The invention in particular relates to passivation solution without chrome which is used for galvanized sheets and a method thereof. The technical scheme thereof comprises: firstly, dissolving inorganic salt corrosion inhibitor, then, adding the inorganic salt corrosion inhibitor into a stirred tank, adding dispersant, organic acid, sealant, silicone-acrylate emulsion and water while stirring, then, using inorganic acid or alkali to regulate the pH value to be 2.0-5.0, and then stirring for 1-2 hours under the condition that the temperature is 20-30 DEG C, the content of the components of each liter is: the inorganic salt corrosion inhibitor 10-55g, additive 4-10g, the organic acid 5-20g, the sealant 5-30g, the silicone-acrylate emulsion 150-300g, and the rest is the water. The method of the invention can additionally form a layer of organic resin separate layer on the basis of forming an inorganic metal compound precipitation film, additionally, since the silicon compound is added, not only the binding force between a passivation layer and zinc coating can be increased, but also the corrosion resistance, the scrubbing resistance and the wear resistance of the passivation layer can be increased, and the coating treatment after passivation can not be affected.