16678 results about "Surface-active agents" patented technology

The invention belongs to the field of petrochemical engineering, and particularly relates to a litchi-shaped hollow polymer microsphere as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing litchi-shaped polymer hollow microspheres by adopting an inverse emulsion polymerization method, uniformly dispersing a water-soluble initiator and a water-soluble monomer solution in an oil-phase continuous phase under the emulsification action of a surfactant, and initiating polymerization in a water-in-oil reaction system through modified mesoporous microspheres loaded with metal copper quantum dots. Because the initiation rates of the water-soluble initiator and the metal copper quantum dots are different, a litchi-shaped structure is presented on the surface of the microsphere, and then the template is etched to form the litchi-shaped hollow-structure microsphere. The hollow structure in the microsphere improves the elastic deformation capacity of the microsphere, and the litchi-shaped appearance of the microsphere can play a better plugging effect, so that the dual functions of'displacement 'and'plugging' of the microsphere are really realized.

The invention belongs to the field of photovoltaic glass coatings, and particularly relates to a super-hydrophilic anti-reflection wear-resistant self-cleaning coating for room-temperature curing of photovoltaic glass, which takes nano silicon dioxide sol as a main film-forming agent to cure and form a film and comprises the following raw materials in parts by weight: 55-90 parts of deionized water, 9-20 parts of nano silicon dioxide sol, 1-10 parts of a silane coupling agent and 0.001-1 part of nano titanium dioxide. The coating is prepared from the following components in parts by weight: 0.01-1 part of a surfactant, 0.01-1 part of modified polyvinyl alcohol, 0.01-1 part of water-based acrylic resin, 0.001-1 part of an antistatic agent, 1-5 parts of a curing agent, 1-5 parts of a flatting agent and 0.1-1 part of a wear-resistant agent. The super-hydrophilic anti-reflection wear-resistant self-cleaning coating has super hydrophilicity, the water contact angle is below 10 degrees, the hydrophilicity, the antistatic property, the anti-reflection property, the wear resistance and other properties of glass can be remarkably improved, and when the super-hydrophilic anti-reflection wear-resistant self-cleaning coating is applied to photovoltaic module glass, the photoelectric conversion efficiency in photovoltaic power generation can be improved.

The invention provides a petroleum hydrocarbon pollution remediation method based on soil microorganisms, and provides an innovative solution aiming at the problems of high cost, high energy consumption and secondary pollution of an existing remediation technology. The method comprises the following steps: firstly, carrying out sampling analysis and pretreatment on polluted soil, screening out a microbial strain capable of efficiently degrading petroleum hydrocarbon, and fixing the microbial strain on a biochar carrier to form an immobilized microbial composite material; then, the material is added into the contaminated soil, and tolerant plants are planted to construct a combined remediation system. Meanwhile, nutrient substances such as nitrogen and phosphorus and a surfactant are added, so that the bioavailability and the microbial degradation efficiency of the petroleum hydrocarbon are improved. In the repairing process, the petroleum hydrocarbon content and the microbial activity are monitored regularly, and the repairing scheme is dynamically adjusted. According to the method, the biochar is prepared from agricultural waste, the cost is reduced, efficient and environment-friendly remediation is achieved by combining the synergistic effect of microorganisms and plants, and the method has remarkable economic and environmental benefits and is suitable for treatment of soil polluted by various petroleum hydrocarbons.

This application relates to an EPP material and a folding mat using this EPP material, which relates to the field of EPP material technology. The EPP material is formed into a plate by welding EPP particles, and the surface of the plate is coated with a hydrophobic antibacterial paint. The raw materials for preparing the EPP particles include 80-100 parts by weight of polypropylene resin, 1-3 parts by weight of a nucleating agent, 6-8 parts by weight of a modified graphene composite material, 5-10 parts by weight of a flame retardant, 5-15 parts by weight of a reinforcing agent, and 0.5-1.5 parts by weight of a surfactant. The raw materials for preparing the modified graphene composite material include hydrophobic modified graphene oxide, hydrophobic antibacterial nano-zinc oxide, and a modified ammonium polyphosphate coupling agent. The folding mat using this EPP material includes an EPP material, a surface layer, and a sewing thread, and the surface layer and the EPP material are fixedly connected by the sewing thread. This application has the effect of improving the flame retardancy, waterproofness, and antibacterial properties of EPP material, and the resulting tatami mat is environmentally friendly, comfortable, and has a good user experience.

