822 results about "Carbon deposition" patented technology

The invention belongs to the technical field of metallurgical process control, and discloses a multi-sensor fused intelligent control system and method for the titanium reduction process of fine iron powder. The method aims at solving the problem that local carbon deposition is difficult to monitor and inhibit in real time in a traditional process. The method comprises the following steps of: constructing an in-furnace reaction thermodynamic constraint diagram by acquiring in-furnace temperature distribution, gas component distribution, a furnace wall vibration signal and a local pressure signal, and dividing an in-furnace region into a plurality of reaction front subregions according to the in-furnace reaction thermodynamic constraint diagram; in each partition, the system constructs a carbon deposition triggering network based on vibration-pressure coupling, the carbon deposition triggering probability is accurately calculated, and then a targeted self-adaptive gas injection strategy is generated. By globally optimizing gas injection parameters, real-time inhibition of local carbon deposition and effective separation of titanium in the titanium reduction process of the fine iron powder are achieved. According to the invention, the agglomeration phenomenon of the fine iron powder is reduced, the smoothness of a gas channel is kept, and the titanium recovery rate and the product quality are improved.

The invention discloses a catalyst for hydrogen production through tar steam reforming and a preparation method and application thereof. The catalyst comprises a cobalt-magnesium-aluminum composite spinel carrier and an active component loaded on the cobalt-magnesium-aluminum composite spinel carrier, the active component comprises nickel and at least one metal additive selected from iron, zirconium and ruthenium. The preparation method mainly comprises the following steps: preparing the carrier by adopting a coprecipitation method, loading the active component by adopting an impregnation method, and drying and reducing to obtain the final catalyst. The catalyst is used for tar component steam reforming hydrogen production reaction, especially for treating raw materials containing phenol and water vapor at 600-700 DEG C, tar conversion can be efficiently catalyzed, product gas rich in hydrogen can be generated, hydrogen selectivity is high, and almost no methane is generated. The catalyst has the advantages of high activity, good stability, strong carbon deposition resistance and the like, and is suitable for purification and high-value utilization of biomass pyrolysis tar.

The invention relates to a composite electrode material of an A-C core-shell structure, and belongs to the technical field of electrode materials. In the core-shell structure composite electrode material, A is any one element, two elements, three elements, four elements or five elements selected from Mn, Ni, Co, Fe, Cu, Zn, Ru, Pd and Rh; c is RE < x > Ce < 1-x > O < 2 >, and RE is any one element or two elements selected from La, Pr, Nd, Sm and Gd; x is the mole fraction of RE. By improving the interaction between the oxide and the core multi-component alloy and the synergistic effect between the elements, the structural stability and the carbon deposition resistance of the electrode material under the high-temperature condition are remarkably enhanced.

The invention belongs to the technical field of catalytic materials and hydrocarbon reforming, and particularly relates to a high-entropy catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a metal salt solution containing lanthanum, chromium, copper, zinc, manganese, nickel, iron and cobalt ions with a chelating agent and a dispersing agent for reaction, carrying out ultrasonic cavitation treatment to obtain sol, adjusting the pH value, gelatinizing under an oil bath heating condition to obtain a colloidal precursor, drying, and calcining in an air atmosphere to obtain a perovskite type high-entropy oxide precursor; and then treating in a reducing atmosphere to obtain the FeZnCuNiCo perovskite type high-entropy alloy catalyst which contains metal components of La, Cr, Ni, Mn, Fe, Zn, Cu and Co and takes a multi-metal alloy active center of Fe-Zn-Cu-Ni-Co as a main component. The high-entropy catalyst can meet the harsh requirements of high temperature, strong carbon deposition driving force and long-period operation in a propane dry reforming reaction, and is suitable for industrial application scenarios of continuous production of high-temperature synthesis gas.

