4783 results about "Material technology" patented technology

The invention discloses a preparation method of preheating-welding-free extra-thick steel S355MLO for ocean engineering, and belongs to the technical field of metal materials. The steel comprises the following chemical components in percentage by mass: 0.04%-0.06% of C, 0.15%-0.50% of Si, 1.35%-1.45% of Mn, less than or equal to 0.008% of P, less than or equal to 0.003% of S, 0.012%-0.02% of Ti, less than or equal to 0.015% of Al, 0.15%-0.25% of Ni, less than or equal to 0.18% of Cu, less than or equal to 0.18% of Cr, less than or equal to 0.35% of Ceq = [C + Mn / 6 + (Cr + Mo + V) / 5 + (Ni + Cu) / 15] and the balance of Fe and inevitable impurities. The low-carbon and high-manganese component design is adopted, the S355MLO super-thick steel plate with the maximum thickness of 100 mm is produced through a continuous casting billet, the carbon equivalent Ceq is smaller than or equal to 0.35, and high strength, high toughness and high welding performance are integrated. The base metal and welding toughness of the thick steel plate produced by the TMCP process are improved through the component and inclusion regulation and control technology, the process is simple, the production cost is low, the production efficiency is high, preheating before welding can be avoided, and energy conservation and consumption reduction are achieved.

The invention discloses a high-temperature-resistant epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials. The high-temperature-resistant epoxy resin composite material is prepared from the following raw materials in parts by weight: 70 to 80 parts of modified epoxy resin, 8 to 15 parts of high-temperature-resistant modifier, 15 to 30 parts of curing agent, 3 to 8 parts of nano reinforcing filler, 1 to 3 parts of coupling agent, 3 to 6 parts of carbon fiber, 2 to 5 parts of nano titanium dioxide, 5 to 10 parts of organic silicon rubber, 1 to 3 parts of conductive agent, 3 to 7 parts of flame retardant and 2 to 4 parts of zinc borate. The high-temperature-resistant epoxy resin composite material has outstanding advantages and strong thermal stability, and can bear high temperature; mechanical performance is excellent, and firmness and durability are achieved; the self-repairing capability is achieved, and the service cycle can be prolonged; the anti-permeability is good, and gas and liquid can be effectively blocked; the surface is smooth, the friction coefficient is low and the application prospect is wide.

An integrated carbon honeycomb structure material and its preparation method are disclosed, belonging to the field of carbon materials technology. Based on a co-sacrificial template low-temperature pyrolysis strategy, the target material can be obtained through three main steps: preparation of a metal salt-colloidal microsphere template precursor, precursor pressing and molding, and subsequent calcination and carbonization. This technology has the characteristics and advantages of simple preparation process, regular and controllable macroscopic structure of the sample (such as shape, area, and thickness), rich and tunable chemical composition, and three-dimensional interconnection of graphene carbon matrix. It has great application potential in many fields such as electrochemical energy storage, catalysis, gas separation, adsorption, and electromagnetic shielding.

This application relates to an EPP material and a folding mat using this EPP material, which relates to the field of EPP material technology. The EPP material is formed into a plate by welding EPP particles, and the surface of the plate is coated with a hydrophobic antibacterial paint. The raw materials for preparing the EPP particles include 80-100 parts by weight of polypropylene resin, 1-3 parts by weight of a nucleating agent, 6-8 parts by weight of a modified graphene composite material, 5-10 parts by weight of a flame retardant, 5-15 parts by weight of a reinforcing agent, and 0.5-1.5 parts by weight of a surfactant. The raw materials for preparing the modified graphene composite material include hydrophobic modified graphene oxide, hydrophobic antibacterial nano-zinc oxide, and a modified ammonium polyphosphate coupling agent. The folding mat using this EPP material includes an EPP material, a surface layer, and a sewing thread, and the surface layer and the EPP material are fixedly connected by the sewing thread. This application has the effect of improving the flame retardancy, waterproofness, and antibacterial properties of EPP material, and the resulting tatami mat is environmentally friendly, comfortable, and has a good user experience.

