573 results about "Nickel salt" patented technology

The invention relates to a sunken porous magnetic alloy ball wave-absorbing material and a preparation method and application thereof.The wave-absorbing material is prepared through the following steps that S1, citric acid, soluble ferric salt, soluble cobalt salt and soluble nickel salt are dissolved in a mixed solvent of ethylene glycol and water, and the mixture is fully stirred to form a uniform mixed solution; and S2, the mixed solution obtained in the step S1 is subjected to spray drying, obtained precursor powder is placed in the air atmosphere to be calcined to remove the carbon source, then the precursor powder is placed in the H2 / Ar atmosphere to be subjected to heating reduction, and the porous FeCoNi alloy balls with the surface pits are obtained and are the target product. The surface of the prepared alloy microsphere has an obvious concave structure, magnetic anisotropy and magnetic performance are enhanced, a small number of pores are generated in the reduction process, impedance matching of the material is optimized, and effective high-frequency electromagnetic absorption is achieved; and due to the synergistic effect of the recesses and the pores, the obtained alloy microspheres have obvious lightweight characteristic, and have good application prospects in the field of electromagnetic absorption.

The invention discloses a preparation method of a rare earth element doped nickel-based selenide nano-material and application of the rare earth element doped nickel-based selenide nano-material in electro-catalysis water full-hydrolysis reaction. According to the method, nickel salt, cerium salt, selenium dioxide and potassium chloride are prepared into electrolyte, and the electrolyte is subjected to electro-deposition on a foamed nickel substrate to obtain Ce-doped Ni0.85Se nanoparticles growing on foamed nickel. The crystal structure and electron distribution of Ni0.85Se are optimized by doping trace rare earth element cerium, so that the HER and OER performances of the Ni0.85Se are greatly improved. The prepared catalyst is self-supporting closely-packed nanoparticles, the formed amorphous structure is easy to expose more active sites, the catalyst has good electrocatalytic hydrogen evolution and oxygen evolution performance under alkaline conditions, the overpotential in electrocatalysis of nickel-based selenide is greatly reduced, and the electrocatalytic performance of nickel-based selenide is improved. And excellent electro-catalytic activity is shown in electro-catalytic water full hydrolysis. And the self-supporting electrode is not easy to fall off due to generation of bubbles in the reaction process, so that the working stability of the catalyst is improved.

The application discloses a preparation method of a catalyst for liquid-phase refining of crude octanol, and the preparation method comprises the following steps: (1) mixing pretreated fly ash and pseudo-boehmite, adding deionized water and nitric acid, stirring until a colloid is formed, drying the colloid, mixing the dried colloid with kaolin, and obtaining a carrier through kneading, extrusion molding, drying and calcination; (2) taking a nickel salt, a manganese salt and a zinc salt as active components, taking a calcium salt as an auxiliary component, dissolving the active components and the auxiliary component in deionized water to obtain a salt solution, adding n-hexane into the salt solution and stirring uniformly to prepare an impregnation solution, immersing the carrier in the impregnation solution, and obtaining the catalyst through washing, drying and calcination. The catalyst prepared by the method is mainly used in a liquid-phase refining reaction process of crude octanol, and has high activity stability and selectivity.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a method for separating nickel and cobalt from a nickel-containing solution and preparing nickel salt, which comprises the following steps: 1) chelating and precipitating impurity metal ions in the nickel-containing solution by using ammonium polyphosphate with the polymerization degree of more than 1000 as an impurity removal agent, thereby removing copper, iron, zinc and aluminum to obtain an impurity-removed solution; 2) extracting the impurity-removed solution by using a diluent, alpha-hydroxyoxime, carboxylic acid and alkyl alcohol as an extraction organic phase to obtain a nickel-loaded organic phase; 3) washing the nickel-loaded organic phase by using nickel-containing washing water; and (4) reverse extraction is conducted on the washed nickel-loaded organic phase through reverse extraction liquid containing acid and nickel ions, nickel-rich liquid is obtained after reverse extraction is completed, nickel salt in the nickel-rich liquid is crystallized, and nickel salt solids are obtained after phase separation. According to the method, nickel is selectively extracted through the compound extraction system after impurity removal, the extraction rate of nickel reaches up to 99.8%, nickel is separated from metal ions such as cobalt and lithium, and the method is simple in process, low in equipment manufacturing cost and low in manufacturing cost.

