The present invention is a tool steel for hot working, and the oxide scale formed on the surface thereof has good adhesion and lubricity and high strength. The tool steel contains C: 0.05-0.5%, Si: 0.1-1%, Mn: 1.6-3.5%, Ni: 0.05-0.5%, Mo: 2-5%, W: 2-5%, Cu: 0.05- 0.5%, and the remainder is substantially composed of Fe. One or more of Cr, Co, REM, Ti, Nb, V, Zr, and B may also be contained. The surface of a tool made of this steel is covered with an oxide scale with a thickness of 50 to 1500 μm. A typical example of the tool is a piercing plug for seamless pipe production.