6292 results about "Material technology" patented technology

The invention belongs to the technical field of polymer plastic materials, and particularly relates to a high-temperature-resistant anti-corrosion polytetrafluoroethylene material and a preparation method thereof. The polytetrafluoroethylene is prepared from the following raw materials in parts by weight: 50 to 60 parts of polytetrafluoroethylene, 5 to 10 parts of fluorinated modified graphene oxide, 3 to 5 parts of aluminum powder, 5 to 8 parts of modified silicon carbide fiber, 3 to 5 parts of silane modified nano silicon dioxide, 2 to 3 parts of polyphenylene sulfide, 2 to 3 parts of polyimide, 0.5 to 0.8 part of dispersing agent and 0.5 to 1 part of antioxidant. The heat conduction performance and the interface bonding force are improved through the fluorinated modified graphene oxide, the impact resistance and the wear resistance are enhanced through the silicon carbide fibers, and the corrosion resistance and the wear resistance are improved through the aluminum powder; silane modified silicon dioxide enhances the mechanical property of the composite material by improving the dispersity of the filler, and PPS and PI interact with the surface of the filler through polar groups in molecular chains, so that the interface strength is improved, and the toughness and the thermal stability are improved.

The invention discloses a preparation method of preheating-welding-free extra-thick steel S355MLO for ocean engineering, and belongs to the technical field of metal materials. The steel comprises the following chemical components in percentage by mass: 0.04%-0.06% of C, 0.15%-0.50% of Si, 1.35%-1.45% of Mn, less than or equal to 0.008% of P, less than or equal to 0.003% of S, 0.012%-0.02% of Ti, less than or equal to 0.015% of Al, 0.15%-0.25% of Ni, less than or equal to 0.18% of Cu, less than or equal to 0.18% of Cr, less than or equal to 0.35% of Ceq = [C + Mn / 6 + (Cr + Mo + V) / 5 + (Ni + Cu) / 15] and the balance of Fe and inevitable impurities. The low-carbon and high-manganese component design is adopted, the S355MLO super-thick steel plate with the maximum thickness of 100 mm is produced through a continuous casting billet, the carbon equivalent Ceq is smaller than or equal to 0.35, and high strength, high toughness and high welding performance are integrated. The base metal and welding toughness of the thick steel plate produced by the TMCP process are improved through the component and inclusion regulation and control technology, the process is simple, the production cost is low, the production efficiency is high, preheating before welding can be avoided, and energy conservation and consumption reduction are achieved.

The invention discloses a high-temperature-resistant epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials. The high-temperature-resistant epoxy resin composite material is prepared from the following raw materials in parts by weight: 70 to 80 parts of modified epoxy resin, 8 to 15 parts of high-temperature-resistant modifier, 15 to 30 parts of curing agent, 3 to 8 parts of nano reinforcing filler, 1 to 3 parts of coupling agent, 3 to 6 parts of carbon fiber, 2 to 5 parts of nano titanium dioxide, 5 to 10 parts of organic silicon rubber, 1 to 3 parts of conductive agent, 3 to 7 parts of flame retardant and 2 to 4 parts of zinc borate. The high-temperature-resistant epoxy resin composite material has outstanding advantages and strong thermal stability, and can bear high temperature; mechanical performance is excellent, and firmness and durability are achieved; the self-repairing capability is achieved, and the service cycle can be prolonged; the anti-permeability is good, and gas and liquid can be effectively blocked; the surface is smooth, the friction coefficient is low and the application prospect is wide.

An integrated carbon honeycomb structure material and its preparation method are disclosed, belonging to the field of carbon materials technology. Based on a co-sacrificial template low-temperature pyrolysis strategy, the target material can be obtained through three main steps: preparation of a metal salt-colloidal microsphere template precursor, precursor pressing and molding, and subsequent calcination and carbonization. This technology has the characteristics and advantages of simple preparation process, regular and controllable macroscopic structure of the sample (such as shape, area, and thickness), rich and tunable chemical composition, and three-dimensional interconnection of graphene carbon matrix. It has great application potential in many fields such as electrochemical energy storage, catalysis, gas separation, adsorption, and electromagnetic shielding.

