melt blending process conditions, the material can achieve crack healing and restore mechanical properties after damage, while also possessing good flexibility, processability, and stability. The preparation process of this application is simple and the conditions are mild. The resulting material can be widely used in coatings, seals, and elastomers, significantly improving material service life and reliability.