The application relates to the technical field of laser cleaning, in particular to a laser cleaning workstation which comprises a clamping mechanism and a cleaning mechanism, the cleaning mechanism is installed on the side of the clamping mechanism, the clamping mechanism comprises a rack, a support frame is fixedly connected to the top of the rack, a motor is installed on the back of the support frame, a rotating shaft is installed at the output end of the motor, a rotating disc is fixedly connected to the end, away from the motor, of the rotating shaft, a clamping assembly is installed on the front of the rotating disc, an elastic clamping block is installed in the clamping assembly, and an arc plate is arranged in the elastic clamping block. The application can effectively reduce pollution emission, improve the reliability of welding quality and the one-time welding qualification rate, save time and manpower cost. The laser cleaning machine can be applied to rust removal, paint removal, oil removal, oxide film removal and cleaning of black ash, carbon deposition and oil stains and other pollutants on the surface of parts after welding on various metal surfaces.

The application discloses a hydrodesulfurization catalyst and a preparation method and application thereof. The hydrodesulfurization catalyst comprises a carrier and a second active metal component; the carrier comprises a first active metal nitride, a first active metal carbide, boron oxide and aluminum oxide; wherein the molar ratio of the first active metal nitride to the first active metal carbide, in terms of the first active metal, is 1:0.15-0.25. The hydrodesulfurization catalyst has the characteristics of good macromolecular diffusion performance, strong desulfurization capacity and good carbon deposition resistance. The hydrodesulfurization catalyst is particularly suitable for a residual oil hydrodesulfurization treatment process and has good desulfurization activity and stability.

The application discloses a preformed methane reforming catalyst and a preparation method thereof. The catalyst comprises a nickel-active alumina first functional component, a cerium oxide nanocluster second functional component and an alumina inert phase. The preparation method comprises preforming an inert phase pretreatment, hydrothermal treatment, calcination and reduction. The preformed inert phase after pretreatment is used as a carrier, which greatly improves the catalyst strength, pertinently weakens the metal-carrier interaction, avoids bed layer temperature drop and carbon deposition caused by local high strength reaction, and improves the operation stability. The first functional component with a layered structure and the second functional component rich in oxygen vacancies further improve the catalyst activity and stability, and the performance indicators are overall superior to those of the existing catalyst products. The preparation method is simple and easy to implement, has no special requirements on equipment, and is conducive to the popularization and application in the fields of methane steam reforming and methane dry reforming.

The invention belongs to the technical field of industrial combustion safety control, and provides a double-channel industrial furnace gas combustion safety interlocking control system which comprises a gas / air flow ratio dynamic monitoring module, a flue CO concentration online detection module, a double-channel data conflict arbitration processor and a visual human-computer interface. Aiming at the prominent problems of incomplete combustion of coal gas, carbon deposition, detonation risk and the like which are easy to occur under the working condition of accelerated temperature rise, the system integrates visual double-insurance safety control of dynamic calculation of a flow ratio and real-time analysis of tail gas components, and all-directional safety protection in the combustion process is realized through a multi-parameter cooperative monitoring and intelligent interlocking mechanism; the detonation risk is obviously reduced; meanwhile, the air-fuel ratio fluctuation is accurately controlled within the range of + / -5%, and the carbon deposition phenomenon is effectively reduced; and remarkable economic benefits are created while reliable operation of equipment is guaranteed.

The invention relates to a method for synthesizing mesitylene by gas-phase non-hydroisomerization of unsym-trimethylbenzene, which comprises the following step of: contacting the unsym-trimethylbenzene with a catalyst under a gas-phase non-hydroisomerization reaction condition in the presence of the catalyst, wherein the catalyst is an EWT structure molecular sieve, the total pore volume of the EWT structure molecular sieve is 0.20-0.51 cm < 3 >. G <-1 >, and the mesoporous volume is 0.11-0.37 cm < 3 >. G <-1 >. According to the method disclosed by the invention, the EWT structure molecular sieve with an ultra-large pore channel structure is adopted as the catalyst, and when the catalyst is used for synthesizing mesitylene through unsym-trimethylbenzene gas-phase non-hydroisomerization, the distribution conditions of raw materials and products are improved, the conversion rate of unsym-trimethylbenzene and the selectivity and the mass yield of mesitylene are improved, heavy component carbon deposition is slowed down, and the yield of mesitylene is improved. The service life of the catalyst is prolonged.

