1888 results about "Carbon deposition" patented technology

The invention discloses a carbon-silicon negative electrode material and a preparation method and application thereof, and the preparation method comprises the following steps: S1, carrying out mixed reaction on a lithium source compound, a lanthanum source compound and a titanium source compound to obtain a mixed reactant; mixing the mixed reactant with a carbon source compound, and dispersing and emulsifying to obtain element-doped microspheres; s2, carbonizing the element-doped microspheres in the step S1 to obtain carbides, and activating the carbides to obtain a porous carbon material; and S3, performing silicon deposition on the porous carbon material in the S2 to obtain silicon deposition porous carbon, and performing carbon deposition on the silicon deposition porous carbon to obtain the carbon-silicon negative electrode material. The carbon-silicon negative electrode material disclosed by the invention is high in lithium ion transmission rate, the problem of poor electronic conductivity of silicon is solved, and the electrical property of a battery can be effectively improved.

The invention relates to the technical field of flue gas treatment, in particular to a sintering flue gas denitration and dust removal integrated post-CO removal method which is specifically completed through cooperation of a sintering flue gas treatment system, and the sintering flue gas treatment system comprises a GGH heat exchanger, a desulfurization reactor, a denitration dust remover and a CO reactor which are sequentially communicated through pipelines. The CO catalyst module is a transition metal oxide CO catalyst; the cleaning device is used for cleaning ash of the CO catalyst module; the ammonia gas is sprayed into the outlet of the desulfurization reactor, so that ammonia escape is reduced, poisoning of the CO catalyst module is reduced, the catalytic efficiency of the CO catalyst module is improved, and the service life of the CO catalyst module is prolonged; the CO catalyst module is regularly subjected to air blowing and back blowing in a closed area, so that impurities such as carbon deposition on the CO catalyst module are cleaned, more active sites are exposed, the service life of the CO catalyst module is prolonged, and the investment and operation cost is reduced by adopting a transition metal oxide CO catalyst.

The invention discloses a silicon carbon material, a preparation method thereof and a lithium ion battery. The preparation method of the silicon-carbon material comprises the following steps: S1, adding an alkaline reagent into a mixed solution containing a porous carbon-loaded silicon substrate, transition metal salt and a solvent, and drying to obtain a first precursor; s2, performing carbon deposition on the first precursor by adopting a chemical vapor deposition method, performing in-situ growth of a carbon nanotube, and then performing acid pickling and drying to obtain a second precursor; s3, performing silicon deposition on the second precursor by adopting a chemical vapor deposition method, and forming silicon nanoparticles and / or silicon nanowires in the carbon nanotubes in situ to obtain a third precursor; and S4, carrying out carbon coating on the third precursor to obtain the silicon carbon material. The silicon-carbon material is excellent in expansion inhibition performance and compressive strength and has excellent conductivity, and the lithium ion battery containing the silicon-carbon material can give consideration to excellent capacity performance, rate performance and cycle performance.

The invention relates to the technical field of battery negative electrode materials, in particular to a silicon-carbon negative electrode material and a preparation method of the silicon-carbon negative electrode material in a low-temperature silicon-carbon deposition mode. The method comprises the following steps: performing synchronous silicon-carbon deposition or step-by-step silicon-carbon deposition on carbon-based material particles in a fluidized bed at a relatively low temperature to form silicon-carbon intermediate phase particles, and further performing carbon coating to form the silicon-carbon negative electrode material. The low-temperature silicon-carbon deposition mode involved in the process can effectively control the stability of heat release of the chemical vapor deposition reaction in the aspect of operation and improve the uniformity of temperature field distribution in the reactor, so that the overall reaction rate is controllable, and parameters such as the particle size and the nano silicon content of the silicon-carbon negative electrode material are easy to regulate and control. When the preparation method provided by the scheme of the invention is adopted, on the basis of ensuring that the safety is effectively improved, the yield and the product quality of the silicon-carbon negative electrode material are obviously optimized, and the silicon-carbon negative electrode material shows excellent electrochemical performance.