The need for a liquid hand dishwashing detergent composition which provides for effective cleaning, as well as enhanced foaming, is met by formulating the composition with a surfactant system which comprises alkyl sulfated anionic surfactant having little or no alkoxylation, an amphoteric and / or zwitterionic co-surfactant, and nonionic surfactant, in combination with a mid-chain 1,2-alkanediol.

The invention discloses an acyltransferase mutant and application of the acyltransferase mutant in synthesis of N-acetyl-trans-4-hydroxyproline, and belongs to the technical field of enzyme engineering. The acyltransferase mutant provided by the invention contains 10th and 95th mutations on the basis of a corresponding amino acid sequence, such as a sequence as shown in SEQ ID NO.1, or contains 62nd or 64th mutations while containing the 10th and 95th mutations. Compared with an original enzyme before mutation, the acyltransferase mutant obtained by the invention has higher acyltransferase activity, and the conversion rate of trans-4-hydroxy-L-proline is greatly improved, so that the yield of N-acetyl-trans-4-hydroxy proline is further improved, and the yield of N-acetyl-trans-4-hydroxy proline is improved. After the surfactant and the metal ions are added, the yield of the N-acetyl-trans-4-hydroxyproline synthesized by the mutant D62K / D10V / D95I under the catalysis is up to 18.7 g / L.

A preparation method of a self-suspending proppant for hydraulic fracturing is characterized in that solid ceramsite is changed into a porous reinforced structure, a self-repairing function is introduced, bio-based macromolecules are adopted to replace a traditional surfactant, the environmental protection property is improved, nano-deposition and microwave technologies are introduced, the performance is improved, meanwhile, the energy consumption is reduced, and the compression resistance enhancement and self-repairing characteristics are newly added; and the method adapts to more complex stratum working conditions.

The invention discloses an efficient-dissolution dotenorad tablet and a preparation method thereof, and relates to the technical field of tablet preparation. The tablet consists of 5-20 parts of a dotenorad active component, 10-30 parts of a disintegrating agent, 40-70 parts of a filling agent, 0.5-5 parts of a surfactant, 0.5-3 parts of a lubricant, 1-5 parts of an adhesive and 0.5-1 part of an antioxidant. The preparation method comprises the following steps: premixing active components and auxiliary materials, carrying out high-shear wet granulation to form porous structure particles, carrying out precise temperature-control drying through a fluidized bed, carrying out micronization treatment to regulate the specific surface area of the particles, and finally, carrying out high-pressure tablet forming through a magnesium stearate / aerosil compound lubrication system. The dissolution rate of the tablet in a medium with the pH value of 6.8 for 15 minutes reaches 85% or above, meanwhile, long-term stability is achieved by inhibiting oxidative degradation, and the tablet has the dual advantages of quick effect taking and stable storage.

The invention relates to the technical field of oilfield exploitation, and discloses a nanometer oil-displacing agent for oilfield oil extraction and a preparation method thereof.The nanometer oil-displacing agent takes modified nanometer silicon dioxide and a surfactant as main components, polymer macromolecules are modified on the surface of the nanometer silicon dioxide to serve as a main body of the nanometer oil-displacing agent, and the nanometer oil-displacing agent is prepared. Under the action of the surfactant, the nano silicon dioxide can flow into the fine throat and the micro throat, and the polymer macromolecules of the branched structure can generate a relatively strong interaction force with the rock, so that the polymer macromolecules are firmly adhered to the surface of the rock, the adhesion of crude oil on the surface of the rock is reduced, a smooth crude oil channel is constructed, and the flowing pressure of liquid is reduced; and crude oil fluidity is improved. The structure of the cross-linking agent contains quaternary ammonium cations, so that the electrostatic repulsion effect between nano silicon dioxide can be greatly enhanced, aggregation between nano silicon dioxide and nano silicon dioxide can be avoided, the interfacial tension can be efficiently maintained, the oil-water interfacial tension is greatly reduced, and the recovery rate of crude oil is effectively increased.