The application discloses a cold plasma microbubble and biomass supercritical water gasification hydrogen production system and method, and belongs to the field of biomass hydrogen production. The system comprises a raw material processing unit, a cold plasma pre-activation unit, a high-pressure subcritical pretreatment unit, a supercritical gasification reaction unit, a gas-liquid separation unit, a hydrogen gas purification unit, a waste heat recovery unit and a circulating water treatment unit. After being pulped, the raw material is modified by the cold plasma pre-activation unit to improve the activity, and then enters the supercritical reactor with a built-in catalytic bed through the high-pressure subcritical pretreatment unit containing plasma microbubble generated active species to complete the gasification. After the product gas-liquid separation, the hydrogen-containing gas is purified to obtain high-purity hydrogen gas, the liquid phase water is purified and reused, the waste heat is recovered to supply system energy consumption, and the circulating water is treated to discharge crystalline salt to prevent salt analysis. The application realizes the deep cooperation of cold plasma and supercritical water gasification, improves the gasification efficiency and hydrogen production selectivity, reduces the energy consumption, tar and carbon deposition, guarantees the stable operation of the system, reduces the comprehensive cost, and is suitable for the industrialization of biomass hydrogen production.

The invention discloses a dispatching method and system based on a distributed diesel generator and a virtual power plant, and relates to the technical field of power systems and energy internet. Comprising the steps that a local control unit establishes an operation constraint model containing a nonlinear fuel efficiency and carbon deposition risk model, and generates a health recommendation domain; the cloud end generates a triple scheduling instruction packet containing reference power, offset bandwidth and weight vectors in combination with power grid constraints; identifying the impedance of a grid-connected point on line at the edge side, and carrying out asymmetric compression correction on the bandwidth based on the voltage sensitivity under a weak grid; and the local unit performs rolling optimization solution under the double constraints of the corrected instruction and the local model, and switches to the anti-carbon deposition autonomous mode containing dummy load input when the communication is interrupted and the carbon deposition risk is high. According to the invention, through cloud-side-end cooperation and hierarchical closed-loop correction, the conflict between the weak network voltage out-of-limit risk and the low-load carbon deposition of the unit is effectively solved, and the safety and the performability of scheduling are improved.

The invention provides a silicate nanotube photo-thermal composite catalyst with CeO2-ZrO2 compositely coated with Ni as well as a preparation method and application of the silicate nanotube photo-thermal composite catalyst, and belongs to the technical field of energy materials. The catalyst takes a layered silicate nanotube as a carrier, is loaded with an active component Ni, and is coated with a CeO2-ZrO2 composite shell layer. The preparation method comprises the steps that firstly, a Ni-PSNTs precursor is synthesized through microwave hydrothermal synthesis, then Ce-Zr hydroxide is deposited in an ethanol solvent, ZrO2 / CeO2 layers are stacked alternately through an atomic layer deposition method, H2 / N2 pulse reduction is conducted after calcination, and the target catalyst is obtained. The methane conversion efficiency and stability are obviously improved. The problems that a traditional catalyst is low in activity, poor in carbon deposition resistance and low in photo-thermal efficiency are solved, and the catalyst is suitable for the fields of efficient conversion of fossil energy and the like.

The invention discloses a composite catalyst for recovering monophenol from waste fan blades as well as a preparation method and application of the composite catalyst. The catalyst is prepared by taking a beta molecular sieve as a carrier and CeO2-Fe2O3 bimetallic oxide as an active component through a coprecipitation-calcination method. By changing the proportion of Ce < 2 + > / Fe < 3 + >, precise regulation and control of intermetallic interaction can be realized, and the content of active oxygen species and acid sites on the surface of the catalyst is remarkably increased. Meanwhile, due to the ordered macroporous structure of the beta molecular sieve, the shape selectivity of reactants is enhanced, the monophenol yield is remarkably increased, and the problem of carbon deposition in the catalysis process is effectively inhibited. The catalyst has high specific surface area, excellent catalytic activity and cycling stability, and can realize efficient catalytic conversion of waste fan blades within 450-650 DEG C. The process is simple and convenient to operate, low in energy consumption and high in monophenol yield, has both environmental and economic benefits, and provides a new strategy for resource utilization of fan blades.