This application relates to an EPP material and a folding mat using this EPP material, which relates to the field of EPP material technology. The EPP material is formed into a plate by welding EPP particles, and the surface of the plate is coated with a hydrophobic antibacterial paint. The raw materials for preparing the EPP particles include 80-100 parts by weight of polypropylene resin, 1-3 parts by weight of a nucleating agent, 6-8 parts by weight of a modified graphene composite material, 5-10 parts by weight of a flame retardant, 5-15 parts by weight of a reinforcing agent, and 0.5-1.5 parts by weight of a surfactant. The raw materials for preparing the modified graphene composite material include hydrophobic modified graphene oxide, hydrophobic antibacterial nano-zinc oxide, and a modified ammonium polyphosphate coupling agent. The folding mat using this EPP material includes an EPP material, a surface layer, and a sewing thread, and the surface layer and the EPP material are fixedly connected by the sewing thread. This application has the effect of improving the flame retardancy, waterproofness, and antibacterial properties of EPP material, and the resulting tatami mat is environmentally friendly, comfortable, and has a good user experience.

The invention relates to the technical field of ceramic materials, in particular to a wear-resistant woven ceramic material and a preparation method thereof, and the preparation method comprises the following steps: preparation of a ceramic body: weighing the following raw materials in parts by weight: 15-20 parts of boron nitride, 5-8 parts of aluminum oxide, 4-7 parts of an additive doped with modified nano titanium dioxide, 2-5 parts of tungsten carbide, 2-4 parts of zirconium oxide and 8-12 parts of ball-milling leveling liquid; according to the wear-resistant woven ceramic material disclosed by the invention, the carbon fibers and the basalt fibers are respectively immersed into the ceramic body for immersion treatment, then orthogonal weaving is performed, and finally sintering improvement is performed to obtain the woven ceramic material, so that the wear resistance, toughness and pollution resistance of the obtained woven ceramic material are improved in a balanced manner, and the product is excellent in ultraviolet resistance and thermal cycling resistance stability.

The invention discloses 460-grade preheating-free welding maritime work steel and a preparation method thereof, and belongs to the technical field of metal materials. The steel comprises the following chemical components in percentage by mass: 0.04 to 0.06 percent of C, 0.15 to 0.50 percent of Si, 1.75 to 1.85 percent of Mn, less than or equal to 0.008 percent of P, less than or equal to 0.003 percent of S, 0.012 to 0.02 percent of Ti, less than or equal to 0.015 percent of Al, 0.25 to 0.35 percent of Ni, 0.20 to 0.28 percent of Cu, 0.20 to 0.25 percent of Cr and the balance of Fe and inevitable impurities. A low-carbon and high-manganese component design is adopted, the S460MLO super-thick steel plate with the maximum thickness capable of reaching 100 mm is produced through a continuous casting billet, the carbon equivalent Ceq is smaller than or equal to 0.45, and high strength, high toughness and high welding performance are integrated. The base metal and welding toughness of the thick steel plate produced by the TMCP process are improved through the component and inclusion regulation and control technology, the process is simple, the production cost is low, the production efficiency is high, preheating before welding can be avoided, energy is saved, consumption is reduced, and the method is environmentally friendly.