The invention relates to an antibacterial PP material and a preparation method thereof, and belongs to the technical field of high polymer materials. The antibacterial PP material is prepared from the following components in parts by weight: 60 to 80 parts of PP resin, 2 to 4 parts of a surfactant, 0.5 to 1.5 parts of a modified antibacterial agent, 0.5 to 1.5 parts of a flame retardant and 0.2 to 0.8 part of an antioxidant, titanium ions in the modified antibacterial agent destroy bacterial cell walls, quaternized intermediate products react with proteins of cell membranes to accelerate bacterial death, and in addition, phenolic hydroxyl groups absorb ultraviolet rays with different wavelengths to inhibit the light aging process; a compact and continuous carbon layer is formed during combustion of the flame retardant and cooperates with phosphorus-oxygen double bonds and melamine, the flame retardant efficiency is improved, aluminum hydroxide coats the surface, hydroxyl is subjected to heat absorption decomposition during combustion, the surface temperature of combustible materials is stabilized, meanwhile, an inert aluminum oxide layer is formed, and the flammability is reduced. The antibacterial PP material prepared by the invention not only has good antibacterial and anti-aging effects, but also has excellent flame retardant property.

The invention discloses a ginsenoside liposome. The ginsenoside liposome comprises ginsenoside, phospholipid and a surfactant, and the ginsenoside comprises protopanoxadiol or / and protopanaxatriol. The invention also discloses a preparation method of the ginsenoside liposome and application of the ginsenoside liposome in preparation of medicines, cosmetics or skin care products. According to the invention, the final desugared product of ginsenoside with the effect of treating skin toxicity reaction is prepared into the liposome, so that the membrane permeation and absorption capabilities of ginsenoside are greatly improved, the skin toxicity caused by tumor treatment can be quickly and effectively relieved, and the drug effect can be played for a long time; the invention provides a new method for treating skin toxic reaction caused by tumor treatment, and makes up for the requirements which cannot be met by the existing treatment means.

The embodiment of the invention discloses a biological composite liquid material capable of releasing negative oxygen ions as well as a preparation method and application of the biological composite liquid material. The invention discloses a preparation method of a traditional Chinese medicine. The biological composite liquid material is prepared from 12 to 18 parts of plant extract, 1 to 4 parts of silver ion solution, 2 to 5 parts of titanium dioxide, 10 to 15 parts of nano silicon dioxide, 2 to 8 parts of sodium oxide, 1 to 6 parts of magnesium oxide dispersion liquid, 0.5 to 1.5 parts of calcium hydroxide solution, 1 to 3 parts of ferric oxide colloidal solution, 2 to 6 parts of zinc oxide dispersion liquid, 12 to 18 parts of mixed silica sol and 15 to 20 parts of nano borosilicate liquid material. 0.5-1.5 parts of a surfactant, 4-8 parts of glycerol and 10-15 parts of deionized water. The biological composite liquid material has the characteristic of efficiently releasing negative oxygen ions, can effectively improve the air quality, is good in stability, convenient to use, safe and reliable, can be widely applied to the fields of air purification, medical care, building materials and the like, and has a wide market prospect.

The preparation method of the silicon-carbon composite material comprises the following steps: uniformly mixing a carbon source, a pore forming agent and a cross-linking agent, and introducing peroxide gas into a tubular furnace for sintering to obtain porous carbon; uniformly mixing the porous carbon with liquid silane and a surfactant, and transferring the mixture into a high-pressure reaction kettle for reaction to obtain a silicon-carbon precursor; and introducing the obtained material into a carbon source gas containing a heteroatom gas for deposition to obtain the silicon-carbon composite material. The obtained material generates porous carbon with high strength and high pore volume by utilizing the cross-linking agent and the pore-forming agent thereof, so that the expansion is reduced; and the liquid silane has the characteristics of low decomposition temperature, low cost and high safety performance, so that the specific capacity is improved, and the cost is reduced.