The invention belongs to the field of catalysts, and discloses a catalytic material based on lignin derivation and a preparation method and application thereof. The catalytic material is prepared from lignin derived carbon and NiFe LDH; the lignin derived carbon is inserted into the interlayer of the NiFe LDH and is coated on the surface of the NiFe LDH. The preparation method comprises the following steps: S1, dissolving a lignin derivative in water to obtain a first solution; s2, dissolving metal salt in water to obtain a second solution, wherein the metal salt comprises ferric salt and nickel salt; s3, mixing the first solution and the second solution, and adjusting the pH value to obtain a mixed solution; and S4, immersing the conductive current collector into the mixed solution for hydrothermal reaction, taking out the conductive current collector after the reaction is finished, and treating the conductive current collector to obtain the catalytic material. The obtained catalytic material is used for an anode oxygen evolution reaction in an electrolytic seawater environment, and has high activity, high stability and good chlorine corrosion resistance.

The invention is suitable for the technical field of water electrolysis hydrogen production, and provides an alkyne-rich carbon-ruthenium nickel alloy catalyst and a preparation method and application thereof. The preparation method comprises the following steps: simultaneously adding a ruthenium salt solution, a nickel salt solution and an organic molecule solution into an alkyne-enriched carbon dispersion liquid for reaction; and carrying out centrifugation, cleaning and vacuum drying treatment on the reacted mixed solution to obtain the alkyne-rich carbon-ruthenium nickel alloy catalyst. According to the invention, the acetylene-rich carbon-ruthenium nickel alloy catalyst uniformly loaded with ruthenium nickel (RuNi) clusters is successfully prepared. In the performance evaluation of hydrogen production by water electrolysis in a simulated seawater environment, the material shows excellent hydrogen evolution activity as a cathode catalyst. Experimental results show that under the applied potential of-0.6 V (relative to a reversible hydrogen electrode, RHE), the absolute value of the current density can reach 0.847 A cm <-2 > to 0.896 A cm <-2 >. The invention provides a feasible material solution for developing a high-performance water electrolysis hydrogen production catalyst suitable for a complex water quality environment.

The invention discloses a non-noble metal ORR catalyst and a preparation method thereof, and belongs to the technical field of electro-catalysis. The method comprises the following steps: (1) adding 5, 10, 15, 20-tetra (4-cyanophenyl) porphyrin and nickel salt into an organic solvent, and synthesizing a supramolecular crystal precursor UPC-S7 through solvothermal reaction; (2) carbonizing the supramolecular crystal precursor UPC-S7 in an inert atmosphere to obtain a Ni-coated NC material; (3) oxidizing the Ni-coated NC material in an oxygen-containing atmosphere to obtain a Ni / NiO-coated NC material; and (4) sequentially soaking and etching the Ni / NiO-coated NC material by using a nitric acid solution and an ammonia water solution, and then washing and drying to obtain the non-noble metal ORR catalyst. The prepared catalyst does not contain precious metal such as platinum, the raw material cost is remarkably reduced on the basis of ensuring the ORR activity and stability of the catalyst, and a new scheme is provided for solving the cost bottleneck of a fuel cell.