The invention discloses 460-grade preheating-free welding maritime work steel and a preparation method thereof, and belongs to the technical field of metal materials. The steel comprises the following chemical components in percentage by mass: 0.04 to 0.06 percent of C, 0.15 to 0.50 percent of Si, 1.75 to 1.85 percent of Mn, less than or equal to 0.008 percent of P, less than or equal to 0.003 percent of S, 0.012 to 0.02 percent of Ti, less than or equal to 0.015 percent of Al, 0.25 to 0.35 percent of Ni, 0.20 to 0.28 percent of Cu, 0.20 to 0.25 percent of Cr and the balance of Fe and inevitable impurities. A low-carbon and high-manganese component design is adopted, the S460MLO super-thick steel plate with the maximum thickness capable of reaching 100 mm is produced through a continuous casting billet, the carbon equivalent Ceq is smaller than or equal to 0.45, and high strength, high toughness and high welding performance are integrated. The base metal and welding toughness of the thick steel plate produced by the TMCP process are improved through the component and inclusion regulation and control technology, the process is simple, the production cost is low, the production efficiency is high, preheating before welding can be avoided, energy is saved, consumption is reduced, and the method is environmentally friendly.

The invention relates to a 1400 MPa-grade nickel-based alloy for a second-generation high-temperature superconducting base band and a preparation method of the 1400 MPa-grade nickel-based alloy, and belongs to the technical field of materials. The nickel-based alloy comprises the following chemical components in percentage by weight: 15.0 to 17.0 percent of Cr, 13.0 to 15.0 percent of Mo, 5.5 to 9.0 percent of W, 5.0 to 7.0 percent of Fe, 0.4 to 0.6 percent of Mn, 0.01 to 0.05 percent of Si, 0.1 to 0.2 percent of V, 0.0 to 2.5 percent of Co, 0.1 to 0.2 percent of Al, 0.001 to 0.01 percent of B and Clt, 0.005%, Plt; 0.005%, Slt; 0.002%, Olt; 0.002%, Nlt; 0.002%, and the balance being nickel. On the basis of the Ni-Cr-Mo alloy, the composition design thought of increasing W and reducing Mo is adopted, the optimized hot working and heat treatment process is matched, and finally the strength of a base body is improved through cold deformation; the content of C is controlled, precipitation of carbides is controlled, and alloy elements are ensured to be completely dissolved into a matrix during homogenization treatment; and a pure smelting process is adopted, so that the oxygen content in the alloy is reduced, the inclusion content is controlled, and high purity is ensured.

The invention relates to the technical field of building materials, and particularly discloses a high-performance solid-waste-based grouting material and a preparation method thereof. Comprising the following raw materials in parts by weight: 32 to 54 parts of Portland cement, 12 to 16 parts of a modified admixture, 2.4 to 3.6 parts of a functional filler, 42 to 56 parts of aggregate, 45 to 55 parts of a photoinitiator solution, 0.6 to 0.8 part of a water reducing agent, 0.9 to 1.1 parts of a composite expanding agent, 0.04 to 0.06 part of a defoaming agent and 9.2 to 12.4 parts of deionized water. Siloxane groups, acylamino groups, ester groups and benzene rings are chemically bonded on the surface of the modified admixture, so that the hydrophilicity of the modified admixture is reduced, the modified admixture can form hydrogen-bond interaction with hydroxyl groups and cement hydrates on the functional filler, and meanwhile, a flexible long-chain alkane structure on the functional filler can be entangled with the modified admixture, so that the flexibility of the modified admixture is improved. The mechanical property, the durability and the fluidity of the grouting material are improved.

The invention relates to the technical field of ceramic materials, in particular to a ceramic composite material and a preparation method thereof.The ceramic composite material is prepared from, by weight, 30-35 parts of silicon carbide, 15-20 parts of boron nitride, 10-15 parts of silicon dioxide, 8-11 parts of additive based on modified filler and 7-10 parts of ball milling agent based on sodium alginate reconditioning modification. According to the ceramic composite material, silicon carbide and boron nitride are matched with silicon dioxide, the additive based on the modified filler and the ball-milling agent based on sodium alginate reconditioning modification are blended and coordinated, and through coordination and synergism of the raw materials, the obtained product can achieve coordinated improvement of strength, wear resistance and thermal conductivity; and the product has remarkable heat-resistant and corrosion-resistant stability effects.

