77443 results about "Ptru catalyst" patented technology

Improved performance ion exchange membranes for use in REM, AEM and DMFC fuel cells, buffered fuel cells, hydrolysis, other applications comprise a molecular matrix of homopolymers, di-monomer, heteropolymers, copolymers, or block-polymers of fluorocarbon and hydrocarbon compounds combined with (i) skeletal support grid to improve durability, handling, reduce membrane swelling, and sequester dopants and nanoparticles from leakage; (ii) microporous membrane formed using a sacrificial filler process enhancing conductivity and limiting fuel crossover; (iii) hetero-ionomeric matrix of two-or-more membrane-bound acids e.g. sulphonic and phosphonic acid expanding usable range; (iv) permanent fillers enhancing conductivity and porosity including nanoparticles, metal-oxides, zeolites, silicates, GOs, CNTs, MOFs, POSS, and others; (v) ionic liquid doping to enhance membrane conductivity; (vi) membrane nanocoating preventing H2O2 diffusion; and / or (vii) catalytic nanocoating with metals, metal-oxides, and MOFs preventing atmospheric toxin catalyst poisoning. Combined with a heterogenous GDI, the IEM is integrated into iBFC power blade and energy bank applications.

A pyrolysis method and system are provided that enhances the production of C3 and C4 alkanes in the resulting pyrolysis effluent. More particularly, the disclosed pyrolysis method and system may be configured to enhance the production of C3 and C4 alkanes due to the use of certain pyrolysis catalysts and more intense pyrolysis conditions.

Methods and systems for converting a renewable fuel intermediate composition to finished transportation fuel are provided herein. In some examples, a renewable fuel intermediate composition is flowed over a first catalyst in a first reaction zone to generate a saturated, hydrodeoxygenated product. A liquid portion of the renewable fuel intermediate composition may be characterized as having more than about 70 wt % of the oxygen being within ketone groups. The saturated, hydrodeoxygenated product may be flowed over a second fixed-bed catalyst in a second reaction zone to generate a product including the finished transportation fuel.

A reactor system includes a reactor that treats a lipid feedstock using a metal oxide catalyst to produce a treated stream comprising a bio-oil. The reactor system includes a catalyst zone in which the metal oxide catalyst reacts with the lipid feedstock to produce the treated stream. The reactor system operates in a reaction mode, during which the lipid feedstock flows in a downward direction through the metal oxide catalyst to produce the treated stream. Alternately, the reactor also operates in a regeneration mode, during which coke is burned from the metal oxide catalyst thereby regenerating the metal oxide catalyst. In one aspect, a regeneration mode pressure is less than a reaction mode pressure within the reactor to fluidize the catalyst.

The invention discloses a chemical process fault diagnosis method and system, and relates to the technical field of chemical process fault diagnos.The scheme aims at the diagnosis bottleneck of catalyst inactivation type progressive faults, fine parameter offset is captured in real time through a dynamic reference model, weak signals are accumulated and amplified in combination with an attenuation weighting mechanism, and the fault diagnosis accuracy is improved. The problem that a traditional method is not sensitive to slow drifting, and consequently report omission is caused is solved, and a fault recognition window is remarkably advanced. The dynamic threshold value is updated in real time based on mobile statistics, and raw material fluctuation and sensor noise can be self-adapted; during working condition switching, the model is automatically reset and the threshold value is relaxed, so that false alarm triggered by parameter mutation is avoided, and the stability of production scheduling is guaranteed; the design that fault half-life period weight and moving window length are associated with an inactivation period is introduced, so that the model autonomously adapts to different catalyst characteristics.

The invention relates to the technical field of power transmission, in particular to a moisture-proof cable which sequentially comprises a conductive wire core, a gradient buffer layer, a dynamic sealing layer, a flexible supporting layer and a self-repairing sheath from inside to outside. A gradient buffer layer; the dynamic sealing layer is of a split type sealing structure formed by an outer ring surface sealing lip and an inner ring surface static sealing belt, the outer ring surface sealing lip is formed by embedding a polytetrafluoroethylene fiber reinforcing layer in a silicone rubber matrix, and the surface of the outer ring surface sealing lip is coated with a humidity response type graphene coating; the flexible supporting layer is formed by spirally winding a nickel-titanium alloy belt, and bionic fish scales are welded to the surface of the nickel-titanium alloy belt; the self-repairing sheath is characterized in that a hexagonal honeycomb structure is molded on the outer layer, hydroxyl-terminated polysiloxane and a platinum catalyst are contained in an A-type microcapsule, and modified epoxy resin is contained in a B-type microcapsule. The moisture-proof cable shows excellent corrosion resistance, moisture resistance and self-repairing capability in a humid environment, and can maintain good performance when subjected to external physical impact.