The invention discloses a preparation method of high-dispersion superfine spherical nickel powder, which comprises the following steps: preparing nickel salt, a complexing agent and a dispersing agent into a nickel salt aqueous solution, converting a precipitant aqueous solution into precipitant micro-nano aerosol, adding the precipitant micro-nano aerosol into the nickel salt aqueous solution, and carrying out gas-liquid phase confinement micro-zone pre-reaction to obtain the high-dispersion superfine spherical nickel powder. And carrying out homogeneous hydrothermal reaction and vacuum roasting to obtain the high-dispersion superfine spherical nickel powder. According to the method, low-cost and low-pollution soluble nickel salt is used as a nickel source, aerosol confinement microcell reaction is established, controllable preparation of spherical nickel particles with high purity, high sphericity degree, high dispersity and uniform morphology is achieved, the high-dispersion superfine spherical nickel powder is effectively obtained under the conditions of low cost and low energy consumption, and the method is suitable for industrial production. The high-dispersion superfine spherical nickel powder meets the requirements of high-dispersion superfine spherical nickel powder required by inner electrode slurry of various sizes for the MLCC, meanwhile, the high-dispersion superfine spherical nickel powder has good fluidity, and preparation of high-performance inner electrode slurry of the MLCC is facilitated.

The invention provides a chlorine corrosion resistant cathode for electrolyzing seawater as well as a preparation method and application of the chlorine corrosion resistant cathode. The preparation method comprises the following steps: S1, dissolving a cobalt salt, a nickel salt, a morphology regulating agent and a structure-directing agent in a solvent according to a molar ratio of (1-2.5): (1-2.5): (8-12): (6-10), and stirring to form a first solution; s2, a titanium mesh and the first solution are subjected to a hydrothermal reaction at the temperature of 100-150 DEG C, and CoNi layered double hydroxide with the shape of a nanoneedle array grows on the titanium mesh in situ; s3, selenium powder and a reducing agent are dissolved in a solvent according to the molar ratio of 1: (0.8-1.5) and stirred to form a second solution; and S4, carrying out hydrothermal reaction on the titanium mesh on which the CoNi layered double hydroxides grow in situ and a second solution at 150-190 DEG C so as to grow cobalt-nickel bimetallic selenide of which the morphology is a nanoneedle array in situ on the titanium mesh, thereby obtaining the chlorine corrosion resistant cathode.

The invention provides a rock salt phase coated full concentration gradient positive electrode material and a preparation method and application thereof, and the preparation method comprises the following steps: firstly adding an ultrahigh nickel salt solution A into a mixing container, then introducing the ultrahigh nickel salt solution A and a high nickel salt solution B into the mixing container to obtain a mixed solution, meanwhile, the mixed solution, a complexing agent solution and a precipitator solution are introduced into the base solution at a third flow speed, a co-precipitation reaction is conducted, and a precursor material is obtained; mixing and sintering a lithium source and the precursor material to obtain a rock salt phase coated full-concentration gradient positive electrode material; the molar content of lithium ions in the lithium source is n1, the molar content of total metal ions in the precursor material is n2, and n1 / n2 is less than or equal to 1. According to the preparation method, the structural stability of the positive electrode material can be improved, the cycle performance is improved, meanwhile, the content of metal ions in the positive electrode material changes from the core to the surface in a gradient mode, microcracks can be avoided, and the cycle performance of the material is further improved.

The invention provides a pulse-direct current electrochemistry composite deposition process of a nickel-tungsten-phosphorus alloy coating, and belongs to the technical field of coating preparation, and the pulse-direct current electrochemistry composite deposition process comprises the following steps: carrying out silane coupling agent modification treatment on alpha-aluminum oxide; carrying out modification treatment on the hexagonal boron nitride nanosheet by adopting hexadecyl trimethyl ammonium bromide; carrying out polyacrylic acid modification treatment on the nano silicon dioxide; nickel salt, tungsten salt, phosphorus salt, a complexing agent, a buffering agent, a primary brightener, a secondary brightener, a wetting agent, modified aluminum oxide, modified boron nitride, modified silicon dioxide and deionized water are mixed, stirred and heated, and a composite plating solution is obtained; the substrate serves as a cathode, pulse current is applied to the substrate for pulse electroplating, then the current density of the pulse current is continuously and linearly reduced to a target value, and finally direct current electroplating is conducted under the target value; by optimizing the formula of the composite plating solution and the pulse-direct current composite electroplating process, the nickel-tungsten-phosphorus alloy composite plating layer with high hardness, low friction, high wear resistance and corrosion resistance is finally obtained.

