The application discloses a kind of
polymer rheological property prediction method and
system based on
global optimization, to solve the problems that traditional rheological data exists apparent physical deviation,
engineering constitutive parameter step fitting is easy to fall into
local optimum and
microstructure feature is difficult to quantify.The method first obtains the apparent data of
polymer in multiple temperature zones steady shearing and dynamic oscillation;Then, based on Rabinowitsch equation, polynomial
differential correction is carried out, and the deviation of
pipe wall velocity distribution is eliminated to extract the real physical
viscosity;Subsequently, a Cross-WLF three-dimensional
space model containing temperature and
shear rate is constructed, and Levenberg-Marquardt
algorithm is used to perform global nonlinear iterative optimization, and the kinetic and thermodynamic constants are extracted in one step;At the same time,
dynamic modulus data is introduced to perform Cox-Merz rule self-consistency
verification, and a multi-dimensional diagnostic atlas matrix is constructed.The application breaks the limitation of traditional single-temperature zone fitting, and realizes the automatic extraction of high-precision mold flow
simulation parameters and the accurate diagnosis of material microphase separation.