The invention discloses spherical aluminum oxide and a silicone rubber heat conduction composite material thereof, and belongs to the technical field of functional polymer materials. The spherical aluminum oxide is subjected to surface modification through an amphiphilic fluorosilicone heat conduction interface synergist; comprising the following raw materials in parts by weight: 100-200 parts of vinyl silicone oil, 1-6 parts of side hydrogen-containing silicone oil, 1-6 parts of end hydrogen-containing silicone oil, 0.2-2 parts of a platinum catalyst, 0.01-0.1 part of an inhibitor and 2500-6000 parts of amphiphilic fluorine-silicon heat-conducting interface synergistic spherical aluminum oxide powder. Through surface modification of spherical aluminum oxide, the prepared silicone rubber heat-conducting composite material realizes synergistic gain of heat conduction, insulation and flexibility, and can meet the requirements of multiple fields such as power battery pack heat dissipation gaskets, high-frequency circuit packaging and wearable equipment.

The invention belongs to the technical field of sewage treatment, and discloses a catalyst monitoring system based on sensing linkage and a control method.The system comprises a mixing pool, a settling pool and a backflow pool which are circularly arranged through pipelines, and further comprises a strong oxidant adding device, a powder catalyst adding device and a controller. According to the technical scheme, through combined use of the sensor, the flow meter and the valve, the problem of high loss rate of the powder type catalyst is solved, the service life of the catalytic reactor is prolonged, and the risk of environmental pollution is reduced. Meanwhile, the invention further discloses a powder type catalyst loss monitoring and controlling method based on the sensor and automatic control, in the method, hierarchical control is adopted on a controller control framework: a bottom-layer MPC is combined with a top-layer PINN prediction model to form a double-layer framework of network prediction and classical control, accurate monitoring and control are achieved, and the reliability of the controller is improved. Therefore, the purposes of reducing the loss rate of the catalyst, improving the stability of the catalytic reactor and prolonging the service life are achieved.

The disclosure relates to hydrogen mediated anionically copolymerized conjugated diene vinyl aromatic compositions, copolymers of isoprene and / or butadiene with styrene, and processes and compositions for preparing them.

The invention discloses a cobalt-loaded covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. The cobalt-loaded covalent organic framework material is prepared by taking a carbonized covalent organic framework as a matrix and cobalt nitrate hexahydrate as a cobalt source, reducing by using a sodium borohydride methanol solution, and introducing transition metal cobalt into the framework through room-temperature impregnation and thermal reduction processes. In the material, active components comprise Co0 and Co < 2 + > which are uniformly distributed on a carrier. Moreover, the metal cobalt is stably loaded in a carbon skeleton through the bonding effect of heteroatoms such as nitrogen and carbon, so that the stability, the catalytic activity and the durability of the metal cobalt are effectively improved, the dissolution risk of the metal cobalt is reduced, the hidden danger of environmental pollution is reduced, and efficient catalytic activity is shown in the aspect of catalyzing and activating peroxymonosulfate to degrade organic pollutants; and good recycling stability is achieved.

The invention provides a silicon-carbon material and a preparation method thereof, a porous carbon substrate, a negative electrode material and a battery, and relates to the technical field of battery materials. The core point provided by the invention is controllable synthesis of the porous carbon substrate in the silicon-carbon material, a phenolic monomer and an aldehyde monomer are polymerized in the presence of a catalyst and a dispersing agent, meanwhile, a doping agent and a pre-carbonized biomass carbon precursor are added into a solution, the phenolic resin formed by polymerization is of a spherical structure, and the silicon-carbon composite material is obtained. Homogeneous doping of elements is completed in the synthesis process, the added biomass carbon precursor is of a blocky structure, matching of carbon-based particles of different structures can better exert respective beneficial effects and complement each other, the battery performance is comprehensively improved, and the battery has excellent cycle performance and conductivity.