The invention relates to a high-entropy metal oxide catalyst and a preparation method and application thereof.The preparation method comprises the following steps that S1, ferric salt, cobalt salt, manganese salt, nickel salt, copper salt and organic alkaline matter are mixed to obtain a mixed solution, hydrothermal reaction is conducted, and a precursor is obtained; and S2, calcining the precursor at the temperature of 500-600 DEG C to obtain the high-entropy metal oxide catalyst. The high-entropy metal oxide catalyst uniformly doped with iron, cobalt, manganese, nickel and copper is prepared by adopting a hydrothermal reaction and calcination method, and the high-entropy metal oxide catalyst not only can efficiently catalyze ozone to remove antibiotics, but also can still keep an excellent antibiotic removal rate constant in a water body containing hetero ions and humic acid; and the anti-interference capability is excellent.

The invention relates to a porous nickel-iron alloy integrated electrode and a preparation method and application thereof, and belongs to the technical field of electrochemistry. The preparation method comprises the following steps: carrying out cleaning pretreatment on a stainless steel mesh substrate; then electro-deposition is carried out in a solution containing ferric salt and nickel salt, and a nickel-iron alloy layer is formed; carrying out secondary electro-deposition in a solution containing zinc salt, and carrying out high-temperature calcination treatment to obtain a nickel-iron-zinc alloy; and finally, the zinc component is removed through selective corrosion of an alkaline solution, and the nickel-iron alloy integrated electrode with the porous structure is formed on the stainless steel mesh. The method is controllable in process, and a porous structure which is high in specific surface area and beneficial to mass transfer is effectively constructed through step-by-step electro-deposition, calcination and corrosion treatment. The obtained integrated electrode can be directly used as an alkaline water electrolysis oxygen evolution reaction (OER) anode, shows high electrocatalytic activity and stability, and is suitable for the fields of water electrolysis hydrogen production and the like.

The invention discloses preparation and application of a nickel selenide / ferronickel phosphate crystal / amorphous heterogeneous catalyst, and relates to the technical field of electrochemistry. Selenizing the foamed nickel at low temperature in an inert atmosphere to generate a crystalline NiSex layer in situ; and by taking the obtained electrode as a working electrode, carrying out electrodeposition in a deposition solution containing nickel salt, ferric salt, hypophosphite and acetate by adopting a cyclic voltammetry method, so that amorphous NiFePOy is deposited on the surface of NiSex, and a NiSex / NiFePOy crystal / amorphous heterostructure nanosheet layer is constructed and is used for an alkaline medium urea oxidation reaction. The invention has the following beneficial effects: crystalline / amorphous interface coupling and a nanosheet self-supporting structure synergistically improve active sites and charge transfer capability, reduce energy consumption and improve current output; meanwhile, the electrode stability and durability are enhanced; the method has the advantages of low material cost, mild and simple process, suitableness for amplified preparation, and application potential of urea-assisted water electrolysis energy-saving hydrogen production.

The invention discloses a preparation method and application of a high-entropy layered double hydroxide oxygen evolution catalyst, and relates to the field of oxygen evolution reaction catalysis, and the preparation method comprises the following steps: S1, washing foamed nickel in absolute ethyl alcohol and deionized water, and then carrying out ultrasonic treatment in a hydrochloric acid solution to obtain pretreated foamed nickel; s2, adding ferric salt, cobalt salt, nickel salt, manganese salt, zinc salt and a proper amount of urea into deionized water, then adding ammonium fluoride, and uniformly stirring to obtain a mixed solution; and S3, transferring the mixed solution and the pretreated foamed nickel into a reaction kettle, carrying out a hydrothermal reaction, and washing and drying the obtained product to obtain the high-entropy layered double hydroxide oxygen evolution catalyst. According to the method, the key regulation and control effect of NH4F on the structure, chemical and electro-catalytic properties of HELDHs in the synthesis process of the HELDHs is analyzed, and the performance enhancement is attributed to NH4F-induced morphology and crystal engineering and catalytic active cation vacancies generated in situ through selective leaching of Zn < 2 + > and adsorption of sulfate under the alkaline condition.