The invention discloses an ultrahigh-barrier homogenized composite packaging film and a preparation process thereof, and belongs to the technical field of packaging materials. The ultrahigh-barrier homogenized composite packaging film comprises a base material layer, an ink layer, a barrier layer and a heat sealing layer, wherein the base material layer is a BOPP film, the ink layer is water-based ink, the barrier layer is a VMBOPP film, and the heat sealing layer is a PE composite film; the BOPP film is prepared from the following raw materials in parts by mass: 60 to 70 parts of polypropylene, 15 to 22 parts of hyperbranched polymer modified POE (Polyolefin Elastomer), 10 to 18 parts of ethylene-vinyl acetate copolymer, 0.1 to 0.5 part of nucleating agent and 0.1 to 0.4 part of antioxidant. The ultrahigh-barrier homogenized composite packaging film disclosed by the invention is simple in preparation process and stable in structural barrier property, has ultrahigh oxygen barrier property and water vapor barrier property and excellent mechanical strength, toughness and high and low temperature resistance, a heat sealing process is easy to control, and the edge sealing flatness after packaging is improved; the single polyolefin material is adopted, the raw materials are environment-friendly, the barrier property of the same structure of an aluminum foil can be obtained, and the cost is reduced.

The invention relates to a 1400 MPa-grade nickel-based alloy for a second-generation high-temperature superconducting base band and a preparation method of the 1400 MPa-grade nickel-based alloy, and belongs to the technical field of materials. The nickel-based alloy comprises the following chemical components in percentage by weight: 15.0 to 17.0 percent of Cr, 13.0 to 15.0 percent of Mo, 5.5 to 9.0 percent of W, 5.0 to 7.0 percent of Fe, 0.4 to 0.6 percent of Mn, 0.01 to 0.05 percent of Si, 0.1 to 0.2 percent of V, 0.0 to 2.5 percent of Co, 0.1 to 0.2 percent of Al, 0.001 to 0.01 percent of B and Clt, 0.005%, Plt; 0.005%, Slt; 0.002%, Olt; 0.002%, Nlt; 0.002%, and the balance being nickel. On the basis of the Ni-Cr-Mo alloy, the composition design thought of increasing W and reducing Mo is adopted, the optimized hot working and heat treatment process is matched, and finally the strength of a base body is improved through cold deformation; the content of C is controlled, precipitation of carbides is controlled, and alloy elements are ensured to be completely dissolved into a matrix during homogenization treatment; and a pure smelting process is adopted, so that the oxygen content in the alloy is reduced, the inclusion content is controlled, and high purity is ensured.

The invention relates to the technical field of building materials, and particularly discloses a high-performance solid-waste-based grouting material and a preparation method thereof. Comprising the following raw materials in parts by weight: 32 to 54 parts of Portland cement, 12 to 16 parts of a modified admixture, 2.4 to 3.6 parts of a functional filler, 42 to 56 parts of aggregate, 45 to 55 parts of a photoinitiator solution, 0.6 to 0.8 part of a water reducing agent, 0.9 to 1.1 parts of a composite expanding agent, 0.04 to 0.06 part of a defoaming agent and 9.2 to 12.4 parts of deionized water. Siloxane groups, acylamino groups, ester groups and benzene rings are chemically bonded on the surface of the modified admixture, so that the hydrophilicity of the modified admixture is reduced, the modified admixture can form hydrogen-bond interaction with hydroxyl groups and cement hydrates on the functional filler, and meanwhile, a flexible long-chain alkane structure on the functional filler can be entangled with the modified admixture, so that the flexibility of the modified admixture is improved. The mechanical property, the durability and the fluidity of the grouting material are improved.

The invention relates to the technical field of woven ceramic materials, in particular to a high-toughness woven ceramic material and a preparation method thereof, and the high-toughness woven ceramic material comprises the following raw materials in parts by weight: 30-40 parts of diopside, 20-30 parts of quartz, 10-15 parts of silicon carbide, 7-11 parts of boron nitride, 6-10 parts of a modified carbon nanotube reblended admixture, 5-7 parts of an intercalated synergistic supplement, 4-6 parts of aluminum oxide, 10-15 parts of water and 3-5 parts of a sodium dodecyl benzene sulfonate solution. According to the high-toughness woven ceramic material, the diopside is matched with the quartz, the silicon carbide, the boron nitride and the aluminum oxide raw materials, the blending and matching effects of the raw materials are optimized by improving the interfacial activity of the sodium dodecyl benzene sulfonate solution, and meanwhile, the added modified carbon nanotube reblended admixture and the intercalated synergistic supplement are used for carrying out coordination and synergistic effects, so that the high-toughness woven ceramic material is prepared. The durable usability of the product is enhanced, the fracture toughness of the product is excellent, the scrubbing-resistant and corrosion-resistant stability effects are remarkable, and the performance improvement effect of the product is remarkable.