The invention discloses a silicon-carbon material, a preparation method and application thereof and a lithium ion battery. The preparation method of the silicon carbon material comprises the following steps: S1, performing carbonization treatment and activation treatment on a mixture of a carbon source and transition metal salt to obtain porous carbon; s2, performing carbon deposition on the porous carbon by adopting a chemical vapor deposition method, and growing a carbon nanotube in situ to obtain a first precursor; s3, performing silicon deposition on the first precursor by adopting a chemical vapor deposition method to obtain a second precursor; s4, carrying out carbon coating on the second precursor; and carrying out acid pickling and drying to obtain the silicon-carbon material. The silicon-carbon material is relatively good in conductivity and pressure resistance and excellent in expansion inhibition performance, and the prepared lithium ion battery can give consideration to excellent first effect, gram volume, rate capability and cycle performance.

The invention discloses a watermelon structure-imitated silicon-carbon negative electrode material as well as a preparation method and application thereof. The preparation method comprises the following steps: step 1, liquid phase coating: adding nano silicon particles into a carbon source solution containing organic matters, uniformly stirring, filtering and drying to obtain an organic carbon source-coated nano silicon material; step 2, stirring and calcining the material obtained in the step 1 in the atmosphere of introducing protective gas, then heating, and introducing the protective gas to obtain an intermediate material; and 3, introducing a carbon source gas into the intermediate material obtained in the step 2, and collecting a product after carbon deposition on the surface of the intermediate material is completed, wherein the product is the silicon-carbon negative electrode material with the watermelon-like structure. According to the silicon-carbon negative electrode material disclosed by the invention, a gap is reserved between the carbon layer and the silicon, so that a space can be provided for volume expansion of the silicon, the carbon layer and the deposited carbon can provide buffer for the volume expansion of the silicon and inhibit the volume expansion of the silicon, so that a stable SEI film is formed on the outer side of the material, and the consumption of lithium ions is reduced.

A combustor includes a housing and a combustion chamber assembly. The combustion cavity assembly comprises a cylinder part, a mounting base, a first spark plug, a second spark plug and a diesel nozzle assembly. The barrel part comprises a combustion cavity. The mounting base comprises an air inlet channel, a first air hole through hole and a second air hole through hole. The first sparking plug and the second sparking plug stretch into the combustion cavity in a protruding mode. A first airflow purging channel is further arranged between the first spark plug and the first wall part so that part of air can be used for purging the first spark plug. A second airflow purging channel is further arranged between the second spark plug and the second wall part so that part of air can be used for purging the second spark plug. According to the combustor, the probability of carbon deposition of the first spark plug and the second spark plug can be reduced.

The invention discloses a porous tubular methanol solid oxide fuel cell with a closed end, the fuel cell is a tubular solid oxide fuel cell (SOFC) stack, and the tubular SOFC stack comprises a plurality of tubular SOFC single cells; in the moving direction of fuel in the inner tube, the bottom end of the inner tube of the tubular SOFC single cell is open, the top end of the inner tube of the tubular SOFC single cell is closed, and a plurality of sections of closed areas and a plurality of sections of perforated areas are arranged on the tube wall of the inner tube and are sequentially and alternately arranged. According to the inner tube structure of the tubular SOFC single cell, the distribution uniformity of methanol on the surface of the anode of the solid oxide fuel cell can be effectively improved, so that the problem of serious carbon deposition caused by non-uniform distribution of methanol on the surface of the anode of the solid oxide fuel cell is effectively solved.

The invention provides a method for preparing a carbon nanotube with assistance of carbon dioxide, which is characterized in that methane is used as a carbon source, carbon dioxide is used as auxiliary gas, and the carbon nanotube is prepared under the action of a catalyst. Carbon deposition generated by using methane as carbon source gas is reduced by using carbon dioxide, and the quality and performance of single-wall, double-wall or three-wall carbon nanotubes are improved, so that application requirements are met.