The application discloses a supported PtNi b-site adiponitrile hydrogenation catalyst and a preparation method and application thereof, and belongs to the technical field of thermal catalysis. The preparation method comprises the following steps: (1) dispersing ammonium tungsten oxide pentahydrate in water, adding an acidic solution, condensing and refluxing, heating and reacting, centrifugal filtering and drying the precipitate to prepare tungsten oxide nanorod carriers; (2) dispersing the tungsten oxide nanorod carriers in a solvent, adding a platinum salt solution, stirring, evaporating the solvent, and calcining the solid to prepare a catalyst precursor; and (3) dispersing the catalyst precursor in a solvent, adding a nickel salt solution, stirring, evaporating the solvent, and calcining the solid to prepare the catalyst. The application introduces Pt and Ni on the reducible WO3 carrier to construct a bimetallic active site catalyst, and the bimetallic active site catalyst can catalyze the reaction of adiponitrile hydrogenation to prepare primary amine under mild conditions, has the characteristics of low noble metal loading, high activity and high selectivity, and has important industrial application value.

The application belongs to the technical field of lithium ion batteries, and particularly relates to a kind of one-dimensional LiNi 1 / 3 Co 1 / 3 Mn 1 / 3 O2 ternary layered oxide positive electrode material and a preparation method thereof, which comprises the following steps: adding a nickel salt, a cobalt salt and a manganese salt into water, stirring and dissolving to obtain a solution A; adding LiMn2O4 into the solution A and stirring uniformly to obtain a solution B; mixing a lithium salt with water to obtain a solution C, and under stirring, adding the solution C into the solution B to obtain a solution D; evaporating the solution D under stirring to obtain a precursor powder; and sintering the precursor powder at 400-600 DEG C, and then sintering at 750-850 DEG C to obtain the positive electrode material. 1 / 3 Co 1 / 3 Mn 1 / 3 O2 material.

The invention belongs to the field of sewage treatment, and particularly relates to a tencel production wastewater treatment process. Comprising the following steps: etching a carbon nanotube to obtain a porous carbon nanotube; carrying out amino functional modification on the porous carbon nanotube to obtain a modified carbon nanotube; loading cobaltosic oxide on the modified carbon nanotube, and then forming a nickel-cobalt composite oxide on the outer wall of the modified activated carbon by adopting nickel salt to obtain the catalyst, the method comprises the following steps: adding a catalyst into wastewater, heating a system to 70-90 DEG C, then stopping heating, and carrying out an illumination reaction in an oxygen-containing atmosphere; according to the process, through the synergistic effect of light, heat and oxygen, the reaction activity of active sites on the surface of the catalyst is enhanced, the reaction time is shortened, meanwhile, the interaction between amino and reactants is enhanced, and desorption and degradation of pollutants are accelerated.