The invention relates to the technical field of inorganic non-metal coating materials, in particular to high-stain-resistance enamel matte glaze and a preparation method thereof.The high-stain-resistance enamel matte glaze is prepared from selected quartz sand, feldspar and other basic raw materials by adding a composite additive Y and a rare earth activator Z. The preparation method comprises the steps that the basic raw materials are mixed and subjected to ball milling, then the additives are added for continuous ball milling, high-temperature melting, water quenching and secondary ball milling are conducted, and the high-stain-resistance enamel matte glaze is obtained. The granularity is controlled, and the stain resistance is improved. The enamel matte glaze has the advantages of obvious advantages, high stain resistance, difficulty in stain attachment, easiness in cleaning, capability of prolonging the service life of a product and reducing the maintenance cost, photocatalytic self-cleaning and environment-friendly characteristics, good matte effect and capability of improving the competitiveness of the product.

The invention relates to a 1300MPa-grade nickel-based alloy for a second-generation high-temperature superconducting baseband and a preparation method of the 1300MPa-grade nickel-based alloy, and belongs to the technical field of materials. The high-strength wear-resistant steel comprises the following chemical components in percentage by weight: 15.0%-17.0% of Cr, 15.0%-17.0% of Mo, 3.0%-4.5% of W, 5.0%-7.0% of Fe, 0.3%-0.7% of Mn, 0.01%-0.05% of Si, 0.1%-0.2% of V, 0.1%-0.5% of Co, 0.1%-0.2% of Al, 0.040%-0.080% of N, Clt and the balance of Fe. 0.002%, Plt; 0.005%, Slt; 0.002%, Olt; 0.002%, and the balance being nickel. The purification smelting process is adopted, the oxygen content in the alloy is reduced, the inclusion content is controlled, and the high purity of the material is guaranteed. By adopting the component control strategy, the heat treatment process and the final cold machining preparation, the nickel-based alloy with the yield strength being 1100 MPa or above, the tensile strength being 1300 MPa or above, the ductility being 15% or above and the product of strength and elongation being 20 GPa.% or above can be obtained after annealing is conducted for 5 min at the temperature of 900 DEG C, and the requirements of a second-generation high-temperature superconducting high-performance metal base band are met.

The invention relates to the technical field of biomedical ceramic materials, in particular to a zirconia-based biomedical ceramic material and a preparation method thereof.The preparation method comprises the following steps: preparing a zirconia-based biomedical ceramic material on the basis of preset opening degrees of air channels of a first heating part and a second heating part in a heating assembly and a preset working state of a first stirring structure; synchronously and continuously adding a plurality of to-be-reacted substances into the first space of the container for primary reaction; after the interval is fixed, opening a circulation channel based on a preset liquid channel opening degree of the circulation channel of the first space and the second space of the container, so that the material in the first space flows into the second space, and performing a second-section reaction at a preset second temperature and a preset rotating speed of a second stirring structure to generate a precipitate; according to the invention, the materials to be reacted can be heated at a stepped temperature, and the reaction process is fully adjusted according to the ion concentration and uniformity in the detected solution, so that the high-precision preparation of the zirconium oxide-based biomedical ceramic material is stably and efficiently carried out.

The invention provides a wear early-warning intelligent material based on conductive core-shell micro-nano particles and a preparation method of the wear early-warning intelligent material, and belongs to the technical field of sensing materials. Conductive core-shell micro-nano particles are used as basic sensing function units to be doped into a polymer matrix to form a sensing layer, a three-layer structure material of a bottom residual life layer, a middle sensing layer and a surface self-lubricating wear-resistant layer is designed, and the material is prepared on a metal auxiliary surface. The surface self-lubricating wear-resistant layer is consumed in the wear process, so that the wear reaches the middle sensing layer, and the resistance of the middle sensing layer is obviously changed due to the damage of the conductive micro-nano particles as an early warning signal, so that the early warning information that the surface self-lubricating wear-resistant layer is worn out and friction pair parts need to be replaced in time is realized.