The invention belongs to the technical field of metallurgical process control, and discloses a multi-sensor fused intelligent control system and method for the titanium reduction process of fine iron powder. The method aims at solving the problem that local carbon deposition is difficult to monitor and inhibit in real time in a traditional process. The method comprises the following steps of: constructing an in-furnace reaction thermodynamic constraint diagram by acquiring in-furnace temperature distribution, gas component distribution, a furnace wall vibration signal and a local pressure signal, and dividing an in-furnace region into a plurality of reaction front subregions according to the in-furnace reaction thermodynamic constraint diagram; in each partition, the system constructs a carbon deposition triggering network based on vibration-pressure coupling, the carbon deposition triggering probability is accurately calculated, and then a targeted self-adaptive gas injection strategy is generated. By globally optimizing gas injection parameters, real-time inhibition of local carbon deposition and effective separation of titanium in the titanium reduction process of the fine iron powder are achieved. According to the invention, the agglomeration phenomenon of the fine iron powder is reduced, the smoothness of a gas channel is kept, and the titanium recovery rate and the product quality are improved.

The invention provides a modeling method for SOFC electrode poisoning and performance degradation based on multiple factors, and belongs to the technical field of fuel cell numerical simulation. An SOFC three-dimensional geometric model is established, hypothesis conditions of the SOFC three-dimensional geometric model are established, physical parameters and boundary conditions of an SOFC are globally defined, physical field coupling setting is performed on a single cell geometric model of the SOFC, and the SOFC electrode poisoning and performance degradation modeling method based on multiple factors is established. Based on the Ni coarsening numerical model, the carbon deposition numerical model and the chromium poisoning numerical model, finally establishing a mathematical model of SOFC electrode poisoning and performance attenuation with multiple comprehensive factors; carrying out transient solution on different numerical models of the three-dimensional SOFC, and integrating the influence of various poisoning to obtain an SOFC electrode poisoning and performance attenuation rule; and based on the model, solving attenuation data of poisoning on electrochemical and mechanical properties of the SOFC to predict the residual service life of the SOFC.

The invention aims to provide a nickel-zinc alloy catalyst doped with a metal oxide auxiliary agent and a preparation method and application thereof, and belongs to the technical field of waste gas treatment and environment-friendly catalytic environment, the molecular formula of the catalyst is NixZn (at) yMOn-Al2O3, x represents the feeding molar ratio of nickel to zinc, y represents the mass fraction of the auxiliary agent, and y represents the mass fraction of the auxiliary agent. MOn represents oxides of different alkaline earth metals or rare earth metals; the catalyst has good catalytic performance in a methane dry reforming reaction, the CH4 conversion rate can be about 46%, the CO2 conversion rate can be about 70%, the hydrogen-carbon ratio of the product synthesis gas is about 1, and no carbon deposition is generated in a 100-hour stability test.

The invention discloses a catalyst for hydrogen production through tar steam reforming and a preparation method and application thereof. The catalyst comprises a cobalt-magnesium-aluminum composite spinel carrier and an active component loaded on the cobalt-magnesium-aluminum composite spinel carrier, the active component comprises nickel and at least one metal additive selected from iron, zirconium and ruthenium. The preparation method mainly comprises the following steps: preparing the carrier by adopting a coprecipitation method, loading the active component by adopting an impregnation method, and drying and reducing to obtain the final catalyst. The catalyst is used for tar component steam reforming hydrogen production reaction, especially for treating raw materials containing phenol and water vapor at 600-700 DEG C, tar conversion can be efficiently catalyzed, product gas rich in hydrogen can be generated, hydrogen selectivity is high, and almost no methane is generated. The catalyst has the advantages of high activity, good stability, strong carbon deposition resistance and the like, and is suitable for purification and high-value utilization of biomass pyrolysis tar.