The present disclosure belongs to the technical field of silver powder preparation, and particularly relates to a method for preparing a silver powder having adjustable sintering activity, and a conductive silver powder and the use thereof. The preparation method comprises the following steps: S1, subjecting a reducing agent, a sintering regulator, a dispersing agent and water to primary mixing, then adding an oxidizing agent solution under stirring conditions, and reacting same after the addition is finished, wherein a surfactant is introduced during the primary mixing and / or the surfactant is introduced into the oxidizing agent solution; and S2, filtering the material obtained in S1, then subjecting the material and a coating liquid containing a coating agent to secondary mixing, and then drying the mixture, so as to obtain a silver powder. The present disclosure can result in a silver powder having different sintering activities, and can satisfy usage scenarios of carrying out sintering in different temperature sections, such as the use in different temperature scenarios including low-temperature sintering and high-temperature sintering; and during the silver powder preparation process of the present disclosure, no slurry is formulated, and the sintering activity of the silver powder is directly tested by means of a thermal mechanical analyzer, such that the development process is more convenient, and characterization is more accurate.

The invention discloses a nano imbibition oil displacement agent as well as a preparation method and application thereof. The preparation method of the nano imbibition oil-displacing agent comprises the following steps: reacting citric acid, glucose, long-chain amine, a surfactant, an organic solvent, short-chain alcohol and water at 140-200 DEG C under 0.4-0.5 MPa for 6-16 hours to obtain the nano imbibition oil-displacing agent. The method disclosed by the invention is simple, convenient, environment-friendly and low in cost, and the prepared nano imbibition oil displacement agent has good surface and interface activity at high temperature and high salt, can be used as an imbibition oil recovery agent for an ultra-low permeability reservoir, and can remarkably improve the oil recovery rate.

The invention relates to the technical field of daily chemicals, and provides shampoo and a preparation method and application thereof.The shampoo is prepared from, by mass, 3%-15% of a sulfate-free anionic surfactant, 8%-20% of an ampholytic surfactant, 0-5% of a nonionic surfactant, 0.3%-1% of a hair cationic conditioner and 0.1%-3% of emulsified silicone oil based on the total mass of the shampoo; the cationic conditioner for hair comprises a polyquaternium cationic polymer and cationic guar gum, and the mass ratio of the polyquaternium cationic polymer to the cationic guar gum is (1: 2)-(2: 1). According to the application, the polyquaternium cationic polymer and the cationic guar gum are selected as the cationic conditioner for hair, and the sulfate-free anionic surfactant and the emulsified silicone oil are matched, so that mild cleaning of scalp can be realized, water-oil balance of the scalp can be maintained, damage to hair scales can be reduced, and the combability and fluffy effect of the hair can be improved.

The invention relates to the technical field of farmland water-retaining agents, in particular to a multifunctional farmland water-retaining agent as well as a preparation method and a use method thereof, and the multifunctional farmland water-retaining agent comprises the following components in parts by mass: 30-60 parts of a temperature-sensitive monomer, 20-40 parts of a polymer monomer, 1-10 parts of a cross-linking agent, 5-20 parts of a functional filler, 1-5 parts of a surfactant and 0.1-5 parts of an initiator. According to the multifunctional farmland water-retaining agent as well as the preparation method and the use method thereof, the temperature-sensitive monomer exists in the three-dimensional network structure of the provided farmland water-retaining agent, and the water supply mode can be automatically adjusted according to the soil water content and the water demand condition of crops.