The invention relates to the technical field of ceramic materials, in particular to a ceramic composite material and a preparation method thereof.The ceramic composite material is prepared from, by weight, 30-35 parts of silicon carbide, 15-20 parts of boron nitride, 10-15 parts of silicon dioxide, 8-11 parts of additive based on modified filler and 7-10 parts of ball milling agent based on sodium alginate reconditioning modification. According to the ceramic composite material, silicon carbide and boron nitride are matched with silicon dioxide, the additive based on the modified filler and the ball-milling agent based on sodium alginate reconditioning modification are blended and coordinated, and through coordination and synergism of the raw materials, the obtained product can achieve coordinated improvement of strength, wear resistance and thermal conductivity; and the product has remarkable heat-resistant and corrosion-resistant stability effects.

The invention relates to the technical field of inorganic nonmetal ceramic materials, in particular to a ceramic tile and a preparation method thereof. The ceramic tile comprises the following raw materials: 40-50 parts of waste residues, 1-5 parts of barium carbonate, 5-8 parts of feldspar powder, 0.5-3 parts of zinc oxide, 2-7 parts of pigment, 15-20 parts of modified kaolin and 1-5 parts of water. The preparation process of the modified kaolin comprises the following steps: (1) adding kaolin into deionized water, then adding octadecyl bis (hydroxyethyl) methyl ammonium chloride, stirring, filtering and drying to obtain pretreated kaolin; and (2) adding the kaolin pretreated in the step (1) into deionized water, then adding cellulose and manganous nitrate, carrying out heating reaction, and then filtering, washing and drying to obtain the modified kaolin. Cellulose is carbonized on the surface of kaolin through a hydrothermal carbonization reaction, the heat conduction efficiency of the ceramic tile is reduced, the hybridization degree of the surface structure of kaolin is further improved by adding manganous nitrate, and the strength of the ceramic tile is improved.

The invention relates to the technical field of inorganic non-metal coating materials, in particular to high-stain-resistance enamel matte glaze and a preparation method thereof.The high-stain-resistance enamel matte glaze is prepared from selected quartz sand, feldspar and other basic raw materials by adding a composite additive Y and a rare earth activator Z. The preparation method comprises the steps that the basic raw materials are mixed and subjected to ball milling, then the additives are added for continuous ball milling, high-temperature melting, water quenching and secondary ball milling are conducted, and the high-stain-resistance enamel matte glaze is obtained. The granularity is controlled, and the stain resistance is improved. The enamel matte glaze has the advantages of obvious advantages, high stain resistance, difficulty in stain attachment, easiness in cleaning, capability of prolonging the service life of a product and reducing the maintenance cost, photocatalytic self-cleaning and environment-friendly characteristics, good matte effect and capability of improving the competitiveness of the product.

The invention relates to a 1300MPa-grade nickel-based alloy for a second-generation high-temperature superconducting baseband and a preparation method of the 1300MPa-grade nickel-based alloy, and belongs to the technical field of materials. The high-strength wear-resistant steel comprises the following chemical components in percentage by weight: 15.0%-17.0% of Cr, 15.0%-17.0% of Mo, 3.0%-4.5% of W, 5.0%-7.0% of Fe, 0.3%-0.7% of Mn, 0.01%-0.05% of Si, 0.1%-0.2% of V, 0.1%-0.5% of Co, 0.1%-0.2% of Al, 0.040%-0.080% of N, Clt and the balance of Fe. 0.002%, Plt; 0.005%, Slt; 0.002%, Olt; 0.002%, and the balance being nickel. The purification smelting process is adopted, the oxygen content in the alloy is reduced, the inclusion content is controlled, and the high purity of the material is guaranteed. By adopting the component control strategy, the heat treatment process and the final cold machining preparation, the nickel-based alloy with the yield strength being 1100 MPa or above, the tensile strength being 1300 MPa or above, the ductility being 15% or above and the product of strength and elongation being 20 GPa.% or above can be obtained after annealing is conducted for 5 min at the temperature of 900 DEG C, and the requirements of a second-generation high-temperature superconducting high-performance metal base band are met.