The invention relates to the technical field of flue gas treatment, in particular to a sintering flue gas denitration and dust removal integrated post-CO removal method which is specifically completed through cooperation of a sintering flue gas treatment system, and the sintering flue gas treatment system comprises a GGH heat exchanger, a desulfurization reactor, a denitration dust remover and a CO reactor which are sequentially communicated through pipelines. The CO catalyst module is a transition metal oxide CO catalyst; the cleaning device is used for cleaning ash of the CO catalyst module; the ammonia gas is sprayed into the outlet of the desulfurization reactor, so that ammonia escape is reduced, poisoning of the CO catalyst module is reduced, the catalytic efficiency of the CO catalyst module is improved, and the service life of the CO catalyst module is prolonged; the CO catalyst module is regularly subjected to air blowing and back blowing in a closed area, so that impurities such as carbon deposition on the CO catalyst module are cleaned, more active sites are exposed, the service life of the CO catalyst module is prolonged, and the investment and operation cost is reduced by adopting a transition metal oxide CO catalyst.

The invention discloses a preparation process of a modified porous carbon material catalyst. The preparation process comprises the following steps: (1) mixing and calcining a biomass precursor and a template agent to prepare graded porous carbon; (2) low-frequency plasma pretreatment and high-frequency plasma fluorination modification are adopted; (3) introducing the pulse plasma into a nitrogen doping site; (4) spraying ionic liquid and activating H2 plasma to form a B / F co-doped layer; and (5) loading alloy nanoparticles such as PtRu through pulse electrodeposition. According to the obtained catalyst, biomass derived porous carbon serves as a carrier, a fluorine / nitrogen co-doped active layer is constructed on the surface of the carrier through multi-frequency plasma synergistic modification and ionic liquid auxiliary modification, superfine precious metal nanoparticles are loaded, the hydrogen evolution overpotential of the catalyst is smaller than or equal to 28 mV under the current density of 10 mA / cm < 2 >, the activity attenuation is smaller than 5% after 1000 times of circulation, and the catalyst has a good catalytic activity. The water electrolysis hydrogen production device is suitable for a large-scale water electrolysis hydrogen production device.

The invention discloses metal element-doped nano silicon carbon as well as a preparation method and application thereof, and relates to the field of negative electrode materials. The nano silicon carbon takes porous carbon as a carbon skeleton, and the porous carbon is sequentially attached with nano silicon and coated with a carbon material layer through a chemical vapor deposition method; the porous carbon is prepared by carbonizing resin containing metal nitride after alkali activation and pore forming, and the resin containing the metal nitride is prepared by condensation polymerization of a phenolic compound, an aldehyde compound and the metal nitride in the presence of a catalyst. The porous carbon is doped with the metal nitride in the resin polycondensation process, the conductivity of the nano silicon carbon is effectively improved, the powder resistance is reduced, holes in the surface of the porous carbon provide more expansion space for deposited nano silicon, a carbon material layer formed by subsequent deposition and coating provides a protection effect, the reaction between silicon and an electrolyte can be inhibited, and the service life of the nano silicon carbon is prolonged. A stable SEI film is formed, the cycling stability of the material is improved, the volume expansion rate of a pole piece is inhibited, and the cycling life and the stability of the battery are improved.

A process for upgrading plastic derived oil includes contacting the plastic derived oil with a mixed catalyst in a first reactor, where the mixed catalyst includes a decontamination catalyst and a cracking catalyst different from the decontamination catalyst. The first reactor reduces concentrations of halogen-containing compounds in the plastic derived oil. The process includes passing the first reactor effluent to a second reactor and contacting the first reactor effluent with the cracking catalyst to produce a second effluent comprising light olefins and naphtha range hydrocarbons. The process includes separating used mixed catalyst from the first reactor to produce a used decontamination catalyst and a second used cracking catalyst, and regenerating the decontamination catalyst and cracking catalyst in separate regenerators to reduce exposure of the cracking catalyst to halogen-containing compounds produced during regeneration of the used decontamination catalyst.