The invention provides a composite catalyst for supercritical water gasification hydrogen production and a preparation method and application thereof, and relates to the technical field of organic solid waste recycling, the composite catalyst comprises a carrier, an active component and an auxiliary agent; the carrier is prepared from a ZrO2 mesoporous material co-doped with Ce and La; the active component comprises Ni-Co bimetallic nanoparticles, and the Ni-Co bimetallic nanoparticles are subjected to vulcanization treatment to form a core-shell structure in which Ni-Co metal is wrapped by sulfur; and the auxiliary agent comprises MoO3. According to the composite catalyst, a Ce-La-ZrO2 mesoporous material serves as a carrier, Ni-Co bimetallic nanoparticles serve as an active component, a core-shell structure (NiCo at S) is formed after vulcanization treatment, the surface of the core-shell structure is covered with a layer of sulfur atoms, carbon deposition can be effectively inhibited, the chlorine poisoning resistance of the catalyst is enhanced through the added MoO3 auxiliary, and the service life of the catalyst is prolonged.

The invention belongs to the technical field of energy chemical industry and catalysis, and discloses a preparation method for preparing synthesis gas through iron-catalyzed methane dry reforming. According to the method, gamma-aluminum oxide is taken as a carrier, ferric nitrate is loaded by adopting an equivalent-volume impregnation method, an iron oxide catalyst is formed through drying and roasting, and metal iron active sites with high dispersity are obtained through hydrogen reduction. The reaction is carried out in a fixed bed reactor, the reaction temperature is controlled to be 650-700 DEG C, methane and carbon dioxide are mixed according to the volume ratio of 1: 1 and introduced into the reactor under the normal pressure condition, and efficient dry reforming is realized to generate synthesis gas. According to the method, the methane conversion rate can reach 85% or above, and the carbon dioxide conversion rate can reach 90% or above. Compared with the existing noble metal or nickel-based catalytic system, the catalyst disclosed by the invention has the advantages of cheap raw materials, simple and convenient preparation process, excellent carbon deposition resistance, capability of keeping high activity and stability at lower temperature, low energy consumption, low cost, strong environmental protection property and suitability for industrial amplification.

The invention provides a low-cost silicon-carbon negative electrode material and a preparation method thereof, and belongs to the field of lithium ion battery negative electrode materials. The preparation method of the low-cost silicon-carbon negative electrode material provided by the invention comprises the following steps: introducing a gaseous silicon source and a first protective gas into a reactor, and carrying out silicon deposition on the pore wall surface of porous carbon to obtain a silicon-carbon composite material; and introducing a gaseous organic carbon source and a second protective gas into the reactor for carbon deposition to obtain the low-cost silicon-carbon negative electrode material, the staying time of the gaseous organic carbon source in the reactor is 20-95 seconds. The method comprises the following steps: introducing a gaseous silicon source and a first protective gas into a reactor, and carrying out silicon deposition on the surface of the porous carbon to obtain the silicon-modified porous carbon. By controlling the retention time of the organic carbon source in the reactor, the deposition rate of the organic carbon source is effectively improved, and the problems of low carbon deposition rate, poor coating effect and high production cost in the process of preparing the low-cost silicon-carbon negative electrode material by a vapor deposition method are solved.

The invention discloses a preparation method of a Sn-Bi-Ni-Cu quaternary liquid alloy methane cracking catalyst, production raw materials comprise composite melt metal and composite transition metal, and the mass ratio of the composite melt metal to the composite transition metal is 1: (0.3-1.2); the composite melt metal is composed of Sn and Bi according to the mass ratio of 1: (1.3-1.7); the composite transition metal is composed of Ni and Cu according to the mass ratio of 1: 0.15-1.2. The quaternary liquid alloy catalyst has the advantages that: 1) compared with the existing catalyst for hydrogen production by methane cracking, the quaternary liquid alloy catalyst provided by the invention can stably operate for more than 1000 hours in a range of normal pressure to 3MPa and air speed of 100-100mL. G <-1 >. H <-1 >, the active phase retention rate is more than 95%, and the quaternary liquid alloy catalyst is especially suitable for alkane pyrolysis hydrogen production, CO2 hydrogenation and easy carbon deposition reaction systems, and has a wide application prospect; a new material design thought and an engineering implementation scheme are provided for the field of liquid metal high-temperature catalysis; and 2) experiments show that the quaternary liquid alloy catalyst prepared by the method provided by the invention can significantly improve the carbon sequestration rate and the hydrogen yield.