The invention discloses a nickel-cobalt layered double hydroxide for a supercapacitor and a preparation method and application thereof, and belongs to the technical field of energy storage. The preparation method of the nickel-cobalt layered double hydroxide for the supercapacitor comprises the following steps: performing hydrothermal reaction on nickel salt, cobalt salt, ammonium citrate and urea to obtain the nickel-cobalt layered double hydroxide, the temperature of the hydrothermal reaction is 120-150 DEG C, and the time of the hydrothermal reaction is 6-12 hours. According to the invention, ammonium citrate is added to regulate the precipitation rate of the precursor, so that the morphology of the nickel-cobalt layered double hydroxide can be regulated and controlled, and the situation that the nickel-cobalt layered double hydroxide is rapidly combined with hydroxyl ions to cause too fast crystallization and coarse crystal grains is avoided; and meanwhile, the concentration uniformity of metal ions in the solution is regulated and controlled, so that the crystallinity of the nickel-cobalt layered double hydroxide is uniform, and lattice defects are reduced. Therefore, when the material is used as an electrode material of a supercapacitor, the material has relatively high specific discharge capacity.

This invention relates to the field of water electrolysis and hydrogen energy utilization technology, and provides an in-situ electrodeposition method for improving NiMoP. x O y A method for studying the catalytic activity and stability of a self-supporting nickel-based hydrogen evolution electrode (NMOP). First, NiMoP... x O y The / NF self-supporting foam nickel-based electrode is prepared by immersing it in a nickel salt solution for a certain period of time, drying it, and then immersing it in a sodium sulfate solution for electrodeposition reduction reaction. This invention provides a simple and convenient method for adjusting the amount of metallic nickel deposited, ensuring its distribution among the active component particles of the electrode. This effectively improves the adhesion of the active component and prevents its detachment, significantly enhancing the hydrogen evolution activity and stability of the hydrogen evolution electrode. At an industrial current density of 100 mA / cm², the overpotential of the modified electrode prepared by this method is reduced by approximately 20% compared to the unmodified electrode, and the charge transfer resistance is reduced by approximately 41%. After 30,000 CV cycle accelerated durability tests, the increases in overpotential and charge transfer resistance are less than 7% and 26% of those of the unmodified electrode, respectively. Therefore, this invention has promising prospects for industrial application.

The invention discloses a titanium dioxide nanorod / dissimilar metal MOFs heterojunction material and a preparation method and application thereof, and belongs to the technical field of photoelectrochemistry seawater hydrogen production. Soluble nickel salt, soluble cadmium salt or soluble cobalt salt and ammonium molybdate are adopted as metal sources, spherical dissimilar metal MOFs grow on the surface of a TiO2 nanorod in situ, and the TiO2 nanorod / dissimilar metal MOFs heterojunction material is prepared. According to the present invention, the oxygen deficiency-regulated dissimilar metal MOFs material (i.e., the titanium dioxide nanorod / dissimilar metal MOFs heterojunction material) is obtained through subsequent acid etching and annealing treatment, the material is subjected to in-situ reconstruction during the OER process to spontaneously form the active hydroxide (NiOOH) of anion protection (MoO4 < 2->), and the excellent stability is represented; only small Faraday efficiency loss (1.2-2.3%) occurs in a high chloride ion environment (3.5 wt%-7wt% of NaCl), and an extensible path is provided for industrial-scale solar hydrogen production by using seawater.

The application relates to a catalyst for catalytically synthesizing propylene acid from propane and application thereof, and the catalyst is represented by the following general formula: Mo a V b Te c Nb d Ni e O x Wherein, a, b, c, d and e respectively represent the atom numbers of Mo, V, Te, Nb and Ni, and the molar ratio of a:b:c:d:e is 7.0-9.0:1.7-2.5:1.0-1.5:1.7-2.3:0.1-1.0, and the value of x is determined by the oxidation state of each element; Ni is introduced by nickel molybdate, Mo is introduced by a molybdate and the nickel molybdate, and the nickel molybdate is prepared by co-precipitation of a molybdate and a nickel salt in the presence of an organic acid. According to the application, the content of different valence metals on the surface of the catalyst can be adjusted by introducing nickel into the catalyst through nickel molybdate, so that the content of high-valence elements Mo 6+ , V 5+ and Ni 2+ in the catalyst and the oxygen vacancy are increased, and the redox capacity of the catalyst is enhanced.