The invention discloses a p-type or n-type COF film, the film thickness is 50 nm to 5 m, the aperture is 0.7 nm to 4 nm, and the film has a regular pore channel structure and light response performance. According to the invention, proper monomers are selected, and liquid-solid interface polymerization reaction is carried out, so that COF membranes grow along the tube wall, and p-type and n-type COF membranes are respectively prepared. The growth direction of the film is inconsistent with the transmission direction of the monomer and the catalyst, and the process can effectively promote the dissolution growth and self-repair of the COF film, so that the crystallinity and stacking orientation of the film are improved, and the structural characteristics of the COF film are optimized. The obtained COF film has a remarkable advantage of light-driven ion pump performance. The obtained COF membrane is used for preparing a desalting device.

The invention discloses a cyanamide axial coordination cobalt monatomic catalyst for persulfate activation and a preparation method and application thereof, and belongs to the technical field of persulfate advanced oxidation. The catalyst is prepared by the following method: simultaneously adding NH2CN and NaOH into a CoCl2 solution, stirring for reaction, and after the reaction is finished, washing, filtering and drying to obtain the catalyst CoN4 (NCN). The catalyst CoN4 (NCN) with an isolated Co site and cyanamide ([NCN] 2-) coordination structure is synthesized by adopting a one-step precipitation method. The catalyst can be used for an advanced oxidation system based on persulfate activation, and can be used for deeply treating a water body polluted by high-concentration organic matters, so that the biodegradability of the water body is improved. In addition, CoN4 (NCN) also has obvious stability and environmental adaptability, and has important application prospect and value in the field of organic pollutant degradation.

The invention discloses a composite electrode material for removing uranium through photoelectrocatalysis and a preparation method and application of the composite electrode material, and belongs to the technical field of catalytic materials and wastewater treatment.The preparation method of the composite electrode material comprises the following steps that a ZIF-8 material, copper salt and ferric salt are mixed, and a first metal composite material is prepared; reacting the first metal composite material with a KOH solution to prepare a second metal composite material; carrying out carbonization treatment on the second metal composite material, and then carrying out acid treatment by using acid to obtain a bimetallic atom catalytic material; the preparation method comprises the following steps: dispersing a bimetallic atom catalytic material and a g-C3N4 material in a mixed solution containing phytic acid and a Nafion solution to obtain catalyst ink; and coating the catalyst ink on a substrate, and carrying out illumination drying to obtain the composite electrode material. According to the composite electrode material, under the synergistic effect of the bimetallic single atomic cluster catalyst and g-C3N4, respective advantages are fully exerted, and efficient deposition removal of uranium is achieved.

A process for upgrading a plastic derived oil includes providing the plastic derived oil comprising hydrocarbons and greater than or equal to 100 ppmw halogen-containing compounds and contacting the plastic derived oil with an MMO catalyst in a first reactor at reaction conditions to remove halogens from the plastic derived oil to produce a first reactor effluent with less than 100 ppmw halogen-containing compounds. The process includes contacting the first reactor effluent with an adsorbent to produce a treated first reactor effluent, passing the treated first reactor effluent to a second reactor, and contacting the treated first reactor effluent with a cracking catalyst in the second reactor. Contacting with the cracking catalyst may cause hydrocarbons in the treated first reactor effluent to undergo catalytic cracking to produce a second reactor effluent comprising light olefins, naphtha range hydrocarbons, or combinations thereof.

The invention provides a novel acrylonitrile catalyst and a preparation method thereof. The novel acrylonitrile catalyst is prepared from the following raw materials: mixed salt, an active component, silica sol, a rare earth precursor, a carrier and a cosolvent, by introducing the cosolvent and optimizing the carrier structure, the dispersity of the rare earth precursor is improved, the production process is optimized, the doping efficiency of the rare earth precursor is remarkably improved, the activity, selectivity and stability of the novel acrylonitrile catalyst are improved, generation of by-products CO, CO2, acrolein and acrylic acid during acrylonitrile production can be reduced, and industrial efficient preparation is achieved.