The invention relates to the technical field of diesel engine tail gas treatment, in particular to a mining explosion-proof diesel engine tail gas treatment device which comprises a treatment box body, a tail gas inlet and a tail gas outlet are formed in the two sides of the treatment box body respectively, a splitter plate is arranged in the treatment box body, and a plurality of splitter holes are formed in the splitter plate. According to the device, the entering tail gas is uniformly shunted through the shunting plate, so that the treatment effect of the subsequent purification step is favorably improved. Tail gas often contains impurities such as oil stains and carbon deposition particles, and shunting holes are prone to being blocked after long-time operation. The through mechanism arranged in the device can be automatically started when blockage is detected, the flow dividing hole is physically dredged through the dredging rod, the airflow channel is effectively recovered, the continuity and stability of the tail gas treatment process are guaranteed, the equipment shutdown time caused by blockage is shortened, and the overall operation efficiency is improved.

The invention relates to the technical field of antistatic materials, and relates to an antistatic styrene copolymer for producing a carrier tape and a preparation method thereof, and the antistatic styrene copolymer comprises the following components by mass: 45%-60% of HIPS, 6%-10% of HIPS / PPO alloy, 15%-25% of conductive carbon black, 5%-15% of a compatilizer, 6%-15% of a flexibilizer, 2%-5% of a carbon black dispersant, 0.3%-0.8% of an antioxidant, and 0.5%-1% of a lubricant. The carbon black dispersing agent comprises a coupling agent and medium-chain and long-chain aliphatic tertiary amine. Through the collaborative design of the tertiary amine-coupling agent binary carbon black dispersing agent and the HIPS / PPO heat-resistant alloy, the styrene system filled with 15%-25% high carbon black has no crystal point, no carbon deposit, no melting in 225 DEG C heat sealing and no black falling in tape tearing, and the industrial-grade requirement of continuous high-speed production of carrier tapes is met.

The invention particularly relates to a phosphotungstic acid / amino-functionalized UiO-66 bifunctional catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving zircon salt, terephthalic acid and 2-aminoterephthalic acid in an organic solvent; adding a regulator acetic acid, and activating to prepare amino-functionalized UiO-66; and slowly dropwise adding a phosphotungstic acid acetonitrile solution into the amino-functionalized UiO-66 acetonitrile dispersion liquid, stirring and reacting at room temperature, and separating and drying to obtain the catalyst HPW at amino-functionalized UiO-66. The bifunctional catalyst (phosphotungstic acid / amino-functionalized UiO-66) is coordinated through an acid-base site at a lower temperature (170 DEG C vsgt; according to the present invention, the reaction is performed at the temperature of 200 DEG C, the formation of carbon deposition can be substantially inhibited at the low temperature, and the catalyst has characteristics of high catalytic activity after five cycles, extraordinary hydrothermal stability and chemical stability, can maintain the stability of the catalyst in the reaction environment with the existence of a small amount of water, and has good and broad application prospects.

According to the nickel-based catalyst and the preparation method and application thereof, through Ga modification, the methane cracking depth can be reduced, and then carbon deposition is effectively inhibited; ceO2 oxygen vacancies can effectively activate CO2, the generated intermediate oxygen species O further reacts with deposited carbon so as to achieve the purpose of carbon cleaning, the GaxNi / CeO2 catalyst is prepared by adopting a urea homogeneous precipitation method, 1000-hour long-term stable catalytic conversion of the nickel-based catalyst in a carbon dioxide methane dry reforming reaction is achieved, and the catalyst has the advantages of simple process, low cost and high efficiency. The nickel-based catalyst prepared by the method can keep good catalytic stability.