The invention discloses a preparation method of a mesoporous Zn-ZSM-5 molecular sieve for preparing aromatic hydrocarbon from methanol, and belongs to the technical field of synthesis of inorganic materials. Aiming at the problems that a conventional mesoporous Zn / ZSM-5 molecular sieve catalyst Zn blocks orifices, the mesoporous structure is disordered, the molecular sieve solid yield is low, a molecular sieve framework is seriously damaged and the like, the preparation method comprises the following steps: uniformly mixing zinc gluconate with an aluminum source, a silicon source and a template agent, putting the mixture into a closed reaction container, carrying out hydrothermal crystallization, and sequentially washing, drying and roasting to obtain the mesoporous Zn / ZSM-5 molecular sieve catalyst. The sodium type molecular sieve is obtained; the preparation method comprises the following steps: carrying out multiple ion exchange on a sodium type molecular sieve by using an ammonium chloride solution, and sequentially carrying out suction filtration, washing, drying and roasting to obtain the mesoporous Zn-ZSM-5 molecular sieve. According to the preparation method of the methanol-to-aromatic hydrocarbon Zn / ZSM-5 molecular sieve provided by the invention, the obtained molecular sieve is used in the methanol-to-aromatic hydrocarbon process, and has the characteristics of high carbon deposition resistance, high aromatic hydrocarbon selectivity, low Zn wastage rate and the like.

The invention provides a high-selectivity anti-carbon-deposition CO oxidation catalyst and a preparation method thereof. The CO oxidation catalyst comprises a carrier, an active component loaded on the surface and / or in the carrier, and an auxiliary agent, wherein the active component comprises a noble metal element, and the auxiliary agent comprises a non-noble metal element; by taking the total mass of the carrier as 100%, the content of the auxiliary agent is less than 10%, preferably 3-6%; the total mass of the carrier and the auxiliary agent is 100%, and the content of the active component is less than 1.5%, preferably 0.5-1.5%. The CO oxidation catalyst disclosed by the invention has the characteristics of NOx resistance, carbon deposition resistance, difficulty in oxidizing NO, high CO catalytic combustion activity and the like, and has excellent CO catalytic combustion performance, especially the performance of catalytic combustion of steel sintering flue gas CO.

The invention provides an SOFC (solid oxide fuel cell) stack and a method for converting methane into low-carbon hydrocarbon and generating electric energy, the SOFC stack comprises a plurality of stack basic units, each cell stack basic unit comprises an electrolyte, a cathode and an anode which are arranged on two sides of the electrolyte, a cathode current collecting layer and an anode current collecting layer which are respectively arranged on the cathode and the anode, and a current collecting connector for connecting the cathode and the anode of the adjacent cell stack basic unit; wherein the collector connector is made of martensitic stainless steel, and chemical modification layers are arranged on the cathode side and the anode side of the collector connector; and a methane oxidative coupling catalyst is loaded on the chemical modification layer on the anode side of the current collecting connector. According to the invention, the chemical modification layer is formed on the surface of the collector connector made of martensitic stainless steel, and the methane oxidative coupling catalyst is loaded on the chemical modification layer on the anode side of the collector connector, so that the formation of carbon deposition on the surface is effectively inhibited, and the yield of low-carbon hydrocarbon products generated by methane conversion is improved.

The invention relates to a self-heating catalysis propane partial oxidation reforming coupling tube type solid oxide fuel cell system and a preparation method of a catalyst and a carrier thereof. The system comprises a fuel cell tube and a honeycomb type catalyst carrier with the catalyst, the fuel cell tube comprises a cathode layer, an electrolyte tube and an anode layer; the anode layer is located on the inner wall of the electrolyte tube, and the cathode layer is located on the outer wall of the electrolyte tube; the honeycomb type catalyst carrier is mounted at a gas inlet end of a fuel cell tube and is communicated with an inner cavity of the fuel cell tube, the catalyst is a ruthenium-based active component, comprises RuO or metal Ru and is doped with CeO as a dispersing aid, the loading capacity of Ru is 0.5-5wt%, and the proportion of CeO is 0.5-3wt%. The method has the advantages that the mechanical stability is good, the influence of the anode reduction process on the starting time is eliminated, the influence of anode carbon deposition on the performance of the SOFC is reduced, and rapid heating and rapid power generation are realized.