The present invention pertains to the technical field of phase-change temperature-reducing materials, and in particular, relates to a phase-change temperature-reducing polyurethane composite material, and a preparation method and application thereof, comprising the following parts by mass of raw materials: 50-80 parts of polyurethane material A+polyurethane material B, 1-3 parts of flake graphite powder with a particle size of 850-1200 meshes, 0.8-1.8 parts of vermicular graphite with a particle size of 10-40 meshes, 10-30 parts of phase-change paraffin, 1-3 parts of activated carbon, 0.5-2 parts of catalyst, and 0.2-1 parts of co-catalyst. The polyurethane composite material made in the present invention is rapid in phase-change temperature reduction, high in heat absorption and dispersion, and free of problems of phase-change paraffin leakage, crystallization, and frosting on the surface thereof. At the same time, it also has softness and high elasticity, and can be widely applied to objects in contact with human bodies. A temperature difference is formed by reducing the temperature of the surface in contact with skin, which can bring a comfortable sense of coolness and a temperature-reducing effect to consumers.

The invention relates to a Bayesian optimization-based ruthenium, tin and indium doped lithium-rich manganese-based electrocatalyst screening method, electronic equipment and a storage medium, and the method comprises the following steps: generating a uniform ruthenium, tin and indium doped lithium-rich manganese-based material data set based on Dirac distribution, and generating a doped structure through element replacement; calculating hydroxyl adsorption energy and extracting descriptors to construct a data set to train a machine learning model; performing cell expansion operation on the initial electrocatalyst structure, predicting hydroxyl adsorption energy of each adsorption site, and mapping adsorption energy deviation into current density characterization component activity in combination with Boltzmann distribution; selecting an initial component based on the obtained component activity information, and constructing an agent model by utilizing Bayesian optimization; and determining a to-be-sampled component through an expectation improvement strategy, sampling and updating the agent model, and outputting an optimal doping proportion. Compared with the prior art, the method has the advantages that the ruthenium, tin and indium doped lithium-rich manganese-based electrocatalyst with excellent catalytic performance can be efficiently screened out, and the experiment cost is reduced.

The invention provides a self-repairing polyurethane film containing a disulfide bond and a DA bond and a preparation method thereof, and the preparation method comprises the following steps: (1) adding an organic solvent into a three-necked flask, then dissolving dihydric alcohol, diisocyanate, a disulfide bond monomer and a DA bond forming monomer in the organic solvent, then adding a catalyst, and mechanically stirring uniformly; (2) introducing nitrogen into the three-necked flask to evacuate air, setting a reaction temperature, and carrying out a reaction under mechanical stirring; (3) in a nitrogen environment, dropwise adding a monomer II forming a DA bond into the solution obtained after the reaction in the step (2), and after the dropwise addition of the monomer II forming the DA bond is completed, setting the reaction temperature and reacting for a period of time; and (4) pouring the solution obtained after the reaction in the step (3) into a polytetrafluoroethylene mold, and drying to obtain the self-repairing polyurethane film. The self-repairing polyurethane film prepared by the preparation method disclosed by the invention has relatively good mechanical properties, relatively good self-repairing performance under mild conditions and high self-repairing efficiency.

The invention relates to the technical field of high-entropy oxide and electrocatalyst synthesis, in particular to a double-phase hollow high-entropy oxide catalyst and a preparation method and application thereof, the double-phase hollow high-entropy oxide catalyst comprises metal elements and non-metal elements, the metal elements comprise ruthenium, nickel, cobalt, iron, manganese and chromium; the non-metallic element is oxygen; the chemical formula of the double-phase hollow high-entropy oxide catalyst is NiCoFeMnCrRuO. The invention further discloses a preparation method of the catalyst. The double-phase hollow high-entropy oxide catalyst has a multi-shell hollow structure, provides a larger specific surface area and exposes a large number of reaction active sites, so that the double-phase hollow high-entropy oxide catalyst has lower overpotential, higher reaction efficiency and good electrochemical stability; meanwhile, the preparation method of the double-phase hollow high-entropy oxide catalyst is simple in process, low in cost, high in repeatability and suitable for industrial mass production, and has a wide application prospect.

A process for upgrading plastic derived oil includes contacting a plastic derived oil stream with a decontamination catalyst in a first reactor, separating a first reactor effluent from a used decontamination catalyst, passing the first reactor effluent to a second reactor downstream of the first reactor, contacting the first reactor effluent with a cracking catalyst in the second reactor, and separating a second reactor effluent from a used cracking catalyst. The cracking catalyst is different from the decontamination catalyst. The process further includes regenerating the used decontamination catalyst in a decontamination catalyst regenerator to produce regenerated decontamination catalyst, and regenerating the used cracking catalyst in a cracking catalyst regenerator separate from the decontamination catalyst regenerator to produce regenerated cracking catalyst. Regenerating the used cracking catalyst separately reduces deactivation of the cracking catalyst by halogen-containing compounds produced during regeneration of the decontamination catalyst.