The invention relates to the technical field of hydrogenation catalysts, and discloses a coal-based cracking C9 + component hydrogenation catalyst and a preparation method and application thereof. The method comprises the following steps: (1) carrying out cocurrent-flow coprecipitation on pseudo-boehmite, mesoporous carbon and a precipitator to obtain precipitated slurry; sequentially aging the obtained precipitate slurry, and separating out a solid phase to obtain modified pseudo-boehmite; (2) mixing, kneading and molding the modified pseudo-boehmite obtained in the step (1), kaolin, an adhesive and an extrusion aid, and then performing first drying and first roasting to obtain a composite carrier; and (3) preparing an impregnation liquid containing a fluoride salt, a first active metal salt and a second active metal salt, impregnating the composite carrier in the impregnation liquid by adopting a rotary spray impregnation mode, introducing gas into the impregnation reactor after impregnation is completed, and then carrying out second drying and second roasting. According to the technical scheme, the catalyst has high catalytic activity, carbon deposition resistance and high hydrodesulfurization activity.

The present invention pertains to the technical field of lithium-ion batteries. Disclosed are a silicon-carbon negative electrode material based on organosilicon waste silicon powder, a preparation method therefor, and use thereof. The preparation method of the present invention comprises the following steps: rapidly annealing organosilicon waste silicon powder; performing acid leaching by mixing the rapidly annealed waste silicon powder with an acid solution to obtain modified waste silicon powder; mechanically grinding the modified waste silicon powder to obtain ground modified waste silicon powder; mixing the ground modified waste silicon powder with an organic carbon source and a solvent, and subjecting the resulting precursor solution to spray granulation to obtain silicon-carbon microspheres; and introducing a carbon deposition precursor source to deposit carbon on the silicon-carbon microspheres, thereby obtaining the silicon-carbon negative electrode material. The present invention achieves the development of a novel silicon-carbon negative electrode material with high tap density, providing new ideas and new paths for the value-adding recycling of hard-to-treat organosilicon waste silicon powder in the organosilicon industry and the low-cost development of high-performance lithium-ion silicon negative electrodes.

The invention discloses a biomass coke-based multifunctional coal pyrolysis catalyst and a preparation method thereof, and belongs to the technical field of preparation of coal pyrolysis catalysts. The preparation method comprises the steps of raw material pretreatment, pyrolysis pore-forming, activation synergism, metal loading, citric acid staged removal and atmosphere replacement, and specifically comprises the following steps: firstly, compounding, crushing and drying straw and wood biomass, and performing pyrolysis in an inert atmosphere to prepare a biomass coke precursor; then carrying out alkali metal activation, acid pickling and water washing to prepare an activated carrier with a high specific surface area; then, citric acid is used for assisting in loading a mixed solution of nickel nitrate and ferric nitrate, citric acid is removed by stages through air low-temperature pre-removal and inert gas medium-temperature deep removal, and the valence state of the metal active component is synchronously regulated and controlled. The prepared catalyst is low in citric acid residual quantity, can realize hydrodeoxygenation, tar cracking and anti-carbon deposition functions, is excellent in catalytic performance and low in cost, meets the requirements of low metamorphic coal pyrolysis volatile component upgrading, and is easy to industrially apply.

This invention relates to the field of chemical synthesis technology, specifically disclosing a high-temperature pyrolysis reaction system and its application. The high-temperature pyrolysis reaction system of this invention employs a two-stage reactor design and is filled with a differentiated catalyst. Combined with acetone as an intermediate feedstock between the two stages, it improves the feedstock conversion rate and the selectivity of the target product. The biomimetic integral catalyst solves the problems of poor mass transfer, high pressure resistance, and backmixing caused by traditional packing materials, achieving precise control of the pyrolysis time and inhibiting secondary polymerization and reverse reactions of the product at high temperatures. Through synergistic optimization of reactor configuration, catalyst structure, and separation technology, the entire system effectively suppresses carbon deposition, achieving efficient preparation of dimethyl ketene. This invention forms an integrated high-temperature pyrolysis reaction system from pyrolysis reactor design, catalyst structure design, and improved separation technology, and applies it to the pyrolysis of isobutyric anhydride to produce dimethyl ketene, achieving high feedstock conversion rate and high selectivity of the target product.

The invention belongs to the technical field of catalysts, and particularly relates to a waste PVC derived carbon composite metal material and a preparation method and application thereof. The waste PVC derived carbon composite metal material comprises a carbon carrier, an active component and a modification reagent, wherein the active component and the modification reagent are loaded in the carbon carrier. According to the present invention, with the introduction of the modification reagents, the electronic structure around the active component metal is adjusted, such that the two modification reagents and the active metal component produce the synergistic effect, the metal component can be stably anchored on the carbon carrier, the dispersibility of the active metal is significantly improved, and the catalytic performance of the catalyst is further improved. Meanwhile, the coordination effect between the active metal component and the modification reagent inhibits the loss of the active metal, the content of the active metal component in a high valence state is increased, and the carbon deposition content in the catalyst is also obviously reduced.