The invention relates to the technical field of preparation of surfactants, in particular to a PPO / PEO block Gemini ductile surfactant suitable for high-temperature and high-salt oil reservoirs and a preparation method of the PPO / PEO block Gemini ductile surfactant. The preparation method comprises the following steps: by taking fatty alcohol as an initial raw material, carrying out gradual addition on the fatty alcohol, propylene oxide (PO) and ethylene oxide (EO) through a potassium hydroxide / 18-crown ether-6 catalytic system to prepare an APOnEOm intermediate; the preparation method comprises the following steps: carrying out esterification with a polyethylene glycol bismaleate connecting group, and finally sulfonating with sodium hydrogen sulfite to obtain polyethylene glycol bismaleate diester sodium sulfonate (T-APOnEOm-S). By regulating and controlling the PPO / PEO block ratio, the product has excellent temperature resistance and salt resistance, is suitable for high-temperature and high-salt oil reservoirs, has strong emulsifying capacity, can reduce the oil-water interfacial tension to 10 <-3 > mN / m level, and remarkably improves the oil recovery rate. The preparation process is mild in condition and adjustable in product performance, and has important application value in the field of tertiary oil recovery.

The invention relates to an activating agent and a method for repairing an organic contaminated site by targeted stimulation of indigenous microorganisms based on negative pressure infiltration promotion, which are characterized in that the activating agent containing nutrient substances, a sustained-release material and a surfactant is promoted to be uniformly distributed in the contaminated site through a negative pressure effect formed in soil by vacuumizing, so that the growth and activity of the indigenous microorganisms can be stimulated, and the effect of repairing the organic contaminated site by targeted stimulation of the indigenous microorganisms is achieved. The degradation of organic pollutants is accelerated. The defects that an existing in-situ organic pollutant site repairing technology is high in energy consumption, poor in effect, incapable of achieving secondary utilization of repaired soil, small in application range and the like are overcome, the provided activating agent can be combined with indigenous microorganisms in the site in a targeted mode, nutrient substances needed by growth are provided for the indigenous microorganisms, biodegradation of organic pollutants is promoted, and the effect of in-situ repairing of the organic pollutant site is achieved. And the activating agent is uniformly distributed in the polluted site under the negative pressure effect, so that more uniform and effective in-situ remediation is realized.

The invention belongs to the technical field of oil and gas development, and particularly relates to an oil and gas well blocking remover and a preparation method thereof. The blocking remover comprises the following components: 5-8% of low-carbon composite organic acid, 5-7% of fluoboric acid, 6-9% of ammonium bifluoride, 4-6% of an anti-acid sludge mutual solvent, 2-4% of a corrosion inhibitor, 2-4% of polyoxypropylene polyoxyethylene propylene glycol ether, 8-12% of a permeation dispersion surfactant, 2-5% of a sulfur dissolving agent, 2-5% of a stable chlorine dioxide solution and the balance of water. The preparation method comprises the following steps: adding the low-carbon composite organic acid, the fluoboric acid and the ammonium bifluoride into water and stirring; adding an acid sludge resisting mutual solvent and a sulfur dissolving agent, and stirring; adding the corrosion inhibitor, the polyoxypropylene polyoxyethylene propylene glycol ether and the permeation dispersion surfactant, and stirring; and finally, reducing the stirring speed, adding the stable chlorine dioxide solution, and stirring to uniformly mix. The blocking remover provided by the invention is comprehensive in blocking removal function, very good in dissolving and dispersing performance on complex blocking substances, very small in corrosion damage to a shaft pipe wall and wide in applicability.

To provide a perfluoropolyether compound expressing excellent surface tension reduction performance, and expressing excellent foamability and foam stability not only during diluting fresh water but also during diluting sea water, and a fluorine-based surface active agent including the compound.SOLUTION: A perfluoropolyether dicarboxylic acid compound or a salt thereof is expressed by the following formula (1). In the formula, Rf1 represents a 1-4C perfluoroalkyl group. R1 represents a substituted or unsubstituted 1-10C hydrocarbon group. R2 represents a substituted or unsubstituted 1-6C hydrocarbon group. R3 and R4 are same or different and each represent a substituted or unsubstituted 1-4C hydrocarbon group. n is an integer of 0-5.SELECTED DRAWING: None