The invention discloses a high-thermal-conductivity radiation refrigeration coating material and a preparation method thereof, and belongs to the technical field of coating materials. The preparation method of the high-thermal-conductivity radiation refrigeration coating material comprises the following steps: coating the surfaces of SiO2 hollow sphere particles subjected to surface amination with surface hydroxylated hBN nanosheets to obtain hollow SiO2 (at) hBN composite particles; the preparation method comprises the following steps: adding surface hydroxylated hBN micron sheets and hollow SiO2-coated hBN composite particles into a solvent containing a dispersant, uniformly dispersing to obtain a raw material solution, then adding a solution of a polymer substrate into the raw material solution, uniformly dispersing, and coating to obtain the high-thermal-conductivity radiation refrigeration coating material. The high-thermal-conductivity radiation refrigeration coating material prepared by the invention has relatively high thermal conductivity and an excellent radiation refrigeration effect, and is suitable for the field of thermal management of electronic devices.

The invention relates to the technical field of PBT materials, and discloses a novel environment-friendly flame-retardant reinforced high glowing filament PBT material. The raw materials comprise the following components in percentage by weight: 23-44.8% of PBT resin, 0-15% of PET resin, 2-10% of a flexibilizer, 8-12% of a brominated flame retardant, 1.5-3% of a synergistic flame retardant, 6-11% of melamine cyanurate, 2-6% of a phosphorus environment-friendly flame retardant, 0.3-3% of a glowing filament synergist, 0.2-1% of an antioxidant, 0.2-1% of a lubricant and 15-35% of glass fibers. According to the novel environment-friendly flame-retardant reinforced high glowing filament PBT material and the preparation method thereof, the PBT material is high in mechanical property and good in fireproof performance, can meet the market requirement that glowing filaments at 750 DEG C and higher grade at 850 DEG C are not ignited in the whole process, meets the latest environment-friendly control requirement on the market, and is wide in market application prospect.

The invention belongs to the technical field of silica gel foam materials, and particularly relates to high-reflection, high-temperature-resistant and heat-insulating ceramic silica gel foam and a preparation method of the high-reflection, high-temperature-resistant and heat-insulating ceramic silica gel foam. The ceramic silica gel foam is obtained by mixing vinyl silicone oil, fumed silica, a platinum catalyst, an inhibitor, hydroxyl silicone oil, hydrogen-containing silicone oil and a composite filler and then performing vulcanization treatment. Wherein the composite filler is composed of a heat reflection filler, a heat-resistant agent, hollow glass beads and low-melting-point glass powder, and each filler is white or transparent; the molar ratio of Si-H groups in the hydrogen-containing silicone oil to Si-OH groups in the hydroxyl silicone oil is (4-6): 1. Through formula design, the silica gel foam has high reflection capability and low heat conductivity coefficient, can keep a complete heat reflection surface at high temperature, is not easy to crack, effectively prolongs the high temperature resistance and heat insulation capability, and is suitable for battery thermal runaway protection. Meanwhile, the compression stress curve of the silica gel foam is gentle, and the silica gel foam has excellent buffering performance.