The invention relates to the technical field of rubber materials, in particular to a rubber composite material with self-lubricating and wear-resistant characteristics and a preparation method thereof. The rubber composite material with self-lubricating and wear-resistant characteristics is prepared from the following raw materials in parts by mass: 70 to 75 parts of nitrile rubber, 15 to 18 parts of carbon black, 30 to 35 parts of self-lubricating filler, 2 to 3 parts of plasticizer, 2 to 3 parts of zinc oxide, 2 to 3 parts of zinc stearate, 3 to 5 parts of coupling agent, 4 to 6 parts of self-lubricating additive, 1 to 1.5 parts of anti-aging agent, 1 to 1.5 parts of accelerant and 2 to 4 parts of vulcanizing agent. The prepared rubber composite material with self-lubricating and wear-resistant characteristics has excellent lubricating property, wear-resistant property and mechanical property. The method is suitable for the fields of automobile manufacturing, mechanical manufacturing, aerospace and the like.

The invention relates to a high-temperature-resistant light stealth coating material and a preparation method thereof, and belongs to the technical field of functional materials, the high-temperature-resistant light stealth coating material comprises the following raw materials: boride, silicide, a titanate fluxing agent, metal coated carbide, a zinc oxide coated nano carbon material and a sintering aid; according to the prepared high-temperature-resistant light stealth coating material, the infrared emissivity at the wavelength of 3-5 [mu] m is 0.231-0.245, the infrared emissivity at the wavelength of 8-14 [mu] m is 0.424-0.441, the tensile bonding strength is 40.8-46.4 MPa, and the thermal shock resistance frequency is 153-167.

The invention relates to the technical field of ceramic materials, and provides a multilayer ceramic substrate and a preparation method thereof, the multilayer ceramic substrate comprises the following raw materials by weight: 100 parts of alumina, 2-3 parts of a flexibilizer, 3-6 parts of a sintering aid, 2-3 parts of a dispersant, 4-8 parts of a binder, 0.5-1 part of an aid, 4-6 parts of polyvinyl alcohol, and 30-35 parts of a solvent; the auxiliary agent is prepared from calcium carboxymethyl cellulose and calcium 2, 5-dihydroxybenzenesulfonate in a weight ratio of 1: (1-3). According to the technical scheme, the problem of poor bending strength of the ceramic substrate in the prior art is solved.

The invention relates to the technical field of tunnel engineering building materials, in particular to a double-slurry synchronous grouting material based on shield silty-fine sand and a preparation method of the double-slurry synchronous grouting material based on shield silty-fine sand. The liquid A is prepared from, by weight, 20%-30% of cement, 30%-50% of shield silty-fine sand, 5%-10% of bentonite, 5%-15% of mineral admixture, 0.1%-0.5% of stabilizer and 20%-30% of water, and the stabilizer is a water-soluble high-molecular polymer; the solution B is a water glass solution, and the volume ratio of the solution A to the solution B is (10-15): 1; the double-slurry synchronous grouting material further comprises a retarder and a coagulant, the retarder is citric acid, and the coagulant is a nano Ca (OH) 2 crystal nucleus. Bidirectional and gradient regulation and control of the gelation time between 5s and 100s can be realized through the coagulant and the retarder, and diversified requirements of different geological conditions and construction progress on slurry operation time are met.

The invention belongs to the technical field of ceramic materials, and discloses a high-entropy boride composite silicon carbide ceramic with a controllable microstructure and a preparation method and application thereof. The method comprises the following steps: carrying out ball milling, drying and sieving on Zr, Ta, Nb, W, Cr, B4C and SiB6 to obtain mixed powder; the preparation method comprises the following steps: putting a boron carbide powder into a graphite mold of which the inner surface is coated with a BN layer, heating to 1850-2050 DEG C, carrying out SPS sintering, and preparing the high-entropy boride composite silicon carbide ceramic with controllable microstructure under 20-35 MPa and a vacuum degree of 10 Pa, and the molecular formula of the high-entropy boride composite silicon carbide ceramic is (Zr0. 2Ta0. 2Nb0. 2W0. 2Cr0. 2) B2-SiC. The ceramic has good mechanical properties, the hardness at room temperature is 27-32 GPa, the fracture toughness is 4.5-6 MPa.m < 1 / 2 >, the bending strength is 450-600 MPa, and the ceramic can be applied to extreme environments or the field of radiation protection.