The invention relates to the technical field of phase change microcapsules, in particular to a polyurea / polyacrylate double-layer shell material phase change microcapsule and a preparation method thereof. The microcapsule sequentially comprises a phase change material core material, a polyacrylate shell material and a polyurea shell material from inside to outside, and is prepared from the following raw materials: a polyisocyanate monomer, an acrylate monomer, an acrylate functional monomer, an acrylate cross-linking agent, a chain extender, an initiator, a surfactant, a phase change material and water. According to the invention, polyurea interfacial polymerization and polyacrylate suspension polymerization are combined to form a double-layer shell material for coating to prepare the phase change microcapsule, so that the phase change microcapsule has excellent sealing property, durability and high enthalpy value performance.

The invention relates to the technical field of preparation of a graphene lubricating oil additive through a graphene uniform dispersion technology, and discloses a preparation method of an efficient dispersion type graphene composite lubricating oil additive, which comprises the following steps: a) carrying out surface modification on graphene by utilizing plasma treatment; b) mixing the modified graphene with a surfactant; c) uniformly mixing the graphene dispersion liquid with poly-alpha-olefin (PAO) base oil with specific molecular weight distribution on a nanoscale by adopting a microfluidic technology to form a premix; d) adding a custom-formulated antioxidant, an extreme pressure additive and nanoscale silicon dioxide particles and / or metal oxide into the premix; through plasma treatment and ultrasonic treatment conditions, the compatibility of graphene and base oil is remarkably enhanced, the comprehensive performance of the lubricating oil is improved, meanwhile, the antioxidant, the extreme pressure additive and the nano material are introduced, and the wear resistance, oxidation resistance and extreme pressure performance of the composite additive are remarkably improved.

The invention provides a method for preparing a high-performance lithium manganese iron phosphate positive electrode material based on a manganese iron phosphate precursor, and relates to the technical field of batteries. A method for preparing a high-performance lithium manganese iron phosphate positive electrode material based on a manganese iron phosphate precursor comprises the following steps: S1, mixing a phosphorus source, an iron source and a manganese source in a water medium, adding a surfactant, and carrying out ball milling, drying and sintering to obtain the manganese iron phosphate precursor; and S2, mixing the manganese iron phosphate precursor, a lithium source, a carbon source, a doping agent, an auxiliary agent and deionized water, and carrying out ball milling, drying and sintering to obtain the lithium manganese iron phosphate positive electrode material. The method can improve the surface / interface stability while improving the surface conductivity of the material, thereby prolonging the cycle life of the battery and improving the charge-discharge capacity of the battery.

The invention belongs to the technical field of laser processing, and provides a quartz crystal etching solution which comprises the following components in volume concentration: 10-30% of hydrofluoric acid, 1-5% of sulfuric acid, 0.1-0.3% of surfactant and the balance of water. By optimizing the proportion, the manufacturing precision and the production and manufacturing efficiency of the tuning fork wafer are improved. And the stable etching rate and the optimal etching surface are obtained, and meanwhile, the cost is saved for process replacement. The invention further provides a method for cutting the tuning fork of the quartz crystal through the laser. The method comprises the steps that S1, the cutting contour line of the tuning fork is preset on the quartz crystal; s2, performing laser cutting on the quartz crystal based on a preset cutting contour line, and forming a tuning fork contour on the quartz crystal; and S3, integrally soaking the quartz crystal in the quartz crystal etching solution, and separating out the tuning fork. The machining process of the quartz crystal tuning fork is simplified, the cutting quality is optimized, the method is suitable for the large-piece manufacturing process, and the cutting efficiency and the yield are greatly improved.

The invention relates to the field of heat transfer films, in particular to a single-sided water-based environment-friendly pyrograph film and a preparation process thereof. The water-based release film sequentially comprises an ink absorption layer, a water-based release layer and a base layer from the upper surface to the lower surface, the water-based release layer is obtained by curing a water-based release agent, and the water-based release agent is prepared from the following raw materials in percentage by weight: modified water-based acrylate, deionized water, a cross-linking agent, a defoaming agent and modified polyurethane; the modified water-based acrylate is prepared from alkenyl siloxane, hydrogen-containing polysiloxane, phenyl hydroxyl reticular silicon resin, a bonding aid, a surfactant and water; according to the scheme, the obtained water-based release layer is stably adhered to the base layer, the ink absorption layer can be rapidly separated from the water-based release layer during heat transfer printing, and the transfer printing efficiency and the transfer printing quality are improved.