The invention provides a preparation method and an application method of a gasified slag-based carbon-zeolite composite material, and belongs to the technical field of carbon-zeolite composite materials. The preparation method comprises the following steps: taking gasified slag as a raw material, mixing the gasified slag with alkali, a silicon source substance, a surfactant and water, and sequentially carrying out aging treatment and hydrothermal reaction to obtain the gasified slag-based carbon-zeolite composite material. The gasified slag-based carbon-zeolite composite functional material is prepared from the gasified slag, the process is simple, the preparation cost is low, meanwhile, high-added-value utilization of the gasified slag is achieved, the purpose of treating waste with waste is achieved, and economic benefits and environmental protection benefits are achieved. The gasified slag-based carbon-zeolite composite functional material prepared by the invention has a good removal effect on low-concentration ammonia nitrogen and organic matter wastewater, has regeneration performance, and still has good ammonia nitrogen adsorption and organic pollutant degradation performance after regeneration.

The invention relates to the technical field of biomedical ceramic materials, in particular to a zirconia-based biomedical ceramic material and a preparation method thereof.The preparation method comprises the following steps: preparing a zirconia-based biomedical ceramic material on the basis of preset opening degrees of air channels of a first heating part and a second heating part in a heating assembly and a preset working state of a first stirring structure; synchronously and continuously adding a plurality of to-be-reacted substances into the first space of the container for primary reaction; after the interval is fixed, opening a circulation channel based on a preset liquid channel opening degree of the circulation channel of the first space and the second space of the container, so that the material in the first space flows into the second space, and performing a second-section reaction at a preset second temperature and a preset rotating speed of a second stirring structure to generate a precipitate; according to the invention, the materials to be reacted can be heated at a stepped temperature, and the reaction process is fully adjusted according to the ion concentration and uniformity in the detected solution, so that the high-precision preparation of the zirconium oxide-based biomedical ceramic material is stably and efficiently carried out.

The invention discloses a preparation process of a silicon dioxide aerogel integrated ball-milling and vacuum adsorption phase-change material, relates to the technical field of phase-change materials, and aims to solve the problems of complicated operation, low efficiency and poor practicability due to the adoption of a conventional dipping-adsorption method during preparation of the phase-change material in the prior art. The method comprises the following steps: step 1, pretreatment: silicon dioxide aerogel felt is fed into a treatment tower through a raw material feed opening, and raw materials enter a crushing chamber for crushing treatment; 2, ball-milling treatment is conducted, specifically, a coarse material enters a ball-milling chamber through a coarse material discharging opening and a ball-milling feeding opening, and coarse material ball-milling is started; step 3, sieving treatment: after ball milling is finished, sieving the silicon dioxide aerogel micro powder layer by layer; and step 4, loading treatment: inputting the silicon dioxide aerogel micro powder into a vacuum adsorption device, inputting octadecane liquid, carrying out vacuum loading in a vacuum chamber of the vacuum adsorption device, and after loading is finished, enabling a product to flow into a loaded product storage tank through a loaded product outlet to be stored.

The invention provides a wear early-warning intelligent material based on conductive core-shell micro-nano particles and a preparation method of the wear early-warning intelligent material, and belongs to the technical field of sensing materials. Conductive core-shell micro-nano particles are used as basic sensing function units to be doped into a polymer matrix to form a sensing layer, a three-layer structure material of a bottom residual life layer, a middle sensing layer and a surface self-lubricating wear-resistant layer is designed, and the material is prepared on a metal auxiliary surface. The surface self-lubricating wear-resistant layer is consumed in the wear process, so that the wear reaches the middle sensing layer, and the resistance of the middle sensing layer is obviously changed due to the damage of the conductive micro-nano particles as an early warning signal, so that the early warning information that the surface self-lubricating wear-resistant layer is worn out and friction pair parts need to be replaced in time is realized.

The invention discloses a packaging bag with high sealing performance and a preparation process thereof, and belongs to the technical field of packaging materials, the packaging bag comprises the following raw materials: polylactic acid, polycaprolactone, a nano-silver filler composite antibacterial agent and an epoxy compatilizer; the nano-silver filler composite antibacterial agent is formed by depositing a hybrid modified coating on the surface of a nano two-dimensional filler and then loading nano-silver; the hybrid modified coating is prepared from polydopamine and hyperbranched polyethyleneimine. The polylactic acid and the polycaprolactone are used as main base materials, and the packaging bag is endowed with good mechanical properties by utilizing high mechanical strength of the polylactic acid and excellent flexibility of the polycaprolactone; a nano-silver filler composite antibacterial agent and an epoxy compatibilizer are also added, the nano-silver filler composite antibacterial agent takes a nano-two-dimensional filler as a raw material, the nano-two-dimensional filler has a high length-diameter ratio and can block permeation of gas molecules, and the dispersion performance is improved by combining the nano-two-dimensional filler with the epoxy compatibilizer; the barrier property and the mechanical property of the packaging bag are further improved.