A method of recovering a nickel, cobalt, and manganese salts includes removing impurities from an acidic aqueous leach solution including cobalt, manganese, and nickel salts to produce a purified aqueous solution including the metal salts and remaining impurity salts. The method includes extracting the purified aqueous solution in a first liquid-liquid extraction step using a first organic extractant to produce a first aqueous raffinate solution including the cobalt, manganese, and nickel salts and a first loaded organic solution including one or more of the remaining impurity salts from the purified aqueous solution. The method further includes extracting the cobalt, manganese, and nickel salts from the first aqueous raffinate solution in a second liquid-liquid extraction step using a second organic extractant to produce a second loaded organic solution including the cobalt, manganese and nickel salts and a second aqueous raffinate solution comprising one or more of the remaining impurity salts.

The invention discloses a Ni-K modified supported catalyst, preparation thereof and application of the Ni-K modified supported catalyst in acetylene semi-hydrogenation reaction. The preparation method of the catalyst comprises the following steps: 1, completely dissolving an active metal salt, a nickel salt and a potassium compound in a solvent to obtain a uniform mixed solution; 2, fully loading the active metal salt, the nickel salt and the potassium compound in the mixed solution onto the carrier through wet impregnation, and then drying and grinding to obtain precursor powder; 3, calcining the precursor powder in an inert or air atmosphere at 300-600 DEG C to obtain a calcined product; and 4, carrying out reduction activation on the calcined product in a reducing atmosphere at 350-450 DEG C to obtain the Ni-K modified supported catalyst. The invention provides the application of the Ni-K modified supported catalyst in acetylene semi-hydrogenation reaction, and the Ni-K modified supported catalyst has high acetylene conversion rate, high ethylene selectivity and good stability.

This invention discloses a transition metal phosphide catalyst, its preparation method, and its application, belonging to the field of electrocatalysis technology. The process includes: firstly, dissolving nickel salt, lanthanum salt, urea, and ammonium fluoride in deionized water to synthesize a nickel-lanthanum layered hydroxide nanosheet precursor via a hydrothermal method; secondly, preparing a lanthanum-doped nickel phosphide catalyst using a phosphating reaction; and thirdly, utilizing a lanthanum doping strategy to modulate the electronic structure of nickel phosphide and improve its electrocatalytic reaction performance. This lanthanum-doped nickel phosphide material exhibits good catalytic activity when used to catalyze hydrogen evolution and sulfide ion oxidation reactions. In an integrated two-electrode electrolyzer for sulfide ion oxidation-assisted hydrogen production, it outputs 10 mA cm⁻¹. ‑2 This invention achieves the goal of producing hydrogen and high-value-added sulfur products with low energy consumption by requiring a relatively low voltage of 0.525 V at a current density. It has advantages such as simple preparation process, controllable operating conditions, and low raw material costs, possessing the potential for large-scale production and serving as a high-performance catalyst for electrocatalytic hydrogen production and sulfur ion oxidation reactions.

This invention provides a self-supporting one-dimensional nanorod array composite material, its preparation method, and its application, belonging to the field of clean energy harvesting technology. The preparation method provided by this invention includes the following steps: mixing soluble nickel salt, soluble molybdate, and water, and carrying out a hydrothermal reaction to obtain a NiMo precursor; heat-treating the NiMo precursor and a modifier under a protective atmosphere to obtain the self-supporting one-dimensional nanorod array composite material. Experimental results show that the composite material prepared by the method provided by this invention has excellent electrocatalytic water splitting activity and operational stability, and photo-assisted synthesis further enhances the electrocatalytic water splitting activity of the composite material, making it applicable to solar-driven electrocatalytic water splitting.