The invention discloses an alkaline earth metal modified aluminum oxide loaded nickel-based catalyst as well as preparation and application thereof. The alkaline earth metal modified aluminum oxide loaded nickel-based catalyst comprises a nanofiber-shaped gamma-Al2O3 carrier, Ni and alkaline earth metal oxide, wherein the Ni and the alkaline earth metal oxide are loaded on the carrier; the alkaline earth metal is at least one of Mg and Ca. The invention provides application of the alkaline earth metal modified aluminum oxide loaded nickel-based catalyst in a methane dry reforming reaction or a methane cracking reaction. The thermal stability and the carbon deposition resistance of the catalyst can be effectively improved, and the catalyst has good catalytic performance in a methane dry reforming reaction and a methane cracking reaction.

The invention belongs to the field of conductive aluminum oxide ceramic preparation, and particularly relates to a treatment method for performing carbon deposition infiltration on the surface of aluminum oxide ceramic to enable the aluminum oxide ceramic to have certain conductivity. According to the invention, wheat starch and corn starch are used as main raw materials and are converted into a volatile carbon source through a high-temperature carbonization process under the protection of inert gas; and placing the carbon source and aluminum oxide ceramic pre-subjected to conductive treatment in a high-temperature furnace protected by inert gas, and performing deposition carburizing treatment on the surface of the aluminum oxide ceramic at 800-900 DEG C to obtain the aluminum oxide conductive ceramic with certain conductivity. The method is low in raw material cost, low in sintering temperature of the related process, low in equipment investment, good in surface carburization uniformity of the aluminum oxide ceramic and stable in property.

The invention relates to a composite electrode material of an A-C core-shell structure, and belongs to the technical field of electrode materials. In the core-shell structure composite electrode material, A is any one element, two elements, three elements, four elements or five elements selected from Mn, Ni, Co, Fe, Cu, Zn, Ru, Pd and Rh; c is RE < x > Ce < 1-x > O < 2 >, and RE is any one element or two elements selected from La, Pr, Nd, Sm and Gd; x is the mole fraction of RE. By improving the interaction between the oxide and the core multi-component alloy and the synergistic effect between the elements, the structural stability and the carbon deposition resistance of the electrode material under the high-temperature condition are remarkably enhanced.

A catalyst and a preparation method therefor and a use thereof, and a method for reforming reaction of methane and carbon dioxide. The catalyst comprises an active matrix and CeO22, wherein the active matrix comprises La-Ni-based oxide having a perovskite structure; upon X-ray diffraction measurement, the catalyst has diffraction peaks at 2θ of 32.7±0.3°, 31.3±0.3°, and 28.0±0.3°; and upon H2-TPR measurement, the catalyst has at least one reduction peak at 400°C or below, and based on the total amount of the catalyst, the content of CeO2 is 1-20 wt%. The catalyst has relatively high activity and stability, can effectively enhance the adsorption of Co2 and reduce the adsorption and cracking of CH4 in the reaction process, and has good carbon deposition resistance.

The invention discloses a preparation method and application of a monatomic catalyst for catalytic degradation of ethanethiol, and belongs to the technical field of organic sulfur pollutant treatment.The atomic-scale dispersion of Ce species is achieved through HY molecular sieve FAU type topological structure constraint and cerium loading capacity limitation, the catalyst shows atomic-scale active sites, and the catalytic degradation of ethanethiol is achieved. The conversion path of ethanethiol can be accurately regulated and controlled, and efficient degradation of ethanethiol is realized; the topological confinement effect guarantees the stability of the monatomic catalyst, and the HY molecular sieve pore channel restrains migration of Ce atoms and inhibits agglomeration of Ce metal, so that the monatomic catalyst shows good anti-sintering ability, and at the same time, sulfur poisoning and carbon deposition rate are slowed down.