The invention belongs to the technical field of CO catalytic oxidation, and particularly discloses a method for synthesizing a CuO / CeO2 catalyst through a rapid fluid mixing method and application thereof.The method comprises the steps that a copper salt solution A and a cerium salt solution B are put into a rapid fluid turbulence mixing reactor, the flow speed is controlled, a catalyst precursor is prepared after product treatment, the catalyst precursor is put into a muffle furnace, air is introduced for calcination, and the catalyst is prepared; and high selectivity and high conversion rate in CO oxidation reaction in a hydrogen-rich environment are realized. The method provided by the invention also improves the traditional MOF synthesis method, adopts water as a solvent, and reduces the synthesis conditions. The prepared catalyst has high conversion rate and selectivity, the CO conversion rate at 90 DEG C reaches 100%, and the corresponding selectivity is 100%.

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The invention discloses preparation and application of a diatomic catalyst modified carbon felt electrode. The preparation method of the modified carbon felt electrode comprises the following steps: dissolving bismuth salt, cobalt salt and urea in water to obtain a complexing solution; immersing the carbon felt substrate subjected to acid activation into a complexing solution for soaking treatment, then taking out the carbon felt substrate, and drying to obtain a precursor-loaded carbon felt; and sequentially carrying out primary heating, cold shock and secondary heating treatment on the precursor-loaded carbon felt, and cooling to obtain the Bi-Co diatom modified carbon felt electrode. The carbon felt electrode can be applied to an all-vanadium redox flow battery. The innovation point of the invention lies in that through the synergistic effect of double atoms and the mutual cooperation of the nitrogen-doped carbon substrate, the intrinsic activity bottleneck of the traditional catalyst is broken through, the comprehensive advantages of high catalytic activity, excellent stability and low cost are achieved, and a new technical solution is provided for the high performance and large-scale application of the flow battery.

The invention relates to the field of white carbon black modifier production, and particularly discloses an activity monitoring and early warning method of a white carbon black modifier based on Internet of Things, which comprises the following steps: acquiring reaction temperature, catalyst dosage and equipment operation parameters in real time through an Internet of Things sensor, and constructing a parameter and efficiency mapping table to form a multi-dimensional process database; encoding the temperature, the stirring rate and the raw material ratio into chromosome genes by utilizing a genetic algorithm, and constructing a multi-target model by taking the bifunctional grafting rate as an optimization target and combining the equipment load rate and the energy consumption constraint; a high-adaptability parameter set is generated by adopting iterative optimization, and a three-level response mechanism of local fine tuning, population resetting and historical optimal parameter loading is realized in combination with a hierarchical early warning system. According to the method, the problems that the synthesis conditions of the bifunctional silane coupling agent cannot be accurately controlled and the continuous production data response is delayed in the traditional process are solved, and the activity dynamic optimization and green and efficient production of the white carbon black modifier are realized.

The invention discloses a photopolymer type holographic recording medium and a preparation method and application thereof.The photopolymer type holographic recording medium comprises a writing monomer, film-forming resin, a photosensitive initiation combination agent and a catalyst, the writing monomer comprises nanoparticles and a polymerizable monomer, and the film-forming resin is prepared from the nanoparticles and the polymerizable monomer; the refractive index of the polymerizable monomer is smaller than that of the nanoparticles, and the difference between the refractive index of the nanoparticles and the refractive index of the polymerizable monomer is larger than 0.5. The film-forming resin includes a polyol compound and an isocyanate-based compound. The catalyst is used for catalyzing a polyol compound and an isocyanate compound to react to form a film. The photosensitive initiation combination agent is used for sensing light and inducing polymerization of the polymerizable monomer. According to the photopolymer type holographic recording medium disclosed by the invention, after exposure, the polymerizable monomers located in the bright area and the nanoparticles extruded to the dark area have relatively large refractive index difference, so that the refractive index modulation degree of the recording grating can be improved; the film-forming resin provides effective support for the nanoparticles, and the nanoparticles are not agglomerated.