The invention relates to the technical field of wear-resistant composite materials, and particularly provides a modification method of ceramic particles, a ceramic-reinforced high-chromium iron-based composite material and a preparation method of the ceramic-reinforced high-chromium iron-based composite material, and the modification method comprises the following steps: carrying out decontamination, hydrofluoric acid coarsening, divalent tin sensitization, metal palladium activation, chemical Ni plating, ceramic micro powder coating and other treatments on SiC or ZTA and other ceramic particles; therefore, metallization modification can be rapidly achieved on the surfaces of the ceramic particles, decomposition of the ceramic particles is prevented, the connection strength between the ceramic particles and the metal-based material is effectively improved, and the ceramic reinforced high-chromium iron-based composite material with high hardness and high abrasion resistance is prepared. And technical support is provided for developing wear-resistant parts of mechanical equipment under harsh working conditions of metallurgy, mines, coal, building materials and the like.

The invention discloses a plasma spraying preparation method for a micro-nano double-layer PTFE coating on the surface of a flexible shaft steel wire, and particularly relates to the technical field of functional materials.The plasma spraying preparation method comprises the following steps that 1, a mandrel and a steel wire are installed on twisting equipment, and an inductive coupling plasma torch tube is installed on a driving guide rail parallel to the mandrel; 2, the pickling solution serves as a raw material, the pickling solution is atomized into micro-droplets through a feeding system and an air supply system, the micro-droplets are rapidly sprayed out of the torch pipe, and pickling spray is formed; 3, the twisting equipment is started, the steel wire is twisted around the mandrel, meanwhile, the driving guide rail is started, the twisted steel wire is subjected to acid pickling treatment through acid pickling spray sprayed out of the torch pipe, and the surface of the steel wire is roughened; 4, feeding of the pickling solution is stopped, high-flow gas is introduced into the torch pipe through the gas supply system to form high-speed gas flow, and the residual pickling solution on the surface of the flexible shaft is blow-dried; and 5, starting an inductively coupled plasma spraying system, injecting the PTFE emulsion serving as a raw material into plasma flame flow, driving a guide rail to move to enable the plasma flame flow to scan the steel wire on the surface of the flexible shaft, and depositing a PTFE coating on the surface of the steel wire. According to the method disclosed by the invention, the double-layered PTFE coating is deposited on the surface of the steel wire by using an inductive coupling plasma spraying process for the first time in the flexible shaft steel wire twisting process, so that one-step rapid preparation of the anti-corrosion coating is realized.

The invention belongs to the technical field of transmission sheet materials, and aims to solve the problems that the service life of a clutch is affected and even potential safety hazards are caused due to poor comprehensive performance of an existing transmission sheet material for the clutch under the working conditions of high temperature, high stress and the like. In order to achieve the purpose, the invention provides a powder metallurgy transmission sheet material for a clutch and a preparation method of the powder metallurgy transmission sheet material. The powder metallurgy transmission sheet material for the clutch comprises, by mass, 55%-65% of high-purity atomized iron powder, 8%-12% of electrolytic copper powder, 4%-8% of hydroxyl nickel powder, 1.5%-4% of ferromolybdenum powder, 1%-3% of chromium powder, 0.3%-1.5% of lanthanum powder, 1.5%-3.5% of nanometer silicon carbide particles, 0.8%-2% of carbon fibers, 0.5%-1.5% of whisker-shaped aluminum oxide, 0.3%-1% of cellulose nanocrystals, 0.5%-2% of rare earth oxide, 2.3%-6% of a lubricating agent and 0.5%-1.8% of a binding agent. The comprehensive performance of the transmission piece for the clutch is greatly improved, the reliability and durability of the transmission piece in a complex mechanical environment are guaranteed, the service life is prolonged, and the safety risk is reduced.