The invention provides MAB-phase ceramic powder as well as a preparation method and application thereof, and belongs to the technical field of ceramic materials. Firstly, elementary substance M powder and boron powder serve as raw materials, and MB powder is prepared through ball milling treatment, tabletting, heat treatment and grinding; the simple substance M powder is selected from transition metal powder; the preparation method comprises the following steps: by taking MB powder and aluminum powder as raw materials, carrying out wet ball-milling treatment, compression molding, packaging and sintering treatment to prepare MAB-phase ceramic powder; the packaging is carried out by adopting potassium bromide powder. According to the invention, an MS3-fused salt shielding synthesis / sintering method is adopted, salt is used as a reaction medium and a salt bed, the exterior of a sample is packaged with salt, so that a synthetic product is prevented from being oxidized during high-temperature synthesis in the air, and the preparation method has the characteristics of rapidness, high efficiency, energy conservation, environmental protection, low cost and the like, and is simple, convenient and feasible in the aspect of promotion of large-scale production.

The invention relates to the technical field of ton bag lining materials, and particularly discloses a shielding antistatic ton bag lining bag and a preparation method thereof. The invention relates to a shielding antistatic ton bag lining bag, which is prepared by processing a multi-layer composite film with a structure of PET / antistatic layer / PA / PE, and the antistatic layer is prepared from the following raw materials by weight: 40-75 parts of a resin material; 20 to 40 parts of filler; 5-10 parts of a color master batch; 1-3 parts of an antistatic agent; 2-5 parts of a dispersant; 0.2 to 0.4 part of an antioxidant; 4 to 6 parts of polyimide nanofiber; 1-3 parts of a modified carbon nanotube; the modified carbon nanotube is prepared by the following method: S1, pretreating a carbon nanotube raw material with a concentrated nitric acid solution to obtain a pretreated carbon nanotube; and S2, dispersing the pretreated carbon nanotubes in xylene, then adding deionized water and p-toluenesulfonic acid, then adding an aniline monomer, then adding ammonium persulfate, and carrying out a reaction to obtain the composite material after the reaction is finished. The shielding anti-static ton bag lining bag can keep stable anti-static performance under the influence of a severe temperature change environment.

The invention relates to the technical field of cable sheath materials, and provides a high-speed locomotive cable super-cold-resistant sheath material and a preparation method thereof, and the super-cold-resistant sheath material comprises the following raw material components by mass: 60-80 parts of a matrix polymer; 5 to 15 parts of a toughening agent; 3-10 parts of a cold-resistant auxiliary agent; 10 to 20 parts of a flame retardant; 1-5 parts of an antioxidant; 3-10 parts of a nano modified filler; and 1-5 parts of a cross-linking agent. The preparation method comprises the following steps: selecting the raw materials according to the proportion, putting the raw materials into mixing equipment, uniformly mixing to form a primary mixture, and preparing the primary mixture into the composite material through a melt blending process under specific temperature and shearing conditions. The obtained composite material is processed through an extrusion molding process to obtain a sheath material with excellent flexibility, impact resistance and aging resistance, and the problem that an existing material still has embrittlement, cracking or performance reduction in an extremely cold environment is solved.

The invention relates to the technical field of building decoration materials, in particular to a high-performance antibacterial mildew-proof sealant and a preparation method thereof. The sealant is prepared from the following raw materials in parts by weight: 20 to 30 parts of silane modified polyurethane, 40 to 50 parts of nano calcium carbonate, 20 to 30 parts of a plasticizer, 3 to 7 parts of a hydroxyl silane coupling agent, 0.4 to 0.8 part of a mildew preventive, 0.3 to 0.7 part of an ultraviolet light absorber, 0.3 to 0.7 part of a de-foaming agent and 0.8 to 1.2 parts of a first catalyst. The high-performance antibacterial and mildew-proof sealant has long-acting antibacterial and mildew-proof performance, and excellent mechanical performance and weather resistance of the sealant can be maintained, so that the requirements of industries such as building, medical treatment and food processing on high-performance, healthy and environment-friendly sealing materials are met; and the preparation method is simple and controllable, the production cost is relatively low, and large-scale production can be realized.