The present invention discloses a waste plastic oil hydrofining catalyst and a preparation method thereof, the catalyst comprises an active component and a carrier, the total mass of the catalyst is 100%, the active component accounts for 10 wt%-30 wt%, the carrier accounts for 70 wt%-90 wt%, the carrier comprises a Ce (at) Cu-M / Al2O3 composite oxide, and M is an alkali metal oxide or an alkaline earth metal oxide. According to the present invention, the synthesized Ce (at) Cu-CaO / Al2O3 composite oxide is adopted in the carrier material, such that the chlorine resistance of the catalyst is improved, the dispersity and the carbon deposition resistance of the active component on the catalyst surface are significantly improved, the high hydrogenation activity of the catalyst is obtained, the hydrogenation catalysis performance of the catalyst is effectively improved, and the waste plastic oil hydrofining dechlorination effect is improved.

The invention discloses a high-yield and low-carbon-deposition regulation and control method and system for a continuous regenerative catalytic reforming reaction. The method comprises the following steps: at the beginning, setting a weighted average inlet temperature for the four-in-one reforming reactor and setting an inlet temperature of each bed layer; measuring the content of naphthenic hydrocarbon in naphtha to be added at the beginning, and setting the initial average pressure of the four-in-one reforming reactor according to the content of naphthenic hydrocarbon in naphtha to be added; naphtha is added into the four-in-one reforming reactor for a reaction; in the reaction process, the weighted average inlet temperature of the four-in-one reforming reactor, the inlet temperature of each bed layer, the catalyst circulation rate and the average pressure are regulated and controlled in real time; and ending the experiment. The method breaks through the critical path of the current technical bottleneck, and has important significance for improving the product selectivity of the continuous regeneration catalytic reforming process, reducing the energy consumption and prolonging the service life of the catalyst.

This invention provides a self-sealing, anti-carbon-deposit, electrically symbiotic solid oxide fuel cell structure, relating to the field of battery technology. The battery structure includes a connecting weight reforming plate, an anode, an electrolyte, and a cathode. The connecting weight reforming plate includes a connecting body, with a battery support porous region and an oxidation gas flow channel respectively on its upper and lower surfaces. The lower surface of the battery support porous region has a reforming and reforming gas flow channel, and a reforming porous region is located between the reforming and reforming gas flow channel and the oxidation gas flow channel. The reforming porous region is separated from the upper and lower flow channels by a leak-free wall. The anode, electrolyte, and cathode are sequentially stacked on the upper surface of the battery support porous region. This battery structure achieves self-sealing of the reformed fuel and reformed gas, reducing the sealing difficulty of planar SOFCs. The indirect reforming of the fuel in the reforming porous region avoids excessive local thermal stress during internal reforming, which could cause battery structural damage and anode carbon deposition, significantly improving battery performance and service life.

The invention relates to the technical field of tail gas purification, in particular to an anti-HCs poisoning SCR catalyst and a preparation method thereof.The SCR catalyst is of a double-layer structure, the lower layer is a first Cu-molecular sieve, and the upper layer is a second Cu-molecular sieve; the first Cu-molecular sieve is a Cu-molecular sieve, and the molar ratio of silicon dioxide to aluminum oxide is less than 40; the second Cu-molecular sieve is a Cu-molecular sieve with a core-shell structure; the core is a Cu-molecular sieve, the shell layer is a mesoporous SiO2-CeO2 protective layer, the shell layer CeO2 accounts for less than 20% of the mass of the molecular sieve, and the shell layer SiO2 accounts for less than 50% of the mass of the molecular sieve. The layered SCR catalyst can effectively prevent HCs from being in contact with an inner core and a lower layer active site, can oxidize the HCs on the surface into CO2 and inhibit formation of carbon deposit, and is good in hydrothermal stability and wide in working temperature window.