The invention belongs to the technical field of environment-friendly materials, and particularly relates to an MIL-88A-WS2 composite material and a preparation method and application thereof. The preparation method comprises the following steps: mixing WS2 taking a 1T phase as a main phase and MIL-88A in a solvent, then carrying out a hydrothermal reaction, in the hydrothermal reaction process, loading the WS2 taking the 1T phase as the main phase on the MIL-88A, forming a Fe < 2 + > / Fe < 3 + > and W < 4 + > / W < 6 + > circulating channel, covalent bonds and ionic bonds between the WS2 taking the 1T phase as the main phase and the MIL-88A, and meanwhile, forming a hollow structure by the MIL-88A, so as to obtain the MIL-88A-WS2 composite material. The MIL-88A-WS2 composite material obtained by the method provided by the invention has many active sites and strong conductivity, and can act together with an oxidizing agent peroxymonosulfate to realize degradation of phenolic pollutants.

The present invention provides a divinylbenzylfluorene and a preparation method and application thereof, a divinylbenzylfluorene hydrocarbon resin and a preparation method and application thereof, and relates to the technical field of high-frequency substrate materials. The divinylbenzylfluorene hydrocarbon resin prepared by using one or a mixture of any proportion of 9,9-bis(2-vinylbenzyl)-9H-fluorene and 9,9-bis(4-vinylbenzyl)-9H-fluorene provided by the present invention as raw materials has very low dielectric constant and dielectric loss tangent, and the higher the content of 9,9-bis(2-vinylbenzyl)-9H-fluorene, the smaller the dielectric loss tangent of the divinylbenzylfluorene hydrocarbon resin; moreover, the solubility of 9,9-bis(2-vinylbenzyl)-9H-fluorene and 9,9-bis(4-vinylbenzyl)-9H-fluorene provided by the present invention in toluene and 2-butanone is high, and has good application prospects as a cross-linking agent of the main resin or olefin resin component of a high-frequency substrate.

The invention relates to the technical field of rubber materials, in particular to a rubber composite material with self-lubricating and wear-resistant characteristics and a preparation method thereof. The rubber composite material with self-lubricating and wear-resistant characteristics is prepared from the following raw materials in parts by mass: 70 to 75 parts of nitrile rubber, 15 to 18 parts of carbon black, 30 to 35 parts of self-lubricating filler, 2 to 3 parts of plasticizer, 2 to 3 parts of zinc oxide, 2 to 3 parts of zinc stearate, 3 to 5 parts of coupling agent, 4 to 6 parts of self-lubricating additive, 1 to 1.5 parts of anti-aging agent, 1 to 1.5 parts of accelerant and 2 to 4 parts of vulcanizing agent. The prepared rubber composite material with self-lubricating and wear-resistant characteristics has excellent lubricating property, wear-resistant property and mechanical property. The method is suitable for the fields of automobile manufacturing, mechanical manufacturing, aerospace and the like.

The invention relates to the technical field of wave-absorbing materials, and particularly discloses a high-frequency wave-absorbing material and a preparation method thereof. The invention discloses a high-frequency wave-absorbing material and a preparation method thereof. The high-frequency wave-absorbing material comprises the following raw materials in parts by mass: 20-35 parts of engineering plastic particles, 60-75 parts of wave-absorbing powder, 3-5 parts of a flame retardant and 5-8 parts of an auxiliary agent, wherein the wave-absorbing powder is formed by compounding a resistance type wave-absorbing agent, a dielectric type wave-absorbing agent and soft magnetic wave-absorbing powder; in addition, the preparation method disclosed by the invention has the advantage of expanding the wave-absorbing frequency band of the wave-absorbing material.