The invention provides a supported catalyst, a preparation method thereof and application of the supported catalyst in a dry reforming reaction of methane and carbon dioxide under a catalytic high-pressure condition, and relates to the technical field of catalysts and synthesis gas preparation through methane reforming. The supported catalyst provided by the invention comprises a MgAl2O4 carrier and metal components supported on the surface of the MgAl2O4 carrier, the metal components comprise Au particles and transition metal dispersed on the surfaces of the Au particles, and the transition metal is Ni or Co. According to the supported catalyst provided by the invention, Au particles are used as dispersed metals of active metals Ni and Co, Ni and Co are highly dispersed on the surfaces of the Au particles to form a highly dispersed catalyst, and the overall area of the active metals is effectively reduced. The supported catalyst is used for catalyzing a high-pressure methane-carbon dioxide dry reforming reaction, has anti-carbon deposition and anti-sintering performance under a high-pressure harsh condition, and can realize long-period stable operation of the reaction.

The invention belongs to the technical field of catalytic materials and hydrocarbon reforming, and particularly relates to a high-entropy catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a metal salt solution containing lanthanum, chromium, copper, zinc, manganese, nickel, iron and cobalt ions with a chelating agent and a dispersing agent for reaction, carrying out ultrasonic cavitation treatment to obtain sol, adjusting the pH value, gelatinizing under an oil bath heating condition to obtain a colloidal precursor, drying, and calcining in an air atmosphere to obtain a perovskite type high-entropy oxide precursor; and then treating in a reducing atmosphere to obtain the FeZnCuNiCo perovskite type high-entropy alloy catalyst which contains metal components of La, Cr, Ni, Mn, Fe, Zn, Cu and Co and takes a multi-metal alloy active center of Fe-Zn-Cu-Ni-Co as a main component. The high-entropy catalyst can meet the harsh requirements of high temperature, strong carbon deposition driving force and long-period operation in a propane dry reforming reaction, and is suitable for industrial application scenarios of continuous production of high-temperature synthesis gas.

According to the method for preparing the synthesis gas through the rare earth modified all-solid-state electrolytic tank, rare earth oxide particles are anchored on a porous SFM framework by dipping the rare earth oxide nano catalyst, so that the catalytic activity of the material is greatly improved, active sites participating in the reaction are increased, the electrochemical reduction reaction is facilitated, and the yield of the synthesis gas is increased. And continuous and controllable preparation of components of the synthesis gas is realized. According to the invention, the preparation process of a traditional dipping mode is simplified, the problem of cathode stability of the solid oxide electrolytic tank during high-temperature operation is solved, meanwhile, rare earth resources are reasonably utilized, the production cost is reduced, and the defects of carbon deposition during traditional cathode operation, need of adding a protective atmosphere to prevent oxidation and the like are avoided.

The invention discloses a short b-axis ZSM-5 molecular sieve as well as a synthesis method and application thereof, tetraethyl orthosilicate and aluminum isopropoxide are taken as an aluminum source, tetrapropylammonium hydroxide is taken as a template agent, ammonium salt is added as an auxiliary agent to limit the growth of particles along a b axis, after a hydrothermal crystallization reaction, the obtained product is washed, baked and calcined, and the short b-axis ZSM-5 molecular sieve is obtained. The method disclosed by the invention is simple to operate, has repeatability, small template agent dosage and low cost, the synthesized ZSM-5 molecular sieve has the advantages of good thermal stability, high specific surface area, strong acid center, slow carbon deposition speed in reaction and the like, meanwhile, more active sites can be exposed, the transmission path of reactants and products is shortened, the diffusion resistance is reduced, and the method is suitable for industrial production. The catalyst is used for catalytic synthesis of pyridine and derivatives thereof, and has high selectivity and high catalytic activity.