The application relates to a ternary metal nanocatalyst and a preparation method and application thereof, and relates to the field of catalytic chemistry. The specific steps of the method are as follows: soluble iron salt, soluble nickel salt and soluble aluminum salt are added into deionized water, and a carbon carrier is added as a substrate and is subjected to ultrasonic treatment. An alkaline solution containing sodium carbonate and sodium hydroxide is added dropwise into the prepared metal salt solution under vigorous stirring. The metal salt suspension is aged; the obtained solution is centrifuged, the solid is collected and vacuum dried and ground. The activated carbon loaded iron-nickel-aluminum ternary metal nanocatalyst can realize the complementary advantages among multiple components, and the synergistic mechanism makes the iron-nickel-aluminum catalyst exhibit better ammonia production rate and selectivity than single metal components in a neutral environment, and can be used for electrocatalytic nitrate reduction to prepare ammonia.

The present application relates to the technical field of supported metal nanoparticle catalysts, in particular to a supported nickel-based carbide acetylene selective hydrogenation catalyst, a preparation method and application thereof. The catalyst is formed by supporting a bimetallic carbide active component on a nanometer gallium oxide carrier, the bimetallic carbide is Ni3GaC 0.7 , and the loading amount of Ni in the catalyst is 1-40 wt.%. A nickel salt is loaded on a nanometer gallium oxide material by an impregnation method, then a NiO / Ga2O3 catalyst is obtained by calcining in air; then the catalyst is treated by heating in a mixed gas of carbon dioxide and hydrogen, and a supported Ni3GaC 0.7 / Ga2O3 catalyst is obtained. The acetylene selective hydrogenation reaction performance test results show that the Ni3GaC 0.7 / Ga2O3 catalyst exhibits excellent selectivity (about 85%) in the hydrogenation reaction, and long-term performance test also shows that the supported catalyst has good stability.

The invention provides a method for preparing nickel hydroxide from laterite-nickel ore, which comprises the following steps: after the laterite-nickel ore is pulped, carrying out iron and aluminum removal treatment to obtain iron and aluminum removed liquid; carrying out resin adsorption treatment on the iron and aluminum removed liquid to obtain nickel adsorbed resin; desorbing the nickel-adsorbed resin to obtain a nickel-rich solution, and sequentially carrying out copper and zinc removal, calcium and magnesium removal, fluorine removal treatment and silicon removal treatment to obtain a nickel salt solution; the nickel salt solution, the liquid caustic soda and the dispersing agent solution are injected into the base solution in a parallel flow mode, nickel hydroxide slurry is obtained through a co-precipitation reaction, and nickel hydroxide is obtained through post-treatment. According to the method, after the laterite-nickel ore is pulped to remove iron and aluminum, nickel is extracted through high selectivity of resin, nickel, manganese and cobalt can be separated and analyzed to obtain nickel-rich solutions, a purified nickel salt solution is obtained through series impurity removal, the purified nickel salt solution reacts with liquid caustic soda, and a high-purity nickel hydroxide product is prepared. And the nickel does not need to be recovered through a complex extraction process.

The application belongs to the technical field of new energy materials and electrochemical catalysis, and provides an oxygen vacancy-rich nitrogen-doped nickel phosphide / cerium oxide composite catalyst, a preparation method and application thereof. A foam nickel is used as a working electrode, a platinum sheet is used as a counter electrode, and a Hg / HgO electrode is used as a reference electrode. In an electrolyte solution containing a nickel salt and a cerium salt, electrodeposition is performed to obtain a precursor. The precursor includes the foam nickel and cerium and nickel deposited on the foam nickel. The precursor is soaked in a tannic acid solution to obtain an impregnated precursor. Ammonium hypophosphite is placed upstream, and the impregnated precursor placed downstream is subjected to phosphorus nitride doping treatment to obtain the oxygen vacancy-rich nitrogen-doped nickel phosphide / cerium oxide composite catalyst. The obtained oxygen vacancy-rich nitrogen-doped nickel phosphide / cerium oxide composite catalyst exhibits excellent electrocatalytic performance for methanol oxidation reaction (MOR) and can be used as a high-efficiency anode catalyst for a direct methanol fuel cell (DMFC).