The invention discloses a rare earth antibacterial ceramic and a preparation method thereof, and belongs to the technical field of ceramic materials, the rare earth antibacterial ceramic comprises a base material, a rare earth antibacterial agent and an auxiliary additive, the base material is coated with a zirconium silicate coating layer; the matrix material is one of aluminum oxide or zirconium oxide, the rare earth antibacterial agent is a ternary composite oxide composed of at least three lanthanide elements, the lanthanide elements comprise Ce, Y, La and Nd, and the invention provides a preparation method of the composite material. Through collaborative innovation of ternary rare earth composite modification, zirconium silicate interface coating and a gradient sintering process, the core problems of single antibacterial spectrum, high-temperature failure and insufficient durability of traditional antibacterial ceramic are solved, and the antibacterial property, stability, biological safety and mechanical property are remarkably improved; and the method has clear technical progress and industrial application value.

The invention belongs to the technical field of metal composite materials and hydrogen storage and transportation materials, and particularly relates to a high-strength hydrogen-embrittlement-resistant layered metal composite material for hydrogen storage and a preparation method and application of the high-strength hydrogen-embrittlement-resistant layered metal composite material. According to the preparation method, the nickel-saving austenitic stainless steel (NEASS) and the 30CrMo steel are alternately overlapped in a multi-layer mode, and the processes of vacuum electron beam welding, high-temperature hot rolling, accumulative ply rolling, multi-stage heat treatment and the like are combined, so that the composite board with the layer number reaching hundreds of layers, firm interface bonding, excellent mechanical performance and good hydrogen embrittlement resistance is prepared; the technical problem that strength, toughness and hydrogen brittleness resistance of an existing metal material in a high-pressure hydrogen environment are difficult to consider at the same time is solved. The obtained composite material has high strength, high plasticity and excellent hydrogen embrittlement resistance, and is suitable for structural materials of high-pressure hydrogen storage tanks, hydrogen conveying pipelines and other key hydrogen energy equipment.

This invention discloses a visible-light-responsive dynamically covalently cross-linked self-healing polyurethane and its preparation method, belonging to the field of self-healing materials technology. The material is prepared by reacting diisocyanate, long-chain diol, butanediol, trimethylolpropane, and a monool containing an azophenylboronic acid structure in a certain proportion at 60°C. This invention achieves visible-light-responsive self-healing of the polyurethane material by introducing a visible-light-responsive azophenylboronic acid structure into the polyurethane and utilizing the photoresponsive cis-trans isomerization of the azo structure to regulate the reversible breakage and recombination of the boron-oxygen hexacyclic ring. The visible-light-responsive dynamically covalently cross-linked self-healing polyurethane material prepared by this invention maintains high mechanical strength (16.47 MPa) while exhibiting a strength self-healing efficiency of 95.8% after 8 hours of visible light irradiation, showing broad application prospects in smart materials, anti-corrosion coatings, and other fields.

The invention relates to the technical field of concrete materials, and discloses rapidly-reinforced high-performance sprayed concrete for an existing tunnel lining and a preparation method of the rapidly-reinforced high-performance sprayed concrete. The sprayed concrete is prepared from the following raw materials in parts by weight: 300 to 350 parts of low-calcium high belite sulphoaluminate cement, 80 to 100 parts of superfine slag powder, 3 to 8 parts of a trigger type activating agent, 5 to 15 parts of slow-release particles, 2 to 5 parts of nanogel, 800 to 900 parts of fine aggregate, 800 to 900 parts of coarse aggregate, 30 to 50 parts of copper-plated steel fiber, 0.8 to 1.2 parts of polypropylene fiber, 30 to 40 parts of a viscosity-adjusting accelerator, 10 to 20 parts of a water reducing agent and 160 to 180 parts of water. The sprayed concrete is high in compressive strength and good in durability, the double threats of chemical corrosion and chloride ion permeation / steel bar corrosion are cooperatively solved, and the requirement for rapid reinforcement of tunnels and underground engineering is met.

The invention relates to the technical field of materials, and discloses a fiber-waste-containing high-temperature-resistant insulation board and a preparation method thereof.The insulation board is prepared by taking thermosetting phenolic resin as a base material and taking ceramic fiber waste, glass fiber waste, aerogel and the like as auxiliary materials through mixing and foaming. Wherein the aerogel material is a cross-linked loofah sponge aerogel material with bentonite as a supporting framework, the aerogel material contains a large number of pore structures and can limit heat transfer and improve the heat preservation performance of the heat preservation plate, and cross-linked loofah sponge is prepared by cross-linking a phosphorus-containing derivative cross-linking agent and loofah sponge, so that the structure contains a large number of phosphorus-based flame-retardant structures, and the heat preservation performance of the heat preservation plate is improved. An organic-inorganic synergistic flame-retardant effect can be generated with bentonite, so that the flame-retardant and fire-resistant performance of the insulation board is improved. By adding the waste fiber material and fully utilizing the high-strength characteristic of the fiber waste material, the recycling of the waste material is realized, and the mechanical strength of the insulation board can be positively enhanced.

The invention discloses flame-retardant green concrete added with expandable graphite and a preparation method of the flame-retardant green concrete, and relates to the technical field of fireproof materials. The expansible graphite cement comprises the following components: cement, aggregate, expansible graphite and water, the mass ratio of the water to the cement is (0.4-0.5): 1, and the addition proportion of the expansible graphite is 1%-10% of the total weight of the cement. According to the expansible graphite flame-retardant concrete provided by the invention, the special material expansible graphite is utilized, the fireproof performance and the heat insulation performance of the concrete can be remarkably improved, and the expansible graphite forms a heat insulation layer through expansion in a high-temperature environment, so that concrete cracking or structural damage caused by a fire disaster is effectively prevented; and the fire resistance and the safety of the building structure are obviously improved. The simple and economical production process is designed, the proportion of the expansible graphite to other raw materials is properly adjusted, so that the production process of the concrete is environment-friendly and efficient, meanwhile, the production cost is effectively reduced, the requirements of modern green buildings are met, and wide application prospects are achieved.

The invention discloses a preparation method of thermal shock resistant magnesium aluminate spinel transparent ceramic, and belongs to the technical field of ceramic materials. The preparation method comprises the following steps: (1) synthesizing crystalline MgAl2O4 nano powder by adopting an additive-free hydrothermal method; (2) depolymerizing the powder, performing water-based gel casting to prepare a green body, and performing staged debonding treatment on the green body; (3) carrying out two-step vacuum presintering on the green body; (4) carrying out hot isostatic pressing densification treatment in a subgrain growth temperature region of 1380-1420 DEG C; and (5) carrying out annealing treatment on the densified ceramic. High-purity crystalline powder is synthesized through an additive-free hydrothermal method, grain boundary impurities are eliminated, and the intermediate infrared transmittance is remarkably improved; by combining the synergistic effect of optimized two-step pre-sintering and hot isostatic pressing in a sub-grain region, precise refinement of the grain size is realized; and finally, the bending strength, the fracture toughness and the critical thermal shock temperature difference of the material are greatly improved under the strengthening mechanism of ultrafine grains and defect-free grain boundaries.

The invention relates to the technical field of 3D printing building materials, in particular to a 3D printing geopolymer composite material with low drying shrinkage and a preparation method thereof.The 3D printing geopolymer composite material is prepared from, by mass, 400 parts of slag powder, 320 parts of fly ash, 80 parts of steel slag micro powder, 1200 parts of quartz sand, 5.1-25.6 parts of sodium hydroxide, 46.4-66.9 parts of sodium silicate, 8 parts of barium chloride and 296 parts of water. The preparation method comprises the following steps: fully mixing the slag powder, the fly ash, the steel slag micro-powder and the quartz sand according to a preset mass ratio to obtain a uniform basic powder mixture; adding an alkali activator and barium chloride into the basic powder mixture, and continuously mixing until the mixture is uniform to obtain a first mixture; and adding water into the first mixture according to a preset water-binder ratio, and carrying out stirring treatment according to a preset stirring method to obtain the 3D printing geopolymer composite material with low drying shrinkage. According to the invention, the drying shrinkage can be reduced.

The invention relates to the technical field of ceramic materials, in particular to high-corrosion-resistance environment-friendly ceramic and a preparation method of the high-corrosion-resistance environment-friendly ceramic. 20 to 22 percent of Al2O3; 4 to 6 percent of Fe2O3; 2.0 to 3.5 percent of CaO; 0.5 to 1.0 percent of MgO; 0.8% to 1.2% of K2O and Na2O; sO3: less than or equal to 0.03%; pb + Cd + Cr < 6 + >: < = 2 ppm; the balance is impurities. According to the scheme, the craft ceramic can be prepared from the tailings, meanwhile, residues such as the heavy metal content are strictly controlled, components are controlled to be stable, and therefore unification of high corrosion resistance and environmental friendliness is achieved.