The invention discloses a silicon-carbon negative electrode material, a preparation method thereof and a battery, and belongs to the technical field of negative electrode materials. The compaction density of the silicon-carbon negative electrode material is greater than or equal to 1.1 g / cm < 3 >, and the NLDFT total pore volume is less than or equal to 0.005 cm < 3 > / g; and in the NLDFT total pore volume of the silicon-carbon negative electrode material, the pore volume not exceeding 10% is provided by pores with the pore diameter not less than 50nm. The silicon-carbon negative electrode material has relatively high compaction density and first efficiency, and is beneficial to improving the volume energy density of the battery. The preparation method comprises the following steps: carrying out silicon deposition on a porous carbon raw material, carrying out high-pressure impregnation on a precursor obtained after primary carbon deposition by using an organic carbon source, and then carrying out secondary carbon deposition. The method is simple to operate, the silicon-carbon negative electrode material with relatively high compaction density can be prepared, and the prepared silicon-carbon negative electrode material can be further used for preparing a battery, so that the volume energy density of the battery is improved.

The invention relates to the field of gas adsorption and catalysis, in particular to a bifunctional catalyst and a preparation method and application thereof. The catalyst is of a hollow tubular structure, takes calcium oxide as a basic component, and further comprises a nickel oxide, a cobalt oxide and a nickel-cobalt bimetallic oxide, wherein the molar ratio of the Ca element in the calcium oxide to the nickel oxide to the Ni element in the nickel-cobalt bimetallic oxide to the cobalt oxide to the Co element in the nickel-cobalt bimetallic oxide is (5-25): (2-15): 1; the Ni element comprises two valence states of Ni < 2 + > and Ni < 3 + >; and the Co element comprises three valence states of Co < 2 + >, Co < 3 + > and Co < 4 + >. Due to the specific elements and content of the hollow tubular catalyst, the gasification catalysis capability and adsorption capability of biomass and waste plastics are improved, and carbon deposition of the catalyst is inhibited.

The invention relates to the field of polyolefin catalytic aromatization, and discloses a low-temperature polyolefin aromatization method based on a zeolite-encapsulated metal catalyst, which comprises the following steps: heating and melting a zeolite-encapsulated metal catalyst as a lower bed layer and a mixture of polyolefin plastic and a lamellar ZSM-5 molecular sieve as an upper bed layer to carry out aromatization reaction; the zeolite encapsulated metal catalyst comprises a matrix and metal encapsulated in the matrix, and the matrix is an HZSM-5 molecular sieve. By designing a double-bed series catalytic route, polyolefin is firstly converted into low-carbon olefin, and then olefin aromatization reaction is performed, so that the reaction temperature and the content of heavy aromatic hydrocarbon are reduced; according to the catalyst for catalyzing the olefin aromatization reaction in the lower bed layer, the metal nanoparticles are encapsulated in zeolite crystals, the pore channel confinement effect is exerted to avoid generation of a large-size carbon deposition precursor, the diffusion speed of reactants and product molecules is adjusted to inhibit a deep reaction, a stable catalytic system is formed, and the catalytic activity of the catalyst is improved. The aromatic hydrocarbon yield and the service life of the catalyst can be improved.

The invention discloses a preparation method and application of a molecular sieve-based honeycomb monolithic denitration catalyst. A molecular sieve-based catalyst, a metal-modified natural silicon-aluminum mineral, an organic binder, an extrusion aid, a pore forming agent, glass fibers, a structure manufacturing agent, an inorganic binder, an acid solution, a humectant and water are mixed, and the molecular sieve-based honeycomb-shaped integral denitration catalyst is obtained through the processes of structured water dissolution and the like. The water-soluble polymer bunchy fiber is used as a structure manufacturing agent, the negative influence of carbon deposition poisoning of a molecular sieve catalyst is reduced, honeycomb inner wall through connection is achieved, and a honeycomb-based multi-channel inner wall is built; and the contact area and the reaction contact time of the reaction gas and the molecular sieve catalyst embedded in the inner wall and the metal modified natural silicon-aluminum mineral are increased. The prepared denitration catalyst has high cohesiveness, strong adsorbability and high reaction activity, can effectively overcome the barren defect of a molecular sieve catalyst, and remarkably improves the extrusion smoothness and the mechanical strength after molding.