The invention discloses a coating as well as a preparation method and application thereof. The coating comprises the following raw materials: potassium silicate; ethyl orthosilicate; a nanometer titanium dioxide sol; rare earth is doped with nano titanium dioxide; compounding zinc oxide nanoparticles; nano silicon dioxide sol; a fluorosilane coupling agent; a fluorocarbon surfactant; a conductive carbon nanotube; nano aluminum oxide sol; an organic silicon modified acrylate emulsion; a boron nitride nanosheet; hollow glass beads; a shape memory polymer; the invention discloses a self-repairing nanofiber. After a coating is formed by using the coating, the coating has the characteristics of high light transmittance, good self-cleaning effect, high hardness, good adhesive force and excellent weather resistance, and can be applied to a photovoltaic module to replace an existing photovoltaic module coating product.

The invention provides a high-performance leak-proof plugging gel for fractured formations and a preparation method thereof, and belongs to the technical field of oil and gas field drilling fluids. The gel is prepared from a copolymerization reaction monomer, fibers, a surfactant and other components, and has high pressure bearing capacity, good temperature and salt resistance, excellent mechanical property and environmental response capacity. The intelligent plugging device can effectively plug a fractured formation leakage channel, adapts to a high-temperature, high-pressure and high-salt environment, and realizes intelligent plugging. The preparation method is simple and small in environmental pollution. The effectiveness and the practicability of the method are verified through specific embodiments, an effective solution is provided for oil and gas drilling fractured formation leaking stoppage, and the method has important industrial application value and market prospects.

The invention relates to the technical field of surfactants, and discloses a preparation method of a modified polycarboxylate surfactant and application of the modified polycarboxylate surfactant in pesticide preparations. 3-hexene-1, 6-diamine and epoxy chloropropane are used as raw materials, 1, 6-tetraglycidylamine-3-hexene is obtained through ring-opening and ring-closing reactions, 1, 6-tetraglycidylamine-3-hexene is utilized twice, and the yield of the 1, 6-tetraglycidylamine-3-hexene is increased. The preparation method comprises the following steps: sequentially reacting 2, 3, 4, 6-tetraglycidylamine-3-hexene with sodium hydrogen sulfite and phosphoric acid to obtain tetrasulfonate hexene and tetraphosphate hexene, and copolymerizing the tetrasulfonate hexene and the tetraphosphate hexene with acrylic acid and methacrylate to obtain the modified polycarboxylate surfactant. The modified polycarboxylate surfactant prepared by the preparation method disclosed by the invention has excellent dispersing performance, heat storage stability and relatively high suspension rate.

The invention belongs to the technical field of desiliconized fly ash, and particularly relates to a high-alumina-silica-ratio material capable of replacing bauxite as well as a preparation method and application of the high-alumina-silica-ratio material. The preparation method comprises the following steps: S1, crushing coal gangue, and grinding the crushed coal gangue until the particle size is less than 40 meshes to obtain a ground material; s2, mixing the ground material and a catalyst according to a weight ratio of 100: (1-2), roasting, and cooling to obtain activated coal gangue; the catalyst comprises sodium carbonate, calcium oxide and aluminum oxide in a weight ratio of 1: (0.3-0.5): (1.4-1.6); s3, mixing a sodium hydroxide solution, the activated coal gangue and a surfactant, and reacting at 50-90 DEG C for 1-6 hours to obtain desiliconized slurry; and S4, filtering the desiliconized slurry, collecting a solid phase, washing with water, and drying to obtain desiliconized fly ash, namely the high alumina-silica ratio material capable of replacing bauxite. The method is high in